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以二甲基二氯硅烷(CH3)2SiCl2)为原料,通过Wuertz还原反应合成出聚二甲基硅烷。实验表明:纯度高的原料使产物产率大幅提高,用UV和FT-IR对聚二甲基硅烷的结构进行表征。 相似文献
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在传统的合成体系中加入适量的二乙烯基苯,通过常压高温自由基聚合反应,获得了产率较高、可纺性优良的先驱体聚碳硅烷。采用正交实验设计研究了反应温度、升温速率、二乙烯基苯的质量分数、裂解温度和保温时间五个因素对聚碳硅烷产率的影响。方差分析表明,在反应温度为420℃、二乙烯基苯的质量分数为1·5%、升温速率为6℃/h、裂解温度为530℃、保温时间为5h条件下,可以得到粗产率为50%的黄色透明固态聚碳硅烷;各因素对聚碳硅烷产率影响的显著性依次为:升温速率>反应温度>二乙烯基苯的质量分数>保温时间>裂解温度。 相似文献
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本文报道了二甲基二氯硅烷直接水解制备二甲基硅二醇的过程,考察了二甲基二氯硅烷、水、乙醚在不同的投料比下产品二甲基硅二醇的收率。当水的加入量为理论需求量的1~1.025倍,乙醚的加入量为2.5~3L/mol(CH_3)_2SiCl_2时,产品的收率在70%以上。实验中选择了苯胺为氯化氢的吸收剂。所得产品为白色有光泽的鱼鳞片状物质,经熔点测定,C、H、Si元素分析及电子轰击质谱测定,所得产品确系纯度较高的二甲基硅二醇。实验中考察了二甲基硅二醇产品的储存稳定性,室温下存放期不超过90天,低温冷冻存放刚可超过一年。 相似文献
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合成了不同链段长度的卤代硅氧烷,并用其与间二乙炔基苯格氏试剂反应,合成了两种硅烷芳炔-硅氧烷芳炔嵌段共聚物(SiO-b-PSA),并制成碳纤维增强树脂复合材料。利用红外光谱(FT-IR)、核磁共振氢谱(1H NMR)、凝胶渗透色谱(GPC)、旋转流变、差示扫描量热分析(DSC)、热失重分析(TGA)和悬梁臂冲击实验对共聚物及其复合材料的结构和性能进行表征。研究结果表明所合成的共聚物具有优良的耐热性和韧性,硅烷芳炔-硅氧烷芳炔嵌段共聚物在氮气气氛下的Td5高于513℃,1000℃残留率高于78.9%,硅烷芳炔-硅氧烷芳炔嵌段共聚物/碳纤维复合材料的冲击强度高达(30.92±0.44) kJ·m-2。 相似文献
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Hyperbranched poly(silyl ester)s were synthesized via the A2 + B4 route by the polycondensation reaction. The solid poly(silyl ester) was obtained by the reaction of di‐tert‐butyl adipate and 1,3‐tetramethyl‐1,3‐bis‐β(methyl‐dicholorosilyl)ethyl disiloxane. The oligomers with tert‐butyl terminal groups were obtained via the A2 + B2 route by the reaction of 1,5‐dichloro‐1,1,5,5‐tetramethyl‐3,3‐diphenyl‐trisi1oxane with excess amount of di‐tert‐butyl adipate. The viscous fluid and soft solid poly(silyl ester)s were obtained by the reaction of the oligomers as big monomers with 1,3‐tetramethyl‐1,3‐bis‐β(methyl‐dicholorosilyl)ethyl disiloxane. The polymers were characterized by 1H NMR, IR, and UV spectroscopies, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The 1H NMR and IR analysis proved the existence of the branched structures in the polymers. The glass transition temperatures (Tg's) of the viscous fluid and soft solid polymers were below room temperature. The Tg of the solid poly(silyl ester) was not found below room temperature but a temperature for the transition in the liquid crystalline phase was found at 42°C. Thermal decomposition of the soft solid and solid poly(silyl ester)s started at about 130°C and for the others it started at about 200°C. The obtained hyperbranched polymers did not decompose completely at 700°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3430–3436, 2006 相似文献
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Linear asymmetrical poly(propylene oxide) was synthesized through four‐step reactions: selective benzylation, alcohol exchange reaction, propylene oxide anionic polymerization, debenzylation. One terminal of the asymmetrical polymer chains is alcohol hydroxyl and the other is phenol hydroxyl. It was characterized with infrared (IR) and 1H Nuclear Magnetic Resonance (1H‐NMR). Peaks at 1.11, 3.38, and 3.53 ppm were attributed to side groups (? OCH2CH(CH3)? ), backbone units (? OCH2CH(CH3)? ) and (? OCH2CH(CH3)? ) of poly(propylene oxide), respectively. Molecular weight and molecular weight distribution were measured with 1H‐NMR and laser light scattering (LLS), which showed that the linear asymmetrical poly(propylene oxide) was mono‐disperse (PDI = 1.02–1.07). Then, its carbamate reaction with phenyl isocyanate was studied; the reaction rate constants for phenol hydroxyl and alcohol hydroxyl of poly(propylene oxide) were k1 = 0.209 mol L?1 min?1 and k2 = 0.051 mol L?1 min?1. There was a great reactivity difference for two types of hydroxyls in asymmetrical poly(propylene oxide), contrasting to the single carbamate reaction rate constant of symmetrical poly(propylene oxide) (k3 = 0.049 mol L?1 min?1). © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
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A. M. Fundo F. L. S. Purgato J. R. Romero L. M. Abrantes 《Journal of Applied Electrochemistry》2008,38(6):861-867
This work reports results achieved when a specially designed monomer, the allyl ether of p-benzenesulphonic acid, with a pendent anionic group, was used to prepare a polymeric matrix. Ion exchange with cupric ions
followed by electrochemical reduction provided polymer films with highly dispersed Cu0 particles. Immersion of the copper bearing modified electrode in a PdCl4
2− containing solution produced a displacement reaction causing the deposition of 50–200 nm sized Pd particles. The presence
of Pd particles in the so-prepared films was confirmed by voltammetry, SEM/EDS and XRD. The behaviour of the submicron Pd
particle/poly(allylbenzene p-sulphonic acid) modified electrode towards the HER was evaluated by recording polarization curves. The electrocatalytic activity
reveals that the methodology is a promising approach for the preparation of cathodes for the electrohydrogenation of organic
molecules. 相似文献
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采用Heck反应法合成了具有较高分子量和立构规整度的聚(3-己基噻吩)。研究了溶剂的种类及配比、相转移催化剂及催化剂的种类以及反应温度、反应时间对所得聚(3-己基噻吩)的分子量和规整度的影响。用凝胶色谱(GPC)和核磁共振谱(1HNMR)对聚(3-己基噻吩)的分子量及立构规整度进行了表征。用紫外-可见分光光度计和荧光分光光度计研究了聚(3-己基噻吩)的吸收光谱和发射光谱。结果表明,当溶剂为二甲基甲酰胺与四氢呋喃(DMF:THF=1:1)的混合溶剂,采用醋酸钯[用量为单体量的5%(摩尔分数)]为催化剂,四丁基溴化铵[用量为单体量的100%(摩尔分数)]为相转移催化剂时,在80℃下反应12h所得聚(3-己基噻吩)的分子量可达6700,立构规整度超过96%。 相似文献
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The efficient synthesis of two new monomers, vinyltris(dimethylsiloxy)silane (2) and tris(dimethylvinylsiloxy)silane (3), was developed. Hydrosilation of these new A–B3 monomers affords highly branched starburst poly(siloxysilane) polymers. Polymerization of2 yields a polymer structure that has siliconhydride functional groups on the outer sphere. Polymerization of3 yields a polymer that has the same hyperbranched poly(siloxysilane) core as the polymer produced from2, but the outer sphere contains vinyl moieties. The presence of silicon-hydride or vinyl groups on the surface of both polymers allows functionalization of these materials with a wide variety of reagents.Presented at the XXVIth Silicon Symposium, Indiana University—Purdue University at Indianapolis, March 26–27, 1993. 相似文献
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聚4-乙烯基吡啶的合成与表征 总被引:2,自引:0,他引:2
以过氧化二苯甲酰(BPO)为引发剂,用悬浮聚合的方法制备了较高相对分子质量的聚4 乙烯基吡啶(P4VP)。通过对聚合产物相对分子质量测试结果的分析,研究了单体与水的体积比、引发剂用量、分散剂用量、反应时间、反应温度、搅拌速度等因素对4 VP聚合反应的影响。结果表明,聚合时间为1h、聚合温度为60℃、引发剂的质量分数(占单体量)为0.8%左右、分散剂的质量分数(占单体量)为0.6%、搅拌速度为300r/min时,P4VP的重均分子量就能达到6×105~9×105。另外,采用紫外吸收光谱(UV)、红外吸收光谱(IR)、核磁共振氢谱(1H NMR)、核磁共振碳谱(13C NMR)、热重 差热分析(TG DTA)等测试手段研究了P4VP的结构和性能。 相似文献
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Graft copolymers that have oligopeptides (OP) as graft molecules were prepared through the coupling reaction of the carboxylic acids of OP with the amino groups of poly(aminostyrene)s (PAS). The three OPs are Boc‐Gly, Z‐Gly‐Pro, and Z‐Gly‐Pro‐Leu‐Gly‐Pro, where Boc and Z are, respectively, the t‐butyloxycarbonyl group and benzyloxycarbonyl group as protective groups on nitrogen. The two PASs are poly(4‐vinylphenylamine) and poly(N‐isopropyl‐4‐vinylbenzylamine). These polymers that have narrow molecular weight distributions were prepared via anionic living polymerization. The coupling reaction to form the peptide bonds was mediated by dicyclohexylcarbodiimide in a mixed solvent of N,N′‐dimethylformamide and methyl chloride. The degree of grafting (DOG) on PAS was determined from the 1H‐NMR spectrum. The dependence of the reaction time (0–8 h) on the DOG, the dependence of the reaction temperature (0–45°C) on the DOG, and the dependence of the molar ratio of OP to the amino group of PAS (1–4 times) on the DOG were studied. By alternating the reaction time and the molar ratio, the DOG values of PAS could be controlled in the range from 0 to 100%. DOG seems to be independent of the molecular weight of OP and the degree of basicity of PAS. The contact angle of the resultant graft copolymers was measured and the preliminary nonthrombogenic test was also performed. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 77: 1558–1567, 2000 相似文献