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1.
The internal riverine processes acting upon phosphorus and dissolved silicon were investigated along a 55 km stretch of the River Swale during four monitoring campaigns. Samples of river water were taken at 3 h intervals at sites on the main river and the three major tributaries. Samples were analysed for soluble reactive phosphorus, total dissolved phosphorus, total phosphorus, dissolved silicon and suspended solid concentration. Mass‐balances for each determinand were calculated by comparing the total load entering the river with the total load measured at the downstream site. The difference, i.e. the residual load, showed that there was a large retention of phosphorus and silicon within the system during the March 1998 flood event, but the other three campaigns produced net‐exports. Cumulative residual loads were calculated for each determinand at 6 h intervals throughout each campaign. This incremental approach showed that the mass‐balance residuals followed relatively consistent patterns under various river discharges. During stable low‐flow, there was a retention of particulate phosphorus within the system and also a retention of total dissolved phosphorus and soluble reactive phosphorus, most likely caused by the sorption of soluble phosphorus by bed‐sediments. In times of high river‐discharge, there was a mobilization and export of stored bed‐sediment phosphorus. During overbank flooding, there was a large retention (58% of total input) of particulate phosphorus within the system, due to the mass deposition of phosphorus‐rich sediment onto the floodplain. Soluble phosphorus was also retained within the system by sequestration from the water column by the high concentration of suspended solids. The dissolved silicon mass‐balance residuals had a less consistent pattern in relation to river discharge. There was a large retention of dissolved silicon during overbank flooding, possibly due to sorption onto floodplain soil, and net‐exports during periods of both stable low‐flow and rising limbs of hydrographs, due to release of dissolved silicon from pore‐waters. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

2.
Concentrations of heavy metals (Cd, Cu, Pb and Zn) on suspended sediments during a flood event at Thwaite Mills, River Aire, were analysed using a five step sequential extraction technique to determine their major chemical associations (exchangeable, surface oxide and carbonate, Fe and Mn oxides, organic and residual metal ions). Total metal concentrations were lowest at higher discharges, resulting from dilution by clean sediment. The major transport fractions are the Fe and Mn oxides, which carry 29% of the total metals. Knowledge of the chemical forms of heavy metals on suspended sediment is essential for estimating their biological availability and physicochemical reactivity. © 1998 John Wiley & Sons, Ltd.  相似文献   

3.
In recent years, there has been an increasing awareness of the important role of fine sediment in the transport and storage of metals in fluvial systems. However, there has been little research on the behaviour of contaminated sediment in industrial rivers in the UK. This paper examines spatial and temporal variations in the concentration and speciation of lead, copper and chromium associated with suspended sediment in the River Aire in Yorkshire, UK. An increase in the total concentration of all three metals in sediment was identified in the lower reaches, which reflected inputs of road dust, sewage and industrial effluents. Spatial variations in the chemical speciation of the metals were also identified. The iron–manganese oxides and organic fractions were the most significant for the adsorption of metals by sediment. Both the concentrations and speciation of sediment‐associated metals exhibited substantial temporal variation. Such variation reflected the accumulation of metals and organic matter on the river‐bed during low flows, the subsequent remobilization of the sediment at high flows and the additional supply of sediment from uncontaminated and contaminated sources, including pulse inputs of road dust, sewage and industrial effluent. The findings presented have important implications for the development of effective catchment management strategies for the control of point‐ and diffuse‐source pollution. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

4.
The channel boundary conditions along the Lower Yellow River (LYR) have been altered significantly since the 1950s with the continual reinforcement and construction of both main and secondary dykes and river training works. To evaluate how the confined complex channel–floodplain system of the LYR responds to floods, this study presents a detailed investigation of the relationship between the tempo‐spatial distribution of sedimentation/erosion and overbank floods occurred in the LYR. For large overbank floods, we found that when the sediment transport coefficient (ratio of sediment concentration of flow to flow discharge) is less than 0.034, the bankfull channel is subject to significant erosion, whereas the main and secondary floodplains both accumulate sediment. The amount of sediment deposited on the main and secondary floodplains is closely related to the ratio of peak discharge to bankfull discharge, volume of water flowing over the floodplains, and sediment concentration of overbank flow, whereas the degree of erosion in the bankfull channel is related to the amount of sediment deposited on the main and secondary floodplains, water volume, and sediment load in flood season. The significant increase in erosion in the bankfull channel is due to the construction of the main and secondary dykes and river training works, which are largely in a wide and narrow alternated pattern along the LYR such that the water flowing over wider floodplains returns to the channel downstream after it drops sediment. For small overbank floods, the bankfull channel is subject to erosion when the sediment transport coefficient is less than 0.028, whereas the amount of sediment deposited on the secondary floodplain is associated closely with the sediment concentration of flow. Over the entire length of the LYR, the situation of erosion in the bankfull channel and sediment deposition on the main and secondary floodplains occurred mainly in the upper reach of the LYR, in which a channel wandering in planform has been well developed.  相似文献   

5.
Before 1900, the Missouri–Mississippi River system transported an estimated 400 million metric tons per year of sediment from the interior of the United States to coastal Louisiana. During the last two decades (1987–2006), this transport has averaged 145 million metric tons per year. The cause for this substantial decrease in sediment has been attributed to the trapping characteristics of dams constructed on the muddy part of the Missouri River during the 1950s. However, reexamination of more than 60 years of water‐ and sediment‐discharge data indicates that the dams alone are not the sole cause. These dams trap about 100–150 million metric tons per year, which represent about half the decrease in sediment discharge near the mouth of the Mississippi. Changes in relations between water discharge and suspended‐sediment concentration suggest that the Missouri–Mississippi has been transformed from a transport‐limited to a supply‐limited system. Thus, other engineering activities such as meander cutoffs, river‐training structures, and bank revetments as well as soil erosion controls have trapped sediment, eliminated sediment sources, or protected sediment that was once available for transport episodically throughout the year. Removing major engineering structures such as dams probably would not restore sediment discharges to pre‐1900 state, mainly because of the numerous smaller engineering structures and other soil‐retention works throughout the Missouri–Mississippi system. Published in 2009 by John Wiley & Sons, Ltd.  相似文献   

6.
Floods have become increasingly important in fluvial export of water, sediment and carbon (C). Using high-frequency sampling, the export of water, sediment and C was examined in the Wuding River catchment on the Chinese Loess Plateau. With groundwater as an important contributor to runoff all year round, floods were relatively less important in the export of water. However, large floods were disproportionately important in exporting sediment and inorganic C (DIC) and organic C (DOC and POC). The three largest floods in each year transported 53.6–97.3 and 41.4–77% of the annual sediment and C fluxes, respectively. An extreme flood in 2017 alone contributed 94.6 and 73.1% of the annual sediment and C fluxes, respectively, in just 7 days, which included 20.3, 92.1 and 35.7% of the annual DOC, POC and DIC fluxes, respectively. A stable carbon isotope (δ13C) analysis of POC indicated that modern soils and C3 plants were its primary source. Furthermore, floods greatly accelerated CO2 degassing due to elevated gas transfer velocity, although stream water CO2 partial pressure (pCO2) exhibited a decreasing trend with flow discharge. Although these results illustrated that increasing runoff diluted pCO2, the timing and magnitude of floods were found to be critical in determining the response of pCO2 to flow dynamics. Low-magnitude floods in the early wet season increased pCO2 because of enhanced organic matter input, while subsequent large floods caused a lower pCO2 due to greatly reduced organic matter supply. Finally, continuous monitoring of a complete flood event showed that the CO2 efflux during the flood (2348 ± 664 mg C m–2 day–1) was three times that under low-flow conditions (808 ± 98 mg C m–2 day–1). Our study suggests that infrequent, heavy storm events, which are predicted to increase under climate change, will greatly alter the transport regimes of sediment and C. © 2020 John Wiley & Sons, Ltd.  相似文献   

7.
This paper describes the geochemistry of sediment samples placed in floodplains and alluvial terraces downstream from gold mines in the Carmo River basin, Quadrilátero Ferrífero, Minas Gerais, Brazil. The geochemistry signature Na2O, K2O, SiO2, CaO, MgO, Al2O3, Fe2O3, TiO2, P2O5, Mn, As, Cu, Zn, Ba, Ni, Cr, S, Co were analyzed in different facies from stratigraphic profiles. As, Cu, Zn, and Mn anomalies are mainly associated with the clayed facies deposited in floodplains and oxbow lakes, and with coarse‐sediment facies deposited in the channel. The facies were accumulated by the gold exploitation activity in the region. The contamination of As, Cu, and Zn was controlled by minerals such as iron oxides and hydroxides (hematite, magnetite, and mainly goethite), manganese oxides, and sulfide‐rich minerals. The As‐bearing sediments of the region characterize one of the most As contaminated area of Brazil. Their main source is associated with gold exploration in the last three centuries.  相似文献   

8.
Serious soil erosion on the Loess Plateau has be-come the focus of world attention.As early as the1950s China has started soil and water conservation work on the Loess Plateau in order to improve the lo-cal eco-environment and mitigate the threat of the coarse sediment in the middle Yellow River to the river channel at downstream.Facts proved that the best alternative is the integrated management of hill slopes and gullies in combination with biological and engineering measures.Biological m…  相似文献   

9.
Deposition and storage of fine‐grained (<62·5 μm) sediment in the hyporheic zone of gravel bed rivers frequently represents an important cause of aquatic habitat degradation. The particle size characteristics of such fine‐grained bed sediment (FGBS) exert an important control on its hydrodynamic properties and environmental impact. Traditionally, particle size analysis of FGBS in gravel bed rivers has focused on the absolute size distribution of the chemically dispersed mineral fraction. However, recent work has indicated that in common with fluvial suspended sediment, significant differences may exist between the absolute and the in situ, or effective, particle size composition of FGBS, as a result of the existence of aggregates, or composite particles. In the investigation reported in this paper, sealable bed traps that could be remotely opened to sample sediment deposited during specific storm runoff events and a laser back‐scatter probe were used to quantify the temporal and spatial variability of both the absolute and effective particle size composition of FGBS, and the associated suspended sediment from four gravel bed rivers in the Exe Basin, Devon, UK. The absolute particle size distributions of both the FGBS and suspended sediment evidenced c. >95%<62·5 μm sized primary particles and displayed a seasonal winter–summer fining, while the opposite trend was displayed by the effective particle size distribution of the FGBS and suspended sediment. The effective particle size distributions of both were typically highly aggregated, comprising up to 68%>62·5 μm sized particles. Spatial variation in the effective particle size and aggregation parameters was of secondary importance relative to temporal variation. The effective particle size distribution of the FGBS was consistently coarser and more aggregated than the associated suspended sediment and there was evidence of aggregate break‐up in samples of resuspended bed sediment. The implications of these findings for sediment transport modelling are considered. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

10.
The central route of the South–North Water Transfer Project (CTP) is designed to divert approximately 9.5 billion m3 of water per year from the Han River, a major tributary of the Yangtze River, to the Hai River basin in the north China. The main purpose of this study is to assess the impact of CTP on groundwater table in the Hai River basin. Our study features a large‐scale distributed hydrological model that couples a physically based groundwater module, which is sub‐basin‐based, with a conceptual surface water module, which is grid‐based. There are several grids in each sub‐basin and water exchange among grid that are considered. Our model couples surface water module and groundwater module and calculates human water use at the same time. The simulation results indicate that even with the water supply by CTP, the groundwater table will continue to decline in the Hai River basin. However, the CTP water can evidently reduce the decline rate, helping alleviate groundwater overexploitation in Hai River region. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

11.
Due to the temporal decoupling of water and sediment sources in a large river basin, a flood from a sediment source area with high suspended sediment concentration (SSC) may be diluted by flow from a major runoff source area with low SSC. In this paper, this dilution effect is considered for 145 flood events from the Yellow River, China. Two indices (β1 and β2) describing the dilution effect are proposed, based on water and sediment from the clear water source area and the coarse sediment producing area. Regression equations between channel sedimentation (Sdep) and β1 and β2 are established based on flood events and annual data, respectively. The results show that dilution reduces channel sedimentation in the lower reaches by 34?1% and that this is related to a reduced frequency of hyperconcentrated flows in the lower reaches. The Longyangxia Reservoir for hydro‐electric generation has stored huge quantities of clear runoff from the upper Yellow River during high‐flow season since 1985, greatly reducing the dilution of the hyperconcentrated floods and therefore enhancing sedimentation in the lower reaches. For the purpose of reducing sedimentation, changing the operational mode of the Longyangxia Reservoir to restore the dilution effect is suggested. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

12.
The flood in the Odra river in 1997 has led to considerable additional pollution of the Stettin Lagoon and the Baltic Sea with contaminated suspended solids. For some priority substances, the pollutant entries via suspended solids during the flood period are estimated to be approximately 1/3 of the usual annual load. Among these priority pollutants there are total organic carbon (TOC), nitrogen, and the heavy metals Cu, Pb and Zn. For the concentrations of the priority pollutants in suspended solids accumulation factors from 2 to 4 in the comparison with normal conditions were observed. On the basis of the analysis of sediments sampled after the flood, main sources of the pollutants should be evaluated. As reference area with an industrial background as well as a typical pollutant pattern the region around Glogow/Legnica is proposed.  相似文献   

13.
The study applies the improved cloud‐free moderate resolution imaging spectral radiometer daily snow cover product (MODMYD_MC) to investigate the snow cover variations from snow hydrologic year (HY) HY2000 to HY2013 in the Amur River basin (ARB), Northeast Asia. The fractions of forest cover were 38%, 63%, and 47% in 2009 in China (the southern ARB), Russia (the northern ARB), and ARB, respectively. Validation results show that MODMYD_MC has a snow agreement of 88% against in situ snow depth (SD) observations (SD ≥ 4 cm). The agreement is about 10% lower at the forested stations than at the nonforested stations. Snow cover durations (SCDs) from MODMYD_MC are 20 days shorter than ground observations (SD ≥ 1 cm) at the forested stations, whereas they are just 8 days shorter than ground observations (SD ≥ 1 cm) at the nonforested stations. Annual mean SCDs from MODMYD_MC in the forested areas are 21 days shorter than those in the nearby farmland in the Sanjiang Plain. This indicates forest has a complex influence on the snow accumulation and melting processes and even on optical satellite snow cover mapping. Meanwhile, SCD and mean snow cover are negatively correlated with air temperature in ARB, especially in the snow melting season, when mean air temperature in March and April can explain 86% and 74% of the mean snow cover variations in China ARB and Russia ARB, respectively. From 1961 to 2015, the annual mean air temperature presented an increased trend by 0.33 °C/decade in both China ARB and Russia ARB, whereas it had a decrease trend from HY2000 to HY2013. The decrease of air temperature led to an increase of snow cover, which is different from the global decrease trend of snow cover variations. SCD and snow cover had larger increase rates in China ARB than in Russia ARB, and they were larger in the forested areas than in the nearby farmland in the Sanjiang Plain.  相似文献   

14.
Low water levels occurring on the Warsaw section of the Vistula River during droughts in 2012 and 2015 stirred considerable interest by exposing parts of the riverbed. The river's low flow discharge created favourable conditions for archaeologists who, from the river's bottom, managed to salvage sculptures, architectural artefacts, and military accessories dating back to the middle of the 17th century. Literature shows that archaeological finds at the bottom of a major lowland river are unique and are attributed to very specific hydrological and geological conditions. Embankments and works meant to regulate the channel of the Vistula River in Warsaw narrowed the channel and accelerated the erosion of the river's bottom. A comparison of rating curves created between 1919 and 2015 shows that the river's bottom had lowered by 225 cm. The diameter of sediment particles that could be moved at maximum shear stress has been calculated using the Meyer–Peter and Muller formula. According to the calculated shear stress corresponding to the highest historical flood of 1844 particles smaller than 0.05 m were transported down the river, and it is true that artefacts of that size had not been collected at the site. Taking into consideration the very specific geological and hydrological conditions, we believe that finding so many 17th century artefacts with a well‐documented history at a site at the bottom of major lowland river with intensive channel processes is indeed unique. Additionally, it is the first time that results of hydrodynamic modelling have been successfully used for archaeological survey to define the critical shear stress and the smallest diameter of artefacts, which could remain stable on a river's bottom.  相似文献   

15.
The glacially formed northeastern German lowlands are characterized by extensive floodplains, often interrupted by relatively steep moraine hills. The hydrological cycle of this area is governed by the tight interaction of surface water dynamics and the corresponding directly connected shallow groundwater aquifer. Runoff generation processes, as well as the extent and spatial distribution of the interaction between surface water and groundwater, are controlled by floodplain topography and by surface water dynamics. A modelling approach based on extensive experimental analyses is presented that describes the specific water balance of lowland areas, including the interactions of groundwater and surface water, as well as reflecting the important role of time‐variable shallow groundwater stages for runoff generation in floodplains. In the first part, experimental investigations of floodplain hydrological characteristics lead to a qualitative understanding of the water balance processes and to the development of a conceptual model of the water balance and groundwater dynamics of the study area. Thereby model requirements which allow for an adequate simulation of the floodplain hydrology, considering also interactions between groundwater and surface water have been characterized. Based on these analyses, the Integrated Modelling of Water Balance and Nutrient Dynamics (IWAN) approach has been developed. This consists of coupling the surface runoff generation and soil water routines of the deterministic, spatially distributed hydrological model WASIM‐ETH‐I with the three‐dimensional finite‐difference‐based numerical groundwater model MODFLOW and Processing MODFLOW. The model was applied successfully to a mesoscale subcatchment of the Havel River in northeast Germany. It was calibrated for two small catchments (1·4 and 25 km2), where the importance of the interaction processes between groundwater and surface waters and the sensitivity of several controlling parameters could be quantified. Validation results are satisfying for different years for the entire 198 km2 catchment. The model approach was further successfully tested for specific events. The experimental area is a typical example of a floodplain‐dominated landscape. It was demonstrated that the lateral flow processes and the interactions between groundwater and surface water have a major importance for the water balance and periodically superimposed on the vertical runoff generation. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

16.
In this study, we investigated the responses of hydrology and sediment yield with impacts of land‐use and climate change scenarios in the Be River Catchment, using the Soil and Water Assessment Tool (SWAT) hydrological model. The calibration and validation results indicated that the SWAT model is a powerful tool for simulating the impact of environmental change on hydrology and sediment yield in this catchment. The hydrologic and sediment yield responses to land‐use and climate changes were simulated based on the calibrated model. The results indicated that a 16.3% decrease in forest land is likely to increase streamflow (0.2 to 0.4%), sediment load (1.8 to 3.0%), and surface runoff (SURQ) (4.8 to 10.7%) and to decrease groundwater discharge (GW_Q) (3.5 to 7.9%). Climate change in the catchment leads to decreases in streamflow (0.7 to 6.9%) and GW_Q (3.0 to 8.4%), increase in evapotranspiration (0.5 to 2.9%), and changes in SURQ (?5.3 to 2.3%) and sediment load (?5.3 to 4.4%). The combined impacts of land‐use and climate changes decrease streamflow (2.0 to 3.9%) and GW_Q (12.3 to 14.0%), increase evapotranspiration (0.7 to 2.8%), SURQ (8.2 to 12.4%), and sediment load (2.0 to 7.9%). In general, the separate impacts of climate and land‐use changes on streamflow, sediment load, and water balance components are offset each other. However, SURQ and some component of subsurface flow are more sensitive to land‐use change than to climate change. Furthermore, the results emphasized water scarcity during the dry season and increased soil erosion during the wet season. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

17.
The annual hydrological regime of the Nakambe River shows substantial changes during the period 1955–1998 with a shift occurring around 1970. From 1970 to the mid-1990s, despite a reduction in rainfall and an increase in the number of dams in the basin, average runoff and maximum daily discharges increased. This paper reviews the hydrological behaviour of the Nakambe River from 1955 to 1998 and examines the potential role of land use change on soil water holding capacity (WHC) in producing the counter-intuitive change in runoff observed after 1970. We compare the results of two monthly hydrological models using different rainfall, potential evapotranspiration and WHC data sets. Model simulations with soil WHC values modified over time based upon historical maps of land use, are compared against simulations with a constant value for WHC. The extent of natural vegetation declined from 43 to 13% of the total basin area between 1965 and 1995, whilst the cultivated areas increased from 53 to 76% and the area of bare soil nearly tripled from 4 to 11%. The total reduction in WHC is estimated to range from 33 to 62% depending on the method used, either considering that the WHC values given by the FAO stand for the environmental situation in 1965 or before. There is a marked improvement in river flow simulation using the time-varying values of soil WHC. The paper ends with a discussion of the role of other factors such as surface runoff processes and groundwater trends in explaining the hydrological behaviour of the Nakambe River.  相似文献   

18.
During 1998/1999, surface and subsurface sediment samples were collected along the entire length of the Spokane River from its outlet at the northern end of Lake Coeur d'Alene (CDA), Idaho, to Lake Roosevelt on the Columbia River, Washington. The study was conducted to determine if the trace element enrichments observed in Lake CDA and on the floodplain and in the CDA River extend through the Spokane River Basin (SRB). As in Lake CDA, surface sediments in the SRB are enriched in Pb, Zn, As, Cd, Sb and Hg relative to local background levels. Pb, Cd and Zn are the most elevated, with maximum enrichment occurring in the upper Spokane River in close proximity to Lake CDA. On average, enrichment decreases downstream, apparently reflecting both increased distance from the inferred source (the CDA River Basin), as well as increased dilution by locally derived but unenriched materials. Only Cd and Zn display marked enrichment throughout the SRB. Pb, Zn and Cd seem to be associated mainly with an operationally defined iron oxide phase, whereas the majority of the As and Sb seem to be matrix‐held. Subsurface sediments also are enriched in Pb, Zn, As, Cd, Sb and Hg relative to background levels. Based on 137Cs and excess 210Pb dating, trace element enrichment began in the middle part of the SRB (Long Lake) between 1900 and 1920. This is contemporaneous with similar enrichments observed in Lake CDA, as well as the completion of Long Lake Dam (1913). In the most downstream part of the basin (Spokane River Arm of Lake Roosevelt), enrichment began substantially later, between 1930 and 1940. The temporal difference in enrichment between Long Lake and the River Arm may reflect the latter's greater distance from the presumed source of the enrichment (the CDA River Basin); however, the difference is more likely the result of the completion of Grand Coulee Dam (1934–1941), which formed Lake Roosevelt, backed up the Spokane River, and increased water levels in the River Arm by about 30 m.  相似文献   

19.
The mining of alluvial tin in the Ringarooma basin began in 1875, reached a peak in 1900–20, and had virtually ceased by 1982. During that time 40 million m3 of mining waste were supplied to the main river, quickly replacing the natural bed material and requiring major adjustments to the channel. Based on estimates of sediment supply from more than 50 widely scattered mines and the frequency of flows capable of transporting the introduced load, the river's transport history is reconstructed using a mass-conservation model. Because of the lengthy time period (110 years) and river distance (75 km) involved, the model cannot predict detailed change but it does reproduce the main pattern of sediment movement in which successive phases of aggradation and degradation progress downstream. Peak storage is predicted in that part of the river where braiding and anastomosis are best developed. Aggradation was most rapid in the upper reaches close to major supply points, becoming slower and later with distance downstream. Channel width increased by up to 300 per cent where the valley floor was broad and braiding became relatively common. Bridges had frequently to be replaced. While bed levels were still rising in lower reaches, degradation began in upper ones, notably after 1950, and by 1984 had progressed downriver over 30 km. Rates of incision reached 0·5 m yr?1, especially in the early 1970s when record high flows occurred. As a result of degradation the bed material became gravelly through either reexposure of the original bed or lag concentration of coarser fractions. Also a narrower unbraided channel has developed. The river is beginning to heal itself and upper reaches now have reasonably stable beds but at least another 50 years will be required for the river to cleanse its channel of mining debris.  相似文献   

20.
From 2002 through 2004, time-series sediment trap samples were collected from a depth of 410 m in Cuenca Alfonso, Bahía de La Paz, on the SW coast of the Gulf of California. The instrument recorded the impact of the local passage of hurricanes “Ignacio” (24–26 August) and “Marty” (21–23 September) in 2003. These two events accounted for 82% of the total rainfall measured in 2003, equivalent to the annual average precipitation in years without hurricanes. Mean total mass fluxes (TMFs) of 2.88 and 3.58 g m−2 d−1 were measured during the week of each hurricane as well as the following week. This may have been enough to produce a lamina in the underlying sediment with characteristics peculiar to such events. The terrigenous component was particularly abundant, with notably higher concentrations of Fe, Sc, Co and Cs and REEs. In contrast, TMFs throughout 2002–2004 (excluding the hurricane periods) averaged only 0.73 g m−2 d−1 and had a larger marine biogenic component. The extraordinary elemental fluxes during the 29 days of hurricane-influenced sedimentation represented a great proportion of the totals over an entire “normal” year: Co (67.8%) >Sc (62.6) >Fe (59.6) >Cs (53.4)>Lu (51.5)>La (51.3)>Yb (51.0)>Ce (49.5) >Tb (48.4) >Sm (44.7)>Cr (36.5) >Ca (31.0)>Eu (25.4%). The terrigenous fraction was calculated using (a) TMF minus the sum of CaCO3, biogenic silica and organic matter and (b) the ratio of Sc in the trap samples to the average in the Earth's crust. The latter was consistently smaller, but the two methods offered similar results following hurricanes (78% vs. 63%, respectively). For normal sedimentation, however, the difference method yielded values twice as large as the Sc method (58% vs. 30%) This suggests that the mineralogy of the terrigenous fraction may also vary, with unsorted dessert soil being carried to sea by the powerful flash floods associated with hurricanes. Eolian supply of particles, particularly Sc-free quartz grains, possibly from beyond the limited fluvial drainage basin, apparently dominates normal sedimentation.  相似文献   

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