Dhofar 081: A new lunar highland meteorite

Abstract— The lunar meteorite Dhofar 081, found as a single fragment of 174 g in the Dhofar region of Oman, is a shocked feldspathic fragmental highland breccia dominated by anorthosite‐rich lithic and mineral clasts embedded into a fine‐grained mostly shock melted clastic matrix. Major mineral phases in the bulk rock are Ca‐rich plagioclase (An_96.5–99.5), pyroxene (FS_21.9–46.2Wo_3.0–41.4), and olivine (Fa_29.3–47.8); accessory phases include Fe‐Ni metal, ilmenite, and Ti‐Cr‐rich spinel. Dhofar 081 contains subordinate crystalline fragments of large anorthosites, intersertal impact‐melt rocks, microporphyritic impact‐melt breccias, dark fine‐grained impact‐melt breccias, large cataclastic feldspars, and irregularly shaped brown glass clasts. Mafic components are rare and no genuine regolith components were found in the sections studied. Minerals in Dhofar 081 show homogeneously distributed shock features: intergranular recrystallization, strong fracturing and mosaicism in feldspar as well as a high density of mostly irregular fractures in pyroxene and olivine. Localized impact melting caused by one or several impacts led to a strong lithification. Based on these effects an equilibration shock pressure of about 15–20 GPa is estimated for the strongest shock event in Dhofar 081. Devitrification of the “glassy” material in the rock indicates thermal annealing after shock melting suggesting that the 15–20 GPa shock event predated the ejection event. According to the concentrations of implanted solar noble gases Dhofar 081 represents a polymict clastic breccia deposit with possibly a minor regolith component. A similar noble gas record of Dhofar 081 and MacAlpine Hills 88104/05 suggests the possibility of a source crater pairing of both meteorites. As indicated by noble gas measurements pairing of Dhofar 081 with the other lunar meteorites found in Oman, Dhofar 025 and Dhofar 026, is unlikely.     

A New Martian Meteorite: the Dhofar 019 Shergottite with an Exposure Age of 20 Million Years

The isotopic composition of the noble gases of the new Martian meteorite, the Dhofar 019 shergottite, found in the desert in the territory of the Sultanate of Oman on January 24, 2001, was investigated. Stepwise thermal annealing with isotopic analysis of each of the noble-gas temperature fractions was employed to determine the component composition. The concentration of the trapped noble gases in the new Martian meteorite Dhofar 019 is relatively high, although it lies within the range of concentrations in known SNC meteorites. A characteristic feature of all the trapped noble gases is the presence of two main components: a low-temperature, probably terrestrial atmospheric, component, trapped during the weathering of the meteorite on Earth, and a high-temperature trapped Martian component. Owing to the different ratios of the quantities of the two components, the trapped neon, argon, krypton, and xenon differ markedly in the kinetics of their release. The isotopic composition of the noble gases varies accordingly. The trapped xenon was found to contain two Martian components. One of them, with typical ratios of ¹²⁹Xe/¹³²Xe and ¹³²Xe/⁸⁴Kr, is representative of xenon and krypton of the Martian atmosphere; the other, of gases of the Martian mantle. Variations of the isotopic compositions of helium, neon, and argon (and also, to a lesser extent, of krypton and xenon) during the thermal annealing of the Dhofar 019 meteorite clearly point to a large proportion of cosmogenic as well as trapped components. The concentration of cosmogenic neon and argon in the meteorite is unusually high. This corresponds to a maximum exposure age among other SNC meteorites: 20 million years. Estimates of the potassium–argon age (gas-retention age) yielded the figure of 560 million years, which is within the range of values obtained for SNC meteorites by other authors, who used the rubidium–strontium and the potassium–argon technique.     

KREEPy lunar meteorite Dhofar 287A: A new lunar mare basalt

Abstract— Dhofar 287 (Dho 287) is a new lunar meteorite, found in Oman on January 14, 2001. The main portion of this meteorite (Dho 287A) consists of a mare basalt, while a smaller portion of breccia (Dho 287B) is attached on the side. Dho 287A is only the fourth crystalline mare basalt meteorite found on Earth to date and is the subject of the present study. The basalt consists mainly of phenocrysts of olivine and pyroxene set in a finer‐grained matrix, which is composed of elongated pyroxene and plagioclase crystals radiating from a common nucleii. The majority of olivine and pyroxene grains are zoned, from core to rim, in terms of Fe and Mg. Accessory minerals include ilmenite, chromite, ulvöspinel, troilite, and FeNi metal. Chromite is invariably mantled by ulvöspinel. This rock is unusually rich in late‐stage mesostasis, composed largely of fayalite, Si‐K‐Ba‐rich glass, fluorapatite, and whitlockite. In texture and mineralogy, Dho 287A is a low‐Ti mare basalt, with similarities to Apollo 12 (A‐12) and Apollo 15 (A‐15) basalts. However, all plagioclase is now present as maskelynite, and its composition is atypical for known low‐Ti mare basalts. The Fe to Mn ratios of olivine and pyroxene, the presence of FeNi metal, and the bulk‐rock oxygen isotopic ratios, along with several other petrological features, are evidence for the lunar origin for this meteorite. Whole‐rock composition further confirms the similarity of Dho 287A with A‐12 and A‐15 samples but requires possible KREEP assimilation to account for its rare‐earth‐element (REE) contents. Cooling‐rate estimates, based on Fo zonation in olivine, yield values of 0.2–0.8°C/hr for the lava, typical for the center of a 10–20 m thick flow. The recalculated major‐element concentrations, after removing 10–15% modal olivine, are comparable to typical A‐15 mare basalts. Crystallization modeling of the recalculated Dho 287A bulk‐composition yields a reasonable fit between predicted and observed mineral abundances and compositions.     

A new martian meteorite from the Sahara: The shergottite Dar al Gani 489

Abstract— Dar al Gani 489 (DaG 489) is a meteorite fragment of 2146 g found in the Libyan Sahara by a meteorite finder during one of his search campaigns in 1997–98. It is a porphyritic rock with millimetersized olivine crystals (Fo_79–59) set in a fine‐grained groundmass (average grain size 0.1 mm) consisting of pigeonite (En_75–57 Wo_5–15) crystals and interstitial feldspathic glass (An_67–56 Or_0–1). Minor phases include enstatite (En_82–71 Wo_2–4), augite (En_48–52 Wo_29–32), chromite, Ti‐chromite, ilmenite, pyrrhotite, merrillite, and secondary calcite and iron oxides. On the basis of mineralogical, petrographic, bulk chemical, O‐isotopic, and noble gas data, DaG 489 can be classified as a highly shocked martian meteorite (e.g., Fe/Mn_(bulk) = 42.1, Ni/Mg_(bulk) = 0.002; δ¹⁷O = 2.89, δ¹⁸O = 4.98, and Δ¹⁷O = 0.305), belonging to the basaltic shergottite subgroup. The texture and modal composition of DaG 489 are indeed those of basalts; nonetheless, the bulk chemistry, the abundance of large olivine and chromite crystals, and enstatitic pyroxene suggest some relationship with lherzolitic shergottites. As such, DaG 489 is similar to the hybrid shergottite Elephant Moraine (EET) A79001 lithology A; however, there are some relevant differences including a higher olivine content (20 vol%), the lack of orthopyroxene megacrysts, a higher molar Mg/(Mg + Fe)_(molar) = 0.68, and a lower rare earth element content in the bulk sample. Therefore, DaG 489 has the potential of providing us with a further petrogenetic link between the basaltic and lherzolitic shergottites. Noble gases data show that DaG 489 has an ejection age of ～1.3 Ma. This young age lends support to the requirement of several ejection events to produce the current population of shergottites, nakhlites, and chassignites (SNC) meteorites. In terms of texture, mineral and bulk compositions, shock level, and weathering features, DaG 489 is essentially identical to DaG 476, another basaltic shergottite independently found ～25 km due northnortheast of DaG 489. Because DaG 489 also has the same exposure history as DaG 476, it is very likely that both meteorites are fragments of the same fall. In addition to the existing hypotheses on the petrogenesis of the similar EETA79001 lithology A and the identical DaG 476, we propose that DaG 489 could have formed through high‐degree partial melting of a lherzolite‐like material.     

A new Martian meteorite from Oman: Mineralogy,petrology, and shock metamorphism of olivine‐phyric basaltic shergottite Sayh al Uhaymir 150

Abstract— The Sayh al Uhaymir (SaU) 150 meteorite was found on a gravel plateau, 43.3 km south of Ghaba, Oman, on October 8, 2002. Oxygen isotope (δ¹⁷O 2.78; δ¹⁸O 4.74), CRE age (?1.3 Ma), and noble gas studies confirm its Martian origin. SaU 150 is classified as an olivine‐phyric basalt, having a porphyritic texture with olivine macrocrysts set in a finer‐grained matrix of pigeonite and interstitial maskelynite, with minor augite, spinel, ilmenite, merrillite, pyrrhotite, pentlandite, and secondary (terrestrial) calcite and iron oxides. The bulk rock composition, in particular mg (68) [molar Mg/(Mg + Fe) x 100], Fe/Mn (37.9), and Na/Al (0.22), are characteristic of Martian meteorites. Based on mineral compositions, cooling rates determined from crystal morphology, and crystal size distribution, it is deduced that the parent magma formed in a steady‐state growth regime (magma chamber) that cooled at <°C/hr. Subsequent eruption as a thick lava flow or hypabyssal intrusion entrained a small fraction of xenocrystic olivine and gave rise to a magmatic foliation, with slow cooling allowing for near homogenization of igneous minerals. SaU 150 experienced an equilibration shock pressure of 33–45 GPa in a single impact event. Post‐shock heat gave rise to localized melting (?11 vol%). Larger volume melts remained fluid after pressure release and crystallized dendritic olivine and pyroxene with fractal dimensions of 1.80–1.89 and 1.89–1.95, respectively, at ‐ΔT >70–365 °C. SaU 150 is essentially identical to SaU 005/094, all representing samples of the same fall that are similar to, but distinct from, the DaG shergottites.     

Noble gases in the Martian meteorite Northwest Africa 2737: A new chassignite signature

Abstract— We report noble gas data for the second chassignite, Northwest Africa (NWA) 2737, which was recently found in the Moroccan desert. The cosmic ray exposure (CRE) age based on cosmogenic ³He, ²¹Ne, and ³⁸Ar around 10–11 Ma is comparable to the CRE ages of Chassigny and the nakhlites and indicates ejection of meteorites belonging to these two families during a discrete event, or a suite of discrete events having occurred in a restricted interval of time. In contrast, U‐Th/He and K/Ar ages <0.5 Ga are in the range of radiometric ages of shergottites, despite a Sm‐Nd signature comparable to that of Chassigny and the nakhlites (Misawa et al. 2005). Overall, the noble gas signature of NWA 2737 resembles that of shergottites rather than that of Chassigny and the nakhlites: NWA 2737 does not contain, in detectable amount, the solar‐like xenon found in Chassigny and thought to characterize the Martian mantle nor apparently fission xenon from ²⁴⁴Pu, which is abundant in Chassigny and some of the nakhlites. In contrast, NWA 2737 contains Martian atmospheric noble gases trapped in amounts comparable to those found in shergottite impact glasses. The loss of Martian mantle noble gases, together with the trapping of Martian atmospheric gases, could have occurred during assimilation of Martian surface components, or more likely during shock metamorphism, which is recorded in the petrology of this meteorite.     

Thermal and irradiation history of lunar meteorite Dhofar 280

Dhofar 280 recorded a complex history on the Moon revealed by high‐resolution ⁴⁰Ar‐³⁹Ar dating. Thermal resetting occurred less than 1 Ga ago, and the rock was exposed to several impact events before and afterwards. The cosmic ray exposure (CRE) age spectrum indicates a 400 ± 40 Ma CRE on the lunar surface. A unique feature of this lunar sample is a partial loss of cosmogenic ³⁸Ar, resulting in a (low‐temperature) CRE age plateau of about 1 Ma. This was likely caused by the same recent impact event that reset the (low‐temperature) ⁴⁰Ar‐³⁹Ar age spectrum and preceded the short transit phase to Earth of ≤1 Ma. Dhofar 280 may be derived from KREEP‐rich lunar frontside terrains, possibly associated with the Copernicus crater or with a recent impact event on the deposits of the South Pole–Aitken basin. Although Dhofar 280 is paired with Dhofar 081, their irradiation and thermal histories on the Moon were different. An important trapped Ar component in Dhofar 280 is “orphan” Ar with a low ⁴⁰Ar/³⁶Ar ratio. It is apparently a mixture of two components, one endmember with ⁴⁰Ar/³⁶Ar = 17.5 ± 0.2 and a second less well‐constrained endmember with ⁴⁰Ar/³⁶Ar ≤10. The presence of two endmembers of trapped Ar, their compositions, and the breccia ages seem to be incompatible with a previously suggested correlation between age or antiquity and the (⁴⁰Ar/³⁶Ar)_trapped ratio (Eugster et al. 2001; Joy et al. 2011a). Alternatively, “orphan” Ar of this impact melt breccia may have an impact origin.     

Shergottites Dhofar 019, SaU 005, Shergotty,and Zagami: 40Ar‐39Ar chronology and trapped Martian atmospheric and interior argon

Abstract— We report a high‐resolution ⁴⁰Ar‐³⁹Ar study of mineral separates and whole‐rock samples of olivine‐phyric (Dhofar 019, Sayh al Uhaymir [SaU] 005) and basaltic (Shergotty, Zagami) shergottites. Excess argon is present in all samples. The highest (⁴⁰Ar/³⁶Ar)_trapped ratios are found for argon in pyroxene melt inclusions (?1500), maskelynite (?1200), impact glass (?1800) of Shergotty and impact glass of SaU 005 (?1200). A high (⁴⁰Ar/³⁶Ar)_trapped component‐usually uniquely ascribed to Martian atmosphere‐can also originate from the Martian interior, indicating a heterogeneous Martian mantle composition. As additional explanation of variable high (⁴⁰Ar/³⁶Ar)_trapped ratios in shocked shergottites, we suggest argon implantation from a “transient atmosphere” during impact induced degassing. The best ⁴⁰Ar‐³⁹Ar age estimate for Dhofar 019 is 642 ± 72 Ma (maskelynite). SaU 005 samples are between 700–900 Ma old. Relatively high ⁴⁰Ar‐³⁹Ar ages of melt inclusions within Dhofar 019 (1086 ± 252 Ma) and SaU 005 olivine (885 ± 66 Ma) could date entrapment of a magmatic liquid during early olivine crystallization, or reflect unrecognized excess ⁴⁰Ar components. The youngest ⁴⁰Ar‐³⁹Ar age of Shergotty separates (maskelynite) is ?370 Ma, that of Zagami is ?200 Ma. The ⁴⁰Ar‐³⁹Ar chronology of Dhofar 019 and SaU 005 indicate >1 Ga ages. Apparent ages uncorrected for trapped (e.g., Martian atmosphere, mantle) argon components approach 4.5 Ga, but are not caused by inherited ⁴⁰Ar, because excess ⁴⁰Ar is supported by ³⁶Ar_trapped. Young ages obtained by ⁴⁰Ar‐³⁹Ar and other chronometers argue for primary rather than secondary events. The cosmic ray exposure ages calculated from cosmogenic argon are 15.7 ± 0.7 Ma (Dhofar 019), 1.0–1.6 Ma (SaU 005), 2.1–2.5 Ma (Shergotty) and 2.2–3.0 Ma (Zagami).     

Various aspects of the petrogenesis of the Martian shergottite meteorites

Several controversies are associated with the age and origin of the shergottite meteorites, a suite of basaltic samples from Mars. Here, it will be argued that (1) the shergottites have a young igneous age, ≤600 Myr, (2) their parent magmas were relatively dry, (3) the range of initial isotopic compositions in shergottites is most likely due to assimilation of crustal materials by mantle‐derived basaltic magmas, and (4) the intercumulus liquid compositions of shergottites such as Shergotty and Zagami are relatively well constrained.     

Petrology of Martian meteorite Northwest Africa 998

Abstract— Nakhlite Northwest Africa (NWA) 998 is an augite-rich cumulate igneous rock with mineral compositions and oxygen isotopic composition consistent with an origin on Mars. This 456-gram, partially fusion-crusted meteorite consists of (by volume) ∼75% augite (core composition Wo₃₉En₃₉Fs₂₂), ∼9% olivine (Fo₃₅), ∼7% plagioclase (Ab₆₁An₃₅) as anhedra among augite and olivine, ∼3.5% low-calcium pyroxenes (pigeonite and orthopyroxene) replacing or forming overgrowths on olivine and augite, ∼1% titanomagnetite, and other phases including potassium feldspar, apatite, pyrrhotite, chalcopyrite, ilmenite, and fine-grained mesostasis material. Minor secondary alteration materials include “iddingsite” associated with olivine (probably Martian), calcite crack fillings, and iron oxide/hydroxide staining (both probably terrestrial). Shock effects are limited to minor cataclasis and twinning in augite. In comparison to other nakhlites, NWA 998 contains more low-calcium pyroxenes and its plagioclase crystals are blockier. The large size of the intercumulus feldspars and the chemical homogeneity of the olivine imply relatively slow cooling and chemical equilibration in the late- and post-igneous history of this specimen, and mineral thermometers give subsolidus temperatures near 730 °C. Oxidation state was near that of the QFM buffer, from about QFM-2 in earliest crystallization to near QFM in late crystallization, and to about QFM + 1.5 in some magmatic inclusions. The replacement or overgrowth of olivine by pigeonite and orthopyroxene (with or without titanomagnetite), and the marginal replacement of augite by pigeonite, are interpreted to result from late-stage reactions with residual melts (consistent with experimental phase equilibrium relationships). Apatite is concentrated in planar zones separating apatite-free domains, which suggests that residual magma (rich in P and REE) was concentrated in planar (fracture?) zones and possibly migrated through them. Loss of late magma through these zones is consistent with the low bulk REE content of NWA 998 compared with the calculated REE content of its parent magma.     

Nature of the Martian uplands: Effect on Martian meteorite age distribution and secondary cratering

Abstract— Martian meteorites (MMs) have been launched from an estimated 5–9 sites on Mars within the last 20 Myr. Some 80–89% of these launch sites sampled igneous rock formations from only the last 29% of Martian time. We hypothesize that this imbalance arises not merely from poor statistics, but because the launch processes are dominated by two main phenomena: first, much of the older Martian surface is inefficient in launching rocks during impacts, and second, the volumetrically enormous reservoir of original cumulate crust enhances launch probability for 4.5 Gyr old rocks. There are four lines of evidence for the first point, not all of equal strength. First, impact theory implies that MM launch is favored by surface exposures of near‐surface coherent rock (≤10² m deep), whereas Noachian surfaces generally should have ≥10² m of loose or weakly cemented regolith with high ice content, reducing efficiency of rock launch. Second, similarly, both Mars Exploration Rovers found sedimentary strata, 1–2 orders of magnitude weaker than Martian igneous rocks, favoring low launch efficiency among some fluvial‐derived Hesperian and Noachian rocks. Even if launched, such rocks may be unrecognized as meteorites on Earth. Third, statistics of MM formation age versus cosmic‐ray exposure (CRE) age weakly suggest that older surfaces may need larger, deeper craters to launch rocks. Fourth, in direct confirmation, one of us (N. G. B.) has found that older surfaces need larger craters to produce secondary impact crater fields (cf. Barlow and Block 2004). In a survey of 200 craters, the smallest Noachian, Hesperian, and Amazonian craters with prominent fields of secondaries have diameters of ?45 km, ?19 km, and ?10 km, respectively. Because 40% of Mars is Noachian, and 74% is either Noachian or Hesperian, the subsurface geologic characteristics of the older areas probably affect statistics of recognized MMs and production rates of secondary crater populations, and the MM and secondary crater statistics may give us clues to those properties.     

Northwest Africa 4797: A strongly shocked ultramafic poikilitic shergottite related to compositionally intermediate Martian meteorites

Abstract– Northwest Africa (NWA) 4797 is an ultramafic Martian meteorite composed of olivine (40.3 vol%), pigeonite (22.2%), augite (11.9%), plagioclase (9.1%), vesicles (1.6%), and a shock vein (10.3%). Minor phases include chromite (3.4%), merrillite (0.8%), and magmatic inclusions (0.4%). Olivine and pyroxene compositions range from Fo_66–72,En_58–74Fs_19–28Wo_6–15, and En_46–60Fs_14–22Wo_34–40, respectively. The rock is texturally similar to “lherzolitic” shergottites. The oxygen fugacity was QFM?2.9 near the liquidus, increasing to QFM?1.7 as crystallization proceeded. Shock effects in olivine and pyroxene include strong mosaicism, grain boundary melting, local recrystallization, and pervasive fracturing. Shock heating has completely melted and vesiculated igneous plagioclase, which upon cooling has quench‐crystallized plagioclase microlites in glass. A mm‐size shock melt vein transects the rock, containing phosphoran olivine (Fo_69–79), pyroxene (En_44–51Fs_14–18Wo_30–42), and chromite in a groundmass of alkali‐rich glass containing iron sulfide spheres. Trace element analysis reveals that (1) REE in plagioclase and the shock melt vein mimics the whole rock pattern; and (2) the reconstructed NWA 4797 whole rock is slightly enriched in LREE relative to other intermediate ultramafic shergottites, attributable to local mobilization of melt by shock. The shock melt vein represents bulk melting of NWA 4797 injected during pressure release. Calculated oxygen fugacity for NWA 4797 indicates that oxygen fugacity is decoupled from incompatible element concentrations. This is attributed to subsolidus re‐equilibration. We propose an alternative nomenclature for “lherzolitic” shergottites that removes genetic connotations. NWA 4797 is classified as an ultramafic poikilitic shergottite with intermediate trace element characteristics.     

Lunar meteorite,Dhofar 1428: Feldspathic breccia containing KREEP and meteoritic components

We have studied the feldspathic lunar meteorite Dhofar 1428 chemically and petrologically to better understand the evolution of the lunar surface. Dhofar 1428 is a feldspathic regolith breccia derived from the lunar highland. Bulk chemical and mineral compositions of Dhofar 1428 are similar to those of other feldspathic lunar meteorites. We found a few clasts of evolved lithologies, such as K‐rich plagioclases and quartz monzogabbro. Dhofar 1428 contains approximately 1 wt% of chondritic materials like CM chondrite on the basis of abundances of platinum group elements (Ru, Rh, Pd, Os, Ir, and Pt).     

Caleta el Cobre 022 Martian meteorite: Increasing nakhlite diversity

Caleta el Cobre (CeC) 022 is a Martian meteorite of the nakhlite group, showing an unbrecciated cumulate texture, composed mainly of clinopyroxene and olivine. Augite shows irregular core zoning, euhedral rims, and thin overgrowths enriched in Fe relative to the core. Low‐Ca pyroxene is found adjacent to olivine. Phenocrysts of Fe‐Ti oxides are titanomagnetite with exsolutions of ilmenite/ulvöspinel. Intercumulus material consists of both coarse plagioclase and fine‐grained mesostasis, comprising K‐feldspars, pyroxene, apatite, ilmenite, Fe‐Ti oxides, and silica. CeC 022 shows a high proportion of Martian aqueous alteration products (iddingsite) in olivine (45.1 vol% of olivine) and mesostasis. This meteorite is the youngest nakhlite with a distinct Sm/Nd crystallization age of 1.215 ± 0.067 Ga. Its ejection age of 11.8 ± 1.8 Ma is similar to other nakhlites. CeC 022 reveals contrasted cooling rates with similarities with faster cooled nakhlites, such as Northwest Africa (NWA) 817, NWA 5790, or Miller Range 03346 nakhlites: augite irregular cores, Fe‐rich overgrowths, fine‐grained K‐feldspars, quenched oxides, and high rare earth element content. CeC 022 also shares similarities with slower cooled nakhlites, including Nakhla and NWA 10153: pyroxene modal abundance, pyroxenes crystal size distribution, average pyroxene size, phenocryst mineral compositions, unzoned olivine, and abundant coarse plagioclase. Moreover, CeC 022 is the most magnetic nakhlite and represents an analog source lithology for the strong magnetization of the Martian crust. With its particular features, CeC 022 must originate from a previously unsampled sill or flow in the same volcanic system as the other nakhlites, increasing Martian sample diversity and our knowledge of nakhlites.     

Terrestrial and Martian weathering signatures of xenon components in shergottite mineral separates

Abstract– Xenon‐isotopic ratios, step‐heating release patterns, and gas concentrations of mineral separates from Martian shergottites Roberts Massif (RBT) 04262, Dar al Gani (DaG) 489, Shergotty, and Elephant Moraine (EET) 79001 lithology B are reported. Concentrations of Martian atmospheric xenon are similar in mineral separates from all meteorites, but more weathered samples contain more terrestrial atmospheric xenon. The distributions of xenon from the Martian and terrestrial atmospheres among minerals in any one sample are similar, suggesting similarities in the processes by which they were acquired. However, in opaque and maskelynite fractions, Martian atmospheric xenon is released at higher temperatures than terrestrial atmospheric xenon. It is suggested that both Martian and terrestrial atmospheric xenon were initially introduced by weathering (low temperature alteration processes). However, the Martian component was redistributed by shock, accounting for its current residence in more retentive sites. The presence or absence of detectable ¹²⁹Xe from the Martian atmosphere in mafic minerals may correspond to the extent of crustal contamination of the rock’s parent melt. Variable contents of excess ¹²⁹Xe contrast with previously reported consistent concentrations of excess ⁴⁰Ar, suggesting distinct sources contributed these gases to the parent magma.     

Martian basalt (shergottite) Queen Alexandra Range 94201 and lunar basalt 15555: A tale of two pyroxenes

Abstract— We present here ion microprobe analyses of rare earth and other selected trace and minor elements in pyroxenes of shergottite Queen Alexandra Range 94201 and lunar basalt 15555. Pyroxene zonation patterns record the crystallization histories of these two basaltic samples from Mars and the Moon, respectively, and allow a comparison of mafic melt evolution on these two planetary bodies. Elemental abundances and trends in pyroxenes of these two rocks indicate that their minerals formed by continuous, closed system fractional crystallization of their respective parent melts. This further supports the idea that QUE 94201 closely represents the composition of a true Martian basaltic melt (McSween et al., 1996). The main differences in pyroxene elemental zonation patterns in these two objects are attributed to earlier crystallization of whitlockite in QUE 94201 (i.e., before the Fe-rich pyroxenes) than in 15555 (after the Fe-rich pyroxenes). The size of Eu anomalies in pyroxenes of QUE 94201 is intermediate between that in pyroxenes of 15555 and the other shergottites and may imply that fO₂ conditions during crystallization of this Martian basalt were significantly more reducing than for other shergottites, although not quite as reducing as for lunar basalts. Cerium anomalies appear to be less prevalent in pyroxenes of QUE 94201 than other Antarctic shergottites and could be indicative of lesser degree of weathering in the Antarctic.     

Martian meteorite Tissint records unique petrogenesis among the depleted shergottites

Tissint, a new unaltered piece of Martian volcanic materials, is the most silica‐poor and Mg‐Fe‐rich igneous rock among the “depleted” olivine‐phyric shergottites. Fe‐Mg zoning of olivine suggests equilibrium growth (<0.1 °C h^?1) in the range of Fo_80–56 and olivine overgrowth (Fo_55–18) through a process of rapid disequilibrium (~1.0–5.0 °C h^?1). The spatially extended (up to 600 μm) flat‐top Fe‐Mg profiles of olivine indicates that the early‐stage cooling rate of Tissint was slower than the other shergottites. The chemically metastable outer rim of olivine (55) consists of oscillatory phosphorus zoning at the impact‐induced melt domains and grew rapidly compared to the early to intermediate‐stage crystallization of the Tissint bulk. High‐Ca pyroxene to low‐Ca pyroxene and high‐Ca pyroxene to plagioclase ratios of Tissint are more comparable to the enriched basaltic and enriched olivine‐phyric shergottites. Dominance of augite over plagioclase induced augite to control the Ca‐buffer in the residual melt suppressing the plagioclase crystallization, which also caused a profound effect on the Al‐content in the late‐crystallized pyroxenes. Mineral chemical stability, phase‐assemblage saturation, and pressure–temperature path of evolution indicates that the parent magma entered the solidus and left the liquidus field at a depth of 40–80 km in the upper mantle. Petrogenesis of Tissint appears to be similar to LAR 06319, an enriched olivine‐phyric shergottite, during the early to intermediate stage of crystallization. A severe shock‐induced deformation resulted in remelting (10–15 vol%), recrystallization (most Fe‐rich phases), and exhumation of Tissint in a time scale of 1–8 yr. Tissint possesses some distinct characteristics, e.g., impact‐induced melting and deformation, forming phosphorus‐rich recrystallization rims of olivine, and shock‐induced melt domains without relative enrichment of LREEs compared to the bulk; and shared characteristics, e.g., modal composition and magmatic evolution with the enriched basaltic shergottites, evidently reflecting unique mantle source in comparison to the clan of the depleted members.     

A new type of isotopic anomaly in shergottite sulfides

The isotopic composition and abundance of sulfur in extraterrestrial materials are of interest for constraining models of both planetary and solar system evolution. A previous study that included phase‐specific extraction of sulfur from 27 shergottites found the sulfur isotopic composition of the Martian mantle to be similar to that of terrestrial mid‐ocean ridge basalts, the Moon, and nonmagmatic iron meteorites. However, the presence of positive Δ³³S anomalies in igneous sulfides from several shergottites, indicating incorporation of atmospherically processed sulfur into the subsurface, complicated this interpretation. The current study expands upon the previous work through analyses of 20 additional shergottites, enabling tighter constraints on the isotopic composition of juvenile Martian sulfur. The updated composition (δ³⁴S = ?0.24 ± 0.05‰, Δ³³S = 0.0015 ± 0.0016‰, and Δ³⁶S = 0.039 ± 0.054‰, 2 s.e.m.), representing the weighted mean for all shergottites within the combined population of 47 without significant Δ³³S anomalies, strengthens our earlier result. The presence of sulfur isotopic anomalies in igneous sulfides of some meteorites suggests that their parent magmas may have assimilated crustal material. We observed small negative Δ³³S anomalies in sulfides from two meteorites, NWA 7635 and NWA 11300. Although negative Δ³³S anomalies have been observed in nakhlites and ALH 84001, previous anomalies in shergottites have all shown positive values of Δ³³S. Because NWA 7635 has formation age of 2.4 Ga and is much more ancient than shergottites analyzed previously, this finding expands our perspective on the continuity of Martian atmospheric sulfur photochemistry over geologic time.     

Petrography,mineralogy, and trace element geochemistry of lunar meteorite Dhofar 1180

Abstract— Here we report the petrography, mineralogy, and trace element geochemistry of the Dhofar 1180 lunar meteorite. Dhofar 1180 is predominantly composed of fine‐grained matrix with abundant mineral fragments and a few lithic and glassy clasts. Lithic clasts show a variety of textures including cataclastic, gabbroic, granulitic, ophitic/subophitic, and microporphyritic. Both feldspathic and mafic lithic clasts are present. Most feldspathic lithic clasts have a strong affinity to ferroan anorthositic suite rocks and one to magnesian suite rocks. Mafic lithic clasts are moderately to extremely Fe‐rich. The Ti/[Ti+Cr]‐Fe/[Fe+Mg] compositional trend of pyroxenes in mafic lithic clasts is consistent with that of low‐Ti mare basalts. Glasses display a wide chemical variation from mafic to feldspathic. Some glasses are very similar to those from Apollo 16 soils. KREEP components are essentially absent in Dhofar 1180. One glassy clast is rich in K, REE and P, but its Mg/[Mg+Fe] is very low (0.25). It is probably a last‐stage differentiation product of mare basalt. Molar Fe/Mn ratios of both olivine and pyroxene are essentially consistent with a lunar origin. Dhofar 1180 has a LREE‐enriched (La 18 × CI, Sm 14 × CI) pattern with a small positive Eu anomaly (Eu 15 × CI). Th concentration is 0.7 ppm in Dhofar 1180. Petrography, mineralogy, and trace element geochemistry of Dhofar 1180 are different from those of other lunar meteorites, indicating that Dhofar 1180 represents a unique mingled lunar breccia derived from an area on the lunar nearside but far away from the center of the Imbrium Basin.