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采用平均粒径分别为3.5 μm、1.5 μm和200 nm的碳化硼粉体为原料经1850℃热压烧结制备了碳化硼陶瓷, 研究了粉体粒径对陶瓷烧结致密化过程及其性能的影响。根据保温时间对线收缩率的影响及热压初期的塑性流动机理, 得出了不同粉体间烧结初期的激活能差。结果表明: 在相同工艺条件下, 随着粉体平均粒径的减小, 粉体的扩散激活能降低, 致密化初始温度降低, 而且完成塑性流动所需时间也会明显缩短, 致密化速率加快, 致密度增大; 碳化硼陶瓷的显微结构与力学性能亦随着粉体粒径的减小而改善; 1850℃保温1 h后, 平均粒径为200 nm的粉体制备的碳化硼陶瓷相对密度可达90.5%, 硬度为(17±1.8) GPa。 相似文献
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为了制备具有良好综合力学性能的TiCN基金属陶瓷,研究了烧结温度对TiCN-HfN陶瓷微观结构和力学性能的影响,构建了颗粒弥散和核-壳共存的微观结构模型,揭示了材料的致密化机制、增硬机制、增韧补强机制。结果表明:在1 500℃下所制备的TiCN-HfN材料具有颗粒弥散与核-壳共存的微观结构,其中弥散的颗粒为HfN,核为TiCN,壳主要为(Ti, Hf, Mo)CN固溶体;材料具有较好的性能,其相对密度为99.7%、硬度为20.6 GPa、抗弯强度为1 682.5 MPa、断裂韧度为8.5 MPa·m1/2;其致密化机制主要为颗粒和金属液相填充到烧结颈实现致密化,增硬机制主要为致密化和颗粒钉扎强化增硬,增韧补强机制主要为颗粒弥散和颗粒钉扎增韧、骨架结构和颗粒钉扎增强。 相似文献
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通过B4C、CeO2和C的化学反应,采用原位生成法,在热压烧结的条件下制备了CeB6/B4C陶瓷材料.研究了CeB6/B4C陶瓷材料的力学性能和显微组织,并对其增韧机理进行了分析.结果表明:原位生成的CeB6/B4C陶瓷只有CeB6和B4C两相,其显微维氏硬度、抗弯强度、断裂韧性最大值分别达到40.64GPa、346.7MPa、5.95MPa·m1/2,比纯碳化硼分别提高了52.50%、17.96%、61.68%.原位生成的CeB6颗粒细晶增韧补强,B4C和CeB6颗粒之间热膨胀系数不匹配产生的残余应力导致的裂纹偏转以及沿晶断裂是CeB6/B4C陶瓷的主要增韧机制. 相似文献
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根据能量散耗特征,本文将陶瓷材料的增韧机制分为两大类——作用区增韧和桥联增韧。讨论了分别包含这两类增韧机制的二个典型复合材料——相变增韧陶瓷和晶须补强陶瓷复合材料的显微结构设计要点。分析了晶须补强与相变增韧机制间的交互作用,引出了利用多种增韧机制制备高韧性陶瓷复合材料的设计思想。 相似文献
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热交换器是将不同温度介质之间的热量通过热传导的形式,由高温介质传递给低温介质,使介质达到生产所需温度的工艺设备,也可作为一种节能设备使用.通过对不同热交换器的结构分析,总结不同热交换器的优缺点、适用环境,为生产工艺设计人员及设备制造单位在选择可降低能耗、提高效率的设备上提供参考. 相似文献
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通过化学氧化法分别制备盐酸,盐酸和十二烷基苯磺酸,碳纳米管(MWNTs-COOH)掺杂的聚苯胺,利用红外光谱,紫外光谱,扫描电子显微镜和透射电子显微镜对所制备聚苯胺的结构和形貌进行分析。分析不同掺杂物对聚苯胺的结构和形貌的影响;同时研究了超声波作用对聚苯胺形貌以及聚苯胺包裹MWNTs-COOH情况的影响。 相似文献
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I. I. Novikov 《Journal of Engineering Physics and Thermophysics》1987,53(5):1227-1232
Principles of the theory of thermodynamic similarity are considered in application to all aggregate states of a substance, including phase transitions, and to the change in dissipative structures in open systems.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 53, No. 5, pp. 709–716, November, 1987. 相似文献
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The curing of thermosets is a complex process involving the transition from a fluid into a (visco-) elastic solid. This phase transition comes along with an increase in stiffness and a volume shrinkage of the polymer. The latter may lead to severe residual strains and stresses, which in turn can cause damage in the final, usually quasi-brittle material. In this contribution a constitutive model is developed which takes into account the curing of a thermosetting material together with the process-induced damage as resulting from curing shrinkage. The curing of the material is governed by a phenomenological hypoelastic constitutive equation which includes temporal evolutions for stiffness and volume shrinkage. Thermal and viscous effects are neglected in the present study. An isotropic gradient-enhanced damage model is adapted to describe the damage evolution. The curing-damage model is implemented into a finite element code and numerical examples for thermosetting materials demonstrate that the proposed model is capable to predict cure-induced damage in thermosets. 相似文献
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A Wolfenden 《Journal of Materials Science》1997,32(9):2275-2282
Measurements of dynamic Young's modulus, E, and damping as a function of temperature, T, were made for alumina and silicon
carbide. The Young's modulus data were compared with some from the literature, and analysed in terms of a theoretical framework
relating the Debye temperature, θD, with the elastic constants. For both materials this analysis yielded a ratio T0/θD which was near 0.4, where T0 is an empirical fitting constant for the plot of (E(0)−E)/T versus 1/T (E(0) is the value of E at 0 K). The analysis of the
damping data in terms of an Arrhenius type dependence led to effective activation energies near kT, where k is Boltzmann's
constant.
This revised version was published online in November 2006 with corrections to the Cover Date. 相似文献
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A. Galerie Y. Wouters M. Pijolat F. Valdivieso M. Soustelle T. Magnin D. Delafosse C. Bosch B. Bayle 《Advanced Engineering Materials》2001,3(8):555-561
Selected topics in field of the study of the mechanisms of corrosion and of oxidation of metals or alloys are presented. The first part reports a new model for the mechanism of the breakaway oxidation of ferritic stainless steels in water vapour. The second part is devoted to the physico‐chemical aspects of oxidation and presents experimental methods useful in the kinetic modelling applied to two alloys, the zircalloy‐4 and an AlMg5 % in the liquid state. In the third part the physical and numerical modelling of the stress corrosion cracking behaviour in face‐centered cubic (fcc) alloys is detailed, which enables the study of the influence of macroscopic parameters (such as the temperature or hydrogen activity) on the fracture process. 相似文献
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Surface-charge density and potential of coal-liquid mixtures and control of their stability and fluidity 总被引:1,自引:0,他引:1
T. Hamieh 《Journal of Materials Science》1996,31(21):5665-5669
The preparation conditions of concentrated (>70%) aqueous suspensions of coal were optimized, as were the surface charge density and the surface potential of the coal-water suspensions. The theoretical study showed that (1–3) or (2–3) electrolytes such as Na2SO4 or Na5P3O10, greatly increase the surface charge density and the surface potential of the coal particles in water. This study has led to the interesting result that thinners and stabilizing agents of concentrated clay suspensions, such as lignosulphonates, tripolyphosphates, polynaphtalene sulphonates, etc., must also be good thinners and stabilizing agents for ground coal-water suspensions. Two parameters were controlled: the stability and the fluidity of the suspensions. A penetrometry technique revealed the importance of the resistance coefficient,C
r that can be used as a criterion for the evaluation of coal-water mixture stability and fluidity. Concentrated coal suspensions (about 75% of solid by weight) were prepared in water by using different additives, for instance sodium tripolyphosphate (NaTPP) and surfactants like lignosulphonates (by coupling of the dispersion and stabilizing effects) with the optimum concentration ratio of these two products equal to 1.9. The stability of the suspensions was then greater than 2 months and the viscosity was 1900 cP. 相似文献
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