Geostatistical analysis of arsenic concentration in the groundwater of Malda district of West Bengal, India

The problem of arsenic (As) poisoning in the upper deltaic plain of the Ganga-Bhagirathi river system in the Bengal Basin of West Bengal, India is an alarming issue. Four blocks (Kaliachak-1, 2, 3 and English Bazar) of Malda district, West Bengal were critically studied. Geomorphologically, the area exhibits three terraces: the present Youngest terrace (T₀-terrace), the Older Shaugaon Surface (T₁-terrace) and the Oldest Baikunthapur Surface (T₂-terrace). On the basis of numerous measurements, including As-content, pH, DO, specific conductivity and salinity, it was observed that maximum As-content beyond the permissible limit (0.05 mg/L, Indian standard) occurs within a depth range of 10–30 m with a non-linear distribution pattern. Variance test also found that a block effect was highly significant in an As-distribution pattern. Mean arsenic level of Kaliachak block-1 is 0.2253 mg/L, followed by Kaliachak-2 with arsenic level 0.1923, Kaliachak-3 with arsenic level 0.1755 and English Bazar with arsenic level 0.1324. The arsenious belt lies mainly within the Older terrace (T₁). The very recent flood plain deposits of silvery white, fine sands lying very close to the Ganga River margin do not contain significant amounts of As. Elevated As-concentration in the ground water was observed in alluvial sands, grayish white to brownish in color and occurring away from the Ganga margin. The Oldest terrace (T2) further away from the Ganga margin (e.g. English Bazar) and Barind surface contains less arsenic. Barind surface acts as a hard capping with ferruginous sands and lateritic concretions-chocolate, mottled and purple brown in color-occurring northeast of the studied area. Arsenic content of ground water in the same locality within a radius of ∼ 20 m varies within wide limits. Thus, it poses problem to delineate its distribution pattern. Such a patchy occurrence possibly could not be explained satisfactorily solely by geomorphology. Chemical analysis of aquifer clay samples of the cores shows a maximum Ascontent of up to 3 mg/kg, whereas the bulk samples (sandclay mixture) of the cores contain a maximum of 17 mg/kg As-value. Therefore, it is not always true that clay contains elevated As-value.     

Application of analytical hierarchy process (AHP) for flood risk assessment: a case study in Malda district of West Bengal,India

A field experiment was conducted from 2 May 2010 to 1 May 2012 in the Gurbantunggut Desert, the second largest desert in China, to investigate saltation activity and its threshold velocity, and their relations with atmospheric and soil conditions. The results showed that saltation activity occurred more frequently during 08:00–20:00 Local Standard Time in spring and summer, with air temperatures between 20.0 and 29.0 °C, water vapor pressures between 0.6 and 0.9 kPa, soil temperatures between 25.0 and 30.0 °C, and a soil moisture lower than 0.04 m³/m³. At 2 m height, the saltation threshold velocity varied between 11.1 and 13.9 m/s, with a mean of 12.5 m/s. Threshold velocity showed clear seasonal variations in the following sequence: spring (11.7 m/s) < autumn (12.7 m/s) < summer (13.6 m/s). Affected by soil conditions, aeolian sand transport was weak, with an average annual aeolian sand that transported across a section (1.0 m × 2.0 m) of less than 6.0 kg.     

Correction to: Application of analytical hierarchy process (AHP) for flood risk assessment: a case study in Malda district of West Bengal,India

Flow pulsations in two-phase and single-phase near-critical fluids are considered as a possible source of ultra-low-frequency seismo-electromagnetic variations. The conditions for generation and suppression of density wave instability in the crust are analyzed and the surface electromagnetic effect due to streaming potential generation is estimated. The upper limit of amplitude of magnetic field variations due to density wave instability is about 0.1 nT for single-phase supercritical and 1 nT for two-phase flow oscillations in the frequency range \(10^{-4}{-}10^{-2}~\) Hz for the temperature gradients and spatial scales possible during strike slip events. The signal is characterized by a decaying amplitude with typical relaxation time of about several quasi-periods. The possibility of generation of very low-frequency flow pulsations in two-phase fluids via individual bubble evolution and interaction with external acoustic waves is discussed.     

Investigation of fluoride contamination and its mobility in groundwater of Simlapal block of Bankura district,West Bengal,India

The occurrence of dental/skeletal fluorosis among the people in the study area provided the motivation to assess the distribution, severity and impact of fluoride contamination in groundwater of Bankura district at Simlapal block, West Bengal, India. To meet the desired objective, groundwater samples were collected from different locations of Laxmisagar, Machatora and Kusumkanali regions of Simlapal block at different depths of tube wells in both pre- and post-monsoon seasons. Geochemical results reveal that the groundwaters are mostly moderate- to hard-water type. Of total groundwater samples, 37% are situated mainly in relatively higher elevated region containing fluoride above 1.5 mg/L, indicating that host aquifers are severely affected by fluoride contamination. Machatora region is highly affected by fluoride contamination with maximum elevated concentration of 12.2 mg/L. Several symptoms of fluorosis among the different age-groups of people in Laxmisagar and Machatora areas are indicating consumption of fluoridated water for prolonged period. The groundwater samples were mainly Na–Ca–HCO₃ type and rock dominance indicating the dissolution of minerals taking place. Ion exchange between OH^? ion and F^? ion present in fluoride-bearing mineral is the most dominant mechanism of fluoride leaching. High concentration of Na⁺ and HCO₃ ^? increases the alkalinity of the water, providing a favorable condition for fluoride to leach into groundwater from its host rocks and minerals.     

Temporal variations in arsenic concentration in the groundwater of Murshidabad District,West Bengal,India

Systematic investigations on seasonal variations in arsenic (As) concentrations in groundwater in both space and time are scarce for most parts of West Bengal (India). Hence, this study has been undertaken to investigate the extent of As pollution and its temporal variability in parts of Murshidabad district (West Bengal, India). Water samples from 35 wells were collected during pre-monsoon, monsoon and post-monsoon seasons and analyzed for various elements. Based on the Indian permissible limit for As (50 μg/L) in the drinking water, water samples were classified into contaminated and uncontaminated category. 18 wells were reported as uncontaminated (on average 12 μg/L As) and 12 wells were found contaminated (129 μg/L As) throughout the year, while 5 wells could be classified as either contaminated or uncontaminated depending on when they were sampled. Although the number of wells that alternate between the contaminated and uncontaminated classification is relatively small (14%), distinct seasonal variation in As concentrations occur in all wells. This suggests that investigations conducted within the study area for the purpose of assessing the health risk posed by As in groundwater should not rely on a single round of water samples. In comparison to other areas, As is mainly released to the groundwater due to reductive dissolution of Fe-oxyhydroxides, a process, which is probably enhanced by anthropogenic input of organic carbon. The seasonal variation in As concentrations appear to be caused mainly by dilution effects during monsoon and post-monsoon. The relatively high concentrations of Mn (mean 0.9 mg/L), well above the WHO limit (0.4 mg/L), also cause great concern and necessitate further investigations.     

Hydrogeological processes controlling the release of arsenic in parts of 24 Parganas district,West Bengal

A study was conducted to understand the hydrogeological processes dominating in the North 24 Parganas and South 24 Parganas based on representative 39 groundwater samples collected from selected area. The abundance of major ions was in the order of Ca²⁺ > Na⁺ > Mg²⁺ > K⁺ > Fe²⁺ for cations and HCO₃ ^? > PO₄ ^3? > Cl^? > SO₄ ^2? > NO₃ ^? for anions. Piper trilinear diagram was plotted to understand the hydrochemical facies. Most of the samples are of Ca-HCO₃ type. Based on conventional graphical plots for (Ca + Mg) vs. (SO₄ + HCO₃) and (Na + K) vs. Cl, it is interpreted that silicate weathering and ion exchange are the dominant processes within the study area. Previous studies have reported quartz, feldspar, illite, and chlorite clay minerals as the major mineral components obtained by the XRD analysis of sediments. Mineralogical investigations by SEM and EDX of aquifer materials have shown the occurrence of arsenic as coating on mineral grains in the silty clay as well as in the sandy layers. Excessive withdrawal of groundwater for irrigation and drinking purposes is responsible for fluctuation of the water table in the West Bengal. Aeration beneath the ground surface caused by fluctuation of the water table may lead to the formation of carbonic acid. Carbonic acid is responsible for the weathering of silicate minerals, and due to the formation of clay as a product of weathering, ion exchange also dominates in the area. These hydrogeological processes may be responsible for the release of arsenic into the groundwater of the study area, which is a part of North 24 Parganas and South 24 Parganas.     

Distribution of arsenic and its mobility in shallow aquifer sediments from Ambikanagar, West Bengal, India

Sediments from a core retrieved during installation of a shallow drinking water well in Ambikanagar (West Bengal, India) were analyzed for various physical and chemical parameters. The geochemical analyses included: (1) a 4-step sequential extraction scheme to determine the distribution of As between different fractions, (2) As speciation (As³⁺ vs. As⁵⁺), and (3) C, N and S isotopes. The sediments have a low percentage of organic C and N (0.10-0.56% and 0.01-0.05%, respectively). Arsenic concentration is between 2 and 7 mg kg⁻¹, and it is mainly associated with the residual fraction, less susceptible to chemical weathering. The proportion of As³⁺ in these sediments is high and ranges from 24% to 74%. Arsenic in the second fraction (reducible) correlates well with Mn, and in the residual fraction As correlates well with several transition elements. The stable isotope results indicate microbial oxidation of organic matter involving SO₄ reduction. Oxidation of primary sulfide minerals and release of As from reduction of Fe-(oxy)hydroxides do not seem important mechanisms in As mobilization. Instead, the dominance of As³⁺ and presence of As⁵⁺ reducing microorganisms in this shallow aquifer imply As remobilization involving microbial processes that needs further investigations.     

Arsenic-enriched aquifers: Occurrences and mobilization of arsenic in groundwater of Ganges Delta Plain, Barasat, West Bengal, India

Hydrogeochemical characteristics and elemental features of groundwater and core sediments have been studied to better understand the sources and mobilization process responsible for As-enrichment in part of the Gangetic plain (Barasat, West Bengal, India). Analysis of water samples from shallow tubewells (depth 24.3–48.5 m) and piezometer wells (depth 12.2–79.2 m) demonstrate that the groundwater is mostly the Ca-HCO₃ type and anoxic in nature (mean Eh_SHE = 34 mV). Arsenic concentrations ranged from <10–538 μg/L, with high concentrations only present in the shallow to medium depth (30–50 m) of the aquifer along with high Fe (0.07–9.8 mg/L) and relatively low Mn (0.15–3.38 mg/L) as also evidenced in core sediments. Most groundwater samples contained both As(III) and As(V) species in which the concentration of As(III) was generally higher than that of As(V), exhibiting the reducing condition. Results show lower concentrations of NO₃, SO₄ and NO₂ along with higher values of DOC and HCO₃, indicating the reducing nature of the aquifer with abundant organic matter that can promote the release of As from sediments into groundwater. Positive correlations of As with Fe and DOC were also observed. The presence of DOC may actively drive the redox processes. This study revealed that reduction processes of FeOOH was the dominant mechanism for the release of As into the groundwater in this part of the Ganges Delta plain.     

A laboratory batch study on arsenic sorption and desorption on guava orchard soils of Baruipur,West Bengal,India

Groundwater contaminated with arsenic (As), when extensively used for irrigation, causes potentially long term detrimental effects to surface soils. Such contamination can also directly affect human health when irrigated crops, such as rice, vegetable and fruits, are used for human consumption. Therefore, an understanding of the sorption and desorption behavior of As in surface soils is of high importance, because these processes regulate the bioavailability of As in the soil environment. In this study, we have collected soils from guava orchards of Baruipur, West Bengal, and characterized soil chemistry and batch sorption and desorption behavior in the laboratory. The sorption and desorption behavior of As in the soils were examined using the Langmuir and Freundlich sorption equation. Regression analysis of the soil chemical characteristics and sorption equation parameters were also performed. The results suggest that the sorption behavior of arsenate is highly dependent on soil characteristics, specifically organic carbon, clay and Al₂O₃ content of the soils. Whereas desorption behavior is critically influenced by the presence of high concentrations of amorphous and/or crystalline Fe₂O₃ in the soils. Retention of the significant portion of As in the soils (~ 84% of the total) suggests that As in the orchard soils may not be highly bioavailable to plants for uptake. However, more detailed studies will be required to ascertain the role of individual soil components on the As sorption and desorption processes.     

Fluoride contamination of groundwater and its seasonal variability in parts of Purulia district,West Bengal,India

The contamination of aquifers by fluoride and arsenic is a major cause of concern in several parts of India. A study has thus been conducted to evaluate the extent and severity of fluoride contamination and also its seasonal variability. Two blocks (Purulia-1 and Purulia-2) were considered for this purpose. Twenty groundwater samples (in each season) were collected from tube wells during the pre-monsoon and post-monsoon seasons. In addition to fluoride, groundwater samples were also analyzed for major cations, anions, and other trace elements. The concentration of fluoride shows significant seasonal variation and ranges between 0.94–2.52 and 0.25–1.43 mg/l during the pre-monsoon and post-monsoon seasons, respectively. In pre-monsoon season, more than 40% of the water samples show fluoride concentrations higher than the WHO limit. However, during the post-monsoon season, none of the groundwater sample shows fluoride concentrations higher than the WHO limit. Lesser concentration during the post-monsoon season is attributed to the dilution effect by the percolating rainwater, which has also been reflected in the form of a decrease in concentrations of other elements. The petrographic studies of the rock samples collected from the study area show that the rocks are mainly composed of plagioclase, orthoclase, and quartz with abundant biotite. The weathering and dissolution of biotite plays an important role in controlling the fluoride concentrations in the groundwater of the study area.     

Inferring the hydro-geochemistry of fluoride contamination in Bankura district, West Bengal: A case study

In view of the recent reports of fluorosis in many parts of Bankura district, West Bengal, a detailed hydrogeochemical monitoring was carried out in the different blocks of Bankura to find out the level and extent of affectation. It is observed that the sub-surface environment of Bankura is appreciably contaminated with the deadly poison of fluoride. Out of the 3617 tube wells surveyed in 10 affected blocks, 612 sources are detected with fluoride above the desirable limit of 1 mg/l. In addition, down-the-hole rock drilling was performed at 15 different locations in 8 worst affected blocks of Bankura. Nearly 75% of the drill-hole rock chip samples and 62% of sub-surface water samples collected from different depths is found to have fluoride equal to or above 4000 mg/kg and 1 mg/l respectively. Detailed microscopic examination of drill chip samples has indicated diverse rock units in close succession, such as Chotanagpur Gneissic Complex, Singhbhum Group of rocks, anorthosite suite and unclassified metamorphics of Archaean-Proterozoic age. All these rocks have been intruded later by granitic fluids causing mineralization of fluoride to take place. Besides, fluoride is also found derived, to lesser extent, from Older Alluvium which bears different fluoride bearing minerals. Preliminary health surveys have revealed that dental and skeletal fluorosis are prevalent in the study area, which further corroborates with the analytical findings.     

Electrical resistivity investigation of the arsenic affected alluvial aquifers in West Bengal,India: usefulness in identifying the areas of low and high groundwater arsenic

This study aims at finding out possible relation between lithology and spatial pattern of dissolved arsenic (As) in groundwater around Chakdaha municipality, West Bengal, India. Satellite image, coupled with electrical resistivity survey and borehole drilling helps to delineate surface and sub-surface lithological framework of the As affected alluvial aquifers. The satellite imagery demonstrate that the high As area are presumably under active flood plain environment (low-lying areas), that constantly receive organics due to periodic flooding. Thick low resistive (fine-grained) layer was observed at the top around the high As areas, which, however, not found in low As areas. The result suggests that hydraulic properties of the surface/sub-surface soil/sediment have an important control on the fate and transport of As in the aquifer. This study demonstrates that electrical resistivity tools can be effectively used for the reconnaissance survey in characterizing the plausible lithological framework of an alluvial aquifer containing As.     

Hydrogeochemical processes and contaminants enrichment with special emphasis on fluoride in groundwater of Birbhum district,West Bengal,India

The hydrogeochemistry of groundwater in rural parts of Birbhum district, West Bengal, India, has been studied to understand the contaminants and prime processes involved in their enrichment with a focus on F^? concentration. The lithological units consist of Quaternary alluviums with underlying Rajmahal basaltic rocks of Middle Jurassic age. Groundwater occurs in the alluviums, weathered residuum and fracture zone of Rajmahal rocks. Studies show elevated concentration of Cl^?, SiO₂, Fe and F^?; excess Cl^? is attributed to anthropogenic inputs, SiO₂ is ascribed to high degree of weathering of silica rich host rocks, and high Fe is due to the interaction of water with Fe-rich sediments under reducing condition. The F^? concentration is found high (>1.20 mg/L) mainly in water from Rajmahal rocks revealing a lithological control on F^? enrichment. The weathering of silicates and ion exchange are the leading controlling processes for major ions in groundwater. The F^? enrichment is due to the dissolution of F^?-bearing minerals and perhaps also through anion exchange (OH^? for F^?) on clay minerals at high alkaline conditions; precipitation of CaCO₃ favours CaF₂ dissolution leading to elevated F^? concentration. CaHCO₃, the dominant water type, contains low F^? while NaHCO₃ and NaCl types exhibit high F^? concentrations. Among the three spatial associations, Cluster-1 and Cluster-2 are CaHCO₃ type; Cluster-3 shows NaHCO₃ and NaCl waters with low Ca²⁺ and Mg²⁺ and high Na⁺ contents. Cluster-1 and Cluster-2 waters are, in general, drinkable barring the elevated Fe content, while Cluster-3 water is unsafe for drinking due to the high F^? concentration.     

Palynological evidence for Jurassic strata in the Panagarh area, West Bengal, India

The Rajmahal Traps were discovered in the Panagarh area, West Bengal, during the exploration for coal resources. A Gondwana succession was found beneath the traps, consisting of the Early Cretaceous Intratrappean Rajmahal Formation, the Early Triassic Panchet Formation and the Late Permian coal-bearing Raniganj Formation. The present palynological study was aimed at confirming the age of the Panchet Formation. As a result of this study it has been found that Jurassic sediments are also included in the Panchet Formation. The study has revealed that the Panchet Formation, defined on a lithological basis, is a time-transgressive unit extending from the Early Triassic to the Late Jurassic, with a phase of non-deposition between the Middle Triassic and Middle Jurassic.     

Geochemical evolution of groundwater in southern Bengal Basin: The example of Rajarhat and adjoining areas,West Bengal,India

Detailed geochemical analysis of groundwater beneath 1223 km² area in southern Bengal Basin along with statistical analysis on the chemical data was attempted, to develop a better understanding of the geochemical processes that control the groundwater evolution in the deltaic aquifer of the region. Groundwater is categorized into three types: ‘excellent’, ‘good’ and ‘poor’ and seven hydrochemical facies are assigned to three broad types: ‘fresh’, ‘mixed’ and ‘brackish’ waters. The ‘fresh’ water type dominated with sodium indicates active flushing of the aquifer, whereas chloride-rich ‘brackish’ groundwater represents freshening of modified connate water. The ‘mixed’ type groundwater has possibly evolved due to hydraulic mixing of ‘fresh’ and ‘brackish’ waters. Enrichment of major ions in groundwater is due to weathering of feldspathic and ferro-magnesian minerals by percolating water. The groundwater of Rajarhat New Town (RNT) and adjacent areas in the north and southeast is contaminated with arsenic. Current-pumping may induce more arsenic to flow into the aquifers of RNT and Kolkata cities. Future large-scale pumping of groundwater beneath RNT can modify the hydrological system, which may transport arsenic and low quality water from adjacent aquifers to presently unpolluted aquifer.     

Geospatial modelling of flood susceptibility pattern in a subtropical area of West Bengal,India

Flood hazards are the most destructive among all natural disasters and are a constant threat to human’s life and property. Effective disaster risk reduction strategies can be improved by geospatial approach in the way of producing information and knowledge that are useful to plan truly effective actions for the protection from floods. This research aims to develop a quantified predictive model of flood susceptibility in the Ghatal and Tamluk subdivision of Medinipur district of West Bengal, India, by means of empirically selected and weighted spatial predictors of flood. The weighted prediction model is used to quantify the spatial associations between individual geospatial factors within the flood inundated study area. Yule’s coefficient and distance distribution analysis are used to assign weights to individual geo-factors, and finally weighted spatial predictors are integrated to a multi-class index overlay analysis to derive the spatially explicit predictive model of flood susceptibility. The resultant susceptibility model reveals that approximately 32.35 and 52.99% of the total study areas (3261.45 km²) are under the category of high-to-moderate flood susceptible zone. Quantitative results of this study could be integrated into the policy process in the formulation of local and national government plans for the future flood mitigation management and also to develop appropriate infrastructure in order to protect the lives and properties of the common people of the Medinipur district.     

Solid waste management through multi-criteria decision making: using analytic hierarchy process as an assessment framework for the Hooghly district,West Bengal

Solid waste management (SWM) is a crucial service governed by urban local bodies (ULB). Hence, it is essential to identify challenges and opportunities in the SWM procedures and practices towards improved delivery of services. In this study, analytic hierarchy process (AHP) has been applied in the three sub-divisional towns of the Hooghly district, West Bengal (India), namely Chandannagar, Hooghly-Chinsurah and Serampore to analyze the existing SWM scenario. As AHP is a Multi-Criteria Decision Making tool, hence, it has been deployed by experts to come up with SWM performance index, clearly demonstrating the strengths and weaknesses of management strategies in selected study sites. This article further advances the significance of the AHP method by carving out multi-layered realities through the quantification of qualitative insights across various segments of waste management in the three towns. While interviews with waste management officials led to the formulation of key performance indicators and sub-indicators matrix, the obtained normalized weights brought to the fore the real engagement and actions executed by each of these towns in managing solid wastes. The application of this innovative AHP method ensured accuracy in the ranking system across performance of the specified ULBs. This AHP-induced situational analysis of SWM is not only significant in terms of policy formulation in the ULBs of the Hooghly district but has potentials to work at scales.

Graphical abstract