Engine combustion and emission fuelled with natural gas: A review

Natural gas (NG) is one of the most important and successful alternative fuels for vehicles. Engine combustion and emission fuelled with natural gas have been reviewed by NG/gasoline bi-fuel engine, pure NG engine, NG/diesel dual fuel engine and HCNG engine. Compared to using gasoline, bi-fuel engine using NG exhibits higher thermal efficiency; produces lower HC, CO and PM emissions and higher NOx emission. The bi-fuel mode can not fully exert the advantages of NG. Optimization of structure design for engine chamber, injection parameters including injection timing, injection pressure and multi injection, and lean burn provides a technological route to achieve high efficiency, low emissions and balance between HC and NOx. Compared to diesel, NG/diesel dual fuel engine exhibits longer ignition delay; has lower thermal efficiency at low and partial loads and higher at medium and high loads; emits higher HC and CO emissions and lower PM and NOx emissions. The addition of hydrogen can further improve the thermal efficiency and decrease the HC, CO and PM emissions of NG engine, while significantly increase the NOx emission. In each mode, methane is the major composition of THC emission and it has great warming potential. Methane emission can be decreased by hydrogen addition and after-treatment technology.     

The effects of hydrogen enriched natural gas under different engine loads in a diesel engine

Natural gas, which is among the alternative fuels, has become widespread in the transportation as it is both economical and environmentally friendly. While the use of natural gas is at a significant level in spark ignition engines, it has not yet been implemented in compression ignition engines (CI) as it worsens combustion due to ignition delay. In CI engines, however, the combustion properties of natural gas (NG) can be improved by adding hydrogen (H₂) to NG. This is one of the methods applied to use natural gas in CI engines. In this experimental study, two different volumetric rates of NG and NG/H₂ mixtures were added to the combustion air in a CI engine, and engine performance and emissions were examined under different engine loads. The experiments were performed at two different engine speeds, four different engine loads and no-load condition. An engine cylinder pressure of 59.16 bar, which is the closest value to the 59.39 bar obtained in the use of diesel fuel, was obtained at 1500 rpm for “Diesel + NG(500 g/h)” and 59.9 bar (highest values) was obtained for “Diesel + (500 g/h) [80%NG+20%H₂]" at 1750 rpm. For “Diesel + NG(250 g/h)” (Mix1) and “Diesel + NG(500 g/h)” (Mix2), as the engine speed increases, at the point where the maximum in-cylinder pressure is obtained occurs further to the right from top dead center (TDC). With the addition of 500 g/h NG, an increase of 4.5% was achieved in the cylinder pressure at full load, while an increase of 6.5% was achieved in the case of using “Diesel + (500 g/h) [80%NG+20%H₂]". Although the effect of the NG and NG/H₂ mixtures on in-cylinder pressure was small, the fuel consumption and thermal efficiency improved. Substantial improvements in hydrocarbon (HC) emissions were observed with the use of “Diesel + (250 g/h)[80%NG+20%H₂]”. Carbon dioxide (CO₂) emissions decreased with speed increase, but no significant differences in terms of CO₂ emissions were observed between the mixtures. There was a maximum difference of 15% between the diesel and the mixtures in CO₂ emissions. Although there was a decrease in nitrogen oxide (NO_x) levels with the increase in engine speed, the lowest NO_x emissions of 447.6 ppmvol was observed in “Diesel + NG(250 g/h)” (Mix1) at 1750 rpm at maximum load.     

A detail study of a RCCI engine performance fueled with diesel fuel and natural gas blended with syngas with different compositions

The catalytic reforming is an applicable method to generate hydrogen as an alliterative fuel directly that is of prime interest to replace hydrocarbon fuels. Although, the use of this type of catalyst has the potential to solve the problem of safe storage of hydrogen in ICEs, but, this method suffers from the simultaneous production of carbon monoxide with hydrogen known as syngas. Depending on the engine operating conditions, different syngas composition in terms of H2/CO volumetric ratio can be produced through the mentioned catalyst. An engine performance which uses onboard hydrogen produced is completely affected by syngas composition. Therefore, the aim of the current simulation study is to evaluate the performance of a heavy-duty diesel engine under RCCI combustion fueled with diesel fuel/natural gas blended with syngas with different compositions. For this purpose, at 9.4 bar gross IMEP, natural gas is gradually replaced by five different compositions of syngas that is H2/CO volumetric ratios of 33.33/66.67, 50/50, 66.67/33.33, 80/20, and 100/0. The simulation results show that not only the engine output power can be improved up to 27.7% by simply increasing of the CO/H2 volumetric ratio in syngas composition to 66.67/33.33, but also the GIE is reduced by less than 9%. In contrast, the risk of the diesel knock occurrence may increase only in higher CO/H2 ratios. Although, the NOx level can be achieved closer to the EURO VI level, but, same level for UHC and CO and also the level of EPA 2007 for formaldehyde are not achievable for syngas with the higher CO/H2 volumetric ratio.     

Performance,emission and combustion characteristics of a variable compression ratio engine using methyl esters of waste cooking oil and diesel blends

The performance, emission and combustion characteristics of a single cylinder four stroke variable compression ratio multi fuel engine when fueled with waste cooking oil methyl ester and its 20%, 40%, 60% and 80% blends with diesel (on a volume basis) are investigated and compared with standard diesel. The suitability of waste cooking oil methyl ester as a biofuel has been established in this study. Bio diesel produced from waste sun flower oil by transesterification process has been used in this study. Experiment has been conducted at a fixed engine speed of 1500 rpm, 50% load and at compression ratios of 18:1, 19:1, 20:1, 21:1 and 22:1. The impact of compression ratio on fuel consumption, combustion pressures and exhaust gas emissions has been investigated and presented. Optimum compression ratio which gives best performance has been identified. The results indicate longer ignition delay, maximum rate of pressure rise, lower heat release rate and higher mass fraction burnt at higher compression ratio for waste cooking oil methyl ester when compared to that of diesel. The brake thermal efficiency at 50% load for waste cooking oil methyl ester blends and diesel has been calculated and the blend B40 is found to give maximum thermal efficiency. The blends when used as fuel results in reduction of carbon monoxide, hydrocarbon and increase in nitrogen oxides emissions.     

Theoretical study of the effects of engine parameters on performance and emissions of a pilot ignited natural gas diesel engine

With the increasing concern regarding diesel vehicle emissions and the rising cost of the liquid diesel fuel as well, more conventional diesel engines internationally are pursuing the option of converting to use natural gas as a supplement for the conventional diesel fuel (dual fuel natural gas/diesel engines). The most common natural gas/diesel operating mode is referred to as the pilot ignited natural gas diesel engine (PINGDE) where most of the engine power output is provided by the gaseous fuel while a pilot amount of the liquid diesel fuel injected near the end of the compression stroke is used only as an ignition source of the gaseous fuel–air mixture. The specific engine operating mode, in comparison with conventional diesel fuel operation, suffers from low brake engine efficiency and high carbon monoxide (CO) emissions. In order to be examined the effect of increased air inlet temperature combined with increased pilot fuel quantity on performance and exhaust emissions of a PINGD engine, a theoretical investigation has been conducted by applying a comprehensive two-zone phenomenological model on a high-speed, pilot ignited, natural gas diesel engine located at the authors' laboratory. The main objectives of the present work are to record the variation of the relative impact each one of the above mentioned parameters has on performance and exhaust emissions and also to reveal the advantages and disadvantages each one of the proposed method. It becomes more necessary at high engine load conditions where the simultaneous increase of the specific engine parameters may lead to undesirable results with nitric oxide emissions.     

Pressure–time characteristics in diesel engine fueled with natural gas

Combustion pressure data are measured and presented for a dual fuel engine running on dual fuel of diesel and compressed natural gas, and compared to the diesel engine case. The maximum pressure rise rate during combustion is presented as a measure of combustion noise. Experimental investigation on diesel and dual fuel engines revealed the noise generated from combustion in both cases. A Ricardo E6 diesel version engine is converted to run on dual fuel of diesel and compressed natural gas and is used throughout the work. The engine is fully computerized and the cylinder pressure data, crank angle data are stored in a PC for off-line analysis. The effect of engine speeds, loads, pilot injection angle, and pilot fuel quantity on combustion noise is examined for both diesel and dual engine. Maximum pressure rise rate and some samples of ensemble averaged pressure–crank angle data are presented in the present work. The combustion noise, generally, is found to increase for the dual fuel engine case as compared to the diesel engine case.     

Hydrogen energy share enhancement in a heavy duty diesel engine under RCCI combustion fueled with natural gas and diesel oil

The aim of this study is to enhance hydrogen energy share in a RCCI engine. The engine under consideration is fueled with diesel oil and natural gas enriched with hydrogen or syngas and is set to operate at 9.4 bar gross indicated mean effective pressure (Mid- Load). The syngas used in this study consists of hydrogen and carbon monoxide which are mixed together on a volumetric ratio of 80:20. A fixed amount of diesel oil is injected per cycle into the combustion chamber of the RCCI engine. Based on two different strategies, hydrogen or syngas mixed with exhaust gas recirculation are admitted gradually along with natural gas while ensuring that always the low temperature combustion concept is fulfilled. The RCCI engine operation is simulated through commercial software coupled with chemical kinetics solver. The simulation results show that without any engine diesel knock occurrence, by adding hydrogen to natural gas, the share of hydrogen energy could be increased up to 40.43% while the engine power output is reduced only by about 1%. Also, syngas addition to natural gas causes that the share of hydrogen energy could be increased up to 27.05% while improves the engine power more than 4%. At the same time, by considering two mentioned strategies, the overall hydrocarbon fuel consumption per cycle can be reduced by up to 46.60% and 33.86%, respectively. Moreover, having the gross indicated efficiency of well over 50% and significant reduction in the engine emissions compared to RCCI combustion fueled solely with natural gas and diesel oil are achievable.     

Large-scale diesel engine emission control parameters

Emission tests were carried out on a large-scale medium-speed supercharged diesel engine (∼1 MW per cylinder) with control parameters compression ratio, start of ignition (SOI) and fuel type (light and heavy fuel oil, LFO and HFO). Emissions of NO_x, CO, hydrocarbons (HC), smoke (FSN) and particulate matter (PM) were measured and are discussed in relation to the control parameters. Regarding turbocharger influence on emissions the control parameters by-pass and waste-gate are also briefly addressed.     

Simulation of a hydrogen/natural gas engine and modelling of engine operating parameters

At the present work for improving the engine performance and decrease of emissions, a port injection gasoline engine is converted into direct injection. Engine performance behavior was investigated by AVL Fire software with adding hydrogen to natural gas from 0% up to 30%. Validation of the simulated model and experimental results show good confirmation. To determine the relationship between independent variables engine speed, ignition timing, injection timing and H₂% versus the dependent variables including engine performance parameters, specific fuel consumption, CO and statistical analysis models were used. Comparison between different errors models shows that Radial basis function model with training algorithm Bayesian regularization back propagation can estimate better engine performance variables. The results showed that adding hydrogen to natural gas cause the output power, torque, fuel consumption efficiency increase and specific fuel consumption drop. Also, CO decreases when ignition and injection timing be advanced and engine speed reaches to its largest.     

Effect of natural gas enrichment with hydrogen on combustion characteristics of a dual fuel diesel engine

Environmental benefits are one of the main motivations encouraging the use of natural gas as fuel for internal combustion engines. In addition to the better impact on pollution, natural gas is available in many areas. In this context, the present work investigates the effect of hydrogen addition to natural gas in dual fuel mode, on combustion characteristics improvement, in relation with engine performance. Various hydrogen fractions (10, 20 and 30 by v%) are examined. Results showed that natural gas enrichment with hydrogen leads in general to an improved gaseous fuel combustion, which corresponds to an enhanced heat release rate during gaseous fuel premixed phase, resulting in an increase in the in-cylinder peak pressure, especially at high engine load (4.1 bar at 70% load). The highest cumulative and rate of heat release correspond to 10% Hydrogen addition. The combustion duration of gaseous fuel combustion phase is reduced for all hydrogen blends. Moreover, this technique resulted in better combustion stability. For all hydrogen test blends, COV_IMEP does not exceed 10%. However, no major effect on combustion noise was noticed and the ignition delay was not affected significantly. Regarding performance, an important improvement in energy conversion was obtained with almost all hydrogen blends as a result of improved gaseous fuel combustion. A maximum thermal efficiency of 32.5%, almost similar to the one under diesel operation, and a minimum fuel consumption of 236 g/kWh, are achieved with 10% hydrogen enrichment at 70% engine load.     

Performance and emission characteristics of a diesel engine with Diesel Premixed Compression Ignition and exhaust gas recirculation

In the present work, diesel was used as a premixed fuel along with the conventional injection of diesel with a premixed ratio of 0.25. The premixed charge was burned in the cylinder along with the fuel directly injected into the cylinder by a conventional injection system. To control nitrogen oxide(s) (NO_x) emissions, Exhaust Gas Recirculation (EGR) was adopted and the exhaust gas was varied from 10% to 30% in steps of 10%. The performance and emission characteristics were compared with conventional 100% diesel injection in the main chamber. Based on the experiments conducted on a Compression Ignition Direct Injection (CIDI) engine, it was found that unburnt hydrocarbons, carbon monoxide, and soot emissions increase. Soot emission decreases with up to 20% EGR and increases when EGR was increased beyond 20%. Hence 20% EGR was found to be the optimum use for DPMCI mode with a premixed ratio of 0.25. Due to the lean operation, significant reduction in NO_x was achieved with the DPMCI combustion mode. Brake thermal efficiency was marginally decreased compared to CIDI mode.     

Numerical study on knock characteristics and mechanism of a heavy duty natural gas/diesel RCCI engine

In this paper, the knock phenomenon of reactivity controlled compression ignition (RCCI) engine fueled with natural gas/diesel was numerically studied. The knock mechanism of the RCCI engine is explained and the strategy of suppressing knock is put forward. The knock characteristics were studied by setting monitoring points in different spaces positions of the cylinder. The results show that the pressure oscillation amplitude at the center and edge of the cylinder is large under the high load condition of RCCI engine. In addition, the knock mechanism was studied by using pressure difference method, maximum amplitude of pressure oscillation, important components, temperature isosurface, pressure fluctuation and heat release rate. The results show that the knock of RCCI engine is mainly caused by the end-gas auto-ignition. The pressure difference results show that the characteristic frequency is consistent with the natural resonance mode (0,1) of the cylindrical combustion chamber. On this basis, the effects of pilot oil injection timing and compression ratio on engine knock are further studied. It is confirmed that diesel knock and end-gas knock may exist simultaneously in the same cycle when RCCI engine knock occurs. And diesel knock occurs before top dead center, and end-gas knock occurs after top dead center. Proper adjustment of pilot oil injection timing and reduction of compression ratio can effectively suppress engine knock.     

Power output characteristics of hydrogen-natural gas blend fuel engine at different compression ratios

Potential and knocking characteristics of a hydrogen-natural gas blend (HCNG) engine with a high compression ratio were examined from a commercial viewpoint since lean combustion with HCNG under a wide-open throttle (WOT) condition requires a high-charging-capacity turbocharger. Supercharging of intake air to extend the lean limit was investigated for a turbocharged, heavy-duty natural gas-fueled engine. Effects of compression ratio changes on fuel economy were assessed in terms of thermal efficiency and torque characteristics. Extension of the lean limit to an excess air ratio of 1.8 for an HCNG engine under WOT conditions is realizable using a supplementary supercharging system. Thermal efficiency improvement at high compression ratios is reduced under relatively rich mixture conditions because spark timing is retarded to avoid knocking. The excess air ratio corresponding to maximum thermal efficiency decreases to 1.6 for an HCNG engine due to the decrease in exhaust gas energy for intake-air charging.     

新型多碳醇-柴油燃料对柴油机性能及排放的影响

试验在一台S195柴油机上进行,试验结果表明,新型多碳醇-柴油混合燃料的油耗率比纯柴油高,但随负荷的增大,差距呈下降趋势。新型混合燃料在较大工况范围都保持较低的CO排放量。新型混合燃料中,小比例多碳醇油料的加入有利于混合燃料的HC排放状况的改善,大比例多碳醇油料的加入,对改善混合燃料的HC排放影响不明显;新型混合燃料的NOx排放均比纯柴油低,并且小比例多碳醇-柴油混合燃料的NOx排放比其大比例混合燃料的NOx排放量低;新型混合燃料的碳烟排放均比纯柴油低,并且随着多碳醇掺混比例的增大,改善效果越好。     

The effect of reformer gas mixture on the performance and emissions of an HSDI diesel engine

Exhaust gas assisted fuel reforming is an attractive on-board hydrogen production method, which can open new frontiers in diesel engines. Apart from hydrogen, and depending on the reactions promoted, the reformate typically contains a significant amount of carbon monoxide, which is produced as a by-product. Moreover, admission of reformed gas into the engine, through the inlet pipe, leads to an increase of intake air nitrogen to oxygen ratio. It is therefore necessary to study how a mixture of syngas and nitrogen affects the performance and emissions of a diesel engine, in order to gain a better understanding of the effects of supplying fuel reformer products into the engine.     

Dual-fuelling of an industrial indirect injection diesel engine by diesel and liquid petroleum gas

For partial substitution of conventional diesel fuel with liquified-petroleum gas (LPG) fuel, in an indirect-injection, (IDI) diesel engine, the so-called ‘mixed diesel gas’ approach has been applied. For this purpose, a carburetted LPG fuel system has been designed and fitted on the inlet manifold of the engine. Extensive performance tests have been carried out at full load conditions of both the pure diesel and diesel-LPG engines. The results show that, at the rated speed, and at equal power of both engines, increasing the LPG proportion in the dual fuel decreases specific fuel consumption, exhaust gas temperature and black smoke but increase pollutants such as UHC and CO, cylinder peak pressure and the rate of pressure rise.     

HHO enrichment of bio-diesohol fuel blends in a single cylinder diesel engine

One of the primary aims of this experimental investigation is to examine hydroxy-gas enrichment effects on environmentally friendly but performance-reducing alternative fuels such as ethanol and biodiesel. Hydroxy gas is a product of the pure water electrolysis method. Entire HHO system has integrated into engine test rig for this purpose. Two different biodiesohol fuel blend prepared and named by their volumetric compositions. Biodiesohol used to describe biodiesel, ethanol and standard diesel blends. Specific fuel properties are measured and ensured to be in EN590 and EN14214 standards. Experiments were conducted on a single cylinder diesel engine which was fuelled with diesel-biodiesel-ethanol fuel blends those enriched by 1 L per minute HHO gas during the entire tests. All of the experiments performed under full load condition within the range of 1200–3200 rpm engine speed. From the view of performance; brake power, brake specific fuel consumption and thermal efficiency results discussed. Besides, carbon monoxide and nitrogen oxides results measured and presented as exhaust emission. Standard diesel fuel outputs determined as a reference line to analyze the changes. A number of studies have been conducted with fuels used in this experimental study and their mixture in different ratios as well, but an examination of the HHO addition to biodiesel is performed for the first time in this research area of the literature.     

The influences of hydrogen on the performance and emission characteristics of a heavy duty natural gas engine

Because blending hydrogen with natural gas can allow the mixture to burn leaner, reducing the emission of nitrogen oxide (NO_x), hydrogen blended with natural gas (HCNG) is a viable alternative to pure fossil fuels because of the effective reduction in total pollutant emissions and the increased engine efficiency.In this research, the performance and emission characteristics of an 11-L heavy duty lean burn engine using HCNG were examined, and an optimization strategy for the control of excess air ratio and of spark advance timing was assessed, in consideration of combustion stability. The thermal efficiency increased with the hydrogen addition, allowing stable combustion under leaner operating conditions. The efficiency of NO_x reduction is closely related to the excess air ratio of the mixture and to the spark advance timing. With the optimization of excess air ratio and spark advance timing, HCNG can effectively reduce NO_x as much as 80%.     

Hydrogen supplemented natural gas effect on a DI diesel engine operating under dual fuel mode with a biodiesel pilot fuel

In order to slow down the continuing environmental deterioration, regulations for pollutant emissions limitations are increasingly rigorous. The development of new alternative fuels for internal combustion engines is a very interesting solution not only to overcome the pollution problem but also because of the petroleum shortage. In this context, the present work investigates the improvement of a DI diesel engine operating at constant speed (1500 rpm) and under dual fuel mode with eucalyptus biodiesel and natural gas (NG) enriched by various H₂ quantities (15, 25 and 30 by v%). The eucalyptus biodiesel quantity injected into the engine cylinder is kept constant, to supply around 10% of the engine nominal power, for all examined engine loads. The engine load is further increased using only the gaseous fuel (NG+H₂), which is introduced with the intake air. The effect of H₂/NG blending ratio on the combustion parameters, performance and pollutant emissions of the engine is investigated and compared with those of pure NG case. An important benefit in terms of brake specific fuel consumption, reaching a decrease of 4–10% with the 25% H₂ blend compared to the pure NG case, is achieved. Concerning the pollutant emissions, NG enrichment with H₂ is an efficient solution to enhance the combustion process and hence reduce carbon monoxide, unburned hydrocarbon and soot emissions at high loads where they are important for pure NG. However for the nitrogen oxide emissions, NG blending with H₂ is attractive only at low and medium loads where their levels are lower than pure NG.