Suppression of coherent population trapping upon spontaneous decay of an excited state

The interaction of a model three-level Λ system with electromagnetic radiation is considered under the conditions where a coherence (an off-diagonal matrix element) between lower sublevels arises upon spontaneous decay of an excited state. The cases of bichromatic and incoherent broadband fields are analyzed. It is shown that the occurrence of coherence may significantly change the character of evolution of the system under study with time. These changes are most pronounced for broadband fields. Some features of this phenomenon are considered for multilevel atomic systems.     

Competition between relaxation and decay of a resonantly excited core-hole state

By a many-body theory it is shown that in general when the time scale of the relaxation from the resonantly excited core-hole state to the fully relaxed core-hole state is much shorter than that of core-hole decay, the autoionization (deexcitation) spectrum is more or less identical to the Auger-electron spectrum by core-hole decay of the fully relaxed core-hole state. Here, the fully relaxed core-hole state is the lowest core-hole state in the X-ray photoelectron spectroscopy spectrum. The present theory explains why the C 1s autoionization spectrum of CO molecule adsorbed on Ni(1 0 0) surface measured at the resonant core-level electron excitation energy is more or less indentical to the Auger-electron spectrum measured at far above the core-level electron ionization limit.     

Electron spin polarization in an excited triplet-radical pair system: Generation and decay of the state

A computational model to simulate electron spin polarization in the three-spin-1/2 system composed of the molecular excited triplet state of (tetraphenylporphinato)zinc(II) (ZnTPP) and the doublet ground state of the 3-(N-nitronyl-notroxide) pyridine (3-NOPy) stable radical is proposed. The model is based on numerical solutions of the stochastic Liouville equation for the diffusively rotating system where the magnetic dipolar, isotropic Heisenberg exchange, and anisotropic Zeeman electron spin interactions are taken into account in a full measure, whereas the intersystem crossing processes between the singlet and triplet states of ZnTPP are considered in terms of kinetic equations for the relevant spin density matrices. Additional longitudinal and transversal paramagnetic relaxation caused by relative rotation motions of the ZnTPP and 3-NOPy moieties is taken into consideration in the form of the generalized relaxation operator.     

Disassembly of an excited nuclear aggregate through sequential decay

The disassembly of an excited nuclear aggregate is described as a time-dependent decay process in which clusters are continuously and sequentially emitted by the primitive aggregate and those which have already been formed at a given time. The dynamics describe the rate at which the different species are generated as well as the rate at which the system de-excites and expands isotropically in space. The model is applied to the study of sequentially decaying⁴⁰Ar as a function of the initial excitation energy.     

Alpha decay of the first excited state of the Th-229 nucleus

The α decay of the anomalously low-lying isomeric level 3/2⁺ (3.5±1.0 eV) of the ²²⁹Th nucleus is studied. The lifetime of the isomer with respect to a decay is predicted and the spectrum of the emitted a particles is calculated. It is noted that the complete α spectrum of the isomer and accelerated α decay of ²²⁹Th can be observed by exciting the nuclei with laser radiation. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 5, 319–323 (10 September 1996)     

Polarization spectroscopy of an excited state transition

We demonstrate polarization spectroscopy of an excited state transition in room-temperature cesium vapor. An anisotropy induced by a circularly polarized pump beam on the D2 transition is observed using a weak probe on the 6P(3/2)→7S(1/2) transition. At high pump power, a subfeature due to Autler-Townes splitting is observed that theoretical modeling shows is enhanced by Doppler averaging. Polarization spectroscopy provides a simple modulation-free signal suitable for laser frequency stabilization to excited state transitions.     

Fission and decay of excited nuclei

The statistical theory of the decay of excited nuclei including the competition between particle emission and fission is considered. Fission barriers are given by a phenomenological formula which is an analog of the known Cameron formula and approximates well experimental data on nuclei up to transuranic elements. The contribution of shell corrections and odd-even effects is discussed. The calculated ratios of evaporation and fission widths Γ_n/Γ_f agree with experiment even in the region of nuclei with Z > 90. The $\text{Γ}{}_{\mathrm{<mtext>n</mtext>}}\text{Γ}{}_{\mathrm{<mtext>f</mtext>}}$ values depend weakly on excitation energy for nuclei with Z ≈ 90, While in other regions this dependence proves rather strong. The last conclusion does not contradict known experimental data since in experiments one usually measures some effective value $\text{〈}\text{Γ}{}_{\mathrm{<mtext>n</mtext>}}\text{Γ}{}_{\mathrm{<mtext>f</mtext>}}\text{〉}$, which is only indirectly related to the real $\text{Γ}{}_{\mathrm{<mtext>n</mtext>}}\text{Γ}{}_{\mathrm{<mtext>f</mtext>}}$, values. It is shown that the calculated values of $\text{〈}\text{Γ}{}_{\mathrm{<mtext>n</mtext>}}\text{Γ}{}_{\mathrm{<mtext>f</mtext>}}\text{〉}$ depend on excitation energy either. The effects of angular momentum and uncertainty in the choice of level density parameter are discussed.     

Renormalized proton- neutron QRPA and double beta decay of 82Se to excited states in 82Kr

We apply the self-consistent renormalized proton-neutron QRPA (RQRPA) method to calculate the two-neutrino double beta (2νββ) decay matrix elements associated with the ground-state and excited-state transitions of the ⁸²Se → ⁸²Kr decay. The RQRPA method is an extension of the pnQRPA method and promotes the Pauli exclusion principle violated by the pnQRPA ground state and yields more stable nuclear matrix elements with increasing strength of the proton-neutron interaction. In the present work the RQRPA wave functions are also used to evaluate 2νββ-decay rates to excited final states. The resulting theoretical half lives are compared with the new stringent experimental limits obtained by using a HPGe detector and external sources of enriched selenium.     

Ionization of ytterbium atoms from an excited state

The cross sections of the photoionization and the electron impact-induced ionization of Yb atoms from the excited 6s6p(³ P ₁) state are numerically calculated. Matrix elements are computed in multielectron relativistic and nonrelativistic approximations with allowance for the superposition of configurations and a relaxation effect. The radial part of the electron wavefunction in a continuous spectrum is calculated using the solutions to one-configuration Hartree-Fock and Dirac-Fock equations. The cross sections calculated by a relativistic method are compared to those for a nonrelativistic approximation. The ratios of the radiation reduced matrix elements and the phase shifts of the wavefunctions of a continuous spectrum calculated for the 6p ɛs and 6p → ɛd transitions are compared to the values obtained by approximating the experimental dependences of the angular distribution of photoelectrons for the photoionization by ultraviolet radiation from an oriented excited state.     

Spontaneous decay of an excited atom placed near a rectangular plate

Using the Born expansion of the Green tensor, we consider the spontaneous decay rate of an excited atom placed in the vicinity of a rectangular plate. We discuss the limitations of the commonly used simplifying assumption that the plate extends to infinity in the lateral directions and examine the effects of the atomic dipole moment orientation, atomic position, and plate boundary and thickness on the atomic decay rate. In particular, it is shown that due to the plate finite size, the spontaneous decay may be inhibited even when the atom is situated very close to the surface, and that in the boundary region, the spontaneous decay rate can be strongly modified.     

The magnetic moment of the first excited state of 19O

The magnetic moment of the first excited 96 keV, $\text{3}\text{2}{}^{\mathrm{+}}$ state of ¹⁹O has been determined by an integral perturbed angular correlation measurement in a transverse external magnetic field. The value obtained for the g-factor, ?0.48(6), is discussed in terms of shell-model configurations. The wave function of the $\text{3}\text{2}{}^{\mathrm{+}}$ level is shown to consist mainly of the $\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}{}^3$ configuration.     

Two-neutrino double β decay of96Zr to excited 2+ state of96Mo

The two-neutrino double beta decay of⁹⁶Zr isotope for 0⁺ → 2⁺ transition has been studied in the PHFB model. In our earlier work, the reliability of the intrinsic wave functions of⁹⁶Zr and⁹⁶Mo isotopes has been established by obtaining an overall agreement between a number of theoretically calculated spectroscopic properties as well as half-lives of 2vββ decay for 0⁺ → 0⁺ transition and the available experimental data. In the present work, the half-life of 2vββ decay for 0⁺ ar 2⁺ transition T ₁ ^2/2v (0⁺ →²⁺) has been calculated using the same set of intrinsic wave functions.     

Excitation and neutron decay of xenon studied by forward-angle scattering of high-energy 17O ions

Excitation energy spectra and neutron decay of xenon have been measured in extreme forward angle scattering of 250A and 400A MeV ¹⁷O ions, using one quadrant of the CELSIUS storage ring as a magnetic spectrometer. The observed excitation energy spectrum, ranging from 12 to 36 MeV, has been compared with Coulomb cross section calculations. Neutron and missing energy spectra are compared with statistical decay calculations using the code CASCADE. In addition to statistical decay from giant resonances and other continuum excitations, a large fraction of forward peaked fast neutrons was observed throughout the entire excitation energy region. A possible reaction mechanism behind these fast neutrons is discussed.     

The decay of the18O giant dipole resonance to excited residual nuclear states

The decay of the¹⁸O GDR to excited residual nuclear states has been examined by measuring spectra of prompt deexcitationγ-rays. The target was irradiated by bremsstrahlung with endpoint energies of 23.5 and 28 MeV. “Bremsstrahlung-weighted” integrated cross sections are given for the population of the residual nuclear states in¹⁷O,¹⁷N,¹⁶O and¹⁴C. Proton decay to excited states in¹⁷N is remarkably weak. It seems that 1p _3/2 excitations play only a minor role in the¹⁸O GDR.     

激发态下甘氨酸与水分子间氢键性质研究

在生物体中氨基酸通常以水作为溶剂,是形成细胞的重要成分.在该环境下,分子间氢键的产生会对氨基酸分子与水分子的结构和性质产生影响.为了研究其在基态和激发态下的性质,本文利用密度泛函理论(DFT)和含时密度泛函理论(TD-DFT)对甘氨酸分子和H₂O分子在基态和激发态下的分子间氢键的静电势、键长、自然键轨道(NBO)电荷、分子中的原子理论(AIM)分析、Wiberg键级b、红外(IR)光谱、空穴-电子轨道和基态与激发态之间的电子转移进行了理论研究.结果表明：分子间氢键的形成会导致分子结构的改变和红外光谱振动频率的移动.在激发态下,分子间氢键有不同程度的增强或减弱.该计算结果为氢键的形成和激发态下分子间氢键的研究提供理论依据.     

Transition rates and sequential decay of excited nuclei

We present two possible sequential decay mechanisms which correspond either to an inverse fusion process (detailed balance) or to a generalised fission process (transition state theory). We compare the corresponding transition rates and try to understand the implications of these two different choices on the behaviour of mass and charge multiplicities. Deviations from percolation calculation predictions and the experiment are also analysed.     

Photon vacuum renormalization and spontaneous decay of an excited atom near a carbon nanotube

A theory of the spontaneous decay process of an excited atom placed inside or outside (near the surface) of a carbon nanotube has been developed. Numerical calculations of the atomic spontaneous decay enhancement factor have been performed for various achiral nanotubes. The effect of the nanotube surface has been demonstrated to dramatically increase the spontaneous decay rate—by 6–7 orders of magnitude—compared with that of the same atom in a vacuum. Such an increase is associated with nonradiative decay via surface excitations in the nanotube. Possible applications of the predicted effect are discussed.