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1.
采用高温固相合成了一种新的类Sr2Be2B2O7族化合物KCaZn2(BO3)2F,利用粉末X射线衍射精修其晶体结构.该晶体同KCdZn2(BO3) 2F同构,为三方晶系,空间群为P31c,单胞参数为a=5.03096(5)A,c=15.3940(2)A,Z=2.晶体基本阴离子基元是平面三角形的BO3和四面体的ZnO3F基元,两个基元通过共顶的O原子相连,在ab平面形成二维的十二元环的(Zn3B3O6 F3)∞结构.(Zn3B3O6F3)∞结构通过F原子连接,形成(Zr6B6O12F3)∞双层单元,双层单元之内的两层BO3基元排列方式基本相反.(Zn6B6O12F3)∞双层单元与同它中心对称的另一个(Zn6B6O12F3)∞双层单元在c方向堆垛成三维的结构,K+和Ca2+分别位于(Zn6B6O12F3)∞双层单元的层内和层间空隙处.紫外可见漫反射光谱表明该晶体在400~2500 nm范围具有高的透过率,晶体的紫外截止波长为235 nm.  相似文献   

2.
以Na2CO3-H3BO3-NaF为助熔剂,使用顶部籽晶法生长出Na3La2(BO3)3透明单晶.测定了Na3La2(BO3)3的晶体结构,该晶体属正交晶系,空间群:mm2(No.38),晶胞参数为a=0.51580(10)nm,b=1.1350(2)nm,c=0.73230(15)nm,α=β=γ=90°,V=0.42871(15)nm3,密度:.053g/cm3.晶体结构中的硼氧基团是平面的BO3基团,BO3基团相互独立,且与Na(1)O6、Na(2)O8、Na(3)O6和La(1)O9配位多面体连结形成三维网络骨架结构.讨论了Na3La2(BO3)3的晶体结构与倍频效应的关系.  相似文献   

3.
本文合成了一系列的(K,Na)3La2(BO3)3硼酸盐,通过自发结晶得到了组分为K1.34,Na1.66La2(BO3)3的单晶.单晶X射线结构分析表明该晶体与Na3La2(BO3)3同构,并且当K+取代Na+的数量小于2/3时,晶体结构仍为Na3La2(BO3)3构型.该晶体的基本结构单元为孤立的(BO3)3-基团.一个单胞中含有6个BO3基团,其中两个沿c方向一致平行排列,而剩余的4个BO3基团的排列方向与c方向呈一定的角度,从而减小了BO3基团对非线性效应的贡献.粉末倍频测试该晶体的有效非线性系数约为KDP的2.4倍.此外,研究表明用适量的Rb+,Li+取代Na+时,固溶晶体结构也不发生改变.  相似文献   

4.
以Na2CO3-H3BO3为助熔剂,用顶部籽晶法生长出Na3La9O3(BO3)8单晶.测定了Na3La9O3(BO3)8晶体结构,结果表明:该晶体属六方晶系,空间群:P62m,晶胞参数为a=b=0.89229(13)nm,c=O.87366(17)nm,α=β=90°,γ=120°,Z=1,V=0.60240(17)nm3,密度为5.066g/cm3.晶体结构中的硼氧基团是平面的BO3基团,BO3基团相互独立,通过与Na(1)O6、La(1)O9和La(2)O8的配位多面体连结形成层状结构,所有层平行于(001)面.描述了Na3La9O3(BO3)8晶体在非线性光学材料领域的应用前景.  相似文献   

5.
系统研究了Ba2Mg(BO3)2∶Eu3荧光粉的高温固相法制备工艺条件,发现在900 ℃C下保温3h制得的样品的发光性能最好.研究了Eu3掺杂浓度对基质晶格环境和发光性质的影响,当Eu3+浓度较低时,荧光粉在594 nm的发射峰强度最大,随着Eu3掺杂浓度的增加,Eu3+偏离对称中心的程度越来越大,当Eu3浓度超过3at;时,荧光粉在613 nm的发射峰强度开始急剧增强,浓度达到3.5at;时,613 nm的发射开始占主导,这是由于晶体结构的扭曲程度导致晶格对称性发生了较大的改变,释放了更多禁戒的5 D0 →7F2电偶极跃迁.制备的橙色荧光粉可以被近紫外InGaN芯片有效激发,应用于白光LED.  相似文献   

6.
本文以起始摩尔比为1:1的Na2CO3:H3BO3,并添加5;质量分数的NaF为助熔剂,用顶部籽晶法生长出φ35mm×5mm的透明Na3La2(BO3)3单晶.该晶体属正交晶系,空间群:Amm2,晶胞参数为a=0.51580(10)nm,b=1.1350(2)nm,c=0.73230(15)nm,α=β=γ=90°.测量了Na3La2(BO3)3晶体在室温下的透过光谱,紫外截止波长约为200nm.该晶体常温下稳定,不吸潮,但却易溶于稀酸.  相似文献   

7.
以Na2CO3-H3BO3为助溶剂,用顶部籽晶法生长了14mm×8mm×2mm的Na3Sm2(BO3)3晶体.差热分析(DTA)表明Na3Sm2(BO3)3非同成分熔融,熔点为1089.1℃.该晶体易溶于酸,在空气条件下能稳定存在,不易潮解.测量了室温下晶体在200~2500nm范围内的吸收光谱,并对跃迁能级进行了初步指认.  相似文献   

8.
CaYO(BO3)3晶体坩埚下降法生长   总被引:4,自引:3,他引:1       下载免费PDF全文
本文首次报道了Ca4YO(BO3)3(YCOB)晶体的坩埚下降法生长.在1600~1650℃炉温下,固液界面处的纵向温度梯度为40~60℃/cm,以0.2~0.6mm/h的生长速率,在近封闭的Pt坩埚中生长出了直径达25mm、长度超过50mm的完整透明YCOB晶体.介绍了生长工艺和原料制备,观察发现晶体中的主要宏观缺陷是包裹体.分析了包裹体生成的原因.  相似文献   

9.
姚倩  张俊英  李静  王继扬 《人工晶体学报》2015,44(12):3479-3481
采用助熔剂法生长了Er: LaAl3(BO3)4晶体.LaAl3(BO3)4晶体属正交晶系,晶胞参数a=0.93586(4) nm,b=0.79904(3) nm,c=0.43626 (6) nm,V=0.34595 nm3.测量了晶体在室温的吸收光谱和荧光光谱.该晶体吸收光谱能级丰富;在1533 nm波长处有较强的荧光光谱,对应于4I13/2→4I15/2的能级跃迁;晶体的荧光寿命为2.72ms.研究了晶体的热学性质,室温时的比热容大约为0.595 J/g·℃.  相似文献   

10.
以廉价的Nb2O5为铌源,采用共沉淀法制备了纳米Ba(Fe0.5Nb0.5)O3粉体.用XRD、TG-DSC、FT-IR、SEM等测试手段分析了烧结温度、保温时间、体系温度、pH值等对前驱体粉体的物相、形貌及晶粒大小的影响,并对粉体的磁学性能进行了表征.结果表明:合成温度在950℃,体系温度在30℃和50℃均可获得纯相立方钙钛矿结构的Ba(Fe0.5 Nb0.5)O3粉体,保温时间和pH值对粉体相结构变化无影响.在体系温度为30℃,pH=10,前驱体粉体在950℃煅烧2h后获得颗粒尺寸约30 nm的Ba(Fe05Nb0.5)O3粉体,且粉体具有弱的铁磁性.  相似文献   

11.
A neodymium doped Ca5(BO3)3F single crystal with size up to 51×48×8 mm3 has been grown by the top seeded solution growth (TSSG) technique with a Li2O‐B2O3‐LiF flux. The spectra of absorption and fluorescence were measured at room temperature. According to Judd‐Ofelt (J‐O) theory, the spectroscopic parameters were calculated and the J‐O parameters Ω2, Ω4, Ω6 were obtained as follows: Ω2 = 1.41×10−20cm2, Ω4 = 3.18×10−20cm2, Ω6 = 2.11×10−20cm2. The room temperature fluorescence lifetime of NCBF was measured to be 51.8 μs. According to the J‐O paramenters, the emission probabilities of transitions, branching ratios, the radiative lifetime and the quantum efficiency from the Nd3+ 4F3/2 metastable state to lower lying J manifolds were also obtained. In comparasion with other Nd‐doped borate crystals, the calculated and experimental parameters show that NCBF is a promising SFD crystal.  相似文献   

12.
为探索新型复合功能晶体材料,采用高温固相反应法合成了Cd4TbO(BO3)3多晶粉末,并以NaF-B2O3为助熔剂生长出了小晶体.结构分析表明,Cd4TbO(BO3)3晶体属于单斜晶系,Cm空间群,晶胞常数为a=7.982(1) (A)、b=15.806(3) (A)、c=3.487(7) (A)、α=90°、β=100.57°、γ=90°,晶体中的阴离子基团为[BO3].测量了TG-DSC曲线、紫外可见透过光谱、红外光谱、拉曼光谱,并计算了晶体单位体积Tb的含量.结果表明, Cd4TbO(BO3)3晶体在500~1500 nm范围内透过率大于70;.Cd4TbO(BO3)3晶体单位体积含Tb量为4.624×1021/cm3,是磁光晶体TGG单位体积含Tb量的0.3倍.综上表明Cd4TbO(BO3)3是一种有前途的复合功能晶体材料.  相似文献   

13.
Nonlinear optical Ba3Ti3O6(BO3)2 crystals were patterned on the surface of CuO (1 mol%)‐doped 40BaO‐40TiO2‐20B2O3 glass by irradiations of continuous‐wave Nd:YAG (wavelength: λ=1064 nm) and Yb:YVO4 (λ=1080 nm) lasers. Laser energies absorbed by Cu2+ ions were transferred to the lattice system through a nonradiative relaxation process, consequently heating the glass and inducing local crystallizations. For the lines patterned by Yb:YVO4 laser irradiations with a power of 1 W and a scanning speed of 20 μm/s, a c‐axis orientation of Ba3Ti3O6(BO3)2 crystals along the laser scanning direction is proposed from measurements of X‐ray diffraction analyses, polarized optical photographs, polarized micro‐Raman scattering spectra, and azimuthal dependence of second harmonic generations. The laser‐induced crystallization technique is found to be applied successfully for the spatially selective patterning of nonlinear optical Ba3Ti3O6(BO3)2 crystals in glass. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

14.
采用顶部籽晶法生长Nd3+:Na3La9O3(BO3)8 晶体.在室温下测试了吸收光谱、发射光谱和荧光寿命.应用Judd-Ofelt理论评价了Nd3+:Na3La9O3(BO3)8晶体的光谱性能.812 nm处较宽的吸收峰适合AlGaAs LD泵浦的吸收.分别计算了Nd3+离子的唯象强度、谱线强度、辐射寿命、荧光分支比和荧光量子效率.  相似文献   

15.
Na3Gd2(BO3)3 crystals with dimensions up to 22 × 20 × 5 mm3has been grown from NaBO2 flux by the top‐seeded solution growth (TSSG) method for the first time. Differential scanning calorimetry (DSC) result shows that Na3Gd2(BO3)3 melts incongruently. The infrared spectrum indicates that Na3Gd2(BO3)3 contains characteristic triangular [BO3]3– groups responsible for the nonlinear optical effect. For the as‐grown crystal, the transmittance exceeds 80% in the wavelength range of 315 nm to 2670 nm, and the UV cutoff wavelength is 207 nm. The damage threshold is 0.47 GW cm–2 at 1064 nm. Moreover, Na3Gd2(BO3)3 crystal exhibits an optical second harmonic generation effect which is 1.3 times as large as that of KH2PO4 (KDP). (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

16.
Single crystals of Sr3Gd(BO3)3 (SGB) and Sr3TbxGd1‐x(BO3)3 (TSGB) with dimension Ø 20 mm×20 mm have been grown by Czochralski method. The grown crystals were characterized by X‐ray powder diffraction analysis which showed the crystals belong to hexagonal structure with lattice parameters of a=b=1.254 nm, c=0.926 nm (SGB) and a=b=1.253 nm, c=0.925 nm (TSGB). In TSGB, x=17.7% was obtained by X‐ray fluorometry which showed the segregation coefficient of Tb is closed to 1. The transmission spectrum was measured, which indicated the crystals have high transmittance in 400‐1100 nm region. The Faraday rotation of single crystals at 532 nm wavelength was measured at room temperature. Finally, the Verdet constants were investigated, (SGB) V=17.9 degcm‐1T‐1 and (TSGB) V=21.3 degcm‐1T‐1. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

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