共查询到20条相似文献,搜索用时 15 毫秒
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Dr. Vinh X. Truong Dr. Katharina Ehrmann Maximilian Seifermann Prof. Dr. Pavel A. Levkin Prof. Dr. Christopher Barner-Kowollik 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(25):e202104466
The ability of light to remotely control the properties of soft matter materials in a dynamic fashion has fascinated material scientists and photochemists for decades. However, only recently has our ability to map photochemical reactivity in a finely wavelength resolved fashion allowed for different colors of light to independently control the material properties of polymer networks with high precision, driven by monochromatic irradiation enabling orthogonal reaction control. The current concept article highlights the progress in visible light-induced photochemistry and explores how it has enabled the design of polymer networks with dynamically adjustable properties. We will explore current applications ranging from dynamic hydrogel design to the light-driven adaptation of 3D printed structures on the macro- and micro-scale. While the alternation of mechanical properties via remote control is largely reality for soft matter materials, we herein propose the next frontiers for adaptive properties, including remote switching between conductive and non-conductive properties, hydrophobic and hydrophilic surfaces, fluorescent or non-fluorescent, and cell adhesive vs. cell repellent properties. 相似文献
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Uptil now it has not been possible to explain the different physical properties of amorphous polymers using a model based on a single conceptual scheme. In this paper, a phenomenological model is proposed which tries to explain the mechanical, optical and thermal properties (both thermal conductivity and expansivity) of amorphous polymers. The model has similarities with the composite model, proposed by the present authors, which has proved to be successful in interpreting the different physical properties of semicrystalline polymers. The present model considers the bulk form of the polymer as an aggregate of microscopic units possessing intrinsic physical properties. On drawing, the development of anisotropy in different physical properties is supposed to be due to the development of preferred orientation of these units. The development of the preferred orientation has been estimated directly from birefringence data. The agreement between the calculated and experimental values of the elastic modulus, thermal conductivity and thermal expansivity of PVC, PMMA and PS is found to be reasonable good. 相似文献
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A coarse-grained model for water is developed which maps five water molecules onto one bead. The coarse-grained potential is derived by iteratively matching the radial distribution function of water in the coarse-grained and target models. It is shown that the coarse-grained model has the optimal balance between computational efficiency and accuracy in structural properties. The model has been used to calculate a number of static and dynamic properties, including the density, isobaric thermal expansivity, isothermal compressibility, surface tension, and diffusion coefficient of water. The effect of coarsening on these properties has been discussed. It is shown that while the present coarse-grained model well describes the structural properties of water, expectedly it has a much faster dynamics than the corresponding atomistic models. 相似文献
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Marschner C Baumgartner J Wallner A 《Dalton transactions (Cambridge, England : 2003)》2006,(48):5667-5674
Possessing the property of sigma-bond electron delocalisation, polysilanes are a class of compounds with unique properties. In recent years major progress has been achieved in the theoretical understanding and the synthesis of polysilanes. Much insight into the connection between conformation and electronic properties has been gained from studies of defined small polysilane molecules. The transition from Wurtz type coupling reactions to the stepwise construction of polysilane molecules employing silyl anions as key intermediates has permitted access to defined compounds with a higher degree of structural complexity. Besides this, several methods have been developed to control the conformational properties and thus gain control over the electronic properties of polysilanes. 相似文献
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Alberty RA 《The journal of physical chemistry. B》2007,111(14):3847-3852
The ionic strength has significant effects on the thermodynamic properties of ionic species and on the transformed thermodynamic properties of biochemical reactants at specified pH values. These effects are discussed for species, reactants, and enzyme-catalyzed reactions. This has led to three new thermodynamic properties: (z(j)(2) - NH(j)), (z(2) - N(H))(i), and Delta(r)(z((2)-N(H)), which are referred to as ionic strength coefficients. The first of these is a property of a species, the second is a property of a reactant, and the third is the property of an enzyme-catalyzed reaction. The effects of ionic strength on standard thermodynamic properties of species, standard transformed thermodynamic properties of reactants, and standard transformed thermodynamic properties of enzyme-catalyzed reactions are proportional to these new thermodynamic properties. 相似文献
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《印度化学会志》2021,98(3):100037
In recent years, research on heat transfer and related equipment has been one of the topics of interest in many different industries. The use of conventional fluids in heat transfer due to their low thermal properties has created problems in this area, so the use of nanofluids in many cases has been a solution to overcome this problem. The parameters affecting the thermophysical and thermal properties of nanofluids are temperature, concentration, size, shape, pH, surfactant and ultrasonic time, among which temperature and concentration have the greatest effect. Existing models and studies in the field of nanofluids are limited to the type of nanoparticles and base fluids and their operating range, and there is no comprehensive model for predicting thermal properties. In the present study, models and theories regarding the determination of thermal conductivity of nanofluids and other thermophysical properties have been comprehensively compiled and the mechanisms for increasing the thermal properties as well as the effective parameters and the effect of each of them on improving the properties are presented. In general, the results showed that thermal properties improve with increasing concentration and temperature. Finally, the role of nanofluids effect on thermal performance in the heat exchangers is studied and the results are summarized. 相似文献
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In this paper, polyvinyl alcohol (PVA) bearing coumarin with different degrees of substitution (DS) are synthesized by esterifying hydroxyl of PVA with 7-carboxylmethoxycoumarin. The grafted polymer has photosensitive property and presents photocrosslinking due to the photodimerization between pendant coumarin groups, which affords PVA–coumarin sample photoinduced shape fixity properties. PVA–coumarin can be cross-linked after being illuminated under UV light of 360 nm; this provides the possibility that the sample has shape memory properties only if the cross-linking extent is suitable. The shape memory properties were induced by thermal as most shape memory polymer do. In fact, the shape fixity and recovery has strong relationship with DS, irradiation time, and thickness of sample. The effect of DS on the grafted polymer structure and properties has been studied by differential scanning calorimetry, thermogravimetric analysis, and UV spectra. 相似文献
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A special version of statistical associating fluid theory (SAFT), the so-called hetero-segmented SAFT equation of state, has been extended to calculate the thermodynamic properties of sodium dodecyl sulfate aqueous solutions. The predicted properties were included the vapor pressure as well as second thermodynamic properties, such as speed of sound. Evaluation of the model has been done through comparison of the calculated vapor pressure with experimental data in the range of 298.15–313.15 K. The hetero-SAFT model is found to be able to correctly describe the thermodynamic derivative properties as well as pVT and VLE properties of ionic surfactant solutions. 相似文献
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The importance of linear low density polyethylene (LLDPE) is being rapidly felt. The combination of favourable production economics and excellent product performance characteristics has enabled this new plastic to gain acceptance for a wide variety of applications. No studies on the rheological properties of LLDPE exist to date. The viscous and elastic properties of this new polymer has now been investigated and unified curves for viscosity and normal stress differences are given. The temperature dependence of the rheological properties of LLDPE has also been studied. 相似文献
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Helmut K. Schmidt 《Macromolecular Symposia》1996,101(1):333-342
A new type of inorganic-organic composite has been developed using organic monomeric or polymerizable silanes (with appropriate organic groupings like double bonds or epoxides) as monomers or in situ prepared or separately added nano-scale ceramic or metal particles. Due to the small size of the particulate phase, these composites are still highly transparent but show properties at least partially to be attributed to the inorganic phase. The introduction of special functions into these materials has been used for the fabrication of interesting functions like non-linear optical properties, low surface free energy coatings, controlled release properties or special mechanical properties (scratch resistance). 相似文献
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Li H 《Organic & biomolecular chemistry》2007,5(21):3399-3406
Elastomeric proteins underlie the elasticity of natural adhesives, cell adhesion and muscle proteins. They also serve as structural materials with superb mechanical properties. Single molecule force spectroscopy has made it possible to directly probe the mechanical properties of elastomeric proteins at the single molecule level and revealed insights into the molecular design principles of elastomeric proteins. Combining single molecule atomic force microscopy and protein engineering techniques, it has become possible to engineer proteins with tailored nanomechanical properties. These efforts are paving the way to design artificial elastomeric proteins with well-defined nanomechanical properties for application in nanomechanics and materials sciences. 相似文献
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T. S. Volkova A. Yu. Isaev A. P. Petrova P. L. Zhuravleva 《Polymer Science Series D》2013,6(4):280-284
The effect of nanosilicates on various polymer systems—thermoplastic and rubber—has been studied. The possibility of optimizing the fireproof properties of these systems has been shown by modifying them with nanosilicates while retaining and, in some cases, increasing their physicomechanical properties. 相似文献
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T. S. Volkova E. Ya. Beider P. L. Zhuravleva 《Russian Journal of General Chemistry》2011,81(5):1047-1052
An effect of different methods of structural modification of the heat-resistant amorphous polysulfone with layered silicate
montmorillonite on the properties of the resulting polymer-silicate nanocomposites has been studied. Comparative evaluation
of the technological, physical, mechanical, thermal, and rheological properties of the nanocomposites has been performed. 相似文献
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V. F. Kablov N. A. Keibal A. E. Mitchenko Yu. Yu. Emel’yanova Yu. I. Yumagulova S. P. Varfolomeeva 《Polymer Science Series D》2016,9(2):172-175
Synthesis of phosphorus-boron-nitrogen-containing modifier (PEDA) has been performed, and the properties thereof have been studied. It has been shown that introduction of PEDA as a modifying additive in elastomeric compositions makes it possible to improve their adhesive and fire–heat protective properties. 相似文献
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用AM1方法对红菌素(包插甲素和乙素)与它们的溴代物进行了量子化学对比计算,得到了生成热,前线轨道能级及偶极矩等,讨论了溴代作用对竹红菌素分子性质的影响。 相似文献
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This review shows the unusual physicochemical properties and wide application of azulene and its derivatives. The recent synthesis strategies of kinds of substituted azulene are also listed. 相似文献