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超高真空电子束蒸发合成晶态AlN薄膜的研究 总被引:4,自引:0,他引:4
用超高真空蒸发Al膜,结合氮化合处理工艺在Si(100)衬底上制备了AlN晶态薄膜,用X射线衍射,傅立叶变换红外光谱和X射线光电子能谱等测试分析技术研究了薄膜的微结构特征。结果表明:经过1000℃分钟氮化处理后,能形成具有(002)择优取向的AlN薄膜。 相似文献
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Ti/AlN快速退火界面反应的实验研究 总被引:4,自引:0,他引:4
在电子封装用的AlN陶瓷多晶衬底上生长250nm的Ti膜,并进行快速退火。用RBS(卢瑟福背散剂)、AES(俄歇有谱)、SIMS(干净人离子质谱)XRD(X射线衍射)等实验技术对界面反应进行了分析研究,用划痕实验测量了退火对Ti/AlN粘附力的影响。实验结果表明:快速退火时,Ti,Al,N以及AlN中掺杂的O均发生明显的界面扩散和界面反应,样品表面的O和AlN衬底中掺杂的O都向Ti膜中扩散,在较低 相似文献
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纳米GaAs—SiO镶嵌复合薄膜的发光特性 总被引:3,自引:0,他引:3
采用射频磁控共溅射法制备了纳米GaAs-SiO2镶嵌复合薄膜。通过X射线衍射、透射电镜观察和X射线光电子能谱等手段研究了薄膜的结构及其与沉积过程中基片温度间的关系。测量了薄膜的光致发光特性。表明,薄膜由晶态的GaAs及非晶Sdisplay status两相组成,GaAs在沉积过程中未明显氧化且以纳米颗粒形式均匀地弥散;GaAs的平均粒径依赖于沉积时的基片温度。通过控制基片温度,成功地获得了GaAs的平均粒径分 相似文献
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AlN陶恣成分怀发对于AlN的性能具有决定性作用,用二次离子质谱(SIMS)和X射线衍(XRD)对清华大学材料系电子封装用的AlN陶瓷进行了研究。SIMS谱表明AlN衬底中除Al,N以我有C,O,Si,Ca,Y等元素,其中有些是表面污染。衬底的SIMS深度分析表明样品O,Ca,Y信号都很强,且分布均匀,说明样口 含有Y2O3,CaO添加剂,AlN样品的XRD谱与AlN的JCPDS卡片对照,在测量范 相似文献
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多孔陶瓷薄膜表面形貌研究 总被引:4,自引:0,他引:4
用原子力显微镜(AFM)观察Al2O3、Al2O3-SiO2及Al2O3-SiO2-TiO2复合陶瓷薄膜的表面形貌,X射线衍射(XRD)分析表明,Al2O3薄膜的上为γ-Al2O3;Al2O3-SiO2薄由γ-Al2O3和非晶诚SiO2组成;而Al2O3-SiO2-TiO2薄膜的相成分为Al2O3、TiO2、Al4Ti2SiO12和非晶态SiO2,各相的含量随化学成分变化而变化,AFM观察结果表明 相似文献
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助烧剂对热压Si3N4基陶瓷组织结构的影响 总被引:1,自引:0,他引:1
用XRD,SEM,TEM分析了用Y2O3+Al2O3及Y2O3+AlN做助烧剂的两种热压Si3N4基陶瓷的组织结构,用EDXA分析了Si,Al,Y等元素的含量。结果表明,两种Si3N4都是由长柱状β相组成; 相似文献
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Hyunsoo Lim Jeonghun Kim Kenya Kani Mostafa Kamal Masud Hyeongyu Park Minjun Kim Saad M. Alsheri Tansir Ahamad Norah Alhokbany Jongbeom Na Victor Malgras Yoshio Bando Yusuke Yamauchi 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(12)
Mesoporous noble metals and their patterning techniques for obtaining unique patterned structures are highly attractive for electrocatalysis, photocatalysis, and optoelectronics device applications owing to their expedient properties such as high level of exposed active locations, cascade electrocatalytic sites, and large surface area. However, patterning techniques for mesoporous substrates are still limited to metal oxide and silica films, although there is growing demand for developing techniques related to patterning mesoporous metals. In this study, the first demonstration of mesoporous metal films on patterned gold (Au) substrates, prefabricated using photolithographic techniques, is reported. First, different growth rates of mesoporous Au metal films on patterned Au substrates are demonstrated by varying deposition times and voltages. In addition, mesoporous Au films are also fabricated on various patterns of Au substrates including stripe and mesh lines. An alternative fabrication method using a photoresist insulating mask also yields growth of mesoporous Au within the patterning. Moreover, patterned mesoporous films of palladium (Pd) and palladium–copper alloy (PdCu) are demonstrated on the same types of substrates to show versatility of this method. Patterned mesoporous Au films (PMGFs) show higher electrochemically active surface area (ECSA) and higher sensitivity toward glucose oxidation than nonpatterned mesoporous Au films (NMGF). 相似文献
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本文介绍了制备聚酰亚胺LB膜的“前聚物法”以及通过引入不同结构基团或各种后处理以得到不同性能的聚酰亚胺LB膜和它们各种可能的应用。 相似文献
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Luciana Gaffo Valtencir Zucolotto Wania C. Moreira Fernando Cerdeira 《Thin solid films》2007,515(18):7307-7312
The processing of macrocyclic phthalocyanines (Pc) in the form of thin, nanostructured films has been usually carried out via evaporation techniques, owing to the low solubility exhibited by these compounds. The fabrication of Pc ultrathin films via the Langmuir-Blodgett technique may be advantageous from a technological point of view, since parameters such as film architecture and organization can be achieved without post-thermal treatments. In this study, a parent zinc phthalocyanine (ZnPc) and its fluorinated derivative (F16ZnPc) were synthesized and manipulated in the form of LB films. The morphological and structural features of ZnPc and F16ZnPc Langmuir-Blodgett films containing up to 31 layers were investigated using Fourier transform infrared spectroscopy (FTIR), micro-Raman spectroscopy and X-ray diffraction analyses and were compared to ZnPc and F16ZnPc cast films. The interplanar distance obtained by X-ray specular reflection decreases from 12.64 Å for ZnPc to 12.16 Å for F16ZnPc. FTIR spectra indicated absence of order in the LB films from ZnPc and F16ZnPc, at least in the direction perpendicular to the substrate surface. Therefore, the order observed in the X-ray diffractograms means that the molecules might be organized in crystallites that are randomly oriented in the film. 相似文献
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利用低温水热合成工艺,在一定浓度皆Pb(NO)3,TiClr的混合强碱性水溶液中,和在(120℃,0.25MPa)的水热反应条件下,首次成功地在SrTeO3单昌衬底上生长出具有面积构的PbTiO3外延薄膜。 相似文献
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采用纯 Zr、添 Y_2O_3的 ZrO_2和添 MgO 的 ZrO_2为靶材,以射频溅射方法生成 ZrO_2薄膜。研究了这三个系列薄膜的物相结构,以及退火和研磨对物相结构的影响。研究表明,ZrO_2薄膜为单斜相,Y-ZrO_2和 Mg-ZrO_2薄膜为单斜相和正方相,且以正方相为主。它们的退火规律也各不相同,这与稳定剂的加入与性质有关。同时研磨并未诱导正方相向单斜相的转变。 相似文献
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The work was focused on the deposition of Al2O3+Pt composite in the form of a nanofilm adherent to the substrate with good surface development and catalytic properties on the surface of 0H20J5 foil. With this end in view, a special carousel fixture for fixing the corrugated and flat foil and then coating with Al and Pt from two magnetron sources, in order to obtain a nanofilm of Al+Pt composite, was designed. A Pt/Al laminate layer was also produced by depositing Pt first and then Al, and the other way round. The layer systems obtained this way were subject to oxidation for 48 h at 860 °C and under Ar+O2. The surface examined has shown that the process of oxidation produces the compact sublayer of columnar crystals (whiskers) well adherent to the substrate from which the needle-like whiskers are growing. Structures of whiskers form a laminar system with a catalytic element having a very-well developed surface. Structure analyses revealed that the films obtained comprised mostly α and θ Al2O3 phases and missed a Pt crystalline phase. The film morphology on the basis of oxide-film sections examined by TEM showed that the α Al2O3 structure was generated mostly deep in oxide films and was integrated with the foil. A microanalysis showed that it was uniformly distributed in its entirety in the Pt-composite based layers; however, in the case of laminate the surface of whiskers was coated. It was found from the comparison of the laminar system activity that the composite layers revealed much better catalytic properties at lower temperature than the laminate layers. 相似文献