Reconstruction of the Grenfell Tower fire – Part 4: Contribution to the understanding of fire propagation and behaviour during horizontal fire spread

The tragic events at Grenfell Tower in 2017, involving a combustible façade system, have raised concerns regarding the fire risk that these systems pose. In this series of articles, so far published, fire development inside the initial apartment has been investigated using an appropriate computational fluid dynamics (CFD) model. Several scenarios including different fire sources and ventilation conditions were addressed. Fire propagation through the window to the external façade and to higher apartments was modelled. This model was validated by comparing the numerical results with the visual observations reported in the Grenfell Inquiry. A CFD model of the complete east face of the Grenfell Tower was then created. This paper details CFD modelling of the complete Grenfell Tower façade during the late horizontal phase of fire spread. As the physics of lateral flame spread is different from that for upward flame spread, it is important to assess the validity of the model, thus far developed, for this configuration. Fire propagation over the whole façade is modelled and compared with observations from the real disaster. This provides a better understanding of its fire behaviour and of the contribution of architectural details and their impact on fire spread.     

Reconstruction of Grenfell Tower fire. Part 2: A numerical investigation of the fire propagation and behaviour from the initial apartment to the façade

The dramatic event of the Grenfell Tower in 2017 reminds the importance of addressing fire issues as a whole and clearly highlighted one of the major roles played by the façade as fire propagation vector. To understand and analyse this disaster, numerical simulation allows particular phenomena to be evaluated more easily. The numerical model addressed for the fire behaviour of the façade system was developed using a multiscale approach and validated at different scales. In this paper, the fire behaviour of the façade and of its window frames is addressed. A computational fluid dynamics (CFD) model is used to investigate the fire spread from the initial apartment to the overall façade with different scenarios for the fire source and ventilation. Fire propagation through windows to the façade and to upper apartments is addressed. General curves representing the re-entry of flames into upper apartment are extracted from simulations. The numerical results are validated by comparison with observations from videos and pictures of the real fire. Numerical results show that whatever the initial fire location and ventilation conditions, even if the fire source is of hundreds kilowatts, it is enough to ignite the adjacent element early and to the appearance of external flames shortly after.     

Numerical analysis of neck propagation in polymeric materials. Part 1 – Neck propagation behaviour of poly (ethylene terephthalate) film

Abstract

Neck formation and propagation in poly (ethylene terephthalate) (PET) films have been investigated using finite element analysis (FEA). First, the criteria for the occurrence of neck propagation are examined and a unique constitutive law for polymers is proposed. Neck propagation is associated with a steep rise of the tangent modulus in the plastic deformation region. The ability of the specimen to form a neck is determined by the ratio of the yield stress to the tangent modulus immediately after the yield point. Next, the characteristic load–displacement behaviour in neck formation and propagation is investigated using FEA. Finally, numerical results are compared with experimental data. The calculated values agree with experimental data on load–displacement behaviour, especially for the decrease in load immediately after yield. An apparent constitutive law representing the load–displacement behaviour of PET film has been successfully obtained. By comparing the experimental results with numerical predictions of the neck localisation and propagation process, it is shown that the decrease in load is related to the recovery of deformation in the region outside the neck.     

Numerical analysis of neck propagation in polymeric materials. Part 2 – Neck propagation behaviour of poly (butylene terephthalate) mouldings

Abstract

This paper examines the factors controlling the formation and propagation of a neck in poly (butylene terephthalate) (PBT) mouldings under tensile loading. Tensile tests were used to investigate the load–displacement and deformation behaviour of PBT and the accompanying changes in surface temperature. In parallel with this experimental study, a numerical model was developed for the deformation of PBT mouldings and neck formation under tensile loading analysed using finite element analysis (FEA). The calculated numerical results were compared with the experimental data. This work has shown that formation does not occur in PBT immediately after the yield point. Instead, plastic deformation first progresses homogeneously through the testpiece. Neck formation and propagation, accompanied by a rise in temperature, then follow. The load–displacement behaviour calculated using FEA could be approximated to the experimental data by adapting an elastic–plastic model at a stable temperature to the necking behaviour of PBT moulding. Furthermore, the dependence of neck formation on strain rate is related to the plastic instability, as demonstrated by the numerical results, and does not depend upon heating effects.     

Method to Characterize the Air Flow and Water Removal Characteristics during Vacuum Dewatering. Part I—Experimental Method

An experimental method using a novel design to characterize the air flow and water removal during vacuum dewatering in paper manufacturing is discussed. The experimental setup involves the intermittent application of vacuum, similar to commercial systems, using a rotating disk with slot opening arrangement. The system is capable of commercially realistic residence times of the order of milliseconds. The intermittent application of vacuum simulates vacuum dewatering on commercial paper machines. The air flow rate is calculated from changes in pressure and temperature in the vacuum tank underneath the sample. The role and importance of air flow during vacuum dewatering is studied by accurately measuring the air flow, properly taking into account the leaks during vacuum dewatering. The method described here provides for the first time accurate air flow and water removal data during vacuum dewatering. Methods of analysis of the experimental data are also presented. This information can be used to better understand the water removal process as well the role and importance of air flow during vacuum dewatering.     

Treatments and modification to improve the reaction to fire of wood and wood based products—An overview

Wood and wood-based products are widely used for structural building elements, but due to their composition, they are susceptible of combusting if exposed to fire. Fire safety is an important issue of building safety, especially when the building's fire load contents enhance the risks of fire spread. Therefore, the involved materials are very important to address the fire safety requirements. When existing timber structures are involved, the most usual way to improve its reaction to fire is to treat wood with fire retardant materials. The idea of this paper is to give an overall overview, on the existing fire-retardant and intumescent coating materials, modification, and treatments that can be applied to wood and wood-based products in order to improve their reaction to fire.     

From laboratory experiments to simulation studies of methanol dehydration to produce dimethyl ether reaction—Part II: Simulation and cost estimation

The vapor phase dimethyl ether (DME) synthesis is simulated by Hysys process simulation software and relevant cost analysis is also conducted. Based on cost estimation results, it is found that capital investment of the classic DME process is greatly influenced by the distillation towers and operating costs. Accordingly, to solve these problems an innovative DME process based on a top-wall dividing-wall column (DWC) in vapor phase is proposed, in this work. It is shown that the novel proposed DWC process leads to 44.53% reduction in operating costs compared to the conventional one, while both schemes predict almost the same output specifications.     

Reply to the discussion by Q. Zeng and S.L. Xu of the paper “Numerical simulation of moisture transport in concrete based on a pore size distribution model”

This paper presents a reply to the discussion of the paper “Numerical simulation of moisture transport in concrete based on a pore size distribution model” by Q. Zeng and S.L. Xu.     

From laboratory experiments to simulation studies of methanol dehydration to produce dimethyl ether—Part I: Reaction kinetic study

Most of the reaction rate equations for methanol dehydration are derived from the experiments conducted for crude methanol as feed and laboratory prepared catalysts, which are not exactly the same as industrial reactors conditions. In the present contribution, it is attempted to find suitable rate of reactions for pure methanol with no water as feed and commercial catalysts of HZSM-5 and γ-alumina at industrial conditions in methanol dehydration process. In addition, a comparison between the performances of the catalysts is performed. It is found that HZSM-5 has superior performances compared to the γ-alumina in terms of conversion. Modeling results are also indicated that the proposed rate of reaction predicts the behavior of the process, properly.     

Studies on the Dehydrogenative Polymerizations of Monolignol β-glycosides. Part 3: Horseradish Peroxidase–Catalyzed Polymerizations of Triandrin and Isosyringin

Abstract

Horseradish peroxidase–catalyzed dehydrogenative polymerizations of the p-hydroxyphenyl monolignol glucoside (triandrin (1P)) and the syringyl monolignol glucoside (isosyringin (1S)) resulted in the formation of water-soluble lignin-like polymers (DHPs). The polymerization of 1P gave highly polymerized DHPs in high yields as did previously reported polymerization of the guaiacyl monolignol glucoside (isoconiferin (1G)). It was shown that the hydrophilic D-glucose units of 1G and 1P contribute to a marked increase in the molecular weights of the resulting DHPs. On the other hand, the homogeneous phase polymerization of 1S, similar to the polymerization of sinapyl alcohol, gave DHPs with extremely low molecular masses in poor yields. Structural characterization indicated that the DHPs from 1P and 1S were lignin-like polymers containing glucosidic units on their sidechains. It was also confirmed that D-glucosyl units introduced onto the γ-position of monolignols do not significantly affect the electrochemical oxidizability and the kinetics of the HRP-catalyzed initial monomer consumption.     

Method to Characterize the Air Flow and Water Removal Characteristics During Vacuum Dewatering. Part II—Analysis and Characterization

This is part II of a study reported earlier on a method to characterize the air flow and water removal characteristics during vacuum dewatering. This article presents experimental data and analysis of results from the use of a cyclically actuated vacuum dewatering device for removing moisture from wetted porous materials such as paper with the intermittent application of vacuum and accompanying air flow though the material. Results presented include sheet moisture content as a function of residence time and hence water removal rate under a variety of process conditions. Also, experimental results on air flow through the wet porous structure and hence the role and importance of air flow during vacuum dewatering are presented. Vacuum dewatering process conditions include exit solids content between 11 and 20% solid under applied vacuum conditions of 13.5 to 67.7 kPa (4 to 20 in. Hg). Regression analysis indicated that the exit sheet moisture content exhibited a nonlinear relationship with residence time with exit solids reaching a plateau after a certain residence time. Final moisture content correlated linearly with the average overall flow rate of air through the paper sample and the basis weight of the material.     

Study of cerium species in molten Li2CO3–Na2CO3 in the conditions used in molten carbonate fuel cells. Part II: Potentiometric and voltammetric behaviour

The electrochemical behaviour of metallic cerium and cerium dioxide is analysed in molten Li₂CO₃–Na₂CO₃ under the anodic and cathodic conditions used for the molten carbonate fuel cells (MCFC). Chronopotentiometric measurements on metallic cerium rods or foils show the influence of CeO₂ growth and the deviation from its stoichiometric composition. A study of the voltammetric characteristics of dissolved cerium at a gold electrode, of metallic cerium and cerium oxide is carried out in both oxidising and reducing MCFC atmospheres. Experimental evidence is given for the existence of a solid–solid cerium system: Ce₂O₃(s)|CeO₂(s) and a system relative to dissolved cerium species Ce₂O₃(l)|CeO₂(l). These systems are in agreement with thermodynamic predictions. Other more complex phenomena involving interactions with alkali species are discussed.     

How to Attain Ultralow Interfacial Tension and Three-Phase Behavior with a Surfactant Formulation for Enhanced Oil Recovery: a Review—Part 3. Practical Procedures to Optimize the Laboratory Research According to the Current State of the Art in Surfactant Mixing

The minimum interfacial tension to be reached in enhanced oil recovery by surfactant flooding implies the attainment of a so-called optimum formulation. Part 1 of the present review showed that this formulation may be described as a numerical correlation between the involved variables defining the oil, the water, the surfactant and the temperature. Since it is unlikely to find a single surfactant matching the crude/brine/T/P system characteristic of a reservoir, a mixture of at least two surfactant species is always used. The scan technique method to test the mixing requires about ten interfacial tension or phase behavior experiments and results in a single data. Hence, the scan experiments have to be repeated many times to find a minimum tension which is low enough, e.g. 0.001 mN/m, for the given crude oil-brine system. Part 2 of this review has shown that there are many formulation variables and thus too many possibilities to easily choose experimental conditions. Since there is no simple method to select two or more surfactant species, the choice is made from partial experience or intuition, and sometimes at random. The laboratory time and cost to reach an appropriate optimum formulation is often excessive. Part 3 of this review shows that by cleverly using a three-surfactant mixture, the experimental work to attain a very low interfacial tension for a given reservoir case can be considerably reduced. It is a matter of using the available information along a proper sequential step by step path toward the optimum.     

Elucidation of Softening Mechanism in Rinse-Cycle Fabric Softeners. Part 2: Uneven Adsorption—The Key Phenomenon to the Effect of Fabric Softeners

We investigated the actual factor determining the softening effect of a fabric softener. The adsorption area of the softener on model cotton cloths and yarns was identified using bromophenol blue. There was almost no softener at the cross-points of the yarns in the cloth samples or in the inner part of the yarns. The softening performance was better when there was less softener at the cross-points of the yarns than when the yarns were evenly covered by the softener. Thus we conclude that the presence of softener at the cross-points of yarns is not a vital factor in the softening effect. In addition, more softener was found on the outer part of the yarn than the inner part, indicating gradation in the adsorption pattern of the softener. Thus, we propose that more softener is adsorbed on the exposed part of the yarn in a cloth, and the formation of a hydrogen-bonding network containing bound water is inhibited, thus softening the outer part of the yarn. However, the presence of a small amount of softener in the inner part of the yarn preserves the hydrogen-bonding network. Favorable elasticity, or bounce, of the yarns and cloth is realized when an appropriate amount of softener is used. Excess softener would reach the inner part of the yarn, reducing the diameter of the core part of the yarn, making the cloth appear wilted.     

Free radical polymerization of ethyl methacrylate and ethyl α-hydroxy methacrylate: A computational approach to the propagation kinetics

The propagation kinetics of ethyl methacrylate (EMA) and ethyl α-hydroxy methacrylate (EHMA) has been subject to a computational study to understand their free radical polymerization (FRP) behavior in bulk and in solution using Density Functional Theory (DFT). The propagation of EHMA is studied in ethanol and toluene to assess the effect of hydrogen-bonding solvents on FRP of monomers with α-hydroxy functionality. Although EMA and EHMA resemble each other in structure, EHMA propagates faster in bulk due to the presence of intermolecular hydrogen-bonds, which tend to facilitate the approach of the propagating species. This falls in contrast with the experimentally observed lower propagation rates of EHMA in ethanol compared to toluene. Calculations show that the 2.28 rate acceleration in toluene is governed by the ratio of the pre-exponential factors, which reflect the entropies of activation, in both media. The polar protic solvent ethanol has a disruptive effect via hydrogen-bonding on the 6-membered ring shape of EHMA monomers thus decreasing the entropy of activation of the reaction. In the case of toluene, there are no special interactions with the hydrophobic solvent, the entropy of activation is higher than in ethanol.     

A method to improve the barrier performance of flexible riser internal pressure sheath—Heat transfer experiment and simulation

A considerable amount of acidic gas penetrates into the annulus between the internal pressure sheath and the outer protective sheath during the service of flexible risers, which will inevitably lead to corrosion of the metal functional layer. Many researchers have modified nanocomposites from the mass transfer perspective to reduce the materials' permeability coefficient. While permeation is an integrated process of heat and mass transfer process, heat distribution directly impacts gas permeation. Herein, the thermal conductivity of flexible riser liner materials is predicted for the first time by a combination of molecular dynamics and experiments, and then the radial temperature distribution under different seawater temperatures and internal fluid temperatures is investigated by finite element analysis. Finally, the effect of temperature distribution on the permeation coefficient was analyzed. The results demonstrate that the thermal conductivity can be predicted by molecular dynamics simulation, and the thermal conductivity of (polyvinylidene difluoride) PVDF/TiO₂ decreases, while the thermal conductivity of PVDF/carbon nanotube (CNT) increases compared with pure PVDF. The temperature distribution of the internal pressure sheath material decreases when condensate water is present. As the fluid temperature rises from 30 to 110°C, the maximum increase ratio in the permeability of PVDF/CNT over PVDF increased from 3.6% to 14.8%, and the maximum decrease ratio of PVDF/TiO₂ permeability coefficient compared with PVDF is from 1.2% to 4.6%. The results present a new idea to improve the barrier properties of materials by decreasing thermal conductivity.     

Is there any contradiction between the stress and energy failure criteria in micromechanical tests? Part III. Experimental observation of crack propagation in the microbond test

A direct observation of crack propagation in the microbond test was carried out for five different fiber/polymer matrix systems. This technique appeared to be a very effective tool for interface characterization. Experimental plots of the force required for further crack propagation as a function of debond length were analyzed using both energy-based and stress-based models of debonding. The fracture mechanics analysis was used to construct families of crack resistance or R-curves which showed the variation of energy release rate, G, with the debond length, and included the effect of interfacial friction in debonded regions. For the first time, analogs of the R-curves were created within the scope of the stress-based model to present the local shear stress near the crack tip, τ, as a function of crack length. In both models, the behavior of the interfacial parameter (G or τ) strongly depends on the assumed value of the interfacial frictional stress (τ_f). However, for each matrix/fiber system there exists such a τ_f value for which the investigated parameter is nearly constant over the whole region of stable crack propagation (70–90% of the embedded length). Moreover, these best-fit τ_f values for each specimen appeared to be practically the same for both energy-based and stress-based approaches. Thus, both interfacial toughness, G _ic, and local interfacial shear strength, τ_d, adequately characterize the strength of a fiber/matrix interface. Extrapolation of R-curves and their analogs to zero crack length allows measurement of the interfacial parameters with good accuracy.     

Keeping properties of edible oils—Part I. The use of accelerated tests for assessment of the keeping properties of oils and the value of antioxidants

Assessment of oil quality by two accelerated oxidation tests gave little or no correlation with organoleptic asessment during storage. Improvements in quality of oils refined in the factory, to which antioxidants had been added, are indicated by the accelerated tests but are not reproduced in normal storage. Howver a treatment of the oils with alumina, as a part of the refining process replacing earth bleaching, appears to remove antagonistic factors, and under these circumstances the addition of antioxidant has a pronounced effect.