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1.
The reactions of transition metal salts with taurine 5‐chlorosalicylaldelyde Schiff base gave two complexes [Ni(TCSSB)(H2O)3].H2O (1) and [Cu(TCSSB)(H2O)2]2[Cu(TCSSB)2].6H2O (2) (TCSSB=taurine‐5‐chlorosalicylaldelyde Schiff base), which were characterized by elemental analysis and X‐ray diffraction analysis. The complex 1 crystallized in monoclinic system with space group P2 1/c, and a=1.4816(2) nm, b=1.3953(2) nm, c= 0.7466(1) nm, β= 100.499(3)°, V=1.5176(4) nm3, Z=4, and an infinite 3‐D network structure was formed by hydrogen bonds among sulfo group, crystal water and coordinated water. Complex 2 crystallized in triclinic system with space group P1 , with the cell parameters: a = 0.6413(2) nm, b= 1.4596(3) nm, c= 1.6188(4) nm, a= 102.473(5)°, β= 98.979(4)°, γ=101.739°, V=1.4165(6) nm3, Z=1. The coordination environment between Cu(1) and Cu(2) is different. Cu(1) is slightly distorted square pyramidal while Cu(2) is distorted square‐plane. The complex 1 is mononuclear while the complex 2 is made up of two coordinated subunits, namely [Cu(TCSSB)2] and [CU(TCSSB)(H2O)2]2. Besides that the TG‐DTG of the complex 1 was analyzed, the thermal decomposition reaction of the complex was studied under a non‐isothermal condition by TG‐DTG. The TG and DTG curves indicate that the complex was decomposed in three stages: . 相似文献
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Wen XU Qi FANG Gang XUE Wen Tao YU Hong Yu CHEN Guo Qun LIU Wei XU Cui Ying XU De Qing ZHANG Dao Ben ZHUState Key Laboratory of Crystal Materials Shandong University Jinan Institute of Chemistry The Chinese Academy of Sciences Beijing 《中国化学快报》2003,14(10):1089-1092
A new molecular conductor (PyH)[Ni(dmit)2]2 (dmit = 4, 5-dimercapto-1, 3-dithiole-2-thione) has been prepared and its crystal structure has been determined. Crystallographic parameters for (PyH)[Ni(dmit)2]2: C17H6NNi2S20; triclinic system; P-1 space group; a = 5.9227 (4) , b =8.2279 (6), c = 16.7535 (9) A, a = 90.233 (5) , 0 = 92.107 (6) , y= 104.654 (6) ; V= 789.25 (9) A3; Z = 1; Dc = 2.068 g/cm3; F (000) = 491. The conductivity at one direction on (001) plane at room temperature was measured to be 0.13 ii^-cmf1. The resistivity-temperature curve in the temperature range of 90-290 K shows that this compound behaves as a semiconductor. 相似文献
3.
A new nickel(Ⅱ) complex, C34H38N8NiO4, has been prepared and characterized by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group P21/c with a = 11.715(5), b = 12.328(5), c =11.113(5)A, β= 92.589(5)°, Z = 2, Dc = 1.411 g/cm^3,μ = 0.658 mml, the final R = 0.0427 and wR = 0.1099 for 2229 observed reflections with I 〉 2σ(I). The complex is a centrosymmetric plane in which nickel(Ⅱ) is coordinated in a regular octahedron to the ligand phenytoin through the nitrogen atoms of ethylenediamine, imine and amine. The complex was valued for its antimicrobial activity against bacterial strands using the agar diffusion method, and found to be active against the four test bacterial organisms. Preliminary screening for antimicrobial activities showed that the title complex is quite active against standard strains of Salmonella species, Staphylococcus aureus, Bacillus pumilus and Eschierichia coli. 相似文献
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ZHOUXiao-hua LEXue-yi LONGLa-sheng CHENShi 《高等学校化学研究》2005,21(1):119-122
It is important to research the mixed-ligand copper complexes containing bioligands, such as amino acids, nucleic acids and proteins, in exploring the functional mechanism of microelement copper in organism because the reaction of any micronutrient with two or more bioligands in the concentrated bioligands background gives mixed-ligand ternary complexes, which are more stable and related with storage of substance and transportationof metal ions in the life process. 相似文献
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1 INTRODUCTIONThecoordinationchemistryofmulti substitutedoxamidesisofimportancetoawidevarietyofchemical[1 ] ,biological[1 ] andappliedsystems[2 ,3] .Themagnetic[4,5]andspectroscopic[6 ,7] propertiesoftheoxamidecomplexesareveryinteresting .Alotofmononuclearandbimetall… 相似文献
6.
The crystal structure of the compound [EDA][Ni(dmit)2]3 (EDA=2-diethylamino-1,3-dithioanylium; dmit=1,3-dithiole-2-thione-4,5-dithiolate)C25H14NNi3S32, has been determined by single crystal X-ray diffraction at 300K. The crystal is triclinic with space group P, a=11.252, b=12.192(2), c=20.055(6) , α=108.127(2), β=106.287(8), γ=90.005(9)°; V=2498.3(3) 3, Z=2, Mr=1530.38, Dc=2.03(2) g/cm3. Final R and Rw values were 0.0603 and 0.0704, respectively. The structure consists of thick layers of stacked Ni(dmit)2 entities separated by EDA cations. This salt shows semiconducting behaviour with room temperature conductivity of 0.2 Scm-1 and activation energy of 0.11 eV. 相似文献
7.
WAN Jun WANG Shi-ying WEN Yong-hong YE Su-juan OUYANG Ping-kan ZHANG Shu-sheng . College of Life Science Pharmaceutical Engineering Nanjing University of Technology Nanjing P. R. China . College of Chemistry Molecular Engineering Qingdao University of Science Technology Qingdao P. R. China 《高等学校化学研究》2005,21(4):415-418
IntroductionSalicylaldoxime can be used in chemically modi-fied glassy-carbon electrodes,and applied to the deter-mination of metals in water.It shows a very high recov-ery[1,2].Direct design of solid-state structures that en-compass frameworks such as grids,ladders,helicesand channels of a desired architecture is central to crys-tal engineering science[3,4].Each of the oxidationstates of copper displays a different stereochemistry,ofwhich Cu(Ⅱ)is the most representative example foritsd9elec… 相似文献
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In an attempt to synthesize a new pyrimidine complex of copper(H) in a solution reaction of CuBr2 with 2,2‘-bis(hexahydropydmidine) and hydro-chloric acid, we unexpectedly obtained a bright yellow chip-like crystal of CuCl4(H2tn) [H2tn=(H3NCH2CH2CH2NH3)^2 ]. Its structure was determined by single-crystal X-ray diffraction analysis. The crystal belongs to orthorhombic system, space group Pnma, with cell parameters: a=0.7216(2)nm, b=1.8308(6)nm, c=0.7553(3)nm, V=0.9953(6)nm^3, Z=4, F(000)=564, Mr=281.49, Dc=1.879 g/cm^3. u(Mo Ka)=3.204 mm^-1, R1=0.0248, wR2=0.0575. The analysis of the crystal structure indicates that the complex has a three-dimensional network structure, which is formed by hydrogen bonds and electrostatic interaction. 相似文献
10.
HAN Qiu-Xiaa ZHANG Da-Lib MA Jian-Ruc WANG Jing-Pingc NIU Jing-Yangc a 《结构化学》2007,26(8):949-954
The synthesis, X-ray crystal structure, thermal properties and electrochemistry of the new complex formulated as {Er(DMSO)7}PW12O40 are reported. The single-crystal X-ray analysis reveals that the crystal crystallizes in the monoclinic system, space group P21/c with a = 11.767(2), b = 14.909(3), c = 34.905(7) , β = 98.97(3)°, Mr = 3591.33, V = 6049(2) 3, Dc = 3.944 g/cm3, Z = 4, GOOF = 1.098, F(000) = 6340, R = 0.0490 and wR = 0.1202. Crystal structure analysis indicates that the Er(Ⅲ) is seven-coordinate with a distorted pentagonal bipyramid and combines to the anion [PW12O40]3- via static electric force. 相似文献
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WU Chang-Jü 《结构化学》2002,21(6)
<正>Mononuclear complex {[Cu(N-men)2(cda)2]·[Cu(N-men)2]-(ClO4)2} was synthesized by sodium carbamyldicyanomethanide Na(cda), N-methylethylenediamine and hydrate copper perchlorate. The crystal belongs to the triclinic system, space group P 1 with a = 7.229(2), b = 8.114(2), c = 15.936(4) A, α = 80.511(4), β = 78.993(4), r= 72.118(4)°, V = 867.6(3) A3, Z = 1, C20H44Cl2Cu2N14O10, Mr = 838.68, Dc = 1.605 g/cm3, F(000) = 434 and μ = 1.449 mm-1. The structure was refined to R = 0.0480 and wR = 0.1289 for 2503 observed reflections (I > 2σ(I)). In the complex there exist two kinds of coordination models for Cu (II) ions. One is that the Cu (II) ion is coordinated by four nitrogen atoms which are from two N-men molecules, and a slightly distorted square planar coordinate environment is formed around the Cu (II) ion; the other is that the Cu (II) ion is coordinated by six nitrogen atoms, of which four are from two N-men molecules and the left from nitrile groups, resulting in a distorted octahedron around the 相似文献
13.
由Cu(Ⅱ)、2,2′-联吡啶(邻菲咯啉)与N-苯基亚氨基二乙酸在溶液中组装得到2个双核配合物[Cu2(L)2(2,2′-bipy)2]·8H2O (1)、[Cu2(L)2(phen)2]·2H2O (2)(H2L=N-苯基亚氨基二乙酸,2,2′-bipy=2,2′-联吡啶,phen=邻菲咯啉)。用元素分析、红外光谱、热重分析等进行了表征,并测定了其晶体结构。晶体结构表明,配合物1的晶体属三斜晶系,空间群P1;配合物2的晶体属单斜晶系,空间群P21/c。在这2个双核配合物中,中心铜离子的配位形式均为五配位的畸变四方锥构型,配体L中的N原子没有参与配位,而是采用1个羧基的1个氧原子与Cu2+离子螯合、另1个羧基上的1个氧原子以μ2-桥联的配位模式连接2个Cu2+离子。 相似文献
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A homochiral complex,Ni 2 (salen) 2 (1,salen=(R,R)-(-)-N,N-bis(3-tert-butyl-5-(4ethynylpyridyl)salicyl-idene)-1,2-diaminocyclohexane),has been synthesized and characterized by IR,microanalysis,CD spectra,TGA,powder and single-crystal X-ray crystallography.It crystallizes in triclinic,space group P1 with a=11.896(2),b=12.571(3),c=13.197(3),α=65.61(3),β=73.90(3),γ=75.87(3)o,V=1707.9(6) 3,Z=2,C 42 H 42 N 4 NiO 2,M r=693.51,D c=1.349 g/cm 3,F(000)=732,μ=0.612 mm-1,GOOF=1.015,the final R=0.0290 and wR=0.0796 for 9002 observed reflections with I > 2σ(Ⅰ).The complex architecture is constructed by intermolecular π···π interaction and assembled into a 2D structure via C-H···π interactions between the cyclohexanes and pyridine rings. 相似文献
15.
The new chelate complex formulated [Cu(NC2H6SO3)(phen)(CH3CO2)]·2H2O (phen is o-phenanthroline) has been synthesized and the crystal structure was determined by X-ray diffraction. The crystal structure of the complex belongs to triclinic system with space group and unite cell parameters: a=7.298(1)?, b=11.573(2)?, c=11.942(3)?;α=69.77(1)°, β=80.05(1)°, γ=76.39(1)°, V=915.2(3)?3, Z=2, F(000)=478. Dc=1.680g·cm-3, μ=1.354mm-1, S=1.045. In the crystal structure Cu(Ⅱ) ion is five-coordinated to form a distorted tragonal cone. CCDC: 193112. 相似文献
16.
The complex Cu2(μ-dppb)2(μ-Cl)2 has been synthesized from the reaction of CuCl, dppb and (n-Bu)4NCl. The crystal belongs to the triclinic with space group P1. The unit cell parameters are: a=9.939(4)?, b=10.083(6)?, c=14.104(5)?, α=76.46(3)°, β=71.02(2)°, γ=70.87(5)°. The single crystal X-ray diffraction analysis reveals that it has a bi-ring structure with a symmetry center at the middle of two Copper atoms. The outer ring is a 14-membered ring of Cu-dppb-Cu-dppb, and the inner ring is a 4-membered ring composed of two Cl- and two Cu(Ⅰ). Investigation of third-order optical nonlinearity shows that it exhibits considerable nonlinear absorptive and self-defocusing effect with α2=1.75×10-13m·W-1 and n2=3.19×10-18m2·W-1. CCDC: 193113. 相似文献
17.
Cu(Ⅱ)-牛磺酸缩水杨醛席夫碱配合物的合成及晶体结构 总被引:21,自引:1,他引:21
The title complex was synthesized by reaction of taurine salicylic schiff base(TSSB), O-phenanthroline(phen) and cupric acetate in water-ethanol solution. The crystal structure was determined by X-ray diffraction method and the chemical formula weight of the complex is 498.00. And the crystal structure belongs to orthorhombic system with space group Pbcn and cell parameters: a=31.072(4)?, b=12.8909(18)?, c=10.3478(14)?; V=4144.7(10)?3,Z=8,Dc=1.596Mg·m-3,μ=1.197mm-1 and F(000)=2048. The compound is an one-dimensional chain complex of infinite length connecting with hydrogen bonds. The Cu(Ⅱ) was coordinated by two oxygen atoms and three nitrogen while the O atoms of Ac- groups did not coordinate. At the same time the Cu(Ⅱ)formed a distorted tragonal cone. Besides the capacities of coordination to Cu(Ⅱ) of atoms were discussed. 相似文献
18.
一维链状配位聚合物[M(H2bpb)(H2O)4](SO4)2·6H2O[M=Zn(Ⅱ),Cu(Ⅱ)]的合成及晶体结构表征 总被引:3,自引:0,他引:3
设计并合成了一个含吡啶基团的柔性配体:N,N′-Bis(3-pyridylmethyl)-1,4-benzenedimethylamine(bpb)。通过bpb与硫酸锌及硫酸铜反应得到了两个新型具有一维链状结构的配位聚合物:[M(H2bpb)(H2O)4](SO4)2·6H2O[M=Zn(Ⅱ) 1,Cu(Ⅱ) 2]。X-射线晶体结构测定表明,这两个 相似文献
19.
合成了含异硫氰酸根和邻菲咯啉(phen)混合配体的镍配合物[Ni(NCS)2(phen)2],通过红外光谱、紫外光谱和X射线单晶衍射等手段对其结构进行了表征.研究了配合物的固体荧光光谱.单晶结构解析结果表明,标题化合物属于正交晶系,Pbcn空间群,晶胞参数为:a=1.296 2(2)nm,b=1.019 0(1)nm,c=1.759 5(2)nm,V=2.323 9(4)nm3,Z=4,Dc=1.530 g/cm3,μ=1.043 mm-1,F(000)=1 096,R1=0.042 1,wR2=0.108 1.配合物中镍离子采用6配位的八面体配位构型,晶体堆积中通过π-π作用形成一维超分子结构. 相似文献