Weldability of spheroidal graphite cast iron

Summary

The weldability of a spheroidal graphite cast iron (SGCI) with a specific chemical composition is analysed. Manual metal arc welding (MAW) and oxy‐acetylene welding (OAW) were used on sample castings of 300 × 900 × 10 mm, with a groove angle of 60°. The influence on weldability of the chemical composition of the different electrodes used is also analysed, as well as that of the preheating temperature. Finally, the micro‐structure of joints is examined in the heat affected zone (HAZ) (near the weld), at the metal‐weld interface and in the fusion zone (the weld bead). The mechanical properties of the joints and their microstructure are correlated.     

湿型球墨铸铁件收缩特性的试验研究

采用正交试验的方法，浇注一系列铸件，测量铸件的冷却曲线；解剖铸件，测定铸件质量、铸件及缩孔体积。研究了碳当量、孕育、铸件模数以及铸型条件对湿型球铁件收缩特性及缩孔缩松的影响。为开展数值模拟预测球铁件缩孔、缩松的工作打下了基础。     

Eutectic solidification mode of spheroidal graphite cast iron and graphitization

The shrinkage and chilling tendency of spheroidal graphite (abbreviated SG) cast iron is much greater than that of the flake graphite cast iron in spite of its higher amount of C and Si contents. Why? The main reason should be the difference in their graphitization during the eutectic solidification. In this paper, we discuss the difference in the solidification mechanism of both cast irons for solving these problems using unidirectional solidification and the cooling curves of the spheroidal graphite cast iron. The eutectic solidification rate of the SG cast iron is controlled by the diffusion of carbon through the austenite shell, and the final thickness is 1.4 times the radius of the SG, therefore, the reduction of the SG size, namely, the increase in the number, is the main solution of these problems.     

Experimental and numerical analysis of effect of cooling rate on thermal–microstructural response of spheroidal graphite cast iron solidification

This work presents an experimental and numerical study of the solidification process of an eutectic spheroidal graphite cast iron (SGI). The effect of the cooling rate on the thermal–microstructural response is particularly analysed. To this end, experiments as well as numerical simulations were carried out. The experiments consisted in a solidification test in a wedge-like casting such that different cooling rates were measured at specific positions along the part. A metallographic analysis was also performed in five locations of the sample with the aim of obtaining the number and size of graphite nodules at the end of the process. The numerical simulations were made using multinodular based and uninodular based models. These two models predicted similar results in terms of cooling curves and nodule counts. Besides, good experimental–numerical agreements were obtained for both the cooling curves and the graphite nodule counts.     

Influence of boron on ferrite formation in copper-added spheroidal graphite cast iron

This paper reviews the original work of the authors published recently,describing the influence of B on the matrix of the Cuadded spheroidal graphite cast iron.The effect of Cu has been corrected as a ferrite formation promoter in the matrix of the grey cast iron by the usage of high-purity material.Also,this paper focuses on the ferrite formation and the observation of the Cu distribution in the B-added and B-free Cu-containing spheroidal graphite cast iron.The Cu film on the spheroidal graphite can be successfully observed in the B-free sample using a special etching method.However,in the B-added sample,no Cu film could be found,while the secondary graphite was formed on the surface of the spheroidal graphite.The interaction between B and Cu is stressed as a peculiar phenomenon by the employment of a contrast experiment of B and Mn.The heat treatment could make Cu precipitate more significantly in the eutectic cells and in the matrix in the form of large Cu particles because of the limited solubility of Cu.     

Numerical simulation of microstructure evolution on near eutectic spheroidal graphite cast iron

A multiphase cellular automaton model was developed to simulate microstructure evolution of near eutectic spheroidal graphite cast iron (SGI) during its solidification process, and both dendritic austenite and spheroidal graphite growth models were adopted. To deduce the mesh anisotropy of cellular automaton method, the composition averaging and geometrical parameter were introduced to simulate the spheroidal graphite growth. Solute balance method and decentered square algorithms were employed to simulate austenite dendrites growth with different crystallographic orientations. The simulated results indicate that the graphite nodule grows in a spherical morphology when the surrounding environment of a single graphite nodule is same. However, for two adjacent graphite nodules, the environment is different. The higher the carbon concentration, the faster the growth of graphite. By comparison with experimental results, it is found that the microstructure evolution of near eutectic spheroidal graphite cast iron during solidification process can be reproduced quantitatively by numerical simulation with this model.     

铁素体球墨铸铁与20钢的闪光对焊

试验使用铁素体球墨铸铁和20钢的实心棒料进行了闪光对焊，通过改变次级电压4～8级，通电时间3～5s，观察其焊接接头组织的变化并测定其抗拉强度。结果表明，接头由三个区组成；当通电时间一定时，抗拉强度随次级电压的升高先减小后增大；当次级电压一定时，抗拉强度随通电时间的增加而增大。在次级电压为8级、通电时间为5s时，抗拉强度达最大值，为370．8MPa，是20钢母材的90.4％，是球墨铸铁母材的83.7％。     

Effect of microstructure on resonant vibration fatigue fracture of ferritic spheroidal graphite cast iron

The effect of graphite nodule size, counts and eutectic cell wall inclusions on the fatigue fracture behaviour under resonant vibration of spheroidal graphite (SG) cast iron was investigated in this study. Experimental results indicated that the variations of graphite nodule size and counts slightly influence resonant frequency. The D-N curves (deflection amplitude vs. number of vibration cycles) of all test materials show similar manner. The deflection amplitude maintains a constant value for a certain period of vibration cycles (region I) and then decreases significantly with increasing the vibration cycles (region II). The feature of fatigue fracture behaviour under resonant vibration of ferritic SG cast iron can be concisely divided into four steps, namely (1) crack initiation, (2) crack linking, (3) the major cracks formation, and (4) deepening of the major cracks in the through-thickness direction. The initial three steps correspond to the region I period of the D-N curves, and the fourth step occurs in the region II period. Increasing the graphite nodule counts and refining the microstructure increase the region I period, and improve the resonant vibration fatigue life. During fatigue fracture process under resonant vibration, cracks mainly initiate from graphite nodules and some from eutectic cell walls. The eutectic cell wall inclusions are more crowded in SF specimen than that in PF specimen. So, the crack path of SF specimen is more tortuosity. The feature of fracture surface is mostly the brittle fracture.     

凝固模拟在球铁飞轮工艺优化上的应用

应用MAGMAsoft对4种不同结构球铁飞轮的不同工艺方案进行凝固模拟,根据凝固模拟结果和实际试生产铸件外观缺陷及内部缩松情况分析比较,提出不同改进工艺方案并对其再进行凝固模拟,选择最佳方案应用于生产。优化后的工艺方案投入批量生产,球铁飞轮的缩孔、缩松缺陷得到降低或消除,满足用户对铸件的技术要求。     

地铁用电机端盖缩孔缺陷分析及预防

通过对球墨铸铁件电机端盖零件材料及热节的分析,合理设计保温冒口,消除热节处的缩孔,确保端盖铸件内部质量合格。     

Computer model for the characterisation of the size distribution of spheroidal graphite in ductile cast iron

A computer model was developed to establish the relationship between the two-dimensional (2D) and the three-dimensional (3D) parameters, specifically the number of particles and particle size distribution. The computer experiments were performed for both monodispersed and lognormally polydispersed systems. The model was based on a random distribution of a number of spherical grains in a cubic unit, with no intersection between the grains. The cubic unit was cut by a random plane and the number of particles which appeared in the section and the area fraction were measured. This procedure was repeated until the average number of particles and the average area fraction became constant. Finally, the 2D size distribution of the particles over all sections was obtained.

It was concluded that the volume fraction is equal to the area fraction, irrespective of the particle size distribution, providing that the total number of measured 2D particles is large enough. As for the number of particles, an equation was found to calculate the number of 3D particles in a monodispersed system from the number of 2D particles and the volume fraction. However, in lognormally polydispersed systems the number of 3D particles could be calculated using the 3D mean and standard deviation, estimated from the 2D mean and standard deviation by a method specifically developed for the purpose.

Finally, the method was applied to two ductile cast iron specimens and the applicability of the present model was verified.     

The effect of graphite shape on the tensile deformation behaviour in hot-swaged and hot-rolled ferritic spheroidal graphite cast iron

The shape of the graphite nodules in ferritic spheroidal graphite (SG) cast iron is changed by hot-swaging and hot-rolling, when symmetric ellipsoidal graphite and asymmetric ellipsoidal graphite can be obtained, respectively. For the symmetric ellipsoidal graphite, the graphite shape ratio tends to decrease with increasing reduction ratio. The increase of flow stress with increasing reduction ratio can be explained by the decrease in the stress concentration induced by the graphite with increasing reduction ratio. On the other hand, the graphite shape ratio is more complex for the asymmetric ellipsoidal graphite than the symmetric ellipsoidal graphite specimens. The graphite shape ratio tends to increase and decrease with increasing reduction ratio in two transverse directions. As a result, a balance exists in the specimen between increasing and decreasing stress concentration, showing that the tensile flow stress is independent of reduction ratio.

To understand the effect of the graphite shape ratio on the tensile flow stress during tensile deformation, specimens with different carbon contents and graphite shape ratios were used in this study. Furthermore, the triaxial parameter (k₁) has been defined such that the larger stress concentration effect will have the larger k₁ value. Based on the present experimental results, the graphite shape ratio tends to decrease with increasing reduction ratio or tensile strain, so that the stress concentration effect and triaxial parameter (K₁) tend to decrease with increasing reduction ratio and tensile strain. Therefore, the effect of the graphite nodules in ferritic SG cast iron on the tensile flow stress is not only reduction of the effective area fraction of the matrix but also development of an uneven triaxial stress field.     

Hydrogen evolution reaction on spheroidal graphite cast iron with different pearlite areas in sulphuric acid solutions

The rate equation of hydrogen evolution reaction of spheroidal graphite cast iron with different pearlite area has been studied in sulphuric acid solutions at 298 K. The cathodic Tafel slope of ?0·130 V/decade and the reaction order with respect to the activity of hydrogen ion of 1 are obtained by linear potential sweep technique. The rate equation of hydrogen evolution reaction does not depend on the area of pearlite. There is no difference in hydrogen evolution reaction mechanisms between pure iron and spheroidal graphite cast iron.