小新厂铜的氧化富集现象

表生条件下铜的迁移是众所周知的现象.一般情况下,氧化淋虑带显著贫铜,而次生硫化带则富铜.小新厂铜矿氧化富集现象较明显.该矿床未见流化富集带,原生矿体薄而贫,但由于氧化富集可形成比原生矿较富厚的矿体,从而提高了矿床的利用价值.本文试图通过分析控制氧化带发育的诸因素,探讨铜的迁移途径和氧化富集部位,以为在该类矿床中寻找较富的矿体参考.     

关于斑岩铜矿的找矿

斑岩型铜矿是当前重要的找铜矿类型之一。８０年代以来,我国斑岩型铜矿找矿进展不大,是因为我国斑岩型铜矿品位较贫,制约着找矿研究和开发。斑岩型富铜矿的找矿,主要应研究斑岩型铜矿与其它类型铜矿床构成成矿系列的主导因素,区域成矿物质来源,多期岩浆成矿作用,多种富集成矿作用等;研究影响斑岩型铜矿氧化带次生富集带发育的因素等,并指出青海南部玉树—扎多—乌丽一带是我国寻找斑岩型富铜矿的最有利地区。     

云南景谷宋家坡铜矿床成岩成矿的Sm-Nd和^40Ar-^39Ar同位素年龄

云南景谷宋家坡铜矿床产于英安斑岩体及其围岩中三叠统火山岩地层中，矿床蚀变发育，原生矿化相对较弱，次生硫化物富集。本文报道了对该矿床的蚀变和矿化英安斑岩进行的Sm-Nd法和^40Ar-^39Ar快中子活化法同位素地质年龄测定结果。同位素年代学研究表明，Sm-Nd法和^40Ar-^39Ar快中子活化法给出了英安斑岩和原生铜矿床的形成年龄，时代为印支期中三叠世；而且^40Ar-^39Ar快中子活化法给出的年代学信息较多，其高温阶段坪年龄大致与特提斯洋闭合时间一致，而较低温阶段的表面年龄反映了燕山期甚至喜马拉雅期构造运动对成矿的改造。总之，宋家坡铜矿床的赋矿英安斑岩及区域中三叠世火山岩的成岩作用相对于特提斯洋的闭合及陆块碰撞俯冲在时间上基本同时。成矿与成岩关系密切、时间相近，且成矿经历了多期作用，原生矿化属斑岩型铜矿化，后期受盆地热卤水淋滤富集和表生氧化改造。     

Eh—pH相图在玉龙铜矿床次生富集作用研究中的应用

玉龙铜矿床表生成矿过程中成矿物质主要呈碳酸盐络合物的形成迁移。以孔雀石,蓝铜矿组合为主的次生富集带是在碱性,氧化的环境中形成的,所以它们相对靠近氧化带的上部及碳酸盐岩发育的地区分布。以赤铜矿,自然铜组合为主的次生氧化物富集带形成环境为弱氧化－还原,它们常靠近氧化带的中,下部分布。表生成矿环境中ＣＯ２含量高是玉龙铜矿床氧化带中黑铜矿极不发育的根本原因。『     

刚果（金）如瓦西铜-钴矿床表生成矿过程及其勘探意义

中非成矿带刚果（金）如瓦西（Ruashi）铜-钴矿床经历了表生成矿作用,但其研究薄弱。在野外地质调查、室内矿物学观察和矿山生产勘探的基础上,对如瓦西铜-钴矿床的表生分带组构与次生富集规律进行研究。结果表明,该矿床原生矿体由黄铜矿、斑铜矿、硫铜钴矿等含铜硫化物矿物组成,矿石品位铜在1%~2%、钴在0.1%~0.3%范围内。矿床在近地表发生表生氧化作用后,上部形成了氧化带,可进一步划分为3个亚带：（1）完全氧化亚带;（2）淋滤亚带;（3）次生氧化物富集亚带。上部完全氧化亚带发育富钴氧化物堆积体“矿帽”（钴品位在1%~3%,部分可达12%）,淋滤亚带几乎不含铜、钴金属矿物,次生富集氧化物亚带由孔雀石、硅孔雀石、蓝铜矿、胆矾、水胆矾等氧化物矿物和碳酸盐矿物组成,矿石品位铜在5%~10%、钴在0.8%~1.0%范围内,相对原生矿石富集了3~5倍。下部为次生硫化物富集带,出现蓝铜矿、辉铜矿等次生硫化物矿物,矿石品位铜在3%~5%、钴在0.3%~0.8%范围内,相对原生硫化矿富集了1~3倍。综合分析认为,如瓦西铜-钴矿床表生成矿作用受岩石地层、地质构造和地下水等因素的控制,次生富集作用明显提高了矿石品位和矿床开发价值,形成了氧化物富铜-钴矿、硫化物富铜-钴矿和碳酸盐岩接触带附近的氧化物富铜矿及黑色富钴矿等类型的高-特高品位矿体。经勘探验证,在矿区深边部新揭露高品位矿石资源量256万吨,平均品位铜为3.68%、钴为0.44%,可采储量143万吨,平均品位铜为3.53%、钴为0.32%。该研究可为矿区及区域同类型矿山硫化矿演化成氧化矿的表生富集过程及深边部找矿预测提供科学依据。     

辽宁抚顺地区金矿的次生富集特征及成因分析

抚顺地区金矿氧化带中金的次生富集特征十分明显,可划分为氧化淋滤贫化带、次生富集带、原生带三个带。次生富集带中金的富集原因主要为原生金矿中的金矿物在氧化环境下溶解或形成胶体金,迁移至有利于汇集的还原环境时发生沉淀并富集。     

四川盐源模范村喜马拉雅期斑岩铜矿床地质特征

文章通过野外地质观察,结合岩矿鉴定、化学分析、稳定同位素测定、稀土元素分析、成岩成矿同位素年龄测定、包裹体测温及成分等的研究,表明四川盐源模范村矿床具有典型斑岩铜矿的特征。成岩的多期次构成复式岩体,断裂构造控制的隐爆碎裂岩筒为成矿提供了通道和沉积场所。多期次成矿,特别是次生富集作用形成了中型规模的Ⅰ号矿体,影响次生富集带发育的F7断裂带起了重要作用。模范村矿床确系典型的斑岩铜矿,但又具独自的成矿特征。     

东天山土屋特大型斑岩铜矿成矿地质特征与矿床对比

土屋特大型斑岩铜矿位于东天山吐鲁番－哈密陆块南部边缘岛弧环境中。多期岩浆活动和矿化是铜金属超常堆集的主要因素。海底火山活动和热泉沸腾逸散造就了铜金属的预富集（矿源层），闪长玢岩和斜长花岗斑岩的侵位和叠加矿化使铜金属进一步富化和最终成矿，以细碧角斑质为主的火山岩喷发于潮坪－滨海环境，闪长玢岩、斜长花岗斑岩形成于较强的氧化环境；强还原示踪矿物黄铁矿含量较少。矿石的低品位、矿石的结构构造、蚀变特征以及矿石建造具典型斑岩矿床特征；矿石高品位、矿床形成较低温度及大量硅化蚀变又表现为某些热液矿床特征（次火山岩热液）。典型斑岩铜矿床、次火山热液矿床、土屋铜矿床对比，土屋铜矿床矿床类型仍不失为斑岩型铜矿，并具有自身特征。     

哈萨克斯坦科翁腊德斑岩型铜矿地质特征与成矿模式

哈萨克斯坦巴尔喀什成矿带科翁腊德斑岩型铜矿床从发现至今已经走过了70年的历程, 它是发育在陆缘弧环境的典型超大型斑岩型矿床, 具有花岗闪长岩型斑岩铜矿成因模式。矿床围岩蚀变与矿石矿物组合的垂直和水平分带明显, 氧化带和次生硫化物富集带矿石品位高, 易开采。矿床整体属于浅部成矿, 受环状构造控制, 次生石英岩和泥化等蚀变与矿床的关系最为密切。目前该矿床已开发殆尽, 前景堪忧。      

西藏班公湖-怒江成矿带上的碰撞后铜矿床

地处藏北高原的班公湖-怒江铜矿带是继藏东的玉龙斑岩铜矿带和藏南的冈底斯斑岩铜矿带之后,在青藏高原上发现的第三条铜矿带。与前两条斑岩铜矿带不同的是,班公湖-怒江铜矿带的铜矿床类型具有多样性,包括:1多龙、雄梅斑岩型铜金矿床;2尕尔穷-嘎拉勒斑岩-矽卡岩型铜金矿床;3拨拉扎斑岩型铜钼矿床;4舍索矽卡岩型铜(铅锌)多金属矿床。不同类型铜矿床的成矿时代集中在120~90 Ma之间,约30 Ma间隔内。文章通过沉积岩岩相学、火成岩岩石地球化学以及锆石U-Pb与辉钼矿Re-Os同位素年代学的综合研究,指出班公湖-怒江中特提斯洋盆的闭合时间为早白垩世初(140~130 Ma之间),班公湖-怒江成矿带上的铜矿床都形成于碰撞后造山环境。该成矿带与铜矿化有关的侵入岩主要为花岗闪长(斑)岩和石英闪长(玢)岩,在岩石地球化学上,富集大离子亲石元素(Rb、Th、U、Ba、K、Pb),亏损高场强元素(Nb、Ta、Ti),显示出俯冲组分对岩浆生成过程产生的重要影响,与碰撞后岩浆作用特征相吻合。除了班公湖-怒江铜矿带外,青藏高原上的另外两条斑岩铜矿带(即藏东的玉龙斑岩铜矿带和藏南的冈底斯斑岩铜矿带),也是形成于洋盆闭合之后的造山带碰撞后环境,因此,青藏高原可以说是地球上碰撞后铜矿床的天堂。     

The geochemistry of gossans associated with Sarcheshmeh porphyry copper deposit,Rafsanjan, Kerman,Iran: Implications for exploration and the environment

The Sarcheshmeh copper deposit is one of the world's largest Oligo-Miocene porphyry copper deposits in a continental arc setting with a well developed supergene sulfide zone, covered mainly by a hematitic gossan. Supergene oxidation and leaching, have developed a chalcocite enrichment blanket averaging 1.99% Cu, more than twice that of hypogene zone (0.89% Cu). The mature gossans overlying the Sarcheshmeh porphyry copper ores contain abundant hematite with variable amounts of goethite and jarosite, whereas immature gossans consist of iron-oxides, malachite, azurite and chrysocolla. In mature gossans, Au, Mo and Ag give significant anomalies much higher than the background concentrations. However, Cu has been leached in mature gossans and gives values close or even less than the normal or crustal content (< 36.7 ppm). Immature gossans are enriched in Cu (160.3 ppm), Zn (826.7 ppm), and Pb (88.6 ppm). Jarosite- and goethite-bearing gossans may have developed over the pyritic shell of most Iranian porphyry copper deposits with pyrite–chalcopyrite ratios greater than 10 and therefore, do not necessarily indicate a promising sulfide-enriched ore (Kader and Ijo). Hematite-bearing gossans overlying nonreactive alteration halos with pyrite–chalcopyrite ratios about 1.5 and quartz stringers have significant supergene sulfide ores (Sarcheshmeh and Miduk). The copper grade in supergene sulfide zone of Sarcheshmeh copper deposit ranges from 0.78% in propylitized rocks to 3.4% in sericitized volcanic rocks, corresponding to the increasing chalcopyrite–pyrite or chalcocite–pyrite ratios from 0.3 to 3, respectively. Immature gossans with dominant malachite and chrysocolla associated with jarosite and goethite give the most weakly developed enrichment zone, as at God-e-Kolvari. The average anomalous values of Au (59.6 ppb), Mo (42.5 ppm) and Ag (2.6 ppm) in mature gossans associated with the Sarcheshmeh copper mine may be a criterion that provides a significant exploration target for regional metallogenic blind porphyry ore districts in central Iranian volcano–plutonic continental arc settings. Drilling for new porphyry ores should be targeted where hematitic gossans are well developed. The ongoing gossan formation may result in natural acidic rock drainage (ARD).     

云南维西大宝山铜矿地质特征及矿石中Ag与Cu关系探讨

云南维西大宝山铜矿区位于青藏高原东南缘,哀牢山-金沙江构造带西北部雪龙山成矿带中,是典型的中低温热液矿床。矿区主要包括望香台及滑石板矿段,根据矿床、矿体特征及详尽的镜下观察,将矿石类型划分为氧化矿、硫化矿及混合矿。氧化矿主要包括孔雀石及蓝铜矿,多分布在望香台矿段中浅部,是辉铜矿次生氧化富集作用的结果,出露形式多以混合矿产出;硫化矿主要包括辉铜矿及黄铜矿,且独立组成不同的矿物组合类型,分别为望香台矿段、滑石板矿段的主要矿石矿物。不同的矿石组合类型所含矿物种类、矿石结构构造不尽相同。通过对不同样品进行化学分析测试,发现在硫化矿辉铜矿等矿物组合中,Cu品位越高,相应Ag品位越高,存在一定的线性关系;而在硫化矿黄铜矿矿体中,Ag含量与Cu品位无相应关系;混合矿(辉铜矿、孔雀石及蓝铜矿)中此类关系更加显著。此外,辉铜矿、孔雀石、蓝铜矿单矿物矿石及混合矿矿石中含有硫砷铜银矿、深红银矿、雌黄及雄黄等伴生矿物,而黄铜矿中矿物种类较为单一。综合矿区地质特征、矿体分布特征、矿物组合类型认为,矿区中辉铜矿、孔雀石、蓝铜矿等组合类型为含银矿物的主要载体。     

Use of Cu isotopes to distinguish primary and secondary Cu mineralization in the Ca?ariaco Norte porphyry copper deposit, Northern Peru

A significant proportion of the copper in the Ca?ariaco Norte porphyry copper deposit in northern Peru occurs in chalcocite and covellite-rich veins and disseminations that exist from the surface to depths greater than 1?km. The overall range of Cu isotopic ratios of 42 mineral separates from Ca?ariaco varies from ?8.42 to 0.61?‰, with near-surface chalcocite and Fe oxides having isotopically depleted values compared to chalcocite, covellite, and chalcopyrite from deeper levels. The majority (34 of 36) of measured Cu sulfides have a typical hypogene copper isotope composition of δ⁶⁵Cu?=?0.18?±?0.38?‰, with no enriched isotopic signature existing in the Ca?ariaco Norte sulfide data. Thus, the copper isotope data indicate that most of the chalcocite and covellite formed from high-temperature hypogene mineralization processes and that only a minor portion of the deposit is enriched by supergene processes. The nonexistence of an enriched δ⁶⁵Cu reservoir suggest the presence of an undiscovered lateral/exotic Cu occurrence that enriched ⁶⁵Cu that remained in solution during weathering. Regardless of the cause, the comparative analysis of the Cu isotope dataset reveals that little exploration potential for an extensive supergene enrichment blanket exists because the weathering history at Ca?ariaco Norte was not conducive to preservation of enriched Cu at depth beneath the leach cap.     

巴布亚新几内亚奥克泰迪铜金矿床成矿特征和控制因素

巴布亚新几内亚西部Fubilan山奥克泰迪矿床是一个世界级铜金矿床,在大地构造上位于新几内亚造山带的巴布亚褶皱带。该矿床的铜金矿化赋存于Fubilan二长斑岩及其周边的磁铁矿夕卡岩和硫化物夕卡岩中。矿石类型以原生硫化物矿石为主,金属矿物包括磁铁矿、黄铁矿、磁黄铁矿、白铁矿、黄铜矿、斑铜矿等。蚀变类型包括夕卡岩化、钾化、泥化和青盘岩化。矿床氧化次生富集带发育,表生矿石矿物为蓝辉铜矿、辉铜矿、自然铜、铜蓝和银金矿。成矿作用主要受区域构造、侵入杂岩体、Darai组灰岩地层、断裂等因素的控制。根据矿床的主岩、矿石特征、蚀变特征和控矿因素,认为该矿床成因类型属于较为典型的夕卡岩一斑岩型矿床。     

Geology of the High Sulfidation Copper Deposits,Monywa Mine,Myanmar

The 50 km² Monywa copper district lies near the Chindwin River within the northward continuation of the Sunda‐Andaman magmatic arc through western Myanmar. There are four deposits; Sabetaung, Sabetaung South, Kyisintaung, and the much larger Letpadaung 7 km to the southeast. Following exploration drilling which began in 1959, production of copper concentrates from a small open pit started at Sabetaung in 1983. Since 1997, when resources totaled 7 million tonnes contained copper in 2 billion tonnes ore, a heap leach–electro‐winning operation has produced over 400,000 t copper cathode from Sabetaung and Sabetaung South. Ore is hosted by mid‐Miocene andesite or dacite porphyry intrusions, and by early mid‐Miocene sandstone and overlying volcaniclastics including eruptive diatreme facies which the porphyries intrude. District‐wide rhyolite dykes and domes with marginal breccias probably post‐date andesite porphyries in the mine area and lack ore‐grade copper. Host rocks to mineralization are altered to phyllic and advanced argillic hydrothermal assemblages within an outer chlorite zone; hypogene alunite is most abundant at Letpadaung and Kyisintaung. Most mineralization is structurally‐controlled with digenite‐chalcocite in breccia dykes, in steeply dipping NE‐trending sheeted veins, and in stockwork and low‐angle sulfide veins. A high‐grade pipe at Sabetaung grades up to 30% Cu, and much of the ore at Sabetaung South is in a NE‐trending zone of mega‐breccia and stockworked sandstone. The hydrothermal alteration, together with replacement quartz, alunite and barite in breccia dykes and veins, the virtual absence of vein quartz, and the presence of chalcopyrite and bornite only as rare veins and as inclusions within the abundant pyrite, indicate that the deposits are high sulfidation. Regional uplift, resistance to erosion and leaching of the altered and mineralized rocks have resulted in porous limonite‐stained leached caps over 200 m thick forming the Letpadaung and Kyisintaung hills. The barren caps pass abruptly downwards at the water table into the highest grade ore at the top of the supergene enrichment zone, within which copper grade, supergene kaolinite and cubic alunite decrease, and pyrite increases with depth; in contrast, marcasite is mostly shallow. Much of the copper to depths exceeding 200 m below the water table occurs as supergene digenite‐chalcocite and minor covellite. Disseminated chalcocite is mostly near‐surface and hence almost certainly supergene. We infer that during prolonged uplift at all four deposits, oxidation of residual pyrite at the water table generated enough acid to leach all the copper from earlier supergene‐enriched ore; below the water table the resulting acid sulfate solutions partly replaced enargite, covellite, chalcopyrite, bornite and pyrite with supergene chalcocite. Undeformed upward‐fining cross‐bedded conglomerates and sands of the ancestral Chindwin River floodplain overlie the margins of the Sabetaung deposits, form a major aquifer up to 40 m thick, and are a potential host for exotic copper mineralization. A mid‐Miocene pluton is inferred to underlie the Monywa deposits, but the possibility of porphyry‐type mineralization within the district is at best highly speculative.     

Lithogeochemistry of hypogene, supergene and leached cap samples, berg porphyry copper deposit, British Columbia

In this paper we examine the influence of the development of supergene oxide and sulphide zones on the original hypogene geochemical patterns at the Berg deposit, British Columbia.The deposit, in the alpine zone of the Tahtsa Range, was logged (GEOLOG) and sampled in fourteen diamond drill holes along a N—S section and from outcrop where possible. Anomalous populations of major and trace elements were defined using log probability graphs and a sequential extraction (10% hydrochloric acid— ammonium oxalate — potassium chlorate/hydrochloric acid — nitric/perchloric acids) was used to study the distribution of elements between carbonate, oxide, sulphide and silicate phases.Core logs and assays show that primary ore minerals (chalcopyrite—molybdenite) extend from the outer part of the porphyry intrusion into the surrounding hornfels where the best grades of copper are found close to the intrusive contact. Maximum copper grades, however, result from development of a supergene enrichment blanket. Within the hypogene zone, principal lithogeochemical patterns reflect the differences in composition of the hornfels, originally intermediate to basic volcanics, and the intrusion, as well as the introduction of F and trace metals (Cu, Mo, Pb, Zn and Ag). Distribution of Ag is broadly comparable to that of Cu and Mo whereas anomalous Pb and Zn are present as peripheral haloes around the potential ore zones.Emergence of strongly acidic ground water and precipitation of iron oxides, indicate that leaching processes are active. Furthermore, although primary sulphides, associated with both their oxidation products and secondary sulphides, can still be found in surface samples, sequential extractions on drill core clearly indicate vertical redistribution of copper between oxide, carbonate and sulphide phases. Using ratios of metal concentrations to TiO₂, the surface concentrations of trace metals can be compared with those at depth and the relative amount of enrichment or depletion can be quantified. In highly leached sites the absolute concentrations of Cu, Mn and Zn are low which is reflected in TiO₂ ratios of <1. However, Mo, Pb and Ag are enriched at the same sites (TiO₂ ratios >1). In areas where physical erosion exceeds leaching (topographic lows) primary sulphides co-exist with secondary sulphide and oxide minerals. Here Cu, Mo, Pb, Zn, Mn and Ag are enriched. Fluorine is relatively unaffected by the leaching process. It would appear signature for a cale alkaline Cu and Mo porphyry deposit in an area where outcrop was intensely leached.     

新生代构造抬升与斑岩型铜、金矿床的次生富集作用

以中国西南"三江"(澜沧江-金沙江-怒江)地区西范坪铜矿床、玉龙铜矿床和北衙金矿床为例说明了该地区斑岩型铜或金矿床的次生分带特征,概述了青藏高原、滇川西部高原的隆升,以及新生代构造抬升对地表化学风化的影响;指出西范坪铜矿床、玉龙铜矿床和北衙金矿床等明显经历过表生成矿作用的典型斑岩型矿床均位于青藏高原强烈隆升区的边部或边缘地带,新生代构造抬升对这些地段气候、地形的影响大大促进了地表的化学风化作用;认为新生代强烈隆升可能是导致这些矿床发生强烈次生富集作用的深层次原因.     

Hydrothermal Alteration and Cu-Au Mineralization at Nena High Sulfidation-type Deposit, Frieda River, Papua New Guinea

Abstract. The Nena Cu‐Au deposit, located in the Frieda River mineral district of northwestern mainland Papua New Guinea, is a composite structurally‐lithologically controlled high sulfidation (HS) system. Its hydrothermal alteration and Cu‐Au mineralization are presented in this paper. Initially propylitized andesitic volcanics veined by epithermal quartz were pervasively superimposed by zoned HS alteration. The zonation grades from vuggy silica core to sulfur‐rich, pyritic silica‐alunite halo followed by pyrophyllite‐dickite‐kaolinite interval and finally to thin illite‐smectite margin, suggesting progressive decrease in temperature and increase in pH. This zonation is enveloped by chlorite‐epidote‐calcite‐gypsum alteration. The acid altered rocks were then invaded by multiple phases of pyrite, subsequently crosscut by quartz, vein alunite and barite. Then sequential deposition of bladed covellite, enargite, luzonite and stibioluzonite occurred from the NW to the SE portions of the deposit, forming a zonation suggestive of progressive decrease in temperature, sulfur fugacity and sulfidation stage. Most ore mineralization occurs in the vuggy silica core. Gold mineralization commenced from the transition of enargite to luzonite and continued throughout the stibioluzonite stage. Associated with gold deposition are Au‐rich pyrite, tennantite‐tetrahedrite, chalcopyrite‐bornite, native tellurium, electrum, calaverite, bismuthinite and galena. Native sulfur occupied the remaining cavities and represents the waning stage of the hydrothermal system. Fluid inclusions studies distinguished magmatic (>300–350d?C, 9–15 wt% NaCl equiv.) and meteoric (<150–200d?C, 1–2 wt% NaCl equiv.) fluids (Holzberger et al., 1996). Temperatures and salinities of fluid inclusions from barite associated with Cu sulfides show a general decrease from NW (330d?C, 9–15 wt% NaCl equiv.) to SE (172d?C, 10 wt% NaCl equiv.) parts of the deposit, indicating gradual entrainment of ground water (Hitchman and Espi, 1997). Interaction of magmatic fluids with meteoric water accompanied by changes in temperature, salinity, acidity and oxidation state of the resultant fluids is interpreted to have been the main cause of metal precipitation. Finally, supergene processes generated Au zone with an underlying chalcocite‐covellite‐digenite blanket over the primary sulfides at depth. Gold occurs as lattice constituent in scorodite, limonite‐goethite and jarosite. Chalcocite is more abundant and widespread than other Cu sulfides. Acidic fluids deposited powdery alunite and kaolinite, vein alunite and amorphous silica. Weakly secondary biotite‐quartz altered porphyry located below the known HS Cu‐Au deposit contains chalcopyrite‐bornite and is overprinted by quartz‐alunite‐pyro‐phyllite‐pyrite assemblage. This feature indicates close temporal, spatial and genetic relation between the two deposit types.     

川西稻城地区竹鸡顶铜矿床花岗细晶岩的特征及其成矿意义

竹鸡顶铜矿是中国西南＂三江＂多金属成矿带的典型铜矿床,矿体主要产于花岗细晶岩体内,目前已圈定3个规模较大的含铜矿花岗细晶岩体,铜矿最高品位达11.42%。花岗细晶岩体微量元素表现为Rb、Th、U等低场强元素含量相对富集,而Ba、Nb、Sr、P、Ti则明显亏损,为轻稀土元素富集型,呈现中等负Eu异常的特点。认为该区岩浆可能起源于中下地壳,形成于滞后型火山弧环境。围岩蚀变特征及次生氧化带的垂直分带特征均显示出类斑岩型铜矿床的特征,Cu-Mo综合异常明显较弱,而Pb-Zn综合异常相对较强,推断竹鸡顶铜矿为热液-斑岩型铜矿床,地表处于含矿斑岩体的顶部,主矿体可能还有一定的埋藏深度。矿床除铜富集外,可能还有锌、铋、钴、砷等的富集。