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Separation and purification of dodecanedioic acid (DDDA) from its homologous compounds were studied experimentally by falling film crystallization (FFC). The influences of various operation parameters, including crystallizing time, flow rate of melt and temperature of glycerine bath, on purity of DDDA and crystallizing rate were investigated. Over 99% (by mole) DDDA was obtained for a feed composition of 96% (by mole). The main factors affecting the separation efficiency are flow rate of melt and temperature of glycerine bath. The crystallizing layer of DDDA was further purified by sweating and blasting. A set of optimized operation data are provided for better understanding the mechanism of heat and mass transfer in FFC, and for further industrial application of DDDA purification process. 相似文献
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采用精馏-结晶法分离以环己酮为原料合成十二烷二酸二甲酯的粗品,探讨了各种工艺条件对结晶分离的影响.结果表明:结晶分离最佳工艺条件为:m(精馏双酯)∶m(甲醇)=1∶0.8~1.5,结晶溶液始温30℃左右,终温5~8 ℃,降温速率2~3 ℃/min,搅拌速度5~25 r/min;结晶母液中甲醇可通过蒸馏回收循环使用,残留双酯返回精馏系统.所得十二烷二酸二甲酯的纯度可达99.5%以上,符合医药中间体、香料等行业的使用要求. 相似文献
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MWB降膜结晶法精萘装置的工艺及生产 总被引:1,自引:0,他引:1
我厂的精萘生产工艺大体可分为三个阶段,第一阶段从50年代至80年代末,精萘生产工艺沿用前苏联技术,即由焦油蒸馏所得的萘油馏分生产压榨菜,菜饼熔化后经酸洗净化和简单蒸馏得产品精萘。由于该工艺存在生产环境恶劣、洗涤需消耗大量酸碱且有外排废液、煤气直接加热蒸馏釜,装置热效率低且不安全以及压榨设备的备品备件奇缺,难以长期维持稳定生产等原因,于1989年停产,并转产工业萘。第二阶段从1989年至1994年,采用双炉双塔工艺,以萘洗混合馏分为原料生产工业萘,不仅较好地解决了上述问题,还极大地改善了操作环境。1992年以来为第三阶段,为提高萘 相似文献
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OLA FLESLAND 《Drying Technology》2013,31(8-9):1713-1739
ABSTRACT Layer crystallization in laminar falling films has been studied for freeze concentration applications. A binary mixture of water and sucrose has been tested in order to compare with literature results from suspension crystallizers. The concentration of sucrose in ice, which is a measure for loss of solute. were from 0.4 to 26.5% for bulk concenwlions of sucrose of 5 to 40%. respectively. The time averaged ice growth rates varied from 3. l0-7 l0 3-10-6 m/s. The results are related to expressions for maximum ice growth rate developed from the gradient criteria. Also an expression for maximum ice growth rate from irreversible thermodvnamics is oresented. Althoueh the exwrimental results show that one–step layercrystallization has amuch lower separation effect than suspension crystallizers with washcolumns, multistep layer crystallization could provide an economical favourable freeze concentration process. A multistep process that combines freeze concentration and reverse osmosis is proposed. A case study shows that it is possibleto reduce the investment costs to less than half of existing processes, for dewatering capacity of 700kg per hour. The energy consumption is also reduced. 相似文献
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分类讨论了目前萃取结晶技术在无机盐及有机物分离领域中的应用现状、发展趋势和相应的分离原理,概括得到萃取结晶的一般原理。与传统的蒸发、结晶过程相比,萃取结晶技术具有很多优势,必将得到更大的发展。 相似文献
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《分离科学与技术》2012,47(5):1021-1033
Abstract Ice crystalline layers were prepared from a binary eutectic mixture of acetic acid and water using layer melt crystallization. The crystalline layers were obtained under the conditions of the cooling temperature at 269, 268, and 267 K, the feed compositions of 0.5, 1.0, and 5.0 wt% acetic acid, and the cooling rates of 0.1, 0.5, and 1.0 K/min. After crystallization, sweating operations were carried out for various crystalline layers obtained in crystallization. The effect of sweating on the impurity behavior inside crystalline layer was investigated. The crystalline layer formed in higher growth rate was purified more easily by sweating operations. Effective distribution coefficient in the sweating process was in the range of 0.2 to 0.01, which depended on the crystalline layers formed in crystallization process. Eventually, layer melt crystallization can be used for the treatment of acetic acid wastewater. 相似文献
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《分离科学与技术》2012,47(7):1056-1061
Separation of acetic acid from acetic acid and water mixture was carried out by melt crystallization. The effect of the cooling rate, the amount of seeds, the seeding temperature, the sweating rate, and the sweating fraction on the distribution coefficient was investigated. The acetic acid was successfully separated by single-stage melt crystallization. As the sweating fraction is increased, the crystalline layers grown at lower cooling rates are purified more highly. Eventually, the crystallization rate is much more important than the sweating rate. The effective distribution coefficient ranges from 0.01 to 0.25 for the crystal growth rates of 1.2 × 10?6 m/s to 4 × 10?6 m/s. 相似文献