共查询到16条相似文献,搜索用时 343 毫秒
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采用搅拌实验装置,研究环丁砜溶液及不同配比的环丁砜-D IPA复合溶液对烟道气中二氧化碳的吸收和解吸性能,揭示了吸收容量与酸碱度、时间之间的内在联系,并对CO2初始逸出温度、试液再生温度、试液再生率、再生pH下降率进行了细致记录分析。实验结果表明,环丁砜-D IPA复合溶液配比为0.4∶0.6时,吸收效果最佳,吸收量约为0.08 mol,再生温度最低为102.5℃,再生率最高为91.64%。实验结果还表明,环丁砜-D IPA复合体系之间存在弱的正交互作用。 相似文献
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芳烃生产中,抽提剂环丁砜在较高温度会发生劣化导致pH的下降,产生酸性物质,并影响抽提效果,随着劣化程度的加深对抽提设备的腐蚀也越加严重,也会影响芳烃产品的生产效率和质量。为解决这一问题,一般采用加入热稳剂的方法减缓环丁砜的劣化情况,增加芳烃抽提剂环丁砜的使用寿命。本文对环丁砜受热劣化的情况进行了考查,选用了三种不同有机胺化合物及其复配物作为减缓环丁砜劣化程度的热稳剂,利用检测热分解产生的SO2量来衡量劣化程度和热稳效果。实验结果发现复配热稳剂效果最佳,其中以乙醇胺与不饱和多元胺A的复配比例在2:1,添加量在400mg/L时的热稳效果最好,热稳率超过最好单一热稳剂10%以上。 相似文献
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萃取剂环丁砜的纯度对萃取精馏有重要影响,过低的环丁砜纯度不但会影响到产品质量还会造成生产波动使生产不能连续稳定进行。本文提供了一种新的劣质化环丁砜提纯方法,通过在劣质化的环丁砜中加入一定比例蒸馏水进行蒸馏,蒸馏水与环丁砜比例为7:3,控制终馏点温度100~101℃可以得到纯度超过98%的环丁砜。 相似文献
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介绍了环丁砜的合成与精制生产工艺技术进展,并通过国内外技术与市场应用分析,指出了环丁砜产品发展方向。 相似文献
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Chang Gyun Kim William P. Clarke David Lockington 《Korean Journal of Chemical Engineering》1999,16(2):215-219
Groundwater samples directly beneath a waste disposal site have been shown to contain a higher concentration of sulfolane
and a relatively low concentration of thiolane. The sulfolane is a source compound of thiolane, a reduced form of sulfolane.
In subsequent analyses of groundwater samples, these compounds have been detected from all of the monitoring wells in the
study area. Since these compounds are present together in an aquifer, a possible competition, that can happen in such a system,
has been investigated. Thiolane is a nonpolar heterocyclic organic compound whereas sulfolane is a weakly acidic dipolar solvent.
As expected, thiolane adsorbs more strongly onto clay than sulfolane in a single solute system. For regression of bisolute
system using Matlab to obtain Q (maximum number of moles of solute adsorbed per unit weight of adsorbent), k1 (constants related to the energy of adsorption for sulfolane), and k2 (constants related to the energy of adsorption for thiolane), the k1 value (sulfolane) is smaller than the k2 value (thiolane) which reflects that thiolane is more strongly adsorbed than sulfolane. This is strongly consistent with
the result obtained from single solute system. The Q for the sulfolane and combined data is the same that indicates that the
sulfolane data is dominantly fitted because the concentrations of sulfolane are much greater than those of thiolane in the
experiments. In combined data regression, the suppression of sulfolane adsorption on clay was also observed by the presence
of thiolane. 相似文献
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将UOP660气相色谱法测定水或烃或环丁砜的方法进行了改进,采用开口管柱代替原方法中的填充柱,色谱操作条件也作了相应的改变。改进的方法与原方法比较具有基线稳定,水的干扰峰不拖尾、水峰和环丁砜的峰完全分开等优点。该新方法准确度高,重复性好,完全能满足生产的需要,具有较大的实用性。 相似文献
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Measurements of kinetics rates of CO2 in aqueous solutions of methyldiethanolamine (MDEA), piperazine (PZ), and mixtures of (MDEA + PZ), (PZ + sulfolane) and (MDEA + sulfolane) were carried out using the stopped flow technique, and reported in terms of pseudo-first-order rate constants (k0). When possible, the second-order reaction rate constants (k2) were regressed from the data. Experiments were performed over new concentration ranges of (10–60), (200–800), (200–800, 10–40), (10–40, 10–200), and (200–800, 10–200) mol/m3 for the above-mentioned five systems, respectively, and at temperatures varying from (298.15–313.15 K). When sulfolane was added to the amine solution, pseudo-first-order rate constants in the mixed solvents were higher than in aqueous MDEA and PZ solutions at all temperatures. The kinetic rates were highest at 298.15 K and decreased at higher temperatures for aqueous (MDEA + sulfolane) solutions but increased with temperature for aqueous (PZ + sulfolane) systems. Reaction orders for both PZ and MDEA were practically one at all sulfolane concentrations and temperatures. The base catalysis mechanism was used to regress very well data for aqueous MDEA and (MDEA + sulfolane + water) and the termolecular mechanism was used for (PZ + sulfolane + water) system. Both the zwitterion and termolecular models were able to fit the experimental data for the aqueous PZ system well. Finally, the termolecular and a hybrid model based on the combination of the Zwitterion and base catalysis mechanisms were able to successfully correlate the experimental data for the mixed aqueous (MDEA + PZ) systems. 相似文献