Electrochemical behavior and the rate of general corrosion of NiAl intermetallic compound in the unbuffered sodium chloride solutions

Highly reproducible Tafel anodic and cathodic plots were obtained on NiAl intermetallic compound in the neutral and nearly neutral unbuffered NaCl solutions. The corrosion potentials and corrosion current densities were determined by the Tafel extrapolation technique at various pH values and concentrations of NaCl. The corrosion current density and Tafel slopes were determined by fitting the equation for the corrosion current density, which involves both anodic and cathodic reactions, to the experimental anodic and cathodic polarization curves in the pre-Tafel region of polarization curves. The results obtained by two methods are in good agreement.     

A simple model for slow strain rate and constant load corrosion tests of austenitic stainless steel in acid aqueous solution containing sodium chloride

The present paper is concerned with the modelling of both slow strain rate and constant load tests of austenitic steels in acid solutions containing sodium chloride at room temperature. In a phenomenological approach, based upon thermodynamics of continuum solids and elasto-viscoplastic damage, besides the classical variables (stress, total strain, and plastic strain), an additional scalar variable related to the damage induced by stress corrosion is introduced. An evolution law depending on the corrosive environment parameters is proposed for this damage variable. The model prediction is compared with curves obtained experimentally considering different strain rates in different solutions showing a good agreement.     

The effect of temperature on the corrosion of steel in concrete. Part 1: Simulated polarization resistance tests and model development

The effect of temperature on the corrosion rate of steel corrosion in concrete is investigated through simulated polarization resistance experiments. The simulated experiments are based on the numerical solution of the Laplace’s equation with predefined boundary conditions of the problem and have been designed to establish independent correlations among corrosion rate, temperature, kinetic parameters, concrete resistivity and limiting current density for a wide range of possible anode/cathode (A/C) distributions on the reinforcement. The results, which successfully capture the resistance and diffusion control mechanisms of corrosion as well as the effect of temperature on the kinetic parameters and concrete/pore solution properties, have been used to develop a closed-form regression model for the prediction of the corrosion rate of steel in concrete.     

Kinetic modelling of the attenuation of carbon steel canister corrosion due to diffusive transport through corrosion product layers

This work models the attenuation of the corrosion of carbon steel canisters due to the influence of diffusive transport through the corrosion product - a growing film of magnetite. The model makes use of an algorithm based on the analytical solution of 1D diffusion equations for the movement of Fe²⁺, H₂, H₂O and OH⁻ through this magnetite film.     

The effect of temperature on the corrosion of steel in concrete. Part 2: Model verification and parametric study

A comprehensive model for predicting the corrosion rate of steel in concrete has been developed using the concept of simulated polarization resistance experiments. This model is developed by carrying out a nonlinear regression analysis on data obtained from numerical experiments that are based on the solution of Laplace’s equation in a domain determined by the polarized length of the rebar. This part of the paper provides a comprehensive verification of the developed model and illustrates the application of the model to investigate the coupled effects of parameters affecting corrosion of steel in concrete. The results of the verification study show that the model predictions are in good agreement with the experimental data.     

Multifractal modelling of electrochemical noise in corrosion of carbon steel

Electrochemical noise analysis of corroding surfaces provides useful information regarding the temporal changes in material degradation, corrosion mechanisms and condition monitoring. In this study, we analyzed the electrochemical potential and current noise originating from the corrosion of carbon steel (ASTM A106) in distilled water using multifractal analysis. The empirical Legendre spectrum and large deviation singularity spectrum are determined for the electrochemical noise at different stages of corrosion. A wavelet-based multifractal model is introduced to describe the multiscaling behaviour.     

Electrochemical corrosion performance of Cr and Al alloy steels using a J55 carbon steel as base alloy

Cr- and Al-modified alloy steels using J55 carbon steel as base alloy were produced by remelting in a vacuum. Their corrosion resistance was estimated by open circuit potential, electrochemical polarisation measurements and immersion tests in a 3.5 wt.% NaCl solution. The modified alloy steels exhibit higher corrosion resistance with a more positive open circuit potential, lower corrosion current density and higher impedance than J55 steel. The immersion tests showed that the new alloy steels have lower corrosion rates and smaller pitting depth than J55 steel and a low-Cr steel.     

Thermodynamic, electrochemical and quantum chemical investigation of some Schiff bases as corrosion inhibitors for mild steel in hydrochloric acid solutions

The corrosion inhibition of mild steel in 1.0 M HCl solution by four Schiff bases was investigated using weight loss and electrochemical measurements and quantum chemical calculations. All compounds showed >90% inhibition efficiency at their optimum concentrations. The activation energy (E_a) of corrosion and other thermodynamic parameters were calculated to elaborate the mechanism of corrosion inhibition. The adsorption of the inhibitors on the mild steel surface follows Langmuir isotherm model. Polarization studies indicated that all studied inhibitors are mixed type. The computed quantum chemical properties viz., electron affinity (EA) and molecular band gap (ΔE_MBG) show good correlation with experimental inhibition efficiencies.     

Corrosion modelling of austenitic steel in molten sulphate deposit

A new explanation of a corrosion test of austenitic steel AISI 316 by Hendry and Lees is presented. A mechanism controlled by the complex alkali iron trisulphate formation reaction is proposed. An attempt has been made to evaluate the equilibrium constant and the rate coefficient of the controlling reaction on basis of the Hendry and Lees experiment. The model describes quantitatively the rate of steel sample corrosion in molten sulphates at 600 °C and its slow down to almost zero as a consequence of the chemical equilibrium state instead of resolidification of the molten sulphates solution.     

Experimental and theoretical study on the inhibition performance of triazole compounds for mild steel corrosion

A relationship between quantum chemical parameters for three triazole compounds and their inhibition ability was studied using electrochemical measurements (potentiodynamic polarization and EIS), molecular dynamic method and quantum chemical calculations. Electrochemical measurements results revealed that the inhibition efficiencies increased with the concentration of inhibitors. The molecular dynamic method results showed that the higher interaction potential between the inhibitor and metal surface, the higher the inhibition efficiency. The quantum chemical calculation results showed that the triazole ring is the active site in these inhibitors and they can absorb on Fe surface by donating electrons to Fe d-orbital.     

Effects of temperature and aggressive anions on corrosion of carbon steel in potable water

Experiments on the corrosion of carbon steel in three kinds of artificial potable waters containing different concentrations of aggressive anions, Cl⁻ and , open to air in the temperature range from 5 to 60 °C were conducted using weight loss and electrochemical methods. The corrosion rate increased in proportion to the concentration of aggressive anions and with increasing temperature. At lower concentrations of aggressive anions and temperatures, the corrosion rate was lower and the corrosion potential was higher, at intermediate concentrations and temperatures, the corrosion rate increased logarithmically with decreasing potential, and at higher concentrations and temperatures, the corrosion rate was higher and the potential was lower. The corrosion behavior in potable water can be determined by the balance between inhibitive action of oxygen (passive film formation) and aggressive action of Cl⁻ and ions.     

Sodium phthalamates as corrosion inhibitors for carbon steel in aqueous hydrochloric acid solution

Three compounds of N-alkyl-sodium phthalamates were synthesized and tested as corrosion inhibitors for carbon steel in 0.5 M aqueous hydrochloric acid. Tests showed that inhibitor efficiencies were related to aliphatic chain length and dependent on concentration. N-1-n-tetradecyl-sodium phthalamate displayed moderate efficiency against uniform corrosion, 42–86% at 25 °C and 25–60% at 40 °C. Tests indicated that compounds behave as mixed type inhibitors where molecular adsorption on steel followed Langmuir isotherm, whereas thermodynamic suggested that a physisorption process occurred. XPS analysis confirmed film formation on surface, where Fe⁺² complexes and Fe⁺² chelates with phthalamates prevented steel from further corrosion.     

Theoretical investigation of corrosion inhibition effect of imidazole and its derivatives on mild steel using cluster model

Interaction energies of imidazole and its seven derivatives on the surface of mild steel were calculated via a cluster model by using quantum chemical calculations at density functional theory level. The mild steel surface and its adsorption sites were considered as some clusters taken from two-layered (0 0 1) planes and the quantum chemical calculations which were carried out consist of adsorption of the inhibitor molecules on the surface of these clusters. It is shown that 90% of inhibition variations of the imidazole derivatives are described by considering perpendicular interaction of the inhibitors by iron atom in the mild steel unit cell.     

Experimental and molecular dynamics studies on corrosion inhibition of mild steel by 2-amino-5-phenyl-1,3,4-thiadiazole

The corrosion inhibition of mild steel in 0.5 M H₂SO₄ and 1.0 M HCl by 2-amino-5-phenyl-1,3,4-thiadiazole (APT) has been studied using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements. The results show that the inhibition efficiency increases with the increase of APT concentration in both acids, and the higher inhibition efficiency is obtained in 0.5 M H₂SO₄. The adsorption of APT molecules on the steel surface obeys Langmuir adsorption isotherm in both acids, and occurs spontaneously. The molecular dynamics method has also been used to simulate the adsorption of ATP molecule and solvent ions on the iron surface. The results show that with the adsorption of sulfate ions the Fe + anion + APT system has the higher negative interaction energy comparing to the case of the adsorption of chloride ions.     

An investigation of benzimidazole derivative as corrosion inhibitor for mild steel in different concentration HCl solutions

The influences of a benzimidazole derivative, namely 1,8-bis (1-chlorobenzyl-benzimidazolyl) -octane (CBO) on the corrosion behaviour of mild steel in different concentration HCl solutions were studied by weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) measurements and SEM observations. The results showed that CBO acted as an excellent and a mixed-type inhibitor via strongly chemical adsorption onto mild steel surface to suppress simultaneously both anodic and cathodic processes according to the Langmuir adsorption isotherm. Inhibition efficiencies increased with increasing concentration of inhibitor and HCl. An inhibition mechanism was proposed in terms of strongly adsorption of inhibitor molecules on mild steel surface.     

Influence of ultrasound on pitting corrosion and crevice corrosion of SUS304 stainless steel in chloride sodium aqueous solution

The change of polarization curves and surface morphologies of SUS304 stainless steel was investigated in 3.5 mass% NaCl solution with or without the application of ultrasound (US). As the result, both the pitting corrosion and the crevice corrosion were largely suppressed by the application of US. The reason is attributed to the decrease in the concentration of hydrogen and chloride ions in pits or in the crevice by removing the corrosion product and stirring the liquid there.     

Investigation on some Schiff bases as corrosion inhibitors for mild steel

In the present work, the effect of some newly synthesized Schiff bases containing sulphur nitrogen as heteroatom was investigated on mild steel corrosion in acidic media. Electrochemical studies of the mild steel samples were performed in an aerated solution of 0.1 M HCl + dimethyl sulphoxide (DMS) as co-solvent. DMS is also behaving as a corrosion inhibitor for mild steel. At low inhibitor concentration and short immersion time one can see only the inhibitive effect of DMS as anodic inhibitor for mild steel. At high concentration and long immersion time inhibition efficiencies are increased and cathodic inhibition is observed.     

A critical crevice solution and IR drop crevice corrosion model

This paper presents a mechanistic model describing the dynamic concentration profiles and corrosion currents within a corroding crevice. The model couples anodic areas within the crevice with cathodic areas on the bold surface. It also incorporates the combined effects of the chemical attack of the crevice solution along with the electric potential changes in the crevice and over the bold surface. The mathematical model is used to predict the dynamic crevice pH profile and remarkable agreement with experimental data is evident. Three crevice corrosion phases were determined that correspond to the evolution of the electric potential drop within the crevice.     

Tryptamine as a corrosion inhibitor of mild steel in hydrochloric acid solution

The inhibitor effect of tryptamine on the corrosion of mild steel in 0.5 M hydrochloric acid at 30 °C was investigated using linear polarization, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The inhibition efficiency increases with an increase in concentration of tryptamine. At 500 ppm tryptamine the inhibition efficiency calculated by these techniques is around 97%. Cathodic and anodic polarization curves of mild steel in the presence of different concentrations of tryptamine at 30 °C reveal that it is a mixed type inhibitor. Tryptamine follows Langmuir adsorption with adsorption free energy of −35.07 kJ mol⁻¹.