REE Geochemistry of Some Metamorphic Rock Types of the Late Archean Fuping Group and Their Anatectic Derivatives in Pingshan,Hebei Province,China—A Preliminary Study

The Late Archean Fuping Group of the Xiaojiao area in Pingshan Couty,Hebei Province consists mainly of three metamorphic rock types of supracrustal affinity,i.e.,Kfeldspar leucoleptite,biotite leptite-gneiss and hornblendic rocks.Their anatectic derivatives formed in the initial stage of anatexis are petrochemically of K-feldspar granitic trondhjemitic and granodioritic compositions respectively,and in general have inherted the main petrochemical featurews from their parent rock types,Probably due to the fact that they contain less REE rich accessory minerals as compared with their parent rocks,the anatectic derivatives are in general lower in EREE content,But both the derivatives and their parent rocks have similar REE patterns,which serves as an additional indication of the genetic relationship between them.     

内蒙古兴和-卓资太古宙孔兹岩系变质峰期水活度、氧逸度及其化学位变化

通过脱水反应的平衡热力学计算确定内蒙古兴和－卓资太古宙孔兹岩系变泥砂质岩中变质峰期ａＨ２Ｏ 总体较低, 变化于０．１２～０．４０ 之间, 黑云紫苏片麻岩中ａＨ２Ｏ为０．２０～０．４３。前者的ｌｏｇｆＯ２ 值最高为－ １３～－ １５, 但在有些岩石中极低,（μＨ２ Ｏ／ＸＢｔＭ ｇ ）Ｐ,Ｔ和（μＯ２ ／ＸＢｔＭ ｇ ）Ｐ,Ｔ的系数主要变化于－ ０．２４１～－ ０．３８３ 和－ １．０５２～－ １．８１０,（μＨ２Ｏ ／μＯ２ ）Ｐ,Ｔ的斜率也有一定变化。这些数值变化特征按 “碳质变质”观点不应出现, 主要也不是脱水熔融作用所致, 它们可能与非完全开放系统中Ｈ２Ｏ较ＣＯ２ 易于逸散有关。     

冀东迁滦地区沉积变质型铁矿床变质作用程度：来自石榴子石的制约

石榴子石是冀东地区沉积变质铁矿中常见的变质矿物之一。本文采集迁安-滦县地区代表性铁矿中含有石榴子石的岩石样品,对其石榴子石进行电子探针和X-射线粉晶衍射分析,得出司马地区为角闪岩相,杏山-黄柏峪一带为角闪岩-麻粒岩相,水厂-大石河地区为麻粒岩相,这与前人对迁滦地区用主要矿物共生组合等来研究变质相的结论相一致;同时迁滦地区沉积变质铁矿中石榴子石的端元组分和晶胞参数a0随变质程度的增加呈规律性变化: 司马地区的铁铝榴石+钙铝榴石→杏山-黄柏峪一带的铁铝榴石→水厂-大石河一带铁铝榴石+镁铝榴石,其晶胞参数a0值逐渐减小。因此在沉积变质型铁矿床中,变质矿物石榴子石的化学成分及晶胞参数特征对不同地区的变质程度具有示踪意义。     

Complete chemical analyses of metamorphic hornblendes: implications for normalizations,calculated H2O activities,and thermobarometry

Twenty-two hornblendes separated from amphibolites and granulites of the Grenville Orogen of Ontario have been quantitatively analyzed for major and minor elements by electron microprobe, for FeO/Fe₂O₃ by wet chemistry, and for H₂O by manometric measurement as H₂. Hornblende formulae were calculated on the basis of 24O+OH+Cl+F. Most samples are magnesio-hornblendes, ferroan pargasitic hornblendes and ferroan hastingsitic hornblendes, with weight fractions of Fe³⁺/(Fe²⁺+Fe³⁺) ranging from 0.15 to 0.50. An oxy-amphibole component of 0–25 mol%, with an average value of 17 mol%, is obtained for these complete analyses. When compared with structural formulae determined solely from microprobe data, normalization based on 13=Si+Ti+Al+Fe+Mn+Mg cations provides the best approximation to hornblende formulae calculated from the complete analyses. Less satisfactory agreement is obtained from a normalization scheme based on 15=Si+Ti+Al+Fe+Mn+Mg+Ca, while worst agreement is obtained from normalization to 23 oxygens assuming all Fe is Fe²⁺. No normalization scheme based on microprobe data alone consistently replicates the measured FeO, Fe₂O₃, and H₂O; accurate determination of these values requires complete chemical analysies. Ionic solution models previously have been proposed to evaluate the activity of Ca₂Mg₅Si₈ O₂₂(OH)₂(a _Trem) in hornblende for use in equilibria that constrain the activity of H₂O (a _{H 2}O) in igneous and metamorphic rocks. Application of ionic models to typical hornblendes produces low a _Trem (usually<0.01), consequetly yielding extremely low a _{H 2}O. If an oxy-amphibole component is present, the calculated a _Trem and H₂O is further reduced. An oxy-amphibole component of 25% reduces the calculated H₂O activity and that of any hydroxyl-amphibole component by 50% below that calculated with simplified assumptions regarding X _OH in the hydroxyl site (i.e., X _OH=1, or X _OH=1–X _Cl–X _f). Thus, methods of amphibole normalizations appear to have a substantial effect on calculated amphibole and H₂O activites. Before quantitative hornblende thermobarometry can be calibrated and applied, the amounts of FeO, Fe₂O₃ and H₂O must be measured in order to fully characterize hornblende solid solutions.Contribution No. 478 from the Mineralogical Laboratory, University of Michigan     

河北矾山超钾质岩浆氧逸度及含水性特征的磷灰石地球化学记录

产于华北克拉通北缘的晚三叠世矾山超钾质碱性岩杂岩体主要由单斜辉石岩和辉石正长岩等组成,以发育内生磷灰石-磁铁矿矿床而闻名。本文选取矾山杂岩体中的磷灰石为研究对象,通过测试磷灰石的主微量元素及原位Sr-Nd同位素组成以探讨母岩浆的氧逸度及含水性特征。研究表明,矾山磷灰石以轻稀土元素富集、重稀土元素亏损为特征,显示出缺乏显著Ce异常的“右倾”的稀土配分型式,且具有较低的Ga含量及较高的δEu值,暗示杂岩体具有较高的岩浆氧逸度,这也得到了磷灰石Mn氧逸度计的支持。所有磷灰石以高Sr、低Y为特征,具有较高的Sr/Y(>30)和La/Yb(>90)比值,且Sr/Y与La/Yb存在明显的正相关关系,表明矾山超钾质岩浆具有较高的含水量。矾山磷灰石的原位Sr-Nd同位素投点位于地幔序列,明显偏离地壳趋势。母岩浆的“氧化且富水”特征是矾山杂岩体得以发生磷灰石-磁铁矿矿化的重要因素,其主要与板片俯冲过程中蚀变洋壳对岩石圈地幔的交代作用有关。通过对比矾山杂岩体与全球范围内其他地质环境中磷灰石的成分数据,发现具有“高Sr、低F、少Cl”特征的磷灰石可作为识别超钾质碱性岩杂岩体(及其相关金属矿床)的...     

赞皇前寒武纪变质杂岩区变质反应结构与变质作用P-T-t轨迹

赞皇变质杂岩位于华北克拉通中部造山带中南段、太行山东麓低山区。出露于该变质杂岩区中南部的含石榴石的斜长角闪片麻岩、泥质片麻岩,均保存了三期矿物组合:进变质、峰期变质和退变质矿物组合。这两大类变质岩石中,进变质阶段矿物组合(M₁)以石榴石变斑晶核部的包裹体矿物组合为代表,变质高峰期矿物组合(M₂)由石榴石变斑晶"边部"和基质矿物组成,退变质阶段矿物组合(M₃)主要是环绕石榴石边部发育的"白眼圈"状后成合晶矿物组合。泥质片麻岩中的石榴石变斑晶均保存了明显的成分环带,且在边部很窄的范围内X_Mn有所增加、Mg/(Mg+Fe)有所降低,指示存在变质高峰期后的退变质过程。温度与压力计算结果表明,赞皇斜长角闪片麻岩所经历的进变质阶段(M₁)温度约为640~710℃、 压力约为8.2~8.6kbar;高峰期(M₂)变质温度超过810℃,压力大于12.1kbar;退变质阶段(M₃)的温压范围为590~670℃和3.2~5.6kbar。此前的研究已说明泥质片麻岩的进变质阶段(M₁)变质温度为660~690℃,压力为9.0~9.2kbar;高峰期(M₂)变质温度超过780℃,压力大于12.5kbar。变质高峰属于中压相系的顶部至高压相系的底部。斜长角闪片麻岩、泥质片麻岩均记录了典型的顺时针P-T轨迹,并显示近等温减压(ITD)的退变质片段。对泥质片麻岩中多颗锆石的变质增生边的SHRIMP U-Pb定年表明,变质高峰期时代为1821±17Ma。变质作用历史说明赞皇变质岩区卷入了华北克拉通东部陆块和西部陆块之间的俯冲-碰撞、随后的快速隆升过程,为华北克拉通中部造山带早元古代末期(~1850Ma)存在的造山事件提供了新的证据 。     

The Higo metamorphic complex in Kyushu, Japan as the fragment of Permo–Triassic metamorphic complexes in East Asia

The Higo terrane in west-central Kyushu Island, southwest Japan consists from north to south of the Manotani, Higo and Ryuhozan metamorphic complexes, which are intruded by the Higo plutonic complex (Miyanohara tonalite and Shiraishino granodiorite).The Higo and Manotani metamorphic complexes indicate an imbricate crustal section in which a sequence of metamorphic rocks with increasing metamorphic grade from high (northern part) to low (southern part) structural levels is exposed. The metamorphic rocks in these complexes can be divided into five metamorphic zones (zone A to zone E) from top to base (i.e., from north to south) on the basis of mineral parageneses of pelitic rocks. Greenschist-facies mineral assemblages in zone A (the Manotani metamorphic complex) give way to amphibolite-facies assemblages in zones B, C and D, which in turn are replaced by granulite-facies assemblages in zone E of the Higo metamorphic complex. The highest-grade part of the complex (zone E) indicates peak P–T conditions of ca. 720 MPa and ca. 870 °C. In addition highly aluminous Spr-bearing granulites and related high-temperature metamorphic rocks occur as blocks in peridotite intrusions and show UHT-metamorphic conditions of ca. 900 MPa and ca. 950 °C. The prograde and retrograde P–T evolution paths of the Higo and Manotani metamorphic complexes are estimated using reaction textures, mineral inclusion analyses and mineral chemistries, especially in zones A and D, which show a clockwise P–T path from Lws-including Pmp–Act field to Act–Chl–Epi field in zone A and St–Ky field to And field through Sil field in zone D.The Higo metamorphic complex has been traditionally considered to be the western-end of the Ryoke metamorphic belt in the Japanese Islands or part of the Kurosegawa–Paleo Ryoke terrane in south-west Japan. However, recent detailed studies including Permo–Triassic age (ca. 250 Ma) determinations from this complex indicate a close relationship with the high-grade metamorphic terranes in eastern-most Asia (e.g., north Dabie terrane) with similar metamorphic and igneous characteristics, protolith assembly, and metamorphic and igneous ages. The north Dabie high-grade terrane as a collisional metamorphic zone between the North China and the South China cratons could be extended to the N-NE along the transcurrent fault (Tan-Lu Fault) as the Sulu belt in Shandong Peninsula and the Imjingang belt in Korean Peninsula. The Higo and Manotani metamorphic complexes as well as the Hida–Oki terrane in Japan would also have belonged to this type of collisional terrane and then experienced a top-to-the-south displacement with forming a regional nappe structure before the intrusion of younger Shiraishino granodiorite (ca. 120 Ma).     

河北大庙斜长岩杂岩体锆石U-Pb年龄及其地质意义

河北承德大庙斜长岩杂岩体是我国唯一的岩体型斜长岩。为了确定杂岩体的形成时代,作者从杂岩体主要组成岩石——苏长岩、纹长二长岩中选取锆石作U-Pb年龄测定,所获得的结晶年龄分别是1693±7 Ma、1715±6 Ma。这些锆石U-Pb年龄数据说明,大庙斜长岩杂岩体的侵位至少持续了约20 Ma。大庙斜长岩杂岩体和密云奥长环斑花岗岩、长城系大红峪组钾质火山岩,以及广泛发育的基性岩墙群一起可能代表华北陆块1750～1650 Ma大陆裂解事件的岩浆作用产物。     

浙西南八都群泥质麻粒岩的变质演化与pT轨迹

浙西南古元古界八都群是目前华夏地块最古老的变质基底,以往研究认为其变质程度仅达角闪岩相。近来在对遂昌地区八都群富铝片麻岩的研究过程中,发现了具有"石榴石+夕线石+正/反条纹长石+黑云母"特征组合的泥质麻粒岩,表明该地体曾经历麻粒岩相变质改造。通过岩相学与矿物化学分析,确定该岩石经历了3个阶段的演化过程,即:早期进变质阶段(M1),形成"石榴石+黑云母+白云母+夕线石+斜长石+石英"的矿物组合;变质峰期阶段(M2-3),形成"石榴石+夕线石+三元长石+黑云母+石英"的矿物组合;峰期后降压冷却阶段(M4),形成"黑云母+白云母+新生斜长石+石英"的矿物组合。岩石中石榴石普遍发育与降温过程有关的扩散成分环带和与降压过程有关的斜长石后生合晶。通过石榴石-黑云母温度计和GASP压力计估算变质峰期的温压条件为800~850℃、0.6~0.7 GPa,峰期后退变质阶段的温压条件为560~590℃、0.25~0.33 GPa,具有顺时针样式的pT演化轨迹,反映一种陆壳碰撞增厚、后又拉伸减薄的动力学过程。     

辽北法库变质杂岩的组成、变形与变质特点及构造属性

辽北法库变质杂岩的形成时代、大地构造属性及其与长春-延吉缝合带的形成过程一直以来都是众多地质学者关注的重要科学问题。本文试图通过U-Pb年代学以及物质组成分析、变形变质作用特点分析和区域对比的方法来建立法库变质杂岩的时空格架,大地构造归属及区域构造演化。通过详细的野外工作和镜下分析得到法库变质杂岩存在至少两期变形作用特点及角闪岩相-高绿片岩相至低绿片岩相的变质作用特点。通过对杂岩体中不同类型变质岩的锆石SHRIMP U-Pb年代学研究得到中志留世糜棱岩化黑云母花岗闪长岩原岩年龄为433±3Ma;晚志留世绢云长英质糜棱岩原岩年龄为423±5Ma;早二叠世绢云绿泥方解斜长糜棱岩原岩年龄为292±2Ma;早三叠世长英质糜棱岩原岩年龄为250±3Ma。通过区域对比,笔者认为法库变质杂岩为索伦-西拉木伦缝合带东延的一部分是长春-延吉缝合带的重要组成,其形成演化具有复合型造山的特点,具有复杂的构造演化史。     

东南极拉斯曼丘陵地区变质杂岩的层序与构造变形过程

东南极拉斯曼丘陵地区位于兰伯特裂谷东缘普里兹湾东岸,该地区主要出露一套麻粒岩相变质岩,前期对原岩时代、变质过程等进行了详细研究,但是对于变质杂岩的层序和变形过程研究相对薄弱。文章通过大比例尺地质填图,发现拉斯曼丘陵地区变质杂岩总体成层有序,在此基础上建立拉斯曼岩群,并将其划分成6个岩组,原岩形成时代为中元古代。拉斯曼岩群经历了格林维尔期和泛非期变质作用的叠加,变质程度均达到高角闪岩相-麻粒岩相。拉斯曼丘陵地区主体构造线方向为北东东—南西西方向,总体上构成往北东东方向翘起的复式向斜构造,几个岩组的分布也显示由东向西逐渐变新。东部米洛半岛一带明显叠加了北北西—南南东向的构造变形。研究表明,拉斯曼岩群经历了6次重要的构造变形,包括新元古代格林维尔期(D1)、新元古代—早古生代泛非期变质变形作用(D2,D3,D4,D5)以及中新生代伸展作用(D6)。目前岩石中保存的主变形面理是格林维尔期和泛非期两次构造热事件的复合型面理,主要是泛非事件形成,格林维尔期变形面理呈残留状。综合拉斯曼岩群变质年龄及早古生代进步花岗岩体形成时代,认为D2~D5变形时代为550~500 Ma左右。因此,拉斯曼丘陵地区变质变形特征显示,中元古代拉斯曼岩群经历了格林维尔期和泛非期两次重要的造山作用,以及冈瓦纳大陆的裂解。