Petrologic and Geochemical Characteristics and Origin of Gusui Cherts,Guangdong Province,China

The characteristic structures of the Precambrian cherts from the Gusui section, Guangdong ,Chi-na, include bedded structure ,laminated structure ,massive structure and pseudobrecciated structure.The chert is characterized by consistently low abundance of TiO2,Al2O3 and most trace elements.Howevver ,it is enriched in Ba,As,Sb,Hg and Se.In Al-Fe-Mn ternary diagrams,it falls into the “hydrothermal field“ .Correspondence analysis and factor analysis show that many elements show up in the factor that represents the leaching of country rocks by hydrothermal solutions,and are the very characteristic element association fo the geochemically anomalous South China basement.Petrologic and geochemical evidence suggests a hydrothermal origin for the chert.The chert may have been formed in a Precambrian fift or an extension zone developed within the Yunkai marginal geosyncline, with a fault system linking it to an unknown heat source at depth.     

REE geochemistry of lamprophyres in Baimazhai nickel deposit, Yunnan Province, China： implication for the mantle source region

Lamprophyresarewidespreadinthe“Sanjiang”(tri river)alkali richintrusiverockbelt(Ailaoshan Jinshajiangalkali richintrusiverockbelt)insouth westernChinaandhaveaclosetemporalandspatialre lationwithAu,Cumineralization(HuYunzhonget al.,1995;HuangZhilongetal.,1999).Therefore,thereiscrucialsignificanceinsuchaspectsastectonic environment,mantlemetasomatism,crust mantlein teraction,magmaticevolutionandassociatedminerali zation.TheBaimazhainickeldepositislocatedinthe southernsegmentofthe“Sanjiang…     

Geological and Geochemical Evidence for Discriminating Anatectic and Subsolidus Migmatites in the Dabieshan Complex,Northeastern Hubei Province

Based on the geological and geochemical information about migmatites,the following lines of evidence have been proposed for discriminating the anatectic leucosome in the Dabieshan Complex:(1)its width is larger than that derived from the subsolidus genesis,cutting across regional foliation,thus giving rise to complicated folds and wider selvages;(2)it is composed of melanic and accessory minerals in addition to quartz and feldspars;(3)the significant dfference in anorthites of plagioclase between paleosome and leucosome;(4)temperature and pressure(P/T) conditions revealed by the mineral compositions and assemblages are over those for the onset of anatexis;and (5)it is enriched in the major elements(e.g.Al2O3.Fe2O3and TiO2)and immobile and incompatible elements(e.g.LREE,Th,Hf and Zr).Finally,by combining the geological and geochemical features with the statistical data for the spatial distribution of minerals and mass-balance in the migatites,it is concluded that anatexis is the cardinal mechanism of migmatization in the Dabieshan Complex.     

Geochemistry of Late Mesozoic mafic dykes in western Fujian Province of China： Sr-Nd isotope and trace element constraints

The Bancun diabase dyke and the Bali hornblende gabbro dyke in western Fujian Province were emplaced in the Early and Late Cretaceous periods, respectively; the former is designated to calc-alkaline series and the latter to K-high-calc-alkaline rock series. Both the dykes are characterized by such geochemical characteristics as high Al and Na2O>K2O. As for the Bancun dyke, Al2O3=16.32%–17.54% and K2O/Na2O=0.65–0.77; as for the Bali dyke, Al2O3=16.89%–17.81% and K2O/Na2O=0.93–0.99. Both the Bancun and Bali mafic dykes are relatively enriched in LILE and LREE, but depleted in HSFE, displaying the geochemical characteristics of continental marginal arc, with high initial Sr isotopic ratios and low εNd (t) values. The (87Sr/86Sr)i ratios of the Bancun diabase dyke are within the range of 0.708556–0.70903 and their εNd (t) values vary between -6.8 and -6.3; those of the Bali hornblende dyke are within the range of 0.710726–0.710746 and their εNd (t) values are -4.7– -4.9, showing the characteristics of enriched mantle EM II. The isotope and trace element data showed that the mafic dykes have not experienced obvious crustal contamination, and metasomatism caused by subduction fluids is the main factor leading to LILE and LREE enrichments. The enriched mantle is the source region for the mafic dykes, and mixing of subduction fluid metasomatized enriched mantle and EM II-type mantle constituted the mantle source region of both the Bancun and Bali mafic dykes. Upwelling of the asthenosphere mantle provided sufficient heat energy for the generation of magmas. In accordance with the discrimination diagram of their tectonic settings as well as their trace element geochemical characteristics, it is considered that the dykes both at Bancun and Bali possess the characteristics of continental marginal arc, revealing the tectonic environment of formation of the mafic dykes, the continental dynamic background as an intraplate tensional belt in which the mafic dykes were emplaced. Meanwhile, it is also indicated that the tensional tectonic stress mechanism is responsible for the formation of the mafic dykes in western Fujian Province.     

Geochronology and geochemistry of Cretaceous Nanshanping alkaline rocks from the Zijinshan district in Fujian Province,South China: Implications for crust–mantle interaction and lithospheric extension

In situ zircon U–Pb ages and Hf isotopic data, major and trace elements, and Sr–Nd–Pb isotopic compositions are reported for Nanshanping alkaline rocks from the Zijingshan district in southwestern Fujian Province (the Interior or Western Cathaysia Block) of South China. The Nanshanping alkaline rocks, which consist of porphyritic quartz monzonite, porphyritic syenite, and syenite, revealed a Late Cretaceous age of 100–93 Ma. All of the rocks show high SiO₂, K₂O + Na₂O, and LREE but low CaO, Fe₂O₃^T, MgO, and HFSE (Nb, Ta, P, and Ti) concentrations. These rocks also exhibit uniform initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7078 to 0.7087 and ε_Nd(t) values of −4.1 to −7.2, thus falling within the compositional field of Cretaceous basalts and mafic dikes occurring in the Cathaysia Block. Additionally, these rocks display initial Pb isotopic compositions with a ²⁰⁶Pb/²⁰⁴Pb_i ratio of 18.25 to 18.45, a ²⁰⁷Pb/²⁰⁴Pb_i ratio of 15.63 to 15.67, and a ²⁰⁸Pb/²⁰⁴Pb_i ratio of 38.45 to 38.88. Combined with the zircon Hf isotopic compositions (ε_Hf(t) = −11.7 to −3.2), which are different from those of the basement rocks, we suggest that Nanshanping alkaline rocks were primarily derived from a subduction-related enriched mantle source. High Rb/Sr (0.29–0.65) and Zr/Hf (37.5–49.2) but relatively low Ba/Rb (4.4–8.1) ratios suggest that the parental magmas of these rocks were most likely formed via partial melting of a phlogopite-bearing mantle source with carbonate metasomatism. The relatively high SiO₂ (62.35–70.79 wt.%) and low Nb/Ta (10.0–15.3) ratios, positive correlation between SiO₂ and (⁸⁷Sr/⁸⁶Sr)_I, and negative correlation between SiO₂ and ε_Nd(t) of these rocks suggest that the crustal materials were also involved in formation of the Nanshanping alkaline rocks. Combined with geochemical and isotopic features, we infer magmatic processes similar to AFC (assimilation and fractional crystallization) involving early fractionation of clinopyroxene and olivine and subsequent fractionation of biotite-dominated assemblages coupled with a lesser amount of crustal contamination, thereby forming the Nanshanping alkaline rocks. The Nanshanping alkaline rocks appear to be associated with an extensional environment in the Cathaysia Block. This extensional regime could have resulted in the slab break-off and rollback of the subducting paleo-Pacific plate and the upwelling of the asthenospheric mantle, which induced partial melting of the enriched lithospheric mantle in the Cretaceous.     

Isotope Geochemistry of the Dongchuan Copper Deposit,Yunnan,SW China： Stratigraphic Chronology and Application of Lead Isotopes in Geochemical Exploration

In this paper the Pb-Pb isochron method was used to determine the isotopic ages of the Luoxue Formation dolomites (1716 ±56 Ma), the Heishan Formation carbonaceous slates ( 1607 ±128 Ma) of the middle sub-group of the Kunyang Group and the Dayingpan Formation carbonaceous slates (1258 ±70Ma) of the upper sub-group of the Kunyang Group. The age of the middle sub-group of the Kunyang Group is about 1800 – 1600 Ma, belonging to the Late Paleo-Proterozoic, and that of the Dayingpan Formation in the upper sub-group of the Kunyang Group is about 1200 – 1300 Ma, belonging to the Middle Proterozoic. In addition, the Pb isotope chemical exploration techniques were used to study systematically the Pb isotopic compositions of rocks and ores across the No. 14 vein in the middle segment of the No. 1 pit of the Tangdan copper deposit and the result showed that the Pb isotope V₁ values are negatively correlated with the copper contents. It is the first trial to use the systematic section method to conduct Pb isotope chemical exploration. This research project was financially supported jointly by the National Natural Science Foundation of China (Grant Nos. 49702022, 40073001) and the State 973 Program (No.G1999043215).     

Elemental and Sr–Nd isotopic systematics of the early Mesozoic volcanic sequence in southern Jiangxi Province, South China: petrogenesis and tectonic implications

Elemental and Sr–Nd isotopic results are presented for the early Mesozoic volcanic sequence (~172 Ma) in southern Jiangxi Province, South China. The sequence is voluminously composed of ~45% subalkaline basaltic rocks (group 1), <5% high-mg andesite–dacites (group 2) and ~50% rhyolites (group 3). The group 1 rocks are characterized by (La/Yb)_cn = 3.8–7.2, Eu/Eu* = 0.65–1.15, Nb/La = 0.64–0.99, ⁸⁷Sr/⁸⁶Sr(t) = 0.70602~0.70822 and _Nd(t) = –1.63 to +0.11, similar to those of an EMII-like source. The group 2 rocks have mg=0.42~0.60, SiO₂=60.24~66.71%, MgO=2.65~ 5.54%, Ni=24~102 ppm and Cr=84~266 ppm, classified as high-mg andesitic rocks. These rocks are more enriched in LILEs and LREE with more significant negative Eu anomaly (0.63~0.79), are more depleted in HFSEs with Nb/La ratios of 0.40–0.56 and have lower _Nd(t) (–9.44 to –7.78) and higher ⁸⁷Sr/⁸⁶Sr(t) (0.70985~0.71016), in comparison with the group 1 rocks. They most likely originated from metasomatised veins in the lithospheric mantle. The origination of the group 1 and group 2 magma suggests the development of a peridotite-plus-vein lithospheric mantle during early Mesozoic era beneath the interior of the Cathaysian block. The group 3 rhyolites are characterized by high SiO₂ (72.75~77.97%), Zr (99~290 ppm), Hf (3.9~9.7 ppm) and Ga/Al (2.76~3.87) and significant Nb–Ta, Ba–Sr and P–Ti depletions. These rhyolites exhibit Sr–Nd isotopic compositions (⁸⁷Sr/⁸⁶Sr(t) = 0.70962~0.71104, _Nd(t) = –4.63 to –5.80) similar to the contemporaneous Zhaibei and Pitou A-type granites in the area. Such characteristics suggest that they might be derived from the underplating basaltic magma contaminated by crustal materials. Therefore, an early Mesozoic rifting model in response to intracontinental lithospheric extension is proposed to account for the early Mesozoic volcanism in southern Jiangxi Province, South China.     

Apatite fission-track study on the thermo-tectonic history of the Huainan Coalfield in Anhui Province, China： Tectonic implications for the potential coalbed methane resource

Coalbed methane (CBM) is a kind of burgeoning and enormously potential clean energy resource, and the temperature of the thermogenic CBM generation is close to that of the partial annealing zone (PAZ) of apatite fission tracks (AFT). In this study the thermo-tectonic history of the Huainan Coalfield and the potential CBM resource were studied and discussed by using the AFT method. The AFT data indicate that the apparent ages of AFT vary from 45.5 to 199.1 Ma. They are younger than the ages of their host strata (255–1800 Ma) except one sample, and the single-grain ages of AFT can be classified as a single age group for each sample. In combination with the geological setting, modeling results of the AFT ages, average lengths, and the thermal history based on the AFT single-grain ages and length distributions, some preliminary conclusions can be drawn as follows: (1) at least three thermo-tectonic events (in the periods of ∼240, 140 and 80 Ma, respectively) have occurred in the study area since the Late Paleozoic. The occurrence of both the first (during 240–220 Ma) and second (during 160–120 Ma) thermo-tectonic events is possibly responsible for the establishment of the patterns of gas generation and reservoir formation. The second thermo-tectonic event also led to slight accumulation of hydrocarbons and generation of thermogenic gas; (2) the AFT ages of most coal-bearing strata lie between 50 and 70 Ma. They should represent the cooling ages and the ages of inferred uplift and denudation, as well as the possible CBM release history. Therefore, the maximum burial depth of coal-bearing strata and the denudation thickness of the overlying strata are over 3000 and 2000 m in the Upper Cretaceous and Paleogene series, respectively; and (3) subsequently, a spot of secondary biogenic and scarcely thermogenic gas generation occurred due to negligible sedimentation during the Neogene and Quaternary periods. Thus, it can be presumed that subsequent tectonism would destroy the CBM reservoir after its formation in the Huainan Coalfield, especially in its structural development region. These AFT data may be helpful for a better understanding of the thermo-tectonic history of the Huainan Coalfield, as well as of CBM generation, storage and release in the Huainan Coalfield.     

Amphibole—Bearing Peridotite Xenoliths from Nushan,Anhui Province：Evidence for Melt Percolation Process in the Upper mantle and Lithospheric uplift

The spinel peridotite xenoliths of Group I in Quaternary basanites from Nushan,Anhui province,can be classified as two suites:a hydrous suite characterized by the ubiquitous occurrence of (Ti-) pargasite and an anhydrous suite.The nineral chemistry reveals that the anhydrous suite and one associated phlogopite-bearing lherzolite are equilibrated under temperature conditions of 1000-1100℃,whereas amplhibole-bearing peridotites display distinct disequilibrum features,indicating partial reequilibration from 1050 to 850℃ and locally down to 750℃. The amplhbole-bearing peridotites were probably the uppermost part of the high temperature anhydrous suite which was modally modifed by fractionating H2O-rich metasomatic agent during regional upwelling.This relatively recent lithospheric uplift event followed an older uplift event recognized from pyroxene unmixing of domains in local equilibrium,as well as the dominant deformation texture in the anhydrous suite.The first thermal disturbance can be linked with the regional extension and widespread basaltic volcanism in Jiangsu-Anhui provinces since Early Tertiary and the formation of the nearby Subei(North Jiangsu) fault-depression basin during the Eocene,while the second event in association with the formation of amphiboles probably indicates the continuation but diminution of upwared mantle flux since Neogene in response to the change in tectonic regime for eastern china.     

Sulfur isotopic composition of the Bainiuchang super-large Ag polymetallic deposit, Yunnan Province, China： Implications for the source of sulfur in ore-forming fluids

The Bainiuchang deposit in Yunnan Province, China, is located geographically between the Gejiu ore field and the Dulong ore field. In addition to >7000 t Ag reserves, the deposit possesses large-scale Pb, Zn, Sn reserves and a mass of dispersed elements (i.e., In, Cd, Ge, Ga, etc.). Based on systematic studies of sulfur isotopic composition, the authors conclude: The Bainiuchang deposit experienced two epochs of metallogenesis, i.e., the Middle-Cambrian sea-floor exhalative sedimentary metallogenic epoch and the Yanshanian magmatic hydrothermal superimposition metallogenic epoch. In the two metallogenic epochs, the δ³⁴S values of sulfides were all near 0, showing a tendency of being enriched slightly in heavy sulfur. The δ³⁴S values of sulfides in the early metallogenic epoch are within the range of 2‰–5‰ with a peak value range of 2‰–3‰ and an average of 3.0‰, and those of sulfides in the late metallogenic epoch are within the range of 2‰–6‰ with a peak value of 3‰–4‰ and an average of 3.9‰. For the single metallogenic epoch, sulfur in the ore-forming fluids in the early epoch already reached isotopic equilibrium and was derived mainly from underneath the magma chamber or basement metamorphic igneous rocks. Sulfur in the sulfides in the late epoch was derived mainly from magmatic hydrothermal fluids formed in the process of remelting of the basement metamorphic igneous rocks.     

辽宁矿洞沟—梁屯元古宙正长岩体的地球化学及成因

矿洞沟 -梁屯正长岩体侵位年龄为 2 175.4Ma ,是年代最古老的正长岩体之一。正长岩浆演化过程中发生了分离结晶作用。岩浆起源于亏损地幔与下地壳组分参予的混合源区 ,有上地壳物质的混染。该岩体是研究岩石圈发展早期碱性岩浆作用的极好标本。     

湖北竹溪蔓荆沟碱性正长岩地球化学特征及其构造环境分析

在南秦岭造山带中发现的竹溪蔓荆沟碱性正长岩,呈透镜状侵入于辉绿岩体内,个别呈独立岩体侵入于早古生代地层中。单个正长岩体规模较小。通过对其进行岩相学及岩石地球化学特征研究,表明其为全碱(Na_2O~+K_2O)含量较高的钾质碱性正长岩;岩石中Mg~#值较低,明显低于原始岩浆Mg~#值,说明其为原始岩浆经历较高程度演化的产物;岩体中稀土元素总量ΣREE较高,轻稀土元素LREE富集明显,重稀土元素HREE亏损;通过微量元素构造环境判别分析认为,研究区正长岩形成于大陆裂谷环境,且形成于大陆裂谷早期阶段,其形成时代为早志留世。     

江西会昌岽背玄武岩地球化学和Sr-Nd同位素特征及其地质意义

江西会昌岽背地区晚中生代玄武岩的SiO2含量为49.06%～50.14%,K2O含量为1.26%～1.63%.其微量元素显示出大离子亲石元素富集,高场强元素亏损,尤以明显的Nb、Ta亏损为特征;REE总量为(135.5～146.8)×10-6,(La/Yb)N≈10,表现出LREE富集的稀土元素配分模式,且无明显的Eu异常;Sr-Nd同位素具有高(87Sr/86Sr)i(0.70678～0.70695)和低εNd(t)(-2.46～-2.18)的特征.据以上特征并结合区域地质背景,反映出岽背玄武岩的源区可能为EMⅡ型富集型大陆岩石圈地幔,其形成的构造环境为活动大陆边缘.较低的Nb/U比值(7～8)暗示该玄武质岩浆在形成过程中遭受了一定程度的大陆地壳混染或与俯冲过程有关的物质的加入.岽背玄武岩具有陆缘弧型地球化学特征,指示会昌地区在晚白垩世晚期(约85 Ma)处于活动大陆边缘的构造环境,该玄武岩的形成可能与燕山晚期古太平洋板块向欧亚大陆的俯冲消减作用关系密切.底侵作用可能为会昌地区燕山晚期成矿岩浆的生成提供了流体和热,有利于铜多金属矿的形成.     

辽东矿洞沟正长岩成因及其构造意义：锆石原位微区U-Pb年龄和Hf同位素制约

矿洞沟岩体位于华北克拉通东部,由粗粒正长岩、细粒正长岩和闪长岩组成,其中细粒正长岩和闪长岩具有明显的岩浆混合特征,它们侵入到粗粒正长岩中.锆石的LA-ICPMS U-Pb年代学研究表明,粗粒正长岩形成于1879±17 Ma,而细粒正长岩和闪长岩分别侵位于1874±18 Ma和1870±18 Ma,三者在误差内基本相同,因此,矿洞沟岩体的侵位时代为古元古代.矿洞沟正长岩和闪长岩富集轻稀土元素和大离子亲石元素,亏损高场强元素,具有相对均一的全岩Nd同位素.但粗粒正长岩、中粒正长岩和闪长岩中锆石Hf同位素组成却不均一,分别为εHf（t）=-2.5～＋3.0,-1.5～＋3.4和-3.5～＋2.7,明显高于辽东地区太古代片麻岩演化到古元古代时的Hf同位素组成,表明它们来源于太古代新生地壳的部分熔融并有大量地幔物质的加入.野外地质观察、主量元素组成及岩石中锆石具有相同U-Pb年龄却具有不同的Hf同位素等特征表明,矿洞沟正长岩和闪长岩是壳源岩浆和幔源岩浆混合作用的结果.矿洞沟正长岩体的侵位标志着辽东地区在古元古代时期处于南北地块碰撞后的伸展环境,与华北克拉通东部陆块的形成和演化以及全球古元古代末期Columbia超大陆的形成和裂解有关.     

辽西凌源河坎子碱性杂岩体地球化学特征及地质意义

分析测定了河坎子碱性杂岩体的稀土、微量元素和Sr、Nd、Pb同位素数据 ,对该杂岩体形成的构造背景、源区特征及意义进行了讨论。河坎子碱性杂岩体稀土元素总量较高 ,富集LREE和大离子亲石元素 ,Eu呈弱负异常或异常不明显 ,Nb、Ta、K、P、Ti和Y呈负异常 ,过渡族元素含量偏低。稀土和微量元素分布模式与辽东凤城碱性杂岩体相似。主侵入期 4个全岩加 1个黑云母样品的全岩矿物Rb_Sr等时线年龄为 2 2 1.4± 8.5 (2σ)Ma ,属于印支期碱性岩浆活动。该岩体的εSr(t)均为正值 ,平均 7.2 3,ISr=0 .70 4 77± 0 .0 0 0 15 ,εNd(t)均为负值。微量元素和Sr、Nd及Pb示踪同位素特征显示其源区与EMⅠ型富集地幔端员有关。河坎子碱性杂岩体地球化学特征不仅揭示了华北地台北缘东部上地幔在三叠纪时具有富集性 ,而且也显示了辽东地区比辽西地区更富集的特点。河坎子碱性杂岩体形成于板内拉张环境 ,岩浆作用以批式部分熔融占主导地位。     

Geochemical and isotopic investigation of the Laiwu–Zibo carbonatites from western Shandong Province, China, and implications for their petrogenesis and enriched mantle source

Major and trace element and Nd–Sr isotope data of the Mesozoic Laiwu–Zibo carbonatites (LZCs) from western Shandong Province, China, provide clues to the petrogenesis and the nature of their mantle source. The Laiwu–Zibo carbonatites can be petrologically classified as calcio-, magnesio- and ferro-carbonatites. All these carbonatites show a similarity in geochemistry. On the one hand, they are extremely enriched in Ba, Sr and LREE and markedly low in K, Rb and Ti, which are similar to those global carbonatites, on the other hand, they have extremely high initial ⁸⁷Sr/⁸⁶Sr (0.7095–0.7106) and very low _Nd (−18.2 to −14.3), a character completely different from those global carbonatites. The small variations in Sr and Nd isotopic ratios suggest that crustal contamination can not modify the primary isotopic compositions of LZC magmas and those values are representatives of their mantle source. The Nd–Sr isotopic compositions of LZCs and their similarity to those of Mesozoic Fangcheng basalts imply that they derived from an enriched lithospheric mantle. The formation of such enriched lithospheric mantle is connected with the major collision between the North China Craton (NCC) and the Yangtze Craton. Crustal materials from the Yangtze Craton were subducted beneath the NCC and melts derived from the subducted crust of the Yangtze Craton produced an enriched Mesozoic mantle, which is the source for the LZCs and Fangcheng basalts. The absence of alkaline silicate rocks, which are usually associated with carbonatites suggest that the LZCs originated from the mantle by directly partial melting.     

四川牦牛坪稀土矿床萤石稀土元素、同位素地球化学

萤石是四川牦牛坪稀土矿床最重要的脉石矿物之一，本身已具有工业价值。根据稀土元素含量、有关参数及分布模式，将矿区萤石分为LREE富集型、LREE平坦型和LREE亏损型三种。不同REE类型中的萤石稀土元素地球化学特征具有连续变化的规律。萤石与围岩REE、同位素分析对比结果表明，LREE富集型、LREE平坦型和LREE亏损型萤石为同源不同阶段形成的产物；萤石成矿流体具有地幔特征，与矿区正长岩－碳酸岩密切相关。     

辽宁盖县梁屯—矿洞沟碱性正长岩杂岩体的U—Pb和Sm—Nd年龄及其地质意义

辽宁梁屯 -矿洞沟杂岩体主要由辉石正长岩、霓辉正长岩和霓辉角闪正长岩等碱性岩石组成 ,具有全岩 Rb- Sr等时线年龄 186 6± 115 Ma和 ISr=0 .70 4 9的同位素特征 ,是我国目前报道的最古老的碱性正长岩类。本文报道了该岩体的锆石U- Pb和全岩 Sm- Nd同位素测试资料 ,获得了锆石 U- Pb同位素年龄为 185 7± 2 0 Ma、Sm- Nd等时年龄为 1787± 180 Ma、εNd(t) =- 4 .8～ - 5 .0的数据。它们反映出该杂岩体形成年龄的上限为 185 7± 2 0 Ma、下限不小于 1787± 180 Ma,来源于富集地幔物质。基于这些数据并结合区域地质资料分析 ,作者提出了华北地台北缘古元古宙存在有富集地幔储库 ,以及辽河群主体形成于 190 0 Ma以前的认识     

Geochemical and Sr-Nd isotopic evidence for origin and evolution of the Miocene Pangeon granitoids,Southern Rhodope,Greece

The Sr-Nd isotopic ratios of selected post-collisional, calc-alkaline, I-type granitoids from the Pangeon pluton, intruding the lower tectonic unit (LTU) in the Southern Rhodope in the Miocene, support the existence of two types of granitoids (PTG porphyritic tonalite granodiorite and MGG biotite granodiorite to two-mica granite) unrelated by crystal fractionation and likely derived by partial melting of the same source under different P-T conditions. The Sr-Nd isotopic ratios of mafic enclaves in the granitoids as well as metamorphic rocks from the LTU have also been determined. At 22 Ma, the IR_Sr range between 0.706850 and 0.708381, whereas the ε_Nd(22) range from –3.86 to –1.05, with no relationship to granitoid types. The relationships between Sr and Nd isotopes as well as these isotopes and SiO₂ provide evidence of contamination of mafic melts by interaction with crust during magma differentiation. Both partial melting and AFC processes (r = 0.2) may account for compositional variations in the Pangeon magmas. The mafic enclaves display IR_Sr from 0.706189 to 0.707139, and ε_Nd(22) from –2.29 to –1.94, similar to the granitoids, supporting the hypothesis of a common origin. Amphibolites inferred to be subduction-enriched metabasalts under-plated crust during old subduction can represent the source of the Pangeon melts. The T_DM of the Pangeon granitoids is in the range 0.7–1.1 Ga for the inferred extraction age of the LILE-enriched subcontinental lithospheric mantle source. The upper crustal geochemical signatures and the relatively small isotopic composition of the Pangeon granitoids make these rocks similar to the coeval eastern-Mediterranean lamproites emplaced within the same geodynamic setting; this prompts similar melt sources. Lastly, the Pangeon granitoids display geochemical characteristics, isotopic ratios, and T_DM also similar to other Tertiary magmatic rocks from the Southern Rhodope and Biga peninsula, western Anatolia, suggesting a similar tectonic environment and co-magmatic evolution throughout the area.     

REE and Sr-Nd Isotope Geochemistry for Yixian Fluorite Deposit,Western Liaoning Province,China,and Its Geological Implications

Up to now,there were no systematic studies of geochemistry and isotopic age for the Yixian(义县) fluorite deposit,western Liaoning(辽宁) Province,China.Based on the analysis of metallogenic geological setting,we studied the REE,Rb-Sr and Sm-Nd isotopes.The chondrite-normalized REE patterns of fluorite are characterized by moderate LREE depletion(LREE/HREE=0.95-3.57,(La/Yb)N=0.08-2.84) and enrichment of Sr(146×10-6-596×10-6) and moderately positive Eu anomalies(δEu=1.10-1.34),which are similar to those of the ho...