Adhesively-bonded joints and repairs in metallic alloys, polymers and composite materials: Adhesives, adhesion theories and surface pretreatment

In the present paper, the following topics are reviewed in detail: (a) the available adhesives, as well as their recent advances, (b) thermodynamic factors affecting the surface pretreatments including adhesion theories, wettability, surface energy, (c) bonding mechanisms in the adhesive joints, (d) surface pretreatment methods for the adhesively bonded joints, and as well as their recent advances, and (e) combined effects of surface pretreatments and environmental conditions on the joint durability and performance. Surface pretreatment is, perhaps, the most important process step governing the quality of an adhesively bonded joint. An adhesive is defined as a polymeric substance with viscoelastic behavior, capable of holding adherends together by surface attachment to produce a joint with a high shear strength. Adhesive bonding is the most suitable method of joining both for metallic and non-metallic structures where strength, stiffness and fatigue life must be maximized at a minimum weight. Polymeric adhesives may be used to join a large variety of materials combinations including metal-metal, metal-plastic, metal-composite, composite-composite, plastic-plastic, metal-ceramic systems. Wetting and adhesion are also studied in some detail in the present paper since the successful surface pretreatments of the adherends for the short- and long-term durability and performance of the adhesive joints mostly depend on these factors. Wetting of the adherends by the adhesive is critical to the formation of secondary bonds in the adsorption theory. It has been theoretically verified that for complete wetting (i.e., for a contact angle equal to zero), the surface energy of the adhesive must be lower than the surface energy of the adherend. Therefore, the primary objective of a surface pretreatment is to increase the surface energy of the adherend as much as possible. The influence of surface pretreatment and aging conditions on the short- and long-term strength of adhesive bonds should be taken into account for durability design. Some form of substrate pretreatment is always necessary to achieve a satisfactory level of long-term bond strength. In order to improve the performance of adhesive bonds, the adherends surfaces (i.e., metallic or non-metallic) are generally pretretead using the (a) physical, (b) mechanical, (c) chemical, (d) photochemical, (e) thermal, or (e) plasma method. Almost all pretreatment methods do bring some degree of change in surface roughness but mechanical surface pretreatment such as grit-blasting is usually considered as one of the most effective methods to control the desired level of surface roughness and joint strength. Moreover, the overall effect of mechanical surface treatment is not limited to the removal of contamination or to an increase in surface area. This also relates to changes in the surface chemistry of adherends and to inherent drawbacks of surface roughness, such as void formations and reduced wetting. Suitable surface pretreatment increases the bond strength by altering the substrate surface in a number of ways including (a) increasing surface tension by producing a surface free from contaminants (i.e., surface contamination may cause insufficient wetting by the adhesive in the liquid state for the creating of a durable bond) or removal of the weak cohesion layer or of the pollution present at the surface, (b) increasing surface roughness on changing surface chemistry and producing of a macro/microscopically rough surface, (c) production of a fresh stable oxide layer, and (d) introducing suitable chemical composition of the oxide, and (e) introduction of new or an increased number of chemical functions. All these parameters can contribute to an improvement of the wettability and/or of the adhesive properties of the surface.     

Composite-to-metal tubular lap joints: strength and fatigue resistance

The axial strength and fatigue resistance of thick-walled, adhesively bonded E-glass composite-to-aluminum tubular lap joints have been measured for tensile and compressive loadings. The joint specimen bonds a 63 mm OD aluminium tube within each end of a 300 mm long, 6 mm thick E-glass/epoxy tube. Untapered, 12.5 mm thick aluminium adherends were used in all but four of the joint specimens. The aluminum adherends in the remaining four specimens were tapered to a thickness of 1 mm at the inner bond end (the bond end where the aluminum adherend terminates). For all loadings, joint failure initiates at the inner bond end as a crack grows in the adhesive adjacent to the interface. Test results for a tension-tension fatigue loading indicate that fatigue can severely degrade joint performance. Interestingly, measured tensile strength and fatigue resistance for joints with untapered adherends is substantially greater than compressive strength and fatigue resistance.The joint specimen has been analyzed in two different ways: one approach models the adhesive as an uncracked, elastic-perfectly plastic material, while the other approach uses a linear elastic fracture mechanics methodology. Results for the uncracked, elastic-plastic adhesive model indicate that observed bond failure occurs in the region of highest calculated stresses, extensive bond yielding occurs at load levels well below that required to fail the joint, and a tensile peel stress is generated by a compressive joint loading when the aluminum adherends are untapered. This latter result is consistent with the observed joint tensile-compressive strength differential. Results of the linear elastic fracture mechanics analysis of a joint with untapered aluminum adherends are also consistent with the observed differential strength effect since a mode I crack loading is predicted for a compressive joint loading. Calculations and a limited number of tests suggest that it may be possible to selectively control the differential strength effect by tapering the aluminum adherends. The effect of adherend material and thickness on fracture mechanics parameters is also investigated. The paper concludes by examining the applicability of linear elastic fracture mechanics to the joints tested.     

Non-destructive testing of structural composites and adhesively bonded composite joints: pulsed thermography

Structural adhesive bonding is an enabling technology for the implementation of composite assemblies in automotive applications. Therefore, the quality and reliability of the composite bond must be assured. An advanced thermal non-destructive test (NDT) method, pulsed thermography, was evaluated for its capability to assess joint quality in an adhesively bonded composite pickup truck box. Pulsed thermography, used under in-plant, pre-production conditions as would exist during process start-up and optimization trials, was shown effective in determining both the quality of the structural adhesive bonds and the quality of the composite itself. With one exception, NDT showed that bonding was performed correctly, i.e. the bond was continuous and properly placed. The exception was a ‘starved’ bond-line that we believe exists due to poor fixturing at that location. Pulsed thermography illustrated the effects of environmental and mechanical exposure on the bonded joints. Finally, the NDT method was able to show mechanical damage to the composite itself, identifying impact damage not visible to the unaided eye.     

Analysis of composite-to-metal joints with bondline flaws

Stress analysis techniques have been developed for load transfer in metal-to-composite adhesively bonded joints with bondline flaws such as variable bondline thickness and debond in the adhesive layer. Two joint configurations, namely, single-step-lap bonded joint and smoothly tapered scarf joint, have been investigated. The problem is formulated on the basis of the assumptions that both the metal and the composite are under generalized plane stress conditions and that the adhesive acts as a shear spring. Differential equations are obtained for the load transfered from the metallic layer to the composite layer. Numerical results are obtained for the force and stress in the composite layer, the stress in the metal and the stress in the adhesive. The influence of bondline flaw location on the stresses in the adhesive and the adherends has been investigated.     

End geometry and pin-hole effects on axially loaded adhesively bonded composite joints

An experimental investigation was performed to analyze the potential impacts of varying joint region geometries and adhesive filled pin holes on adhesively bonded composite structures. Tapers, especially half-length ones are observed to provide an anticipated progress in single lap joints. Besides, scarf joints with aligned adherends in the same plane exhibited enhanced stiffness and strength in consideration of single lap joints. In terms of the stiffness and strength, thickening of adherends was also found to be impressively efficient on composite single lap joints as well as scarf joints. Contrary to the expectation of that the hardened adhesive previously filled into the holes during adhesion would create a pin effect in load bearing, holey specimens exhibited poor performance and induced degradation in joint quality.     

Thermal and geometrically non-linear stress analyses of an adhesively bonded composite tee joint

Adhesive bonding technique is used successfully for joining the carbon fibre reinforced plastics to metals or composite structures. A good design of adhesive joint with either simple or more complex geometry requires its stress and deformation states to be known for different boundary conditions. In case the adhesive joint is subjected to thermal loads, the thermal and mechanical mismatches of the adhesive and adherends cause thermal stresses. The plate-end conditions may also result in the adhesive joint to undergo large displacements and rotations whereas the adhesive and adherends deform elastically (small strain). In this study, the thermal and geometrically non-linear stress analyses of an adhesively bonded composite tee joint with single support plus an angled reinforcement made of unidirectional CFRPs were carried out using the non-linear finite element method. In the stress analysis, the effects of the large displacements were considered using the small displacement–large displacement theory. The stress states in the plates and the adhesive layer of the tee joint configurations bonded to a rigid base and a composite plate were investigated. An initial uniform temperature distribution was attributed to the adhesive joint for a stress free state, and then variable thermal boundary conditions, i.e. air flows with different velocity and temperature were specified along the outer surfaces of the tee joints. The thermal analysis showed that a non-uniform temperature distribution occurred in the tee joints, and high heat fluxes took place along the free surfaces of the adhesive fillets at the adhesive free ends. Later, the geometrical non-linear thermal-stress analysis of the tee joint was carried out for the final temperature distribution and two edge conditions applied to the edges of the vertical and horizontal plates (HP). High stress concentrations occurred around the rounded adherend corners inside the adhesive fillets at the adhesive free ends, and along the adhesive–composite adherend interfaces due to their thermal–mechanical mismatches. The most critical joint regions were adhesive fillets subjected to high thermal gradients, the middle region of HP, the region of the vertical plate corresponding to the free end of the vertical adhesive layer–left support interface. In addition, the support length had a small effect of reducing the peak stresses at the critical adherend and adhesive locations.     

胶接接头界面理论及其表面处理技术研究进展

胶接是用胶粘剂将被粘物表面连接在一起,形成可承受外载的胶接接头的过程,是涉及材料粘附、高分子材料老化机理、表面技术、力学性能测试等多个学科领域的边缘学科.介绍了与胶接接头界面紧密相关的弱界面层理论和润湿理论等领域的研究进展,总结了胶接接头表面处理方面的主要方法.     

CONSIDERING ENVIRONMENTAL CONDITIONS IN THE DESIGN OF BONDED STRUCTURES: A FRACTURE MECHANICS APPROACH

The continued airworthiness of ageing aircraft and long-term durability of new airframes depends, in part, on the integrity of adhesive bonds used for repairs and joining structural components. Additionally, the advent of composite materials and advanced repair techniques incorporating composites has increased the number of adhesively bonded joints specified for use in aerospace structures. Traditionally, adhesive bonds have been analysed and designed using a dependable and rigorous stress-based approach. However, the need to address the effect of bondline flaws and to understand the fatigue characteristics of bonded joints has led to the adoption of a discipline already common in the design of metallic components—fracture mechanics. To understand the durability of bonded structures, however, it is further necessary to examine the effect of environmental exposure on the performance of the adhesive bondline. Familiarity with the stress-based and fracture mechanics analytical approaches, as well as an understanding of environmentally induced trends in bond performance is paramount to quality design. This paper will briefly discuss the attributes of the two main forms of bonded joint analysis, and will broadly outline a design approach that uses fracture mechanics and accounts for environmental effects. Experiments discussed in this paper were performed specifically to use fracture mechanics in assessing the environmental effects on a toughened epoxy adhesive. Results indicate that the Mode I fracture toughness and fatigue crack growth threshold of this adhesive are significantly reduced upon exposure to a high temperature, high humidity aircraft service environment. These results will be used to illustrate the philosophical arguments supporting the design approach.     

Environmental durability of adhesively bonded FRP/steel joints in civil engineering applications: State of the art

Over the past three decades, the strengthening and repair of existing civil engineering structures using FRP laminates has attracted a great deal of attention. With the advances in polymer science, adhesive bonding has become a common joining technology in these applications. Despite numerous studies that address the short-term behaviour of adhesively bonded FRP/steel joints, uncertainty with respect to long-term performance still remains. This knowledge gap is regarded as a critical barrier, hindering the widespread application of FRPs to strengthen and retrofit steel structures. This paper presents the state of the art in terms of the durability of FRP/steel joints used in civil engineering applications. Important influential factors relating to the durability of adhesively bonded joints are reviewed and different damage mechanisms are discussed. Moreover, related investigations of the combined environmental durability of these joints are critically reviewed and the findings are presented. The paper concludes with a discussion to motivate future research topics, while it is emphasised that the generalisation of the available results is questionable.     

铝合金表面特性对其胶接性能影响的研究进展

不同的表面处理方法会导致铝合金表面的表面理化特性发生改变,从而对铝合金板材与胶黏剂的界面结合强度以及胶接接头的耐腐蚀性能有很大的影响。本文从铝合金表面粗糙度、微观织构、表面氧化层和涂层化学特性等方面入手,对铝合金胶接接头的界面强度和耐腐蚀性能影响的研究现状进行了综述。探讨了铝合金胶接研究发展趋势,并认为铝合金表面理化特性的参数化表征以及表面特性与胶接性能的关系模型建立等方面是今后研究的重要方向。     

Waterproof characteristics of nanoclay/epoxy nanocomposite in adhesively bonded joints

When adhesively bonded joints are exposed to a moist environment, the tensile load capability of the joint is significantly decreased because moisture absorption weakens the mechanical properties of epoxy adhesive. In this paper, a nanoclay with excellent penetration resistance properties was used as a filler in epoxy adhesive in order to enhance adhesive strength in moist environments. The water absorption of the epoxy adhesive and the adhesive strength of the adhesively bonded joints were measured in water absorption experiments with respect to the weight fraction of the nanoclay and the moisture exposure time. These results showed that the tensile load capability of the nanoclay-filled adhesively bonded joint was greatly enhanced, even in a moist environment, because the nanoclay reduced water absorption into the epoxy adhesive as well as into the interface between the epoxy adhesive and the steel adherend and increased the strength of the epoxy adhesive itself.     

搭接长度和铺层方式对CFRP复合材料层合板胶接结构连接性能和损伤行为的影响

针对不同搭接长度和铺层方式的碳纤维增强树脂（CFRP）复合材料层合板单搭胶接结构进行了拉伸试验,观察了试件的受力过程和失效形态,获得了载荷-位移曲线;同时基于连续损伤力学模型和三维Hashin失效准则模拟了CFRP复合材料层合板的层内损伤形成和演化,并利用内聚力模型来模拟层间及胶层的失效损伤,对CFRP复合材料层合板单搭胶接结构在拉伸作用下的失效强度和损伤机制进行了预测,通过对比验证了该数值方法的有效性;通过数值试验比较不同搭接长度和铺层方式的单搭胶接结构及双搭胶接结构的连接强度和损伤行为,并提出了一种优化的CFRP复合材料层合板胶接结构。结果表明:CFRP复合材料层合板胶接结构的极限失效载荷随着搭接长度的增大逐渐增加并趋于稳定值,且结构的失效形式逐渐从胶层自身剪切失效过渡到邻近胶层的层合板层间分层失效;CFRP复合材料层合板胶接结构的连接强度和损伤行为随着铺层方式的不同而改变,通过对3种铺层方式的对比和分析,得到性能最好的铺层方式是[0₃/90₃]_2S;在搭接长度为5~20 mm时,通过对搭接长度进行优化,得到单搭胶接结构的最优搭接长度是17 mm,双搭胶接结构的最优搭接长度是19.3 mm,与搭接长度为20 mm相比,单搭胶接结构和双搭胶接结构的连接强度分别提高了13.26%和0.43%。      

Mode I fracture toughness of an adhesively bonded composite–composite joint in a cryogenic environment

To determine the effect of cryogenic temperature on the adhesive fracture toughness of an adhesively bonded joint with composite adherends, monotonic mode I adhesive fracture toughness tests were performed at liquid nitrogen temperature (−196 °C) and at room temperature (27 °C). From these experimental tests, the critical strain energy release rate for both test temperatures was evaluated for the selected bonded joint system constructed of carbon-BMI adherends bonded with AF-191M film adhesive. Experimental results exhibit reduced adhesive fracture toughness at the cryogenic temperature and a profound difference in fracture mode.     

Energy release rate and mode-mixity of adhesive joint specimens

Fracture behaviour of adhesive joints under mixed mode loading is analysed by using the beam/adhesive-layer (b/a) model, in which, the adherends are beamlike and the adhesive is constrained to a thin flexible layer between the adherends. The adhesive layer deforms in peel (mode I), in shear (mode II) or in a combination of peel and shear (mixed mode). Macroscopically, the ends of the bonded part of the joints can be considered as crack tips. The energy release rate of a single-layer adhesive joint is then formulated as a function of the crack tip deformation and the mode-mixity is defined by the shear portion of the total energy release rate. The effects of transversal forces and the flexibility of the adhesive layer are included in the b/a-model, which can be applied to joints with short crack length as well as short bonding length. The commonly used end-loaded unsymmetric semi-infinite joints are examined and closed-form solutions are given. In comparison to the singular-field model in the context of linear elastic fracture mechanics, the b/a-model replaces the singularity at the crack tip with a stress concentration zone. It is shown that the b/a-model and the singular-field model yield fundamentally different mode-mixities for unsymmetric systems. The presented closed-form b/a-model solutions facilitates parametric studies of the influence of unbalance in loading, unsymmetry of the adherends, as well as the flexibility of the adhesive layer, on the mode mixity of an adhesive joint.     

Effects of various parameters on dynamic characteristics in adhesively bonded joints

Adhesively bonded lap joints are used extensively in various industries. Some disadvantages like holes, thermal effects occurring in the bolted, welded, riveted, and soldered joints are not in question in adhesively bonded joints. Strong adhesive materials used in bonding have been greatly developed in recent years, and then the properties of lightness, sealing, corrosion resistance, heat and sound isolation, damping, and quickly mounting facility have been highly improved. In this work, effects of various dynamic characteristics in the adhesively bonded joints subjected to dynamic forces are investigated using the finite element method. The investigation is conducted on a three-dimensional model. The finite element model of the joint is obtained using isoparametric three-dimensional elements having eight nodes with three degrees of freedom each. Mesh generation is accomplished automatically in a computer.The joint is modeled as a thin plate clamped from the left side. The in-plane vibration analysis is constructed. First, the natural frequencies and mode shapes are obtained, and then point and transfer receptances are extracted, employing structural damping. It is observed that the damping greatly decreased the resonance amplitudes.     

Stress-function variational method for stress analysis of bonded joints under mechanical and thermal loads

High interfacial stresses near the ends of adherends are responsible for debonding failure of bonded joints used extensively in structural engineering and microelectronics packaging. This paper proposes a stress-function variational method for determination of the interfacial stresses in a single-sided strap joint subjected to mechanical and thermal loads. During the process, two interfacial shear and normal (peeling) stress functions are introduced, and the planar stresses of adherends of the joints are expressed in terms of the stress functions according to the static equilibrium equations. Two coupled governing ordinary differential equations (ODEs) of the stress functions are obtained through minimizing the complementary strain energy of the joints and solved explicitly in terms of eigenfunctions. The stress field of the joints based on this method can satisfy all the traction boundary conditions (BCs), especially the shear-free condition near the adherend ends. Compared to results based on finite element method (FEM) and other analytic methods in the literature, the present variational method is capable of predicting highly accurate interfacial stresses. Dependencies of the interfacial stresses upon the adherend geometries, moduli and temperature are examined. Results gained in this study are applicable to scaling analysis of joint strength and examination of solutions given by other methods. The present formalism can be extended conveniently to mechanical and thermomechanical stress analysis of other bonded structures such as adhesively bonded joints, composite joints, and recently developed flexible electronics, among others.     

Influence of adherend’s delamination on the response of single lap and socket tubular adhesively bonded joints subjected to torsion

Tubular adhesively bonded joints are widely used in many industries such as the oil-and-gas, aerospace and automotive. Such joints are often used to mate dissimilar materials. Composite materials, because of their superior specific strength and stiffness and high resistance to corrosion, have also been widely used to form tubular components. When composites are mated to other materials (such as metals) by adhesives, the stress concentration in the adhesive layer becomes even more exasperated due to the mismatch in the mechanical properties of the mating adherends, thus posing further challenges. Moreover, the presence of a delamination in the composite adherend can significantly influence the stress distribution within the adhesive layer; therefore, the assessment of the adhesive layer stresses in the presence of a delamination is of importance, thus forms the main objective of the present work.     

Fracture and yield behavior of adhesively bonded joints under triaxial stress conditions

Most of adhesively bonded joints are under complicatedly distributed triaxial stress in the adhesive layer. For the estimating of the strength of adhesively bonded joints, it is crucial to clarify behavior of yield and failure of the adhesives layer under triaxial stress conditions. Two types of the adhesively bonded joints were used in this study: One is the scarf joint which is under considerably uniform normal and shear stresses in the adhesive layer, where their combination ratio can be varied with scarf angle. The other is the butt joint with thin wall tube in which considerably uniform pure shear can be realized in the adhesive layer under torsional load conditions. These joints can cover the stress triaxiality in adhesive layers of most joints in industrial application. The effect of stress triaxiality on the yield and fracture stresses in the adhesive layer were investigated using the joints bonded by three kinds of adhesives in heterogeneous and homogeneous systems. The results showed that both the yield and failure criterion depend on the stress triaxiality and that the fracture mechanism of the homogeneous adhesive is different from that of the heterogeneous one. From these experimental results, a method of estimating the yield and failure stresses was proposed in terms of a stress triaxiality parameter.     

A parametric study on the failure of bonded single-lap joints of carbon composite and aluminum

A parametric study on adhesively bonded carbon composite-to-aluminum single-lap joints was experimentally conducted. FM73m, a high strength adhesive produced by Cytec, was used for bonding. The primary objective of this study is to investigate the effects of various parameters, such as bonding pressure, overlap length, adherend thickness, and material type, on the failure load and failure mode of joints with dissimilar materials. While metal bonded joints generally fail at the adhesive, the final failure mode of all the tested bonded joints with dissimilar materials was delamination of the composite adherend. Bonding strengths of the tested joints were lower than the metal-to-metal bonded joint strength. The specimens bonded under pressure of 4 and 6 atm yielded higher failure loads than under pressure of 3 atm, which is within the range of the manufacturer-recommended bonding pressure. Failure loads of the joint increased slightly at an overlap length larger than 30 mm. Increasing adherend thickness resulted in an increase of the failure load, but was not linearly proportional to the failure load.     

An innovative testing technique for assessing the VHCF response of adhesively bonded joints

In the last few years, the use of adhesive joints for structural applications has rapidly increased and adhesives are more often subject to fatigue loads during their in‐service life. In presence of a rapidly varying load, such as a high‐frequency vibration, adhesively bonded joints may undergo fatigue lives in the Very High Cycle Fatigue (VHCF) region that are significantly larger than those investigated in usual high‐cycle fatigue tests. The present paper proposes an innovative testing technique for performing accelerated fully reversed tension‐compression VHCF tests on adhesive butt‐joints. The procedure for the design of the adherends is described and then experimentally validated. Ultrasonic VHCF tests are finally carried out on a cyanoacrylate butt‐joint up to 10⁹ cycles: experimental results show that the proposed testing equipment permits an effective assessment of the VHCF response of the adhesive in a limited testing time.