共查询到19条相似文献,搜索用时 156 毫秒
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分析了纳米技术对橡胶复合材料增韧的理论,指出纳米增强是橡胶高效增强的必要手段.同时介绍了利用纳米材料对橡胶复合材料进行改性的制备技术及方法.综述了橡胶纳米复合材料的研究现状和未来前景. 相似文献
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采用乳液共凝法,研究了纳米CaCO3/胶清橡胶复合材料的制备与力学性能。结果表明:乳液共凝法制备纳米CaCO3/胶清橡胶复合材料时混合速度、混合时间,纳米CaCO3加入方法以及纳米CaCO3用量对复合材料的力学性能有较大的影响,乳液共凝法制备的复合材料综合性能较机械共混法制备的复合材料综合性能好。 相似文献
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淀粉作为补强填料替代部分炭黑或白炭黑可以改善橡胶轮胎的抗湿滑性和滚动阻力,且淀粉来源广,成本低,无污染,有望成为新型橡胶补强填料。但淀粉极性强,与橡胶相容性差,直接使用无法起到补强效果。本文综述了淀粉细微化、酯化改性、接枝改性、原位改性这四种改性淀粉的方法。这些方法通过减小淀粉颗粒尺寸和引入其他分子链或基团等途径,改善淀粉在橡胶中的分散性及其与橡胶的相容性,使淀粉能够成为橡胶轮胎的优质补强填料。 相似文献
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《塑料、橡胶和复合材料》2013,42(2):50-58
AbstractHollow carbon black (HCB) is introduced in this work. It has a special hollow structure, high specific surface area, high structure and high electric conductivity. Hollow carbon black is used to fill styrene–butadiene rubber (SBR). The bound rubber test results show that the bound rubber of SBR/HCB can be measured when the HCB content reaches 25 phr because a strong filler network is formed, which indicates good electric conductivity of SBR/HCB. In comparison, the bound rubber of SBR/N330 can not be measured even when the N330 content is 40 phr. The mechanical measurements show that HCB has very good reinforcing effect on SBR especially when the filler content is low. The electric conductivity and thermal conductivity increase with the increase in filler content. At the same filler content, the properties of SBR/HCB nanocomposites are better than those of SBR/N330 nanocomposites, which suggests that HCB has good application potential. 相似文献
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扫描探针对炭黑结构及其结合胶微观形貌的研究 总被引:1,自引:0,他引:1
以N234、N330、低滞后DZ13 3种不同结构的橡胶补强炭黑为材料,通过扫描探针对其聚集体形貌及其结合胶的微观形貌进行了研究。实验表明:N234的聚集体小,分布窄,二次结构影响较小;N330的聚集体形貌如同葡萄串,有链枝状;DZ13的聚集体分布较宽,大小不一。通过对结合橡胶结构观察发现,N234的结合方式不同于其它2种结构炭黑,结合胶的量更大,而DZ13表面的橡胶壳大于N330表面的橡胶壳,侧面证明了DZ13的表面活性较大。结合胶形貌的研究有助于了解炭黑结构对橡胶补强的影响,对炭黑补强机理的研究提供了直观的证据。 相似文献
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为了研究炭黑附聚体含量对橡胶补强的影响,本文在165MPa下将炭黑进行不同次数的压缩.采用SPM扫描了原样及压缩4次后的炭黑形貌;利用激光粒度分布仪测定了它们的粒径.讨论不同压缩次数下炭黑吸油值、吸碘值、CTAB及氮吸附值的变化规律.结果表明,从形貌图上看,压缩前后粒子的分布更加均匀.压缩后的颗粒粒径明显减小.随着压缩次数的增加,炭黑的吸油值都减小,且结构越高,减小值越大.炭黑的其余三个参数都随着压缩次数的增多而增大;其中,CTAB值和吸碘值的增幅较小,而氮吸附值增幅较大. 相似文献
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《塑料、橡胶和复合材料》2013,42(9):379-384
AbstractThe effect of carbon black on nanoclay filled polychloroprene (CR) composites has been investigated. The nanoclay loading is fixed at 5 part per hundred rubbers (phr), and carbon black loading varied from 5 to 20 phr in rubber compounds. The rubber nanocomposites are prepared in laboratory by mixing in two-roll mill. The addition of nanoclay enhances mechanical properties especially tear strength and decreases water absorption without change in electrical properties compared to gum rubber vulcanisates. Wide angle X-ray diffraction and transmission electron microscopy are used to study the microstructure of CR nanocomposites. The addition of 5 parts of nanoclay to 15 phr carbon black filled samples shows synergistic effect between the fillers and suggests that the reinforcement is due to a more developed filler network formation in hybrid filler system than that in single phase filler. Significant improvement in mechanical, electrical and low water absorption properties has been obtained with these nanoclay and carbon black filled rubber nanocomposites. The paper concludes that nanocomposites containing a mixture of organoclay and carbon black in right proportion can be a substitute for rubber components used in underwater cable and device encapsulation applications. 相似文献
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Rubber–clay nanocomposites were prepared by two different methods and characterized with TEM and XRD. The TEM showed clay had been dispersed to one or several layers. The XRD showed that the basal spacing in the clay was increased. It was evident that some macromolecules intercalated to the clay layer galleries. The clay layer could be uniformly dispersed in the rubber matrix on the nanometer level. The mechanical tests showed that the nanocomposites had good mechanical properties. Some properties exceeded those of rubber reinforced with carbon black, so the clay layers could be used as an important reinforcing agent as the carbon black was. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 1879–1883, 2000 相似文献
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The mechanical properties, heat aging resistance, dynamic properties, and abrasion resistance of fibrillar silicate (FS)/styrene butadiene rubber (SBR) nanocomposites are discussed in detail. Compared with white carbon black (WCB)/SBR composites, FS/SBR composites exhibit higher tensile stress at definite strain, higher tear strength, and lower elongation at break but poor abrasion resistance and tensile strength. Surprisingly, FS/SBR compounds have better flow properties. This is because by rubber melt blending modified FS can be separated into numerous nanosized fibrils under mechanical shear. Moreover, the composites show visible anisotropy due to the orientation of nanofibrils. There is potential for FS to be used to some extent as a reinforcing agent for rubber instead of short microfibers or white carbon black. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2725–2731, 2006 相似文献