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塑料粉末粉碎机的研制 总被引:1,自引:1,他引:0
介绍了热塑性塑料粉末粉碎机的设计原理,并以粉碎低密度聚乙烯(LDPE)为例,分析了粉碎物凿度及成品粒度的分布情况,总结出塑料粉末粉碎机的主要工作性能及该粉碎机的特点,并对该粉碎机的应用前景进行了预测。 相似文献
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本发明介绍了从铁的氯化物(可以是直接氯化钛铁矿生成的副产物)生产氯气和铁的氧化物的方法,具体步骤包括:使氯化亚铁与氯气反应,转化成三氯化铁;从气相产物中分离出固相,使气相三氯化铁与氧气反应,将不反应的三氯化铁冷凝到氧化铁粒子上,从氧化铁粒子中分离气相产物,将氧化铁粒子循环回氧化或冷凝步骤。 相似文献
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《Ceramics International》2017,43(13):9723-9728
Indium tin oxide (ITO) nanoparticles and gallium-doped indium tin oxide (GITO) nanoparticles with various molar ratios of dopants were prepared by a solution method in oleylamine. Characterization of crystal, morphology, and optical properties was carried out using X-ray diffraction (XRD), transmission electron microscopy (TEM), ultraviolet–visible (UV–Vis), photoluminescent (PL), and Fourier transform infrared spectroscopy (FT-IR). XRD patterns show that with increasing of Sn, the crystal structure of ITO nanoparticles varies gradually from standard cubic bixbyite In2O3 to amorphous and to standard tetragonal SnO2, whereas the GITO nanoparticles retain the crystal structure of ITO. The smallest particle size is around 10 nm, and the morphology of the particles is nearly spherical. The smallest particles, though coated with oleylamine, tend to aggregate forming larger flower-like particles. Defect level emission at the present of dopants was observed in the PL spectra of the ITO and GITO nanoparticles. 相似文献
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液相共沉淀法制备氧化铟锡超细粉体材料的研究进展 总被引:1,自引:0,他引:1
介绍了液相共沉淀法制备氧化锢超细锡粉体材料的工艺,分析了沉淀剂、反应物的浓度、煅烧的温度和时间、分散剂等四个因素对制备过程及产物的影响。按照三氧化铟和二氧化锡的质量比为9∶1选用铟盐和锡盐;用氨水、尿素或碳酸铵作沉淀剂,并且沉淀剂不同,反应时应控制的pH值和反应时间也不同;反应物In~(3+)的浓度0.2mol/L时可得到接近纳米级的超细氧化铟锡粉体材料;700~800℃煅烧3~5h,可使前驱物成为球状,其团聚现象也可以得到综合平衡;分散剂为硫酸铵、硅烷偶联剂KH570等,对其分散机理作了简要的分析。 相似文献
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介绍了六种氧化铟的制备方法,其中以铟的气相沉积法和直流磁控溅射法制备氧化铟具有较大的优势,这两种方法工艺和技术也比较成熟。此外还介绍了制备条件对氧化铟的微观结构和性质的影响,以及根据对制备参数分析确定最佳制备条件,制备条件在氧化铟的制备过程中起着非常关键的作用。 相似文献
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Visible-light enabling titanium oxide/tin indium oxide (TiO2/ITO) thin films deposited on unheated glass slides with prolonged deposition duration were investigated in this study. Structural properties characterized by X-ray diffraction (XRD), Raman spectra and scanning electron microscopy (SEM) showed typical polycrystalline structure with primary anatase phase along with elongated pyramid-like grains lying on the film surface and densely packed columnar structure from cross-sectional profile. The XRD preferential peak of (2 1 1) and the Raman peak intensity at 640 cm−1 dramatically increased without noticeable broadening and shift as the deposition time was prolonged beyond 2 h. This implies that more perfectly crystalline structure, less internal stress, and comparatively larger grains were obtained by this technique. The Ti2p3/2 and O1s XPS peaks shifted toward higher binding energy suggest that the local chemical state was influenced by the prolonged deposition duration in the film, which resulted in red shift of absorption threshold into visible-light region. Under ultra-violet (UV) and visible-light illumination, the visible-light enabling film exhibited the best photocatalytic activity on MB degradation with the rate-constant of about 0.231 h−1. Hydrophilic conversion rate was estimated to be 8.14 × 10−3 deg−1 min−1 and long-term UV-induced hydrophilicity of 10° in the dark storage up to 72 h was observed. In addition to its inherent characteristics of the layered TiO2/ITO structure on hole/electron separation, all these could be attributed to more perfectly formed crystalline structure, densely packed columnar crystals and the surface roughness along with its enlarged surface area. 相似文献
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Microbial cellulose (MC) membranes produced by Acetobacter xylinum NUST4.1,were used as flexible substrates for the fabrication of transparent indium tin oxide (ITO) electrodes.Transparent and conductive ITO thin films were deposited on MC membrane at room temperature using radio frequency (RF) magnetron sputtering.The optimum ITO deposition conditions were achieved by examining crystalline structure,surface morphology and op-toelectrical characteristics with X-ray diffraction (XRD),scanning electron microscopy (SEM),atomic force mi-croscopy (AFM),and UV spectroscopy.The sheet resistance of the samples was measured with a four-point probe and the resistivity of the film was calculated.The results reveal that the preferred orientation of the deposited ITO crystals is strongly dependent upon with oxygen content (O2/Ar,volume ratio) in the sputtering chamber.And the ITO crystalline structure directly determines the conductivity of ITO-deposited films.High conductive [sheet resis-tance ~120 Ω·square-1 (Ω·sq-1)] and transparent (above 76%) ITO thin films (240 nm thick) were obtained with a moderate sputtering power (about 60 W) and with an oxygen flow rate of 0.25 ml·min-1 (sccm) during the deposi-tion.These results show that the ITO-MC electrodes can find their potential application in optoelectrical devices. 相似文献
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Zhiyang Chen Yuan Zhu Qiyao Duan Anqi Chen Zikang Tang 《Journal of the American Ceramic Society》2019,102(1):42-47
Nanocrystalline indium tin oxide (ITO) powders were prepared by a novel spray combustion method. Using single-drop study equipment, we studied the thermodynamics of the combustion reaction. The reaction can be ignited at air temperature as lower as 171.3°C when using urea and glucose as composite fuel. Once the reaction is ignited, the combustion temperature can surge to above 500°C, generating nanocrystalline ITO powders with grain size about 40 nm. Footages from high-speed camera demonstrated that the reaction is in three-step: moderate beginning, violent middle, and decaying end. It is also noticed that the ignition is very sensitive to the air temperature, even 0.2°C minus deviation may fail the combustion. The combustion reaction is self-sustainable, which saves the energy supply. And the low ignition temperature means the combustion reaction can be carried out in a conventional spray dryer. Our results provide a feasible way to mass production of nanocrystalline ITO powders, which as a methodology, may be extended to the production of other oxide nanopowders. 相似文献
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Paria Moarref Atasheh Soleimani-Gorgani Farhood Najafi 《Designed Monomers and Polymers》2016,19(2):138-144
Polypyrrole/indium tin oxide nanocomposites were synthesized via in situ miniemulsion polymerization of pyrrole monomer in the presence of indium tin oxide nanoparticles. Different nanocomposites were synthesized by different loadings of nano indium tin oxide. The morphology and nanoparticles distribution of the nanocomposites were characterized by electron microscopy. The results of XRD and TEM analysis showed that indium tin oxide nanoparticles were well placed in the polymeric structure of latex. FTIR analysis was used for the characterization of synthesized polypyrrole and its nanocomposites. TGA analysis was performed to investigate the thermal behavior of pristine polypyrrole and its nanocomposites. Conductivities of nanocomposites were measured by 4-point probe method and compared to the neat polymer. 相似文献
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Indium tin oxide films, an important n-type semiconductor oxide, show great prospects in optoelectronic device applications. Consequently, as a key raw material of targets for sputtering films, it is important to prepare low-resistivity indium tin oxide powders. Herein, low-resistivity indium tin oxide submicro-cubes are synthesized by a seed-assisted coprecipitation method. The effects of seed content, In3+ concentration, aging time, reaction temperature and calcination temperature on resistivity were investigated by single factor and orthogonal experiments. To ensure reliability and reproducibility of data, each experiment was repeated three times and resistivity of each sample was measured three times to obtain average value. The results indicated that optimal sample was matched with cubic phase In2O3. The single-crystal indium tin oxide particles exhibited a regular cubic shape with a size of nearly 500 nm and low resistivity of 0.814 Ω·cm. Compared with particles prepared by the conventional coprecipitation method, indium tin oxide submicro-cubes showed good dispersion. The presence of seed particles provided nucleation sites with lower energy barriers and promoted formation of submicro-cubes. The face-to-face contact among particles and good dispersion contributed to electron transfer, resulting in lower resistivity. The seed-assisted synthesis provides a novel way to prepare low-resistivity indium tin oxide submicro-cubes. 相似文献
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Chen-Bin Wang Guo-Yuan Gau Shiue-Jiun Gau Chih-Wei Tang Jia-Lin Bi 《Catalysis Letters》2005,101(3-4):241-247
Nanosized nickel oxide was synthesized by a simple liquid-phase process to obtain the hydroxide precursor and then calcined to form the oxide. The precursor and the nickel oxide were characterized by X-ray diffraction (XRD), infrared spectroscopy (IR), thermal analysis (TG) and temperature-programmed reduction (TPR). The results indicated that the particle size of nickel oxide was controlled by the calcined temperature (TC). Mixed phases of nickel oxide and nickel hydroxide were present as the TC was lower than 300 °C. Non-stoichiometric nickel oxide (NiOx, x = 1.2) was formed between 250 °C and 400 °C and a pure nickel oxide was formed as the TC arrived 500 °C. The particle size of nickel oxide changed as the calcined temperature was controlled under 250 °C, 300 °C, 400 °C and 500 °C, the order was 5.6 nm, 6.5 nm, 11 nm and 17 nm, respectively. 相似文献