A photochemical model of Titan's atmosphere and ionosphere

A global-mean model of coupled neutral and ion chemistry on Titan has been developed. Unlike the previous coupled models, the model involves ambipolar diffusion and escape of ions, hydrodynamic escape of light species, and calculates the H₂ and CO densities near the surface that were assigned in some previous models. We tried to reduce the numbers of species and reactions in the model and remove all species and reactions that weakly affect the observed species. Hydrocarbon chemistry is extended to C₁₂H₁₀ for neutrals and C₁₀H⁺₁₁ for ions but does not include PAHs. The model involves 415 reactions of 83 neutrals and 33 ions, effects of magnetospheric electrons, protons, and cosmic rays. UV absorption by Titan's haze was calculated using the Huygens observations and a code for the aggregate particles. Hydrocarbon, nitrile, and ion chemistries are strongly coupled on Titan, and attempt to calculate them separately (e.g., in models of ionospheric composition) may result in significant error. The model densities of various species are typically in good agreement with the observations except vertical profiles in the stratosphere that are steeper than the CIRS limb data. (A model with eddy diffusion that facilitates fitting to the CIRS limb data is considered as well.) The CO densities are supported by the O⁺ flux from Saturn's magnetosphere. The ionosphere includes a peak at 80 km formed by the cosmic rays, steplike layers at 500-700 and 700-900 km and a peak at 1060 km (SZA = 60°). Nighttime densities of major ions agree with the INMS data. Ion chemistry dominates in the production of bicyclic aromatic hydrocarbons above 600 km. The model estimates of heavy positive and negative ions are in reasonable agreement with the Cassini results. The major haze production is in the reactions C₆H + C₄H₂, C₃N + C₄H₂, and condensation of hydrocarbons below 100 km. Overall, precipitation rate of the photochemical products is equal to 4-7 kg cm⁻² Byr⁻¹ (50-90 m Byr⁻¹ while the global-mean depth of the organic sediments is ∼3 m). Escape rates of methane and hydrogen are 2.9 and 1.4 kg cm⁻² Byr⁻¹, respectively. The model does not support the low C/N ratio observed by the Huygens ACP in Titan's haze.     

The water cycle in the general circulation model of the martian atmosphere

Within the numerical general-circulation model of the Martian atmosphere MAOAM (Martian Atmosphere: Observation and Modeling), we have developed the water cycle block, which is an essential component of modern general circulation models of the Martian atmosphere. The MAOAM model has a spectral dynamic core and successfully predicts the temperature regime on Mars through the use of physical parameterizations typical of both terrestrial and Martian models. We have achieved stable computation for three Martian years, while maintaining a conservative advection scheme taking into account the water–ice phase transitions, water exchange between the atmosphere and surface, and corrections for the vertical velocities of ice particles due to sedimentation. The studies show a strong dependence of the amount of water that is actively involved in the water cycle on the initial data, model temperatures, and the mechanism of water exchange between the atmosphere and the surface. The general pattern and seasonal asymmetry of the water cycle depends on the size of ice particles, the albedo, and the thermal inertia of the planet’s surface. One of the modeling tasks, which results from a comparison of the model data with those of the TES experiment on board Mars Global Surveyor, is the increase in the total mass of water vapor in the model in the aphelion season and decrease in the mass of water ice clouds at the poles. The surface evaporation scheme, which takes into account the turbulent rise of water vapor, on the one hand, leads to the most complete evaporation of ice from the surface in the summer season in the northern hemisphere and, on the other hand, supersaturates the atmosphere with ice due to the vigorous evaporation, which leads to worse consistency between the amount of the precipitated atmospheric ice and the experimental data. The full evaporation of ice from the surface increases the model sensitivity to the size of the polar cap; therefore, the increase in the latter leads to better results. The use of a more accurate dust scenario changes the model temperatures, which also strongly affects the water cycle.     

Physical parameters of the martian atmosphere

The following physical parameters have been computed from 0 to 200 km altitude; (1) pressure, (2) density (3), speed of sound, (4) density, (5) number density, (6) mean free path, (7) viscosity, (8) pressure scale, (9) mean particle velocity, (10) collisional frequency and (11) columnar mass.The Viking measurements have been used as input data. A critical comparison of the computed pressures and densities, is given, useful for future explorations.     

Electron reflectometry in the martian atmosphere

The technique of electron reflectometry, a method for remote estimation of planetary magnetic fields, is expanded from its original use of mapping crustal magnetic fields at the Moon to achieving the same purpose at Mars, where the presence of a substantial atmosphere complicates matters considerably. The motion of solar wind electrons, incident on the martian atmosphere, is considered in detail, taking account of the following effects: the electrons' helical paths around the magnetic field lines to which they are bound, the magnetic mirror force they experience due to converging field lines in the vicinity of crustal magnetic anomalies, their acceleration/deceleration by electrostatic potentials, their interactions with thermal plasma, their drifts due to magnetic field line curvature and perpendicular electric fields and their scattering off, and loss of energy through a number of different processes to, atmospheric neutrals. A theoretical framework is thus developed for modeling electron pitch angle distributions expected when a spacecraft is on a magnetic field line which is connected to both the martian crust and the interplanetary magnetic field. This framework, along with measured pitch angle distributions from the Mars Global Surveyor (MGS) Magnetometer/Electron Reflectometer (MAG/ER) experiment, can be used to remotely measure crustal magnetic field magnitudes and atmospheric neutral densities at ∼180 km above the martian datum, as well as estimate average parallel electric fields between 200 and 400 km altitude. Detailed analysis and full results, concerning the crustal magnetic field and upper thermospheric density of Mars, are left to two companion papers.     

Convective instability in the martian middle atmosphere

Dry convective instabilities in Mars’s middle atmosphere are detected and mapped using temperature retrievals from Mars Climate Sounder observations spanning 1.5 martian years. The instabilities are moderately frequent in the winter extratropics. The frequency and strength of middle atmospheric convective instability in the northern extratropics is significantly higher in MY 28 than in MY 29. This may have coupled with changes to the northern hemisphere mid-latitude and tropical middle atmospheric temperatures and contributed to the development of the 2007 global dust storm. We interpret these instabilities to be the result of gravity waves saturating within regions of low stability created by the thermal tides. Gravity wave saturation in the winter extratropics has been proposed to provide the momentum lacking in general circulation models to produce the strong dynamically-maintained temperature maximum at 1-2 Pa over the winter pole, so these observations could be a partial control on modeling experiments.     

Fractionated martian atmosphere in the nakhlites?

Abstract— Considerable evidence points to a martian origin of the SNC meteorites. Noble gas isotopic compositions have been measured in most SNC meteorites. The ¹²⁹Xe/¹³²Xe vs. ⁸⁴Kr/¹³²Xe ratios in Chassigny, most shergottites, and lithology C of EETA 79001 define a linear array. This array is thought to be a mixing line between martian mantle and martian atmosphere. One of the SNC meteorites, Nakhla, contains a leachable component that has an elevated ¹²⁹Xe/¹³²Xe ratio relative to its ⁸⁴Kr/¹³²Xe ratio when compared to this approximately linear array. The leachable component probably consists in part of iddingsite, an alteration product produced by interaction of olivine with aqueous fluid at temperatures lower than 150 °C. The elevated Xe isotopic ratio may represent a distinct reservoir in the martian crust or mantle. More plausibly, it is elementally fractionated martian atmosphere. Formation of sediments fractionates the noble gases in the correct direction. The range of sediment/atmosphere fractionation factors is consistent with the elevated ¹²⁹Xe/¹³²Xe component in Nakhla being contained in iddingsite, a low temperature weathering product. The crystallization age of Nakhla is 1.3 Ga. Its low-shock state suggests that it was ejected from near the surface of Mars. As liquid water is required for the formation of iddingsite, these observations provide further evidence for the near surface existence of aqueous fluids on Mars more recently than 1.3 Ga.     

Isotopic fractionation of methane in the martian atmosphere

The existence of methane in the martian atmosphere may be an indicator of subsurface life. Biological processes are known to fractionate the common isotopologues of methane, and hence measuring these isotopic ratios may yield constraints on the nature of the methane source. Any measurement of the isotopic ratios of atmospheric methane must consider the additional fractionation due to photochemistry in order to quantify the isotopic ratios of the source. Using a one-dimensional photochemical model, we find that photochemistry has a small (4.5‰) contribution to δ¹³C(CH₄) but has a large (114‰) contribution to δD(CH₄). Confirmation of these fractionation values will require additional laboratory data on key model inputs, particularly the ultraviolet absorption cross sections of ¹³CH₄ and kinetic rate coefficients for the reactions of ¹³CH₄ and CH₃D with OH and O(¹D) at pressures and temperatures relevant to the martian atmosphere.     

Low-order dynamical behavior in the martian atmosphere: Diagnosis of general circulation model results

The hypothesis of a low dimensional martian climate attractor is investigated by the application of the proper orthogonal decomposition (POD) to a simulation of martian atmospheric circulation using the UK Mars general circulation model (UK-MGCM). In this article we focus on a time series of the interval between autumn and winter in the northern hemisphere, when baroclinic activity is intense. The POD is a statistical technique that allows the attribution of total energy (TE) to particular structures embedded in the UK-MGCM time-evolving circulation. These structures are called empirical orthogonal functions (EOFs). Ordering the EOFs according to their associated energy content, we were able to determine the necessary number to account for a chosen amount of atmospheric TE. We show that for Mars a large fraction of TE is explained by just a few EOFs (with 90% TE in 23 EOFs), which apparently support the initial hypothesis. We also show that the resulting EOFs represent classical types of atmospheric motion, such as thermal tides and transient waves. Thus, POD is shown to be an efficient method for the identification of different classes of atmospheric modes. It also provides insight into the non-linear interaction of these modes.     

Oxygen and carbon isotope ratios in the martian atmosphere

Oxygen and carbon isotope ratios in the martian CO₂ are key values to study evolution of volatiles on Mars. The major problems in spectroscopic determinations of these ratios on Mars are uncertainties associated with: (1) equivalent widths of the observed absorption lines, (2) line strengths in spectroscopic databases, and (3) thermal structure of the martian atmosphere during the observation. We have made special efforts to reduce all these uncertainties. We observed Mars using the Fourier Transform Spectrometer at the Canada–France–Hawaii Telescope. While the oxygen and carbon isotope ratios on Mars were byproducts in the previous observations, our observation was specifically aimed at these isotope ratios. We covered a range of 6022 to 6308 cm⁻¹ with the highest resolving power of ν/δν=3.5×10⁵ and a signal-to-noise ratio of 180 in the middle of the spectrum. The chosen spectral range involves 475 lines of the main isotope, 184 lines of ¹³CO₂, 181 lines of CO¹⁸O, and 119 lines of CO¹⁷O. (Lines with strengths exceeding 10⁻²⁷ cm at 218 K are considered here.) Due to the high spectral resolution, most of the lines are not blended. Uncertainties of retrieved isotope abundances are in inverse proportion to resolving power, signal-to-noise ratio, and square root of the number of lines. Laboratory studies of the CO₂ isotope spectra in the range of our observation achieved an accuracy of 1% in the line strengths. Detailed observations of temperature profiles using MGS/TES and data on temperature variations with local time from two GCMs are used to simulate each absorption line at various heights in each part of the instrument field of view and then sum up the results. Thermal radiation of Mars' surface and atmosphere is negligible in the chosen spectral range, and this reduces errors associated with uncertainties in the thermal structure on Mars. Using a combination of all these factors, the highest accuracy has been achieved in measuring the CO₂ isotope ratios: ¹³C/¹²C = 0.978 ± 0.020 and ¹⁸O/¹⁶O = 1.018 ± 0.018 times the terrestrial standards. Heavy isotopes in the atmosphere are enriched by nonthermal escape and sputtering, and depleted by fractionation with solid-phase reservoirs. The retrieved ratios show that isotope fractionation between CO₂ and oxygen and carbon reservoirs in the solid phase is almost balanced by nonthermal escape and sputtering of O and C from Mars.     

The photochemical model of Titan’s atmosphere and ionosphere: A version without hydrodynamic escape

There are observational and theoretical evidences both in favor of and against hydrodynamic escape (HDE) on Titan, and the problem remains unsolved. A test presented here for a static thermosphere does not support HDE on Titan and Triton but favors HDE on Pluto. Cooling of the atmosphere by the HCN rotational lines is limited by rotational relaxation above 1100 km and self-absorption below 900 km on Titan. HDE can affect the structure and composition of the atmosphere and its evolution. Hydrocarbon, nitrile, and ion chemistries are strongly coupled on Titan, and attempts to calculate them separately may result in significant errors. Here we apply our photochemical model of Titan’s atmosphere and ionosphere to the case of no hydrodynamic escape. Our model is still the only after-Cassini self-consistent model of coupled neutral and ion chemistry. The lack of HDE is a distinct possibility, and comparing models with and without HDE is of practical interest. The mean difference between the models and the neutral and ion compositions observed by INMS are somewhat better for the model with HDE. A reaction of NH₂ with H₂CN suggested by Yelle et al. (2009) reduces but does not remove a significant difference between the ammonia abundances in the models and INMS observations. Losses of methane and nitrogen and production and deposition to the surface of hydrocarbons and nitriles are evaluated in the model, along with lifetimes and evolutionary aspects.     

Methane adsorption on a martian soil analog: An abiogenic explanation for methane variability in the martian atmosphere

Recent observations suggest methane in the martian atmosphere is variable on short spatial and temporal scales. However, to explain the variability by loss reactions requires production rates much larger than expected. Here, we report results of laboratory studies of methane adsorption onto JSC-Mars-1, a martian soil simulant, and suggest that this process could explain the observations. Uptake coefficient (γ) values were measured as a function of temperature using a high-vacuum Knudsen cell able to simulate martian temperature and pressure conditions. Values of γ were measured from 115 to 135 K, and the data were extrapolated to higher temperatures with more relevance to Mars. Adsorptive uptake was found to increase at lower temperatures and larger methane partial pressures. Although only sub-monolayer methane surface coverage is likely to exist under martian conditions, a very large mineral surface area is available for adsorption as atmospheric methane can diffuse meters into the regolith. As a result, significant methane may be temporarily lost to the regolith on a seasonal time scale. As this weak adsorption is fully reversible, methane will be re-released into the atmosphere when surface and subsurface temperatures rise and so no net loss of methane occurs. Heterogeneous interaction of methane with martian soil grains is the only process proposed thus far which contains both rapid methane loss and rapid methane production mechanisms and is thus fully consistent with the reported variability of methane on Mars.     

Forced waves in the martian atmosphere from MGS TES nadir data

We have analyzed the temperature retrievals from Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) nadir spectra to yield latitude-height resolved maps of various atmospheric forced wave modes as a function of season for a full Mars year. Among the isolated wave modes is the zonal mean, time mean temperature, which we used to derive zonal mean zonal winds and stationary wave quasi-geostrophic indices of refraction, diagnostic of their propagation. The diurnal Kelvin wave was isolated in the data, with results roughly consistent with models (Wilson and Hamilton, 1996, J. Atmos. Sci. 33, 1290-1326). The s = 1 and s = 2 stationary waves were found to have significant amplitude in ducts extending up the winter polar jets, while the s = 3 stationary wave was found to be confined to near the surface. The s = 1 stationary wave was found to have little phase tilt with height during northern winter, but significant westward phase tilt with height in the southern winter. This indicates that the wave carries heat poleward, slightly more than that found in Barnes et al. (1996; J. Geophys. Res. 101, 12,753-12,776). The s = 1 stationary wave is likely the dominant mechanism for eddy meridional heat transport for the southern winter. We noted that the phase of the s = 2 stationary wave is nearly constant with time, but that the s = 1 stationary wave moved 90° of longitude from fall to winter and back in spring in the North. While interannual variability is not yet addressed, overall, these results provide the first comprehensive benchmark for forced waves in Mars’s atmosphere against which future atmospheric models of Mars can be compared.     

Traveling waves in the martian atmosphere from MGS TES Nadir data

We have characterized the annual behavior of martian atmospheric traveling waves in the MGS TES data set from the first two martian years of mapping. There is a high degree of repeatability between the two years. They are dominated by strong low zonal wavenumber waves with high amplitudes near the polar jets, strongest in late northern fall and early northern winter. The m=1 waves have amplitudes up to about 20 K, are vertically extended, and occasionally extend even into the tropics. Periods for m=1 range from 2.5 to 30 sols. Much weaker waves were identified in the south, with amplitudes less than about 3.5 K. Traveling waves with m=2 and m=3 are also seen, but their amplitudes are typically limited to less than 4 K, and are generally more confined near the surface. In the north, they are more evident in fall and spring rather than winter solstice, which is clearly dominated by m=1 waves. Some evidence of storm tracks has been identified in the data, with accentuated weather-related temperature perturbations near longitudes 200° to 320° E for both the southern and northern hemispheres near latitude ±65° at the surface. Some evidence was also found for a sharpening of longitudinal gradients into what may be frontal systems. EP flux divergences show the waves extracting energy from the zonal mean winds. When the m=1 waves were strongest, decelerations of the zonal jet of order 30 m/(s sol) were measured. Above 1 scale height, the waves extract energy from the jet predominately through barotropic processes, but their character is overall mixed barotropic/baroclinic. Inertial instabilities may exist at altitude on the equatorward flanks of the polar jets, and marginal stability extends through to the tropics. This may explain the coordination of the tropical behavior of the waves with that centered along the polar jet, consistent with the ideas expressed in Wilson et al. (2002, Geophys. Res. Lett. 29, #1684) and similar to those in Barnes et al. (1993, J. Geophys. Res. 98, 3125-3148). Throughout the year, there exist large regions with the meridional gradient of PV less than zero, but they are strongest near winter solstice. Poleward of the winter jet, the regions of instability reach the surface, equatorward they do not. These regions, satisfying a necessary criterion for instability, likely explain the genesis of the waves, and perhaps also their bimodal character between surface (faster waves) and altitude (slow m=1 waves).     

Oxygen isotopes in the martian atmosphere: Implications for the evolution of volatiles

Non-thermal escape of oxygen by recombination of exospheric O₂⁺ combined with diffusive separation of gases at lower altitude provides a mechanism through which the Martian atmosphere may be enriched in ¹⁸O relative to ¹⁶O. Measurement of the abundance of ¹⁸O relative to ¹⁶O together with a determination of the turbopause may be used to develop important constraints on the history of Martian volatiles. Models for the interpretation of these data are developed and discussed in light of present information.     

The Ashima/MIT Mars GCM and argon in the martian atmosphere

We investigate the ability of modern general circulation models (GCMs) to simulate transport in the martian atmosphere using measurements of argon as a proxy for the transport processes. Argon provides the simplest measure of transport as it is a noble gas with no sinks or sources on seasonal timescales. Variations in argon result solely from ‘freeze distillation’, as the atmosphere condenses at the winter poles, and from atmospheric transport. Comparison of all previously published models when rescaled to a common definition of the argon enhancement factor (EF) suggest that models generally do a poor job in predicting the peak enhancement in southern winter over the winter pole – the time when the capability of the model transport approaches are most severely tested. Despite observed peak EF values of ～6, previously published model predictions peaked at EF values of only 2–3. We introduce a new GCM that provides a better treatment of mass conservation within the dynamical core, includes more sophisticated tracer transport approaches, and utilizes a cube–sphere grid structure thus avoiding the grid-point convergence problem at the pole that exists for most current Mars GCMs. We describe this model – the Ashima Research/Massachusetts Institute of Technology Mars General Circulation Model (Ashima/MIT Mars GCM) and use it to demonstrate the significant sensitivity of peak EF to the choices of transport approach for both tracers and heat. We obtain a peak EF of 4.75 which, while over 50% higher than any prior model, remains well short of the observed value. We show that the polar EF value in winter is primarily determined by the competition between two processes: (1) mean meridional import of lower-latitude air not enriched in argon and (2) the leakage of enriched argon out of the polar column by eddies in the lowest atmospheric levels. We suggest possibilities for improving GCM representation of the CO₂ cycle and the general circulation that may further improve the simulation of the argon cycle. We conclude that current GCMs may be insufficient for detailed simulation of transport-sensitive problems like the water cycle and potentially also the dust cycle.     

Detectability of minor constituents in the martian atmosphere by infrared and submillimeter spectroscopy

Spectroscopic remote sensing in the infrared and (sub)millimeter range is a powerful technique that is well suited for detecting minor species in planetary atmospheres (Planet Space Sci. 43(1995) 1485). Yet, only a handful of molecules in the Mars atmosphere (CO₂, CO and H₂O along with their isotopic species, O_3, and more recently H₂O₂ and CH₄) have been detected so far by this method. New high performance spectroscopic instruments will become available in the future in the infrared and (sub)millimeter range, for observations from the ground (infrared spectrometers on 8 m class telescopes, large millimeter and submillimeter interferometers) and from space, in particular the Planetary Fourier Spectrometer (PFS) aboard Mars Express (MEx), and the Heterodyne Instrument for the Far-Infrared (HIFI) aboard the Herschel Space Observatory (HSO). In this paper we will present results of a study that determines detectability of minor species in the atmosphere of Mars, taking into account the expected performance of the above spectroscopic instruments. In the near future, a new determination of the D/H value is expected with the PFS, especially during times of maximum H₂O abundance in the martian atmosphere. PFS is also expected to place constraints on the abundance of several minor species (H₂O₂,CH₄,CH₂O, SO₂, H₂S, OCS, HCl) above any local outgassing sources, the hot spots. It will be possible to obtain complementary information on some minor species (O₃,H₂O₂, CH₄) from ground-based infrared spectrometers on large telescopes. In the more distant future, HIFI will be ideally suited for measuring the isotopic ratios with unprecedented accuracy. Moreover, it should be able to observe O₂, which has not yet been detected spectroscopically in the IR/submm range, as well as H₂O₂. HIFI should also provide upper limits for several species that have not yet been detected (HCl, NH₃, PH₃) in the atmosphere of Mars. Some species (SO, SO₂,H₂S, OCS, CH₂O) that may be observable from the ground could be searched for with present single-dish antennae and arrays, and in the future with the Atacama Large Millimeter Array (ALMA) submillimeter interferometer.     

Metastable methane clathrate particles as a source of methane to the martian atmosphere

The observations of methane made by the PFS instrument onboard Mars Express exhibit a definite correlation between methane mixing ratio, water vapor mixing ratio, and cloud optical depth. The recent data obtained from ground-based telescopes seem to confirm the correlation between methane and water vapor. In order to explain this correlation, we suggest that the source of gaseous methane is atmospheric, rather than at the solid surface of the planet, and that this source may consist of metastable submicronic particles of methane clathrate hydrate continuously released to the atmosphere from one or several clathrate layers at depth, according to the phenomenon of “anomalous preservation” evidenced in the laboratory. These particles, lifted up to middle atmospheric levels due to their small size, and therefore filling the whole atmosphere, serve as condensation nuclei for water vapor. The observed correlation between methane and water vapor mixing ratios could be the signature of the decomposition of the clathrate crystals by condensation-sublimation processes related to cloud activity. Under the effect of water condensation on crystal walls, metastability could be broken and particles be eroded, resulting in a subsequent irreversible release of methane to the gas phase. Using PFS data, and according to our hypothesis, the lifetime of gaseous methane is estimated to be smaller than an upper limit of 6 ± 3 months, much smaller than the lifetime of 300 yr calculated from atmospheric chemical models. The reason why methane has a short lifetime might be the occurrence of heterogeneous chemical decomposition of methane in the subsurface, where it is known since Viking biology experiments that oxidants efficiently decompose organic matter. If true, it is shown by using existing models of H₂O₂ penetration in the regolith that methane could prevent H₂O₂ from penetrating in the subsurface, and further oxidizing the soil, at depths larger than a few millimeters. The present source of methane clathrate, acting over the last few hundred thousand or million years, could have given rise to the thin CO₂-ice layer covering the permanent water ice south polar cap. The hypothesis proposed in this paper requires, to be validated, a number of laboratory experiments studying the stability of methane clathrates in martian atmospheric conditions, and the kinetics and amplitude of clathrate particle erosion in presence of condensing water vapor. Detailed future observations of methane, and associated modeling, will allow to more accurately quantify the production rate of methane clathrate, its temporal variability at seasonal scale, and possibly to locate the source(s) of clathrates at the surface.     

The O2 nightglow in the martian atmosphere by SPICAM onboard of Mars-Express

We present observations of the O₂(a¹Δ_g) nightglow at 1.27 μm on Mars using the SPICAM IR spectrometer onboard of the Mars Express orbiter. In contrast to the O₂(a¹Δ_g) dayglow that results from the ozone photodissociation, the O₂(a¹Δ_g) nightglow is a product of the recombination of O atoms formed by CO₂ photolysis on the dayside at altitudes higher than 80 km and transported downward above the winter pole by the Hadley circulation. The first detections of the O₂(a¹Δ_g) nightglow in 2010 indicate that it is about two order of magnitude less intense than the dayglow (Bertaux, J.-L., Gondet, B., Bibring, J.-P., Montmessin, F., Lefèvre, F. [2010]. Bull. Am. Astron. Soc. 42, 1040; Clancy et al. [2010]. Bull. Am. Astron. Soc. 42, 1041). SPICAM IR sounds the martian atmosphere in the near-IR range (1–1.7 μm) with the spectral resolution of 3.5 cm^?1 in nadir, limb and solar occultation modes. In 2010 the vertical profiles of the O₂(a¹Δ_g) nightside emission have been obtained near the South Pole at latitudes of 82–83°S for two sequences of observations: L_s = 111–120° and L_s = 152–165°. The altitude of the emission maximum varied from 45 km on L_s = 111–120° to 38–49 km on L_s = 152–165°. Averaged vertically integrated intensity of the emission at these latitudes has shown an increase from 0.22 to 0.35 MR. Those values of total vertical emission rate are consistent with the OMEGA observations on Mars-Express in 2010. The estimated density of oxygen atoms at altitudes from 50 to 65 km varies from 1.5 × 10¹¹ to 2.5 × 10¹¹ cm^?3. Comparison with the LMD general circulation model with photochemistry (Lefèvre, F., Lebonnois, S., Montmessin, F., Forget, F. [2004]. J. Geophys. Res. 109, E07004; Lefèvre et al. [2008]. Nature 454, 971–975) shows that the model reproduces fairly well the O₂(a¹Δ_g) emission layer observed by SPICAM when the large field of view (>20 km on the limb) of the instrument is taken into account.     

MAWD observations revisited: seasonal behavior of water vapor in the martian atmosphere

Viking/MAWD experiment and more recent MGC/TES observations have provided to date the most detailed information about the annual atmospheric water cycle on Mars. Their data agree in major details but still reveal some disagreements. These disagreements turn out to be most significant in the perihelion season and especially during the major dust storms. We consider the potential influence of aerosol scattering on 1.38 μm water retrieval under various types of observation geometry. In order to obtain new retrievals of water vapor abundance from MAWD data, we apply radiative transfer calculations. The resulting seasonal and spatial distribution of water turns out to be more consistent with TES results, implying a remarkable stability of the martian seasonal water cycle. Mapping data corresponding to particular seasons reveals a distinct wave structure in the global distribution of the water column. We interpret it as a manifestation of a strong control over the water cycle on Mars from the atmospheric circulation.