纵向极化与磁化叠层复合材料磁电效应理论及计算

基于纵向极化压电材料及纵向磁化磁致伸缩材料的压电和压磁方程与磁电元件运动方程,给出磁电元件开路电压表达式;鉴于压电材料高输出阻抗的特点,考虑测试仪器的有限输入阻抗和传输信号引线电缆电容,通过建立等效电路模型推出了非开路情况下磁电电压计算式,取不同材料参数对磁电电压进行了数值计算.研究表明,材料参数、电路参数对输出电压均产生影响.对磁伸材料两端面受非均匀偏置磁场产生外力的非自由边界磁电效应进行研究发现,恒外力作用使压电元件产生不可检测的稳恒电压. 关键词： 纵向极化 磁电效应 磁电元件 层叠材料     

高磁导率材料FeCuNbSiB对超磁致伸缩/压电层合材料磁电性能的影响

采用超磁致伸缩材料TbxDy_1-xFe₂(x≈0.3)(Terfenol-D)、压电材料PbZrxTi_1-xO₃(PZT)和高磁导率材料FeCuNbSiB构造了新型的层合结构.由于引入高磁导率材料FeCuNbSiB改变了Terfenol-D的内部磁场分布,并且在磁场作用下,FeCuNbSiB发生形变对Terfenol-D产生应力,增大了Terfeno 关键词： 磁电效应 磁致伸缩材料 压电材料 高磁导率材料     

磁电双层膜层间耦合的弹性力学研究

基于磁致伸缩相与压电相的本构方程,应用弹性力学模型,简要介绍了如何推导自由状态的磁电双层膜纵向、横向磁电(ME)电压系数. 并采用相应的材料参数计算了La_07Sr_03MnO₃-Pb(Zr,Ti)O₃ (LSMO-PZT),Tb_1-xDy_xFe_2-y(TDF)-PZT双层膜中的磁电电压系数,具体分析了其与压电相 关键词： 磁电效应 双层膜 TDF LSMO PZT     

双层纳米磁电薄膜模型及分析

以层状磁电复合材料弹性力学模型为基础,建立了自由状态下双层纳米磁电薄膜的弹性力学模型,并以此为基础简单介绍了推导其磁电电压系数表达式的方法.计算了CoFe₂Ｏ₄/Pb（Zr_0．52Ti_0．48）Ｏ₃双层纳米复合薄膜的磁电电压系数理论值,分析结果表明基片对薄膜存在强烈的夹持效应,而且基片对压电与磁致伸缩两相材料间最佳体积比有一定的影响. 关键词： 磁电理论 磁电薄膜 铁电材料 磁致伸缩     

偏置磁场对磁致伸缩/弹性/压电层合材料磁电效应的影响

根据磁致伸缩材料的非线性本构关系得到其动态杨氏弹性模量和动态压磁系数,结合等效电路法得到磁致伸缩/弹性/压电层合材料的磁电效应与磁致伸缩材料的动态杨氏弹性模量和动态压磁系数的关系,讨论了偏置磁场对这种层合材料的谐振频率和谐振磁电电压转换系数的影响.理论推导和实验结果均表明,存在最佳偏置磁场使磁致伸缩/弹性/压电层合材料的谐振磁电电压转换系数最大. 关键词： 磁致伸缩/弹性/压电层合材料 磁电效应 偏置磁场 非线性本构关系     

考虑损耗的磁致/压电层合材料谐振磁电响应分析

运用等效电路法，对磁致/压电层合材料谐振状态下的磁电响应进行分析，得到了材料在谐振状态下的磁电电压转换系数理论计算公式. 详细地分析了磁致/压电层合材料在谐振点附近的磁损耗、机械损耗、电损耗，并给出了各种损耗相应的计算方法和大小，发现谐振状态下，材料的主要损耗来源于机械损耗. 分析结论较好地解释了磁电层合材料在不同偏置磁场下磁电响应的实验结果. 关键词： 磁致/压电层合材料 磁电效应 谐振 损耗分析     

Ni/Pb(Zr,Ti)O3/TbFe2层状复合材料的谐振磁电特性研究

采用化学镀和黏接法制备层状磁电复合材料Ni/PZT/TbFe₂,研究其磁电性能及谐振频率随Ni层厚度的变化情况. 结果表明:Ni/PZT/TbFe₂层状磁电复合材料与其他结构的磁电性能不同,其一阶弯曲谐振峰值和纵向谐振峰值都很大. 随着Ni层厚度的增加,Ni/PZT/TbFe₂层状磁电复合材料的一阶纵向谐振峰值逐渐增大. 结合实验数据和理论计算值得出了材料的一阶弯曲谐振频率fr1和一阶纵向谐振频率f 关键词： 磁电效应 正磁致伸缩 负磁致伸缩 谐振频率     

对称磁电层合板磁电转换效应理论研究

磁致伸缩和压电层合材料通过磁致伸缩和压电效应的乘积可以获得大的磁电效应.通过材料的力学本构方程，建立了对称磁电层合板磁电耦合的静态力学模型；采用ANSYS 80多物理场有限元分析软件，对层合结构的磁电转化效应进行了数值计算，并与理论计算值进行了对比.研究结果表明：磁致伸缩/压电的厚度比增加使磁电电压系数增大；所推导的磁电电压系数公式的计算值与等效电路模型推导的公式计算值符合很好；有限元数值计算结果介于两种模型的计算结果之间. 关键词： 磁电效应 层合板 本构方程 有限元分析     

磁致伸缩/压电叠层复合材料磁-机-电耦合系数分析

分析和推导了磁致伸缩/压电叠层复合材料的机-电耦合系数、磁-机耦合系数及磁-电耦合系数与磁致伸缩层和压电层性能参数及几何参数之间的关系.进一步分析表明,叠层复合材料低频时的磁电电压系数正比于磁-电耦合系数,谐振时的磁电电压系数正比于磁-电耦合系数与机械品质因素的乘积;磁电电压系数还与复合结构的本征阻抗有关,本征阻抗越大磁电电压系数越大.通过性能差异较大的Terfenol-D和FeNi基弹性合金分别与压电材料PZT5-H和PZT8相互组合构成复合材料的比较分析,进一步阐明了磁电复合材料磁-电耦合系数和机械品 关键词： 磁电效应 磁-机-电耦合系数 磁致伸缩材料 压电材料     

过渡族元素掺杂BaTiO3-Tb1-xDyxFe2-y层状复合材料中的磁电效应

用溶胶-凝胶法制备1.0%mol Mn,Cr,Co掺杂 BaTiO₃(BTO)粉体,在1350℃下烧结成多晶陶瓷样品.X射线衍射和差示扫描量热分析表明,室温下掺杂BaTiO₃具有四方钙钛矿结构;居里点和相变潜热随Cr,Mn,Co掺杂逐渐降低.将掺杂BaTiO₃与Tb_1-xDy_xFe_2-y(TDF)胶合制成双层磁电复合材料,并研究了Cr:BTO-TDF,Mn∶BTO-TDF,Co:BTO-TDF层状复合材料中的磁电效应.实验表明,在340×80 A·m^-1偏置磁场下, Cr:BTO-TDF的横向磁电电压系数达到最大值586 mV·cm^-1·(80 A·m^-1)^-1.在400×80 A·m^-1偏置磁场下,Mn∶BTO-TDF和Co:BTO-TDF的横向磁电电压系数的最大值分别为480 mV·cm^-1·(80 A·m^-1)^-1和445mV·cm^-1·(80 A·m^-1)^-1.研究表明掺杂BaTiO₃-TDF层状复合材料中具有较强的磁电耦合.作为无铅压电材料,掺杂BaTiO₃制备的磁电效应器件颇具应用前景. 关键词： 磁电效应 双层复合材料 3')" href="#">掺杂BaTiO₃ 1-xDy_xFe_2-y')" href="#">Tb_1-xDy_xFe_2-y     

Dielectric, ferroelectric, magnetic and magnetoelectric properties of PMN-PT based ME composites

A systematic study of magnetoelectric composite system (x) CoFe₂O₄+(1−x) Pb(Mg_1/3Nb_2/3)_0.67Ti_0.33O₃ with x=0, 0.15, 0.30, 0.45 and 1 was carried out. The lattice strain was calculated using Williamson and Hall equation, which depends on the content of constituent phases in composites. The microstructure was studied using scanning electron microscopy. The ferroelectric transition temperature was independent of the content of individual phases, suggesting that the ferroelectric character is maintained in the composite. Observed P–E and M–H loops indicate that the multiferroic nature of magnetoelectric ceramics is dependent on the content of individual phases. The variation of magnetostriction with dc magnetic field was studied. The maximum magnetoelectric voltage coefficient of 7.2 mV/cm Oe is obtained for the synthesized composites. The magnetoelectric measurements are well explained with magnetostrictive behavior of the magnetic phase.     

Magnetoelectric effect in composites of magnet,metal-cap,and piezoceramic

We report on the magnetoelectric (ME) effect in three-phase magnet-metal-cap-piezoceramic composites of a thickness-polarized Pb(Zr,Ti)O₃ disk bonded between two truncated conical brass caps and two thickness-magnetized NdFeB magnets along the thickness direction. The effect originated from the product of the magnetic attractive–repellent effect in the magnets and the amplified piezoelectric effect in the cap-disk assembly. The composites exhibited a ME voltage coefficient α_V of ∼2.6 mV/Oe in the non-resonance frequency range of 0.1–10 kHz with good voltage-field linearity in the field range of 10^-3–10 Oe, besides an enhanced α_V of 167.4 mV/Oe at a resonance frequency of 14.4 kHz. Compared to conventional two-phase and three-phase magnetostrictive material-contained ME composites, these composites possessed two distinct benefits of higher property-tailorable flexibility and requiring no external dc bias magnetic field to enable an obvious α_V. PACS 77.84.-S; 75.80.+q; 77.84.Dy; 77.65.-j; 85.80.Jm     

Magnetoelectric effect in laminates of polymer-based pseudo-1–3 (Tb0.3Dy0.7)0.5Pr0.5Fe1.55 composite and?0.3Pb(Mg1/3Nb2/3)O3–0.7PbTiO3 single crystal

We report an extrinsic magnetoelectric effect in composite laminates made by sandwiching one thickness-polarized 0.7Pb(Mg_1/3Nb_2/3)O₃–0.3PbTiO₃ (PMN–PT) piezoelectric single crystal plate between two length-magnetized, polymer-based pseudo-1–3 (Tb_0.3Dy_0.7)_0.5Pr_0.5Fe_1.55 magnetostrictive composite plates. The laminates exhibit large magnetoelectric voltage coefficients (α _V ) of ∼0.17 V/Oe with a flat response for frequencies in excess of 40 kHz and of ∼2.97 V/Oe at the natural resonance frequency of ∼65 kHz. The distinct advantages of the laminates include high magnetic field sensitivity, low Joule heating loss, wide operating bandwidth, and low cost.     

偏置电压对磁致伸缩/压电层合换能结构磁电性能影响

分析和测试了偏置电压调整时PZT5/Terfenol-D/PZT8层合换能结构磁电性能. 提出了一种磁致伸缩/压电层合磁电换能结构的一阶谐振频率控制方法. 通过改变压电驱动层的直流电压对磁电层合结构的预应变进行改变, 从而调整谐振频率. 分析偏置电压、 应变、 弹性模量、 谐振频率和谐振磁电电压系数之间关系. 分析表明: 在较小应变情况下, 控制电压几乎可以线性调节谐振频率, 而层合结构谐振磁电电压系数几乎与偏置电压无关. 实验研究验证: 理论与实验结果较好吻合. 在-170 V-+170 V的偏置电压时, 谐振频率可以几乎线性调整. 最大频率调整量达到1 kHz, 偏置电压对一阶纵振频率的控制率达到: 2.94 Hz/V. 在偏置磁场为0-225 Oe时, 谐振频率调整量与偏置磁场无关. 偏置磁场会改变谐振磁电电压系数, 在大于178 Oe静态磁场偏置时, 磁电电压系数最大, 达到1.65 V/Oe.     

Enhanced mangnetoelectric voltage in multiferroic particulate Ni0.83Co0.15Cu0.02Fe1.9O4−δ/PbZr0.52Ti0.48O3 composites – dielectric,piezoelectric and magnetic properties

Multiferroic particulate composites of Ni_0.83Co_0.15Cu_0.02Fe_1.9O_4−δ– NCCF and lead zirconate titanate (PZT) were prepared conventional ceramic method. The generic formulae x NCCF + (1−x) PZT where x = 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6 mole fractions. The presence of two phases in multiferroic was confirmed with XRD technique. The dielectric constant and loss tangent were studied as a function of frequency (100 Hz to 1 M Hz) and temperature (30–500 °C). The piezoelectric coefficient d₃₃ were also studied on these particulate composites. The hysteresis behaviour was studied to understand the magnetic properties such as saturation magnetization (Ms) and magnetic moment (μ_B). The static magnetoelectric (ME) voltage coefficient was measured as a function of dc magnetic bias field. A high value of ME output (3151 mV/Oe.cm) was obtained in the composite containing 50% highly magnetostrictive ferrite component NCCF – 50% highly piezoelectric ferroelectric component PZT. These multiferroic particulate composites are used as phase shifters, magnetic sensors, cables etc.     

Fe掺杂量对双层复合结构BaTi1-zFezO3+δ-Tb1-xDyxFe2-y中磁电耦合的影响

采用溶胶凝胶方法制备了Fe掺杂钛酸钡多晶系列陶瓷BaTi_1-zFe_zO_3+δ(0.005≤z≤0.02) (BTFO).X射线衍射实验显示,所制备的BTFO的结构仍然为四方相钙钛矿.差热分析表明,该BTFO样品的铁电-顺电转变温度及相变潜热随掺杂量z的增加而下降.将该BTFO极化后与Tb_1-xDy_xF 关键词： 磁电耦合 掺杂效应 掺杂钛酸钡     

Study of dielectric and magnetic properties of PbZr0.52Ti0.48O3-Mn0.3Co0.6Zn0.4Fe1.7O4 composite

Results of detailed structural, dielectric, magnetic and magnetoelectric studies of (x)PbZr_0.52Ti_0.48O₃-(1−x)Mn_0.3Co_0.6Zn_0.4Fe_1.7O₄ composites where x=65, 70, 75 and 80 are shown in this work. Manganese substituted cobalt ferrites are known to exhibit large strain derivative (dx/dH) and on the other hand substitution of Zn in pure cobalt ferrite is known to enhance its permeability μ and permittivity ε. The choice of ferrite as Mn, Zn simultaneously substituted cobalt ferrite (MCZFO) is made keeping in view that for good magnetoelectric (ME) voltage coefficient the magnetostrictive constituent phase of the composite should have large strain derivative (dx/dH) along with large permittivity and permeability. It is shown here that although the dielectric transition temperature changes significantly with change in the mole ratio of the two component phases, magnetic transition temperature (much less compared to the bulk cobalt ferrite) is relatively non-responsive to the changing molar ratio of the two component phases. In the vicinity of the magnetic transition temperature we observed an anomaly in tan δ vs. T plots, which indicates a possible magnetoelectric coupling in the samples. Magnetoelectric voltage coefficient (α_E) has been measured using static magnetoelectric method. Highest magnetoelectric voltage coefficient (α_E=0.312 mV/cmOe) is obtained for sample 80:20 at H_DC=1000 Oe.     

Resonance magnetoelectric effect without a bias field in a piezoelectric langatate-hysteretic ferromagnet monolithic structure

The frequency, field, temperature, and amplitude characteristics of the direct magnetoelectric effect are studied in a planar monolithic structure consisting of a piezoelectric langatate crystal and a layer of electrolytic nickel. A relation between the magnetic and magnetoelectric properties of the structure is demonstrated, which explains the effects observed in structures with hysteretic layers. At the planar acoustic resonance frequency of the structure (about 70 kHz), the effect amounting to 23 V/(Oe cm) in the absence of a bias field is discovered. In the temperature interval 150–400 K, the amount of the effect changes nearly twofold, the resonance frequency changes by about 1%, and the Q factor on cooling rises to about 8 × 10³. The field sensitivity of the structure is on the order of 1 V/Oe, which makes it possible to detect magnetic fields with an amplitude down to ～10^?6 Oe.     

磁致伸缩/压电层叠复合材料磁电效应分析

采用有限元分析软件COMSOL5.0建立了三维悬臂梁模型,分析了磁致伸缩/压电/磁致伸缩叠层复合材料的磁电系数α_(ME),并就几何参数对复合结构磁电系数的影响进行了优化分析.首先,利用稳态求解器研究了磁电层状复合结构内部的应力、应变、位移以及电势分布情况,利用瞬态求解分析了磁电复合结构各变量动态分布规律;其次,应用小信号频域分析研究了该结构的谐振频率以及在不同偏置磁场对输出电压的影响,结果表明,随着直流偏置磁场的增加,输出电压逐渐减小.改变复合材料不同层的厚度,分析了磁电层与压电层厚度比t_m/t_p对磁电系数的影响,结果表明,随着厚度比增加,α_(ME)逐渐增大,其增加速率逐渐减小;最后,分析了磁电系数α_(ME)随复合结构面积、长宽比的变化情况.分析表明,α_(ME)随磁电复合结构面积的增加逐渐增加,其增加速率逐渐减小;当磁电复合结构面积恒定时,其磁电系数随长宽比L/W增加表现出先增加后减小的趋势,存在最优值.