共查询到20条相似文献,搜索用时 125 毫秒
1.
在过去的10年中,由于含有微小的纳米级金的负载型金催化剂的特殊活性,因此对此催化剂的研究热情空前高涨。这种催化剂上的一氧化碳低温氧化已经得到深入研究。尽管研究的步伐在加快,但是如制备参数和催化活性的关系、活性中心的性质和反应的机理等的议题仍然是时下争论的课题。这些争论的解决需要进一步的研究。 相似文献
2.
3.
本文概述了Au催化剂的研究进展,各类反应对Au催化剂的微观结构非常敏感,催化剂的活性与载体的种类,催化剂表面Au晶粒大小,载体与Au相互作用的强弱以及制备方法密切相关,载体主要包括各种氧化物和分子筛;表面Au粒子平均直径小于5nm,一般会有较好的催化活性,常用沉积-沉淀法或共沉淀法来制备,Au催化剂主要应用于CO低温氧化与丙烯环氧化等反应中。 相似文献
4.
本文主要介绍了Au催化剂参与的催化反应,如CO的氧化、NOx的还原、烃类及有机挥发物(VOCS)的燃烧、低温水煤气变换反应以及新型燃料电池反应等,并对CO的氧化反应进行了详细的描述。 相似文献
5.
6.
7.
负载型非晶态合金催化剂研究进展 总被引:4,自引:0,他引:4
介绍了负载型非晶态合金催化剂制备技术和最新应用技术领域。阐述了溶胶-凝胶法技术制备非晶催化剂的基本原理、特性和活性比较;对非晶催化材料在不饱和化合物加氢等领域的应用情况进行了归纳总结。分析提出:研究功能载体、添加助催化剂或改性剂以及降低还原成本是研究非晶态催化剂制备技术的发展方向,在应用领域应首先加强在乙烯裂解馏分选择加氢除炔烃技术上的研究。 相似文献
8.
9.
10.
11.
12.
Sutarawadee Monyanon Sangobtip Pongstabodee Apanee Luengnaruemitchai 《Journal of the Chinese Institute of Chemical Engineers》2007,38(5-6):435-441
The objective of this paper was to study a preferential oxidation (PROX) of carbon monoxide over monometallic catalysts including Pt, Au and Pt–Au bimetallic catalyst supported on ceria in hydrogen-rich reformate. Single step sol–gel method (SSG) and impregnation on sol–gel method (ISG) were chosen for the preparation of the catalysts. The characteristics of these catalysts were investigated by X-ray diffractometer (XRD), Brunauer–Emmet–Teller (BET) method, transmission electron microscope (TEM), scanning electron microscope (SEM) and temperature-programmed reduction (TPR). The XRD patterns of the catalysts showed only the peaks of ceria crystallite and no metal peak appeared. From TEM images, the active components were seen to be dispersed throughout the ceria support. The TPR patterns of PtAu/CeO2 catalyst prepared by SSG showed the reduction peaks were within a low temperature range and therefore, the catalysts prepared by SSG exhibited excellent catalytic activity for preferential oxidation of CO. Bimetallic Pt–Au catalyst improved the activity (90% conversion and 50% selectivity at 90 °C) because of the formation of a new phase. When the metal content of (1:1) PtAu/CeO2 catalyst prepared by SSG was increased, the CO conversion did not change much while the selectivity decreased in the low temperature range (50–90 °C). The CO conversion increased with increasing W/F ratio. The presence of CO2 and H2O had a negative effect on CO conversion and selectivity due to blocking of carbonate and water on active sites. 相似文献
13.
采用溶胶固定法制备了一系列的Au/C纳米催化剂,进行了透射电镜(TEM)表征,用于常压下以氧气为氧化剂碱性溶液中葡萄糖氧化制备葡萄糖酸钠,并对最佳的催化剂进行了反应条件影响考察。结果显示,使用溶胶固定法制备的质量分数为1%的Au/C催化效果最佳,纳米金颗粒直径小于2 nm且分布均匀,其较佳反应条件为50℃,pH 9.5,氧气流量40 mL/min,催化剂0.22 g,水溶液中质量分数为7.5%的葡萄糖,葡萄糖在1 h内,选择性及转化率均可同时达到100%,反应的转化频率(Turnover Frequency,TOF)高达1 560 h-1。上述研究表明溶胶固定法能制备一定纳米金颗粒大小的Au/C催化剂,且在该多相催化剂上反应时间短,活性高,选择性高。 相似文献
14.
It was demonstrated that, in contrast to previous results, an NCO surface complex does form on Au/TiO2 catalysts in the high-temperature reaction of NO + CO. By means of Fourier transform infrared spectroscopy two new absorption bands at 2285 and 2105-2210 cm-1, not observed in separate adsorption of reacting gases, were detected during the catalytic reaction. The former is attributed to Au-NCO and the latter to Ti-NCO species. It was assumed that, similar to the case of supported Pt metals, NCO is primarily formed on Au crystallites and then spills over onto titania. This idea was strengthened by the results obtained following the adsorption of HNCO on the catalyst and on the support. 相似文献
15.
介绍聚合物固载催化剂有6类,包括离子交换树脂催化剂,聚合物固载的相转移催化剂,聚合物固载的酸催化剂,聚合物固载的碱催化剂,聚合物固载的金属催化剂,聚合物固载的生物催化剂等。综述了近年来聚合物固载催化剂的研究进展。 相似文献
16.
17.
18.
After a high-temperature reduction (HTR) at 773 K, TiO2-supported Au became very active for CO oxidation at 313 K and was an order of magnitude more active than SiO2-supported Au, whereas a low-temperature reduction (LTR) at 473 K produced a Au/TiO2 catalyst with very low activity. A HTR step followed by calcination at 673 K and a LTR step gave the most active Au/TiO2 catalyst of all, which was 100-fold more active at 313 K than a typical 2% Pd/Al2O3 catalyst and was stable above 400 K whereas a sharp decrease in activity occurred with the other Au/TiO2 (HTR) sample. With a feed of 5% CO, 5% O2 in He, almost 40% of the CO was converted at 313 K and essentially all the CO was oxidized at 413 K over the best Au/TiO2 catalyst at a space velocity of 333 h–1 based on CO + O2. Half the chloride in the Au precursor was retained in the Au/TiO2 (LTR) sample whereas only 16% was retained in the other three catalysts; this may be one reason for the low activity of the Au/TiO2 (LTR) sample. The reaction order on O2 was approximately 0.4 between 310 and 360 K, while that on CO varied from 0.2 to 0.6. The chemistry associated with this high activity is not yet known but is presently attributed to a synergistic interaction between gold and titania. 相似文献
19.
分子筛超酸为一种同时具备分子筛和超强酸的特性的新型催化材料,在此介绍了这类催化剂的最新研究情况。着重介绍这类催化剂合成和表征技术,展望了它的应用前景,并提出了今后研究的一些设想。 相似文献
20.