铸造Mg-6Zn-3Sn-0.5Mn镁合金组织和力学性能

通过OM、SEM、XRD和力学性能测试等手段研究了半连续铸造Mg-6Zn-3Sn-0.5Mn(ZTM630)镁合金铸锭的组织和力学性能。结果表明,铸态显微组织主要由α-Mg相、Mg_2Sn相、Mg_7Zn_3相组成;经过420℃×8 h固溶处理,Mg_7Zn_3相和绝大部分的Mg_2Sn相全部溶解到基体中,剩余少量Mg_2Sn相呈颗粒状分布在晶界或晶粒内部;固溶处理后实验合金的抗拉强度、屈服强度和伸长率均有所提高。     

热处理工艺对Mg-6Zn-2.5Cu镁合金显微组织和力学性能的影响

利用光学显微镜(OM)、扫描电镜(SEM)、透射电镜(TEM)、X射线衍射仪(XRD)和力学试验机等研究了铸造Mg-6Zn-2.5Cu合金在铸态、固溶和时效处理下的显微组织和力学性能。结果表明:合金的铸态组织主要由α-Mg和(α-Mg+MgZn2+Mg2Cu+CuZnMg)共晶相组成。在455℃固溶12~36 h时,随着时间增加,固溶效果逐渐增强,且在20 h时合金获得了较理想的显微组织及218 MPa的抗拉强度和8.68%的伸长率。随后在180℃时效6~72 h后,合金的拉伸性能随时效时间的增加呈先增加后减小的趋势,其中时效24 h时后,合金的抗拉强度和硬度达到峰值,分别为249.5 MPa和64.6 HV0.1,比铸态的分别提高了66.5 MPa和26.29%,伸长率在时效12 h时后达到了峰值6.72%。铸态合金的断裂方式以沿晶断裂为主,时效处理后合金的断裂方式为准解理断裂。     

固溶处理对Mg-6Al-3Zn-0.25Mn合金组织和性能影响

研究了固溶处理对Mg-6Al-3Zn-0.25Mn铸造镁合金显微组织和力学性能的影响。结果表明,铸态和固溶态组织主要由α-Mg基体和Mg₁₇Al₁₂相组成,经过400、410和420℃保温18 h固溶处理后,第二相的种类没有发生变化,大量的Mg₁₇Al₁₂相溶入到α-Mg基体中,合金组织中残留了少量颗粒状Al₄Mn相,同时也出现了梅花状Mg₁₇Al₁₂相。此外,合金经400℃×18 h处理后,晶粒细化程度最好,且表面清晰平整无缺陷,其室温力学性能得到了明显改善,抗拉强度、屈服强度和伸长率分别达到了184.1 MPa、135.5 MPa和8.9%。     

热处理对Mg-12Gd-1Zn-0.5Zr合金显微组织和力学性能的影响

采用光学显微镜、扫描电镜、X射线衍射仪和拉伸试验机等研究了不同热处理状态下Mg-12Gd-1Zn-0.5Zr合金的物相、显微组织和力学性能.结果 表明:铸态Mg-12Gd-1Zn-0.5Zr合金的组织主要由α-Mg基体、Mg5(Gd,Zn)、Mg5Gd以及Mg10ZnGd(18R-LPSO)相构成.固溶处理后,LPSO...     

Mn含量对Mg-Zn-Mn变形镁合金显微组织和力学性能的影响

通过对3种不同Mn含量的Mg-6Zn-XMn变形镁合金的微观组织的观察及力学性能的测定,研究了Mn含量对Mg-Zn-Mn镁合金显微组织和力学性能的影响。结果表明：Mn元素以单质形式弥散地分布于Mg-Zn-Mn合金中,起到阻碍晶粒长大的作用,即随着Mn含量的增加,晶粒尺寸减小;Mn含量的变化对合金的屈服强度有一定的影响,即随着Mn含量的增加,屈服强度增加,其中挤压态增幅最大,双级时效次之,增幅分别是14%和5%;而Mn含量的变化对T6、T4+双级时效后合金的抗拉强度和延伸率的影响规律不明显,其中含0.68%Mn(质量分数, 下同)的合金整体性能较优,经双级时效后具有最高抗拉强度,达到360 MPa,伸长率为5.2%     

高塑性Mg-3Zn-1Y-1Mn合金在不同挤压温度下的组织演变、强化机制和变形行为（英文）

为了改善铸态Mg-3Zn-1Y-1Mn合金的力学性能、研究合金在不同变形温度下的组织演变规律和变形机理,对铸态Mg-3Zn-1Y-1Mn合金进行热挤压实验。实验结果显示,当挤压温度为330℃时,挤压态合金具有最佳的力学性能,抗拉强度和伸长率分别达到270 MPa和16.8%。挤压态合金性能大幅提高主要归因于3个方面：由动态再结晶导致的细晶强化作用、未被动态再结晶抵消的加工硬化以及第二相粒子强化作用。在热挤压过程中,当挤压温度为300℃时,同时发生连续动态再结晶和动态回复;而当挤压温度为330和360℃时,发生不连续动态再结晶。此外,在热变形过程中{0001}基面滑移、{■}Ⅰ型柱面滑移和{■}Ⅱ型柱面滑移对塑性变形的贡献受挤压温度影响很大,而{■}Ⅱ型柱面是3个滑移系中最难启动的滑移系。     

Sb对Mg-8Zn-4Al-0.3Mn合金显微组织的影响

试验研究了Sb对Mg-8Zn-4Al-0·3Mn铸造镁合金显微组织的影响。结果表明,含Sb铸造镁合金Mg-8Zn-4Al-0·3Mn-xSb的显微组织由基体α(Mg)、共晶[α(Mg) τ]、三元相τ(Mg32(Al,Zn)49、二元相MgZn2和Mg3Sb2组成;随着Sb含量的增加,合金晶界上三元相的形态逐渐由半连续网状变为分散均匀的颗粒状;w(Sb)=0.3%为最佳加入量,此时的合金铸态组织被明显细化,晶粒大小由120μm~130μm减小到50μm~60μm。同时,合金的显微硬度值也随Sb含量的增加而增加。     

热处理工艺对Mg-8Zn-4Al-0.25Mn镁合金组织和性能的影响

研究固溶和时效处理对Mg-8Zn-4Al-0.25Mn合金组织和性能的影响.结果表明,试验合金经345 ℃固溶12 h水冷后,合金组织中的Mg32(Al,Zn)49和Al2Mg5Zn2相三元化合物数量急剧减小,并且原有连续网状Mg32(Al,Zn)49相变为断续网状,颗粒状Mg32(Al,Zn)49相和小块状Al2Mg5Zn2相变得更加圆整和细小.同时,合金的显微硬度随固溶时间增加而逐渐降低.经180 ℃时效处理后,析出大量弥散分布的细小Mg-Zn-Al三元颗粒状析出物,并且随着时效时间延长,合金的显微硬度逐渐增加,在12 h时达到最大值.     

热处理对Mg-5Zn-0.63Er合金显微组织及力学性能的影响

通过不同的热处理工艺研究含有准晶Ⅰ相的铸态Mg-5Zn-0.63Er(质量分数,％)合金的显微组织演变.结果表明:合金在480℃固溶10 h后,除有W相颗粒析出外,准晶Ⅰ相几乎全部固溶在基体中.固溶态Mg-5Zn-0.63Er合金在175℃下时效6～10h.合金在峰时效态的抗拉强度约为261MPa、伸长率为10.5％.合金拉伸强度的提高归因于杆状MgZn2相的析出.     

Mn含量对Mg-5Al合金铸态组织和力学性能的影响

研究了合金元素Mn对Mg-5Al合金铸态组织和力学性能的影响。结果表明,在Mg-5Al合金中加入Mn后,合金组织细化,连续或半连续网状分布的β-Mg17Al12相逐渐转变为断续、分散的骨骼状相,晶界附近出现颗粒相并且数量逐渐增多。随着Mn含量增加,合金室温抗拉强度、伸长率及冲击韧度先上升然后下降。当Mn含量为0.3%时,合金综合力学性能最好,抗拉强度、伸长率与冲击韧度达到190MPa、7.3%与21.1J·cm-2,分别提高了7.9%、9.1%与9.3%。继续增加Mn含量至0.5%时,Al8Mn5颗粒聚集长大粗化,导致Mg-5Al合金综合力学性能下降。     

Effects of Cu addition on microstructure and mechanical properties of as-cast Mg-6Zn magnesium alloy

The application of Mg-Zn binary alloys is restricted due to their developed dendritic microstructure and poor mechanical properties. In this study, an alloying method was used to improve the mechanical properties of Mg-Zn alloy. The Mg-6Zn magnesium alloys microalloyed with varying Cu content(0, 0.8, 1.5, 2.0 and 2.5wt.%) were fabricated by permanent mould casting, and the effects of Cu content on the microstructure and mechanical properties of as-cast Mg-6Zn alloys were studied using OM, SEM, XRD and tensile tests at room temperature. The obtained results show that the addition of Cu not only can refine the grains effectively, but also can modify the eutectic morphology and improve the mechanical properties of the alloys. The main phases of the studied alloys include α-Mg, MgZn_2, Mg_2Cu and CuMgZn. When the content of Cu exceeds 0.8wt.%, Mg_2Cu phase appears. Meanwhile, the eutectic morphology is modified into dendritic shape or lamellar structure, which has an adverse effect on the tensile properties. Furthermore, among the investigated alloys, the alloy containing 0.8% Cu shows an optimalultimate tensile strength of 196 MPa, while the alloy with 1.5wt.% Cu obtains an excellent elongation of 7.22%. The experimental alloys under different Cu contents show distinguishing fracture behaviors: the fracture of the alloy with 0.8wt.% Cu reveals a mixed mode of inter-granular and quasi-cleavage, while in other investigated alloys, the fracture behaviors are dominated by cleavage fracture.     

添加微量Sc对Mg-3%Li合金组织与性能的影响

用真空感应熔炼炉制备了Mg-3%Li和Mg-3%Li-1%Sc两种不同成分的合金。对Mg-3%Li-1%Sc合金进行了固溶和时效热处理。分析了添加Sc对合金组织及性能的影响。结果表明,添加1%Sc后,Mg-3%Li合金的晶粒细化,组织更加均匀,经200℃×9h时效热处理后,Mg-3%Li-1%Sc合金的硬度更高,综合力学性能得到提高。MgSc点状相在基体上均匀地弥散析出和晶粒细化是合金强化的主要原因。     

Effects of Sm addition on microstructure and mechanical properties of a Mg-10Y alloy简

To further increase the mechanical properties, 0.5wt.% Sm was introduced to a Mg-10Y alloy in this study. The effects of Sm addition on the microstructures and mechanical properties of the Mg-10Y alloy, especially the aged Mg-10Y alloy, were investigated. The microstructure observation and tensile tests were performed by using an optical microscopy, a scanning electron microscopy and a universal material testing machine, respectively. The phase analysis was performed using X-ray diffractometer. The results show that the 0.5wt.% Sm addition can not only promote the formation of fine and dispersed Mg24Y5 phases, but also improve their morphology and distribution; it also increases the thermal stability of Mg24Y5 phases. Sm addition is seen to increase the ultimate tensile strength of Mg-10Y alloy at elevated temperatures(200, 250, 300 and 350 ℃), while decrease the elongation. But the elongation is still up to 7.5% even at 350 ℃. In the range of 250 ℃ to 300℃, the ultimate tensile strength of the alloy reaches its maximum(with a range average of 235 MPa) and is not sensitive to the temperature change, which is very useful to the application of heat-resistant magnesium alloys. Even at 350 ℃, the ultimate tensile strength of Mg-10Y-0.5Sm is still up to 155 MPa. Considering both of the ultimate tensile strength and elongation, the maximum application temperature of the Mg-10Y-0.5Sm alloy can be up to 300 ℃. The strengthening mechanisms of Mg-10Y-0.5Sm alloy are mainly attributed to dispersion strengthening of Mg24Y5 phase particles with a certain solubility of Sm and grain refinement strengthening of α-Mg matrix.     

Effects of yttrium on microstructure and mechanical properties of Mg-6Al magnesium alloy

Since Y has a great solid solubility in magnesium alloys, it helps enhancing the heat-resistant property of magnesium alloys. The effects of Y on microstructures and mechanical properties of Mg-6Al alloy have been studied in this work. The results show that Y addition refines grains of Mg-6Al alloy, and reduces the amount of the Mg 17 Al 12 phase. At the same time, the high melting-point Al 2 Y phase particles are formed. According to the mathematical model of the two-dimensional lattice misfit proposed by Braffit, it is believed that the Al 2 Y particles can serve as the nucleation sites for α-Mg. After T6 treatment, both elongation and ultimate tensile strength of Mg-6Al alloy at the room temperature and high-temperature increased firstly and then decreased, with increasing Y addition. The peak mechanical properties were achieved in the Mg-6Al-1.2Y alloy system. Y addition appears to change the fracture characteristic of Mg-6Al alloy. With 1.2wt%Y, the fracture surface of the alloy showed a lot of dimples and tearing ridges which connected the microscopic dimples and the fracture is mixed fracture of quasi-cleavage and ductile fracture.     

含量对 Mg-6Zn-Y-Zr-xSb 合金组织与性能的影响(英文)

利用OM、SEM、XRD及力学性能测试,研究Sb含量对Mg6ZnYZrxSb合金铸态组织及性能的影响。结果表明:添加Sb可以使晶界处网状连续组织变为颗粒状,并且随着Sb含量增加,颗粒的体积分数增加。低Sb含量合金的铸造组织由α-Mg、富锌相、共晶组织(α-Mg+I相)和YSb组成;随着Sb含量的增加,I相逐渐消失,Mg3Sb2和二元共晶Mg4Zn7开始出现。起初合金的拉伸强度和延伸率随Sb含量的增加而提高,而当Sb含量过大时,合金的综合力学性能下降。     

钇钕复合合金化对Mg-6Al合金力学性能的影响

研究了Y、Nd复合合金化(Y:Nd=2:1,wt%)对Mg-6Al合金显微组织和力学性能的影响.结果表明,添加稀土元素Y和Nd可显著提高合金从室温至175℃区间的屈服强度和抗拉强度.在Mg-6Al合金中加入总含量为0.9wt%～3.6wt%的Y Nd后,合金的晶粒得到明显细化,且出现Al2Y、Al2Nd高熔点稀土合金相.并探讨了钇钕复合合金化对提高镁铝基合金力学性能的机理:室温下主要是细晶强化机制;高温下则主要是高熔点稀土合金相(Al2Y、Al2Nd)的弥散强化,并由此使热稳定性差的β-Mg17Al12相的数量减少.     

Effects of calcium addition on as-cast microstructure and mechanical properties of Mg-5Zn-5Sn alloy

The effects of Ca addition on the as-cast microstructure and mechanical properties of the Mg-5Zn-5Sn (mass fraction,%) alloy were investigated.The results indicate that an addition of 0.5%-1.5% (mass fraction) Ca to the Mg-5Zn-5Sn alloy not only refines the as-cast microstructure of the alloy but also causes the formation of the primary and/or eutectic CaMgSn phases with high thermal stability;an increase in Ca amount from 0.5% to 1.5% (mass fraction) increases the amount and size of the CaMgSn phase.In addition,Ca addition to the Mg-5Zn-5Sn alloy improves not only the tensile properties at room temperature and 150 ℃ but also the creep properties.Among the Ca-containing Mg-5Zn-5Sn alloys,the one added 0.5% (mass fraction) Ca obtains the optimum ultimate tensile strength and elongation at room temperature and 150 ℃,however,the alloy added 1.5% (mass fraction) Ca exhibits the optimum yield strength and creep properties.     

Effects of little Ce addition on as-cast microstructure and creep properties of Mg-3Sn-2Ca magnesium alloy

The effects of little Ce addition on the as-cast microstructure and creep properties of Mg-3Sn-2Ca magnesium alloy were investigated. The results indicate that adding 0.5% (mass fraction) Ce to Mg-3Sn-2Ca alloy does not cause the formation of any new phase in the alloy. However, an interesting microstructural change in the as-cast Mg-3Sn-2Ca alloy added with 0.5%Ce is observed. After adding 0.5%Ce to Mg-3Sn-2Ca alloy, not only the volume fraction of CaMgSn phase in the alloy is decreased but also the CaMgSn phases in the alloy are refined. In addition, adding 0.5%Ce to Mg-3Sn-2Ca alloy can also improve the creep-resistant properties of the alloy. After adding 0.5%Ce to Mg-3Sn-2Ca alloy, the second creep rate of the alloy at 150 °C and 70 MPa for 100 h changes from 3.28×10⁻⁸ to 1.81×10⁻⁸ s⁻¹.     

Zn含量对铸态Mg-2Er合金的微观结构及力学性能影响

采用XRD和SEM等微观表征技术研究不同Zn添加量对Mg-2Er合金微观组织和力学性能的影响。结果表明：当Zn添加量为1%和2%时,合金主要相组成为W相和α-Mg;当Zn添加量为4%-10%时,合金中则有I相析出,合金相成分变为W相、I相和α-Mg;当Zn添加量增加至12%时,W相消失,合金中主要第二相则为I相和Mg4Zn7相。当Zn添加量为6%时,合金具有较好的拉伸力学性能,其抗拉强度、屈服强度和伸长率分别为224 MPa、134 MPa和10.4%。