［（Cdse）_m（ZnSe）_n］_p－Znse多量子阱中的多声子散射

对用原子层外延方法，在［００１］晶向ＧａＡｓ衬底上生长的［（Ｃｄｓｅ）ｍ（Ｚｎｓｅ）ｎ］ｐ－ＺｎＳｅ应变量子阱结构，在１０～３００Ｋ温度范围内测量了喇曼散射光谱，观察到两种类ＺｎＳｅＬＯ声子限制模．利用改变样品温度和入射光能量实现了共振喇曼散射，观察到高达７阶的类ＺｎＳｅＬＯ声子模．并讨论了多声子喇曼散射和热萤光过程的区别．     

Zn1—xMnxSe／ZnSe应变超晶格的分子束外延生长及特性研究

用分子束外延方法在ＧａＡｓ（１００）衬底上成功生长了高质量的Ｚｎ１－ｘＭｎｘＳｅ／ＺｎＳｅ（ｘ＝０．１６，ｘ＝０．１４）超晶格结构，用Ｘ射线衍身 喇曼散射对其结构，应变分布以及光散射性能进行了研究，江超晶格的总厚度大于最度是格将完全弛豫至一个新的平衡晶格常数，此时在（１００）平面，ＺｎＳｅ阱层受到张应变，而Ｚｎ１－ｘＭｎｘＳｅ垒层受到压变应。从而，导致其喇曼光谱中，ＺｎＳｅ Ｚｎ１－ｘＭｎｘＳｅ垒     

不同生长温度下Ge_（0．5）Si_（0．5）／Si应变层超晶格材料结构的X射线双晶衍射研究

本文通过Ｘ射线双晶衍射和双晶摇摆曲线的计算机模拟方法研究了在Ｓｉ（００１）上生长的Ｇｅ０．５Ｓｉ０．５／Ｓｉ应变层超晶格的结构及其完整性，结果表明：在３５０－５５０℃的低温生长条件下，可生长出较高质量的超晶棺材料，并且在３５０℃时质量最好．在这些样品的生长过程中界面上产生了不同程度的失配位错，并与生长温度有关．周期厚度有４％以内的波动，层与层之间有轻微的混元，观察到了超晶格卫星衍射峰的分裂现象，并进行了讨论．     

ZnSe/ZnCdSe多量子阱激子光学非线性

本文采用泵浦－探测技术研究了ＺｎＳｅ／ＺｎＣｄＳｅ多量子阱室温激子饱和吸收，并根据Ｋ－Ｋ关系计算得到５２１．６ｎｍ至５４４ｎｍ的光学非线性折射率的变化．观测到由折射率变化引起的ＺｎＳｅ／ＣｄＺｎＳｅ多量子阱光双稳器件的室温激子光双稳．根据ＺｎＳｅ／ＺｎＣｄＳｅ多量子阱的激子吸收谱及激子的非线性理论，归结其主要非线性机制为激子态的相空间填充和激子带展宽．     

静压下（CdSe）m／（ZnSe）n—ZnSe超短周期超晶格量子阱的共振…

在静压和液氮温度下观察到（ＣｄＳｅ）ｍ／（ＺｎＳｅ）ｎ短周期超晶格中重空穴激子的复合发光和多达４阶的类ＺｎＳｅＬＯ多声子喇曼散射，并观察到厚ＺｎＳｅ势垒层的带边发光和限制在厚势垒层中的类ＺｎＳｅＬＯ声子散射。结果表明，加压后（ＣｄＳｅ）ｍ／（ＺｎＳｅ）ｎ短周期超晶格中的类ＺｎＳｅ的１ＬＯ和２ＬＯ声子模频率分别以３．７６和７．１１ｃｍ＾－１／ＧＰａ的速率向高频方向移动，超晶格阱层光致发光峰的压力系数     

静压下（CdSe）_m／（ZnSe）_n－ZnSe超短周期超晶格量子阱的共振喇曼散射研究

在静压和液氮温度下观察到（ＣｄＳｅ）ｍ／（ＺｎＳｅ）ｎ短周期超晶格中重空穴激子的复合发光和多达４阶的类ＺｎＳｅＬＯ多声子喇曼散射，并观察到厚ＺｎＳｅ势垒层的带边发光和限制在厚势垒层中的类ＺｎＳｅＬＯ声子散射．结果表明，加压后（ＣｄＳｅ）ｍ／（ＺｎＳｅ）ｎ短周期超晶格中的类ＺｎＳｅ的１ＬＯ和２ＬＯ声子模频率分别以３．７６和７．１１ｃｍ－１／ＧＰａ的速率向高频方向移动，超晶格阱层光致发光峰的压力系数为５９．８ｍｅＶ／ＧＰａ．与（ＣｄＳｅ）ｍ／（ＺｎＳｅ）ｎ短周期超晶格共振时的类ＺｎＳｅ１ＬＯ声子模频率比与ＺｎＳｅ势垒层共振时的类ＺｎＳｅ１ＬＯ声子模频率低２．０ｃｍ－１，反映了（ＣｄＳｅ）ｍ／（ＺｎＳｅ）ｎ短周期超晶格中ＬＯ声子的限制效应     

ZnCdSe—ZnSe／CaF2多量子阱中的三阶非线性

我们首次利用Ｚ－扫描技术在室温下研究了ＺｎＣｄＳｅ－ＺｎＳｅ／ＣａＦ２多量子了进中的三阶非线性，得到非线性系数ｎ２为－４．４６×１０＾－８ｅｓｕ。其主要非线性机理归结为ＺｎＣｄＳｅ－ＺｎＳｅ／ＣａＦ２多量子阱中的带填充效应。     

Si（001）上MBE异质生长Ge中表面活化剂Sd的作用的研究

本利用ＲＨＥＥＤ、Ｘ射线双晶衍射及ＴＥＭ等技术，研究了在Ｓｉ（００１）衬底上，用晶化了的列定形Ｇｅ层做缓冲层ＭＢＥ生长Ｇｅ时，引入表面活化剂Ｓｄ所产生的影响。研究表明，Ｓｄ的引入将全使Ｓｉ（００１）衬底上无定形Ｇｅ膜的晶化温度显提高，并在一定的生长条件下，破坏Ｇｅ外延层的结晶性。     

GaAs／AlGaAs分子束外延量子阱材料的研究

采用进口分子束外延设备生长了ＧａＡｓ／ＡｌＧａＡｓ单量子阱和多量子阱材料。在理论分析和实验总结的基础上，对材料结构进行了优化，增加了ＧａＡｓ／ＡｌＧａＡｓ超晶格缓冲层来进行缺陷抑制，并在外延时精确地控制生长，这样获得的量子阱材料通过Ｘ射线双晶衍射和Ｃ－Ｖ测量表明：得到的材料性能良，为新型光电器件的制作和进一步的材料研究打下了基础。     

高精度双晶衍射（HRDCD）方法检测InGaAs／GaAs超薄应变层量子阱结构参数

应变超薄层结构的组分、厚度、应变状态的直接检测，对于器件应用具有重要的意义，本文中，利用ＭＯＣＶＤ方法得到高质量的ＩｎＧａＡｓ／ＧａＡｓ量子阱材料，采用双晶衍射方法的弱信号收集技术，结合运动学理论模拟，得出同时包含几个不同阱宽的ＩｎＧａＡｓ／ＧａＡｓ量子阶结构的重要参数，其检测结果与光致发光（ＰＬ）、透射电子显微镜（ＴＥＭ）等方法的测试结果基本一致，表明Ｘ射线双晶衍射方法是检测超薄层应变量子阱结构的一个有效方法．     

Germanium quantum dots in an unstrained GaAs/ZnSe/Ge/ZnSe heterosystem

Arrays of Ge quantum dots in unstrained GaAs/ZnSe/Ge heterostructures were obtained by molecular-beam epitaxy for the first time. Their spatial parameters are examined by scanning tunneling microscopy, and their electronic structure is studied by Raman spectroscopy.     

P-down ZnSTeSe/ZnSe/GaAs heterostructure photodiodes

High-quality quaternary ZnSTeSe epitaxial layers with uniform carrier concentration of 1/spl times/10/sup 17/ cm/sup -3/ were successfully grown on p-GaAs substrates by molecular beam epitaxy. P-down ZnSTeSe/ZnSe/GaAs heterostructure photodiodes were also fabricated. It was found that the maximum quantum efficiency of the fabricated ZnSTeSe photodiodes was around 75% with a large spectral width of 500 nm.     

ZnSe/ZnMgSSe blue laser diode

The continuous wave operation of an ZnSe/ZnMgSSe laser diode was achieved for the first time at 77 K. Blue stimulated emission was observed at a wavelength of 447 nm and the threshold current density was 225 A/cm/sup 2/.<>     

Stromverstärkung in ZnSe/CdSe-photoleiterschichten

ZnSe/CdSe heterojunctions have been prepared by vacuum evaporation. By applying positive potential to the CdSe-layer and contacting the ZnSe by an electron beam current-voltage measurements have been made in the voltage range from about 5–50 V. The results can be described by ln $\text{j = a}\text{exp}\text{(bU}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)}$. High photosensitivity with a gain factor exceeding 100 has also been observed. The experiments suggest a theoretical model, which interpretes the current to be mainly caused by thermal emission of electrons from interface states.     

Optimum Parameters of MgZnSSe/ZnSe BRAQWET

Atheoretical basis of optimally designed BRAQWET is presented.The optimum parameters of MgZnSSe/ZnSe BRAQWET are obtained by the calculation of band-structure according to the depletion approximation.     

Low pressure MOVPE growth of ZnSe,ZnTe, and ZnSe/ZnTe strained-layer superlattices

ZnSe and ZnTe single-crystal layers have been grown onto (100) GaAs substrates by low-pressure metalorganic vapor-phase epitaxy (LP-MOVPE) using the triethylamine-dimethylzinc adduct [DMZn(NEt₃)] as the zinc precursor. The selenium and tellurium precursors were H₂Se (5% in H₂) and di-isopropyltellurium (DiPTe), respectively. These two semiconductors have been grown with different VI/II molar ratios, at different growth temperatures, and with an overall growth pressure ranging from 40 to 400 Torr. Optimal growth parameters have been determined by optical means for the two materials. This information was then used to grow ZnTe/ZnSe strained-layer superlattices. We have studied structures grown on both ZnSe and ZnTe relaxed buffer layers which display a drastic dependence of the Stokes shift between photoluminescence and the optical bandgap on the nature of the buffer layer. Growth interruptions have been used to optimize the optical properties of the superlattices. Theoretical modeling of superlattice band structures has been performed using results of optical and structural characterizations. Observations of zone center transitions as well as excitons associated with the miniband dispersion of the superlattices are reported, in agreement with the theoretical calculation.     

应变层异质结ZnS／ZnSe的价带带阶

采用基于ＬＭＴＯ－ＡＳＡ的平均结合能计算方法，研究了在ＺｎＳｘＳｅ１－ｘ衬底上沿（００１）方向外延生长的应变层异质结ＺｎＳ／ＺｎＳｅ的价带带阶值。研究表明，应变的结果使价带带阶随衬底组分（ｘ）的变化呈非线性且单调的关系；与其他理论计算和实验结果比较，本文的计算结果比较理想。     

`Flip-chip' transfer of ZnSSe/ZnSe/CdZnSe LED films

A ZnSSe/ZnSe/CdZnSe light-emitting diode (LED) film grown on GaAs by molecular beam epitaxy (MBE) has been successfully transferred from a GaAs substrate to a silicon substrate by combining both mechanical polishing and chemical wet etching techniques. The external quantum efficiency of the LED was enhanced by more than a factor of 2 via insertion of a reflector layer beneath the device structure. The device can be implemented in hybrid quasimonolithic integration. Technology applications include fabrication of LEDs with enhanced external quantum efficiency and II-VI surface emitting lasers     

ZnO/ZnSe/ZnTe Heterojunctions for ZnTe-Based Solar Cells

ZnO and ZnSe are proposed as n-type layers in ZnTe heterojunction diodes to overcome problems associated with the n-type doping of ZnTe. The structural properties and electrical characteristics of ZnO/ZnTe and ZnO/ZnSe/ZnTe heterojunctions grown by molecular beam epitaxy on (001) GaAs substrates are presented. ZnO shows a strong preference for c-plane (0001) orientation resulting in a nonepitaxial relationship and high density of rotational domains for growth on ZnTe (001). ZnSe/ZnTe structures demonstrate a (001) epitaxial relationship with high density of {111} stacking faults originating at the heterojunction interface. ZnO/ZnSe/ZnTe heterojunction diodes show excellent diode rectification and clear photovoltaic response with open-circuit voltage of V _OC = 0.8 V.