Synthesis Crystal Structureof Quaternary Mixed AnionComplex of Lanthanides[Ln(CCl_3COO)_2 (CH_3COO)(phen) (H_2O)]_2

Synthesis Crystal Structureof Quaternary Mixed AnionComplex of Lanthanides[Ln(CCl_3COO)_2 (CH_3COO)(phen) (H_2O)]_2     

Crystal Structure and Spectra of the Complex Eu(p-ClC_6H_4COO)_3C_(12)H_8N_2

ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅａｎｄＳｐｅｃｔｒａｏｆｔｈｅＣｏｍｐｌｅｘＥｕ（ｐ－ＣｌＣ_６Ｈ_４ＣＯＯ）_３Ｃ_（１２）Ｈ_８Ｎ_２ＪｉｎＬｉｎｐｅｉ（金林培）（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｓｔｒｙ，ＢｅｉｊｉｎｇＮｏｒｍａｌＵｎｉｖｅｒｓｉｔ...     

Binuclear Lanthanide Complexes Containing SodiumSyntheses and Crystal Structure of (C_5Me_5)_2Nd(μ-Cl)_2Na(DME)_2 and (C_5Me_5)_2Nd(μ-OCH_3)_2Na(DME)_2

The reaction of NdCl_3 with NaC_5Me_5 generates a novel complex (C_5Me_5)_2Nd(μ-Cl)_2Na(DME)_2 (1).Then (1) reacts with 1 mol ratio Na and a little methyl-naphthalene generating another novel complex(C_5Me_5)_2Nd(μ-OCH_3)_2Na(DME)_2 (2).Complex (1) belongs to orthorhombic crystal system,space groupPbn2_1 with a=1.2635(3) nm,b=1.6127(5) nm,c=1.6543(4J nm,V=3.371(2) nm~3,D_c=1.36 gcm~(-3) andZ=4.The central metal Nd is coordinated by two C_5Me5 ring centroids and two μ-chlorine atoms forming adistorted tetrahedron.The crystal of complex (2) is monoclinic,space group C2/n with a=1.7482(5) nm,b=1.3260(4) nm,c=1.6406(7) nm,β=109.39(3)°,V=3.5874(1) nm~3,D_c=1.26 gcm~(-3) and Z=4,Twofive-membered ring centroids and two p-oxygens of OCH_3 form a distorted tetrahedron around the centralneodymium ion.     

Synthesis and Crystal Structure of [Yb(NTO)_3(H_2O)_4]·6H_2O

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ［Ｙｂ（ＮＴＯ）３（Ｈ２Ｏ）４］·６Ｈ２ＯＳｏｎｇＪｉｒｏｎｇ（宋纪蓉），ＤｏｎｇＷｕ（董武）（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｃａｌＥｎｇｉｎｅｒｉｎｇ，ＮｏｒｔｈｗｅｓｔＵｎｉｖｅｒ...     

Synthesis and Structural Determination of Eight Coordinate NH_4[Yb(Ⅲ)(Cydta)(H_2O)_2]·5H_2O

ｅｃａｕｓｅｓｏｍｅｒａｒｅｅａｒｔｈｍｅｔａｌｃｏｍｐｏｕｎｄｓｈａｖｅｔｈｅｐｒｏｍｏｔｉｖｅａｃｔｉｏｎｔｏｔｈｅｇｒｏｗｔｈｏｆａｎｉ ｍａｌｓａｎｄｐｌａｎｔｓ[1 ] ,ａｎｄｔｈｅｆｕｎｃｔｉｏｎｏｆａｎｔｉｉｎ ｆｌａｍｍａｔｉｏｎ ,ａｎｔｉｂａｃｔｅｒｉｕｍ ,ａｎｔｉｃｏａｇｕｌａｎｔｉｏｎａｎｄａｎｔｉｃａｎｅｒ[2 ] ,ｔｈｅｉｎｖｅｓｔｉｇａｔｉｏｎｏｎｔｈｅｓｙｎ ｔｈｅｓｅｓａｎｄｓｔｒｕｃｔｕｒｅｓｏｆｔｈｅｅｖｅｒｙｋｉｎｄｓｏｆｒａｒｅｅａｒｔｈｍｅｔａｌｃｏｍｐｏｕｎｄｓ…     

Synthesis,Characterization and Crystal Structure of Ln(CCl_3COO)_3·(phen)_2·2H_2O

Coordination compounds of lanthanide trichloroacetates with 1,10-phenanthroline weresynthesized and characterized as Ln(CCl_3COO)_3·(phen)_2·2H_2O(phen=1,10-phenanthroline,Ln=Tb～Lu)by chemical analysis,IR spectra,thermal analysis and crystal X-ray structural analysis.The crystal ofEr(CCl_3COO)_3·(phen)_2·2H_2O belongs to monoclinic system,with space group P2_1/c,a=1.6969(6)nm,b=1.3776(5)nm,c=1.7563(9)nm,β=114.79(9)°,V=3.727(1)nm~3,Z=4.     

Synthesis and Crystal Structure of a 4f-3d Complex [La(DMF)_6(H_2O)_3][Cr(CN)_6]·2H_2O

Ｒｅｃｅｎｔｌｙ ,ｔｈｅｒｅｈａｓｂｅｅｎｃｏｎｓｉｄｅｒａｂｌｅｉｎ ｔｅｒｅｓｔｉｎｌａｎｔｈａｎｉｄｅ(Ⅲ )ｈｅｘａｃｙａｎｏｆｅｒｒａｔｅｓａｎｄｔｈｅａｎａｌｏｇｏｕｓｃｏｂａｌｔ(Ⅲ )ａｓｗｅｌｌａｓｃｈｒｏｍｉｕｍ(Ⅲ )ｃｏｍｐｌｅｘｅｓｂｅｃａｕｓｅｏｆｔｈｅｉｒｐｏｔｅｎｔｉａｌａｓｃａｔａｌｙｔｉｃ ,ｓｅｍｉｃｏｎｄｕｃｔｉｖｅ ,ａｎｄｍａｇｎｅｔｉｃｍａｔｅ ｒｉａｌｓ[1～ 4] .Ｆｏｒｅｘａｍｐｌｅ ,ｍａｇｎｅｔｉｃｓｔｕｄｉｅｓｏｎａｓｅｒｉｅｓｏｆｔｈｒｅｅ ｄｉｍｅｎｓｉｏ…     

Reaction of (C_5H_5)_2NdCl·2LiCl with n-Butyllithium: Formation and Crystal Structure of [Li(DME)_3][(C_5H_5)_3Nd(μ-H)Nd(C_5H_5)_3]

Reaction of (C_5H_5)_2NdCl·2LiCl with n-Butyllithium: Formation and Crystal Structure of [Li(DME)_3][(C_5H_5)_3Nd(μ-H)Nd(C_5H_5)_3]     

Lanthanide Complex [Nd(dpdo)_4(H_2O)_3][ClO_4]_3·4.5H_2O·dpdo Containing Framework Based on 4,4′-Dipyradine-Dioxide

Ｃｒｙｓｔａｌｅｎｇｉｎｅｅｒｉｎｇｏｆｃｏｏｒｄｉｎａｔｉｏｎｐｏｌｙ ｍｅｒｓｗｉｔｈｏｐｅｎｆｒａｍｅｗｏｒｋｓａｓｓｅｍｂｌｅｄｆｒｏｍｏｒ ｇａｎｉｃ ｍｅｔａｌｃｏｍｐｏｕｎｄｓｈａｓｂｅｅｎｏｆｇｒｅａｔｉｎｔｅｒ ｅｓｔｓｏｗｉｎｇｔｏｔｈｅｉｒｐｏｔｅｎｔｉａｌｐｒｏｐｅｒｔｉｅｓａｓｎｏｖｅｌｍａｔｅｒｉａｌｓｓｕｃｈａｓｇａｓａｄｓｏｒｐｔｉｏｎ[1,2 ] ,ｉｏｎ ｅｘ ｃｈａｎｇｅ[3] ａｎｄｃａｔａｌｙｓｉｓ[4] .Ｔｈｅｃｏｎｓｔｒｕｃｔｉｏｎｏｆｃｏｏｒｄｉｎａｔｉｏｎｐｏｌｙｍ…     

Synthesis and Crystal Structure of a Novel Ion-pair Complex of [Li(THF)_4Nd(C_8H_8)_2]·2THF

The reaction of NdCl_3 with lithium methylnaphthalene in 1:2 mole ratio in THF generates black powder.The powder reacts with cyclooctatetraene(COT)in THF to form the title complex.[Li(THF)_4Nd(C_8H_8)_2]·2THF crystallizes in the monoclinic space group P2/c with unit-cell dimensions a=1.7858(7)nm,h=1.3243(4)nm,c=1.8086(6)nm.β=106.52(4)°,V=4.10 nm~3 and D_c=1.268 g/cm~3 for Z=4.F(000)=1660,R=0.0774,R_n=0.0733.The complex consists of discrete ion-pair and two THF moleculesadduct.In the anion,the neodymium atom is coordinated by two COT rings.The structure of the cation showsthat the lithium atom is attached with THF molecules only.     

Synthesis and Structure of Polynuclear Complex [La(bphsb)2(NO3)3]n

Ｓｏｍｅｌａｎｔｈａｎｉｄｅｃｏｍｐｌｅｘｅｓｗｉｔｈｄｉｓｕｌｆｏｘｉｄｅｓｈａｖｅｂｅｅｎｓｔｕｄｉｅｄ［１，２］．Ｈｏｗｅｖｅｒ，ｒｅｌａｔｉｖｅｌｙｌｉｔｌｅｗｏｒｋｈａｓｂｅｅｎｄｏｎｅｏｎｃｒｙｓｔａｌｓｔｒｕｃｔｕｒｅｏｆｔｈｅｓｅｃｏ...     

Synthesis，Characterization，Crystal Structure and Quantum Chemistry Calculation of the Mixed Ligand Complexes ［Ln（CF_3COO）_3·（Phen）_2·（H_2O）_2］·CH_3COCH_3·H_2O

Ｓｙｎｔｈｅｓｉｓ，Ｃｈａｒａｃｔｅｒｉｚａｔｉｏｎ，ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅａｎｄＱｕａｎｔｕｍＣｈｅｍｉｓｔｒｙＣａｌｃｕｌａｔｉｏｎｏｆｔｈｅＭｉｘｅｄＬｉｇａｎｄＣｏｍｐｌｅｘｅｓ［Ｌｎ（ＣＦ_３ＣＯＯ）_３·（Ｐｈｅｎ）_２·（Ｈ_２Ｏ...     

配合物[Dy(C_7H_5O_3)_2(C_4H_6NO_2S)]·2H_2O的热化学研究

合成了镝和硫代脯氨酸、水杨酸的三元固体配合物,通过元素分析、热重分析、红外光谱、摩尔电导等手段进行表征,确定其化学组成为[Dy(C7H5O3)2(C4H6NO2S)].2H2O。根据盖斯定律设计一个热化学循环,用恒温环境溶解-反应量热法研究得到配合反应的标准反应焓为261.290.87 kJ.mol-1,进而算出配合物298.15K时的标准摩尔生成焓为-27803 kJ.mol-1。     

Crystal Structure of a Heteronuclear Complex of Erbium-Yttrium and Glycine [ErY(GIy)_6(H_2O)_4] (ClO_4)_6·5H_2O

The title complex [ErY(Gly)_6(H_2O)4](ClO_4)_6·51H_2O has been synthesized.Its crystal structure has beendetermined by X-ray diffraction method.The crystal is triclinic with space group P.The unit cell parametersare as follows:a=1.1518(4) nm,b=1.4105(7) nm,c=1.5530(6) nm,α=96.61(3)°,β=102.74(3)°,γ=105.70(3)°,V=2.3277(17) nm~3,Z=2,D_(calc)=2.091 g/cm~3.The structure has been refined to a final R of0.0785.The crystal-is an infinite chain complex,in which four carboxyl groups from glycine molecules bridge theEr~(3+) and Y~(3+) ions,and the other two carboxyl groups bridge two adjacent Er~(3+) or Y~(3+) ions.     

Synthesis and Crystal Structure of an Erbium Complex with Valine [Er_2(Val)_4(H_2O)_8](ClO_4)_6·4H_2O

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆａｎＥｒｂｉｕｍＣｏｍｐｌｅｘｗｉｔｈＶａｌｉｎｅ［Ｅｒ２（Ｖａｌ）４（Ｈ２Ｏ）８］（ＣｌＯ４）６·４Ｈ２ＯＹａｎｇＷｅｉｃｈｕｎ（杨维春），ＷａｎｇＲｕｉｙａｏ（王瑞瑶），ＪｉｎＴｉａｎ...     

Crystal Structure of{[(μ_2-Cl)(C_5H_5)Sm(μ_2-Cl)]_2(μ_3-Cl)(μ_4-O)Sm(μ_2-Cl)·THF}_2~(2-)·[Li(DME)_2·Li(THF)_2·DME]~(2 )·DME

The crystal structure of title complex has been determined by the method of X-ray single crystaldiffraction.The crystal belongs to monoclinic space group C_(2/c)with the unit parameters a=2.8907(7),b=2.0431(5),c=1.5723(3)nm;β=115.67(2)°.The unit volume V is 8.36924(348)nm~3;Z=8,Dc=1,82g·cm~(-3),μ(MoK_α)=46.4cn~(-1); F(000)=4416.The final R is 0.083,Rw 0.088.The title complex con-sists of two univalent cations and one divalent anion.The anion has a cluster structure including six Sm~(3 ).Coordination numbers of all six Sm~(3 )are eight,but their surroundings are different from each other.Two ofthem are decahedral array,and the others are octahedral array f the centroid of each pentacyclodienyl ring istaken as one point.     

Syntheses and Structures of Two Heteronuclear Complexes with Glycine {[CuEr(Gly)_5(H_2O)_2](ClO_4)_5·H_2O}_n and {[Cu_2Gd_2(Gly)_10 (H_2O)_4](ClO_4)_10·4H_2O}_n

Ｉｎｔｈｅｐａｓｔｆｅｗｙｅａｒｓ ,ｔｈｅｍａｇｎｅｔｉｃｐｒｏｐ ｅｒｔｉｅｓｏｆｃｏｍｐｌｅｘｅｓｃｏｍｐｒｉｓｉｎｇｌａｎｔｈａｎｉｄｅａｎｄｔｒａｎｓｉｔｉｏｎｍｅｔａｌｉｏｎｓｈａｖｅａｔｔｒａｃｔｅｄｉｎｃｒｅａｓｉｎｇｉｎｔｅｒｅｓｔ[1～ 6 ] .Ｔｈｅｓｅｃｏｍｐｌｅｘｅｓａｒｅｉｍｐｏｒｔａｎｔｉｎｔｈｅｓｔｕｄｉｅｓｏｆｍａｇｎｅｔｉｃｅｘｃｈａｎｇｅｉｎｔｅｒａｃｔｉｏｎｂｅｔｗｅｅｎｌａｎｔｈａｎｉｄｅａｎｄｄ ｔｒａｎｓｉｔｉｏｎｍｅｔａｌｉｏｎｓ,ａｎｄｔｈｅｙｃａｎｐｒｏ…     

Synthesis and Crystal Structure of [Er(OH_2)_8](ClO_4)·3·5(1,4Diox.)·2H_2O

Ｓｅｖｅｒａｌｒａｒｅｅａｒｔｈｃｏｍｐｌｅｘｅｓｗｉｔｈｃｒｏｗｎｅｔｈｅｒｓｏｆｓｔｒｕｃｔｕｒｅｆｏｒｍｕｌａ［ＲＥ（ＯＨ２）８］Ｃｌ３·ｍＬ·ｎＨ２Ｏｈａｖｅｂｅｅｎｓｔｒｕｃｔｕｒａｌｙｄｅｔｅｒｍｉｎｅｄ［１～４］，ｗｈｅｒｅＬ＝１２ｃ...     

Synthesis and Crystal Structure of RE[CH_2(CH_2)_4CONC_4H_9]_3(NO_3)_3(RE=Dy,La)

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＲＥ［ＣＨ２（ＣＨ２）４ＣＯＮＣ４Ｈ９］３（ＮＯ３）３（ＲＥ＝Ｄｙ，Ｌａ）ＷａｎｇＨａｎｚｈａｎｇ（王汉章），ＸｕＱｉｎｇｆｅｎｇ（徐庆锋），ＱｉａｎＰｕ（钱朴）ＳｕｎＪｉａｎｐｉｎｇ（孙建...     

Synthesis and Crystal Structure of Lutetium Complex withTriethylenetetraaminehexaacetic Acid (H_6ttha):{[Lu_2 (ttha) (H_2O)_6Lu_2 (ttha) (H_2O)_4]·21H_2O}_n

Paramagneticmetali0ncomplexeshavemanyapplicati0nsinbiomedicine,especiallyasbioconjugatesf0rmonoclonalantib0dyradioiso-topelabelingandasmagneticresonanceimaging(MRI)agents["'].Polyaminepolycarboxylicacidsandtheirderivativesareveryimportantchelatingagentsformetalions,anddiethylene-triaminepentaaceticacid(H,dtpa)complexwithgadoliniumhasbeenusedasMRlagentintheNMRdiagnosisoft....,[3'4j.HavingsimilarcoordinationabilitywithH5dtpatowardlan-thanideions,triethylenetetraaminehexaaceticacid(H,ttha)can…