共查询到16条相似文献,搜索用时 625 毫秒
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测试了不同掺杂浓度和不同厚度下Yb3+磷酸盐玻璃的吸收光谱、荧光光谱和荧 光寿命,计算了积分吸收截面、吸收截面、受激发射截面、自发辐射寿命以及荧光有效线宽等光谱参数,讨论了荧光俘获效应对Yb3+磷酸盐玻璃光谱性质的影响.结果表明荧光俘 获效应随样品厚度和掺杂浓度的增加而增大.由于荧光俘获效应的存在使得测量的Yb3+磷酸盐玻璃荧光寿命明显长于计算的荧光寿命,在0.2mol%Yb2O3低掺 杂浓度下
关键词:
荧光俘获
掺镱磷酸盐玻璃
荧光光谱 相似文献
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采用固相反应方法,制备了Er3+离子浓度为0.5 at.%,Yb掺杂浓度范围为0.0— 6.0 at.%的Er/Yb共掺激光玻璃,并对激光玻璃的吸收光谱和光致荧光光谱进行了分析.研究 结果显示,Yb3+掺杂对Er3+在980 nm附近的吸收起到了非常显著的 增强作用.在 980 nm的激光抽运下,激光玻璃在1530 nm处的光致发光强度随着Yb离子浓度 的增加而先增大后减小, 当Yb3+离子浓度为Er3+离子浓度6倍时光 致发光强度达到最大值.同时还发现了Yb3+对Er3+的光致荧光光谱 的展宽作用,并讨论了荧光光谱的展宽机理.
关键词:
Er/Yb共掺玻璃
光致发光
吸收光谱 相似文献
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Yb3+/Er3+共掺杂TeO2-WO3-ZnO玻璃的光谱性质 总被引:3,自引:3,他引:0
制备了Yb3+/Er3+共掺杂的TeO2-WO3-ZnO玻璃,测量了Er3+在玻璃中的吸收光谱和970nmLD激发下的荧光光谱、荧光寿命和上转换光谱.计算了Yb3+/Er3+间的能量传递效率和Er3+离子1.5μm波段的吸收截面、发射截面,并研究了其荧光强度和上转换发光与Yb3+掺杂浓度间的关系.结果表明,Yb3+共掺杂可明显提高Er3+离子1.5μm发射的荧光强度,实验所得Yb3+离子的最佳掺杂浓度为Er3+离子浓度的3倍,在7.28×1020ions/cm3左右.Er3+离子1.5μm发射的荧光半峰全宽为67~72nm;上转换红、绿光均为双光子过程,随Yb3+掺杂浓度的增加,上转换红、绿光强度均增强. 相似文献
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制备了高折射率Tm3+/Yb3+共掺杂铋碲酸盐玻璃,利用棱镜耦合法测量出玻璃在632.8和1550nm波长处的折射率分别为2.0365和1.9795. 对玻璃的吸收、荧光和红外透过光谱展开了测试与分析,根据Judd-Ofelt理论对吸收光谱进行拟合,求得Tm3+的振子强度参数Ωt(t=2,4,6)分别为3.90×10-20, 2.03×10-20和9.03×10-2
关键词:
3+/Yb3+共掺')" href="#">Tm3+/Yb3+共掺
铋碲酸盐玻璃
光谱参数
上转换荧光 相似文献
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用高温熔融法制备了Er3+/Yb3+共掺杂的45Bi2O3-45GeO2-10PbO玻璃,对玻璃样品进行了光谱测试,分析了上转换发光机制和Yb3+→Er3+的能量传递效率。通过Yb3+离子浓度对Er3+离子在铋酸盐玻璃中的上转换荧光强度影响的研究,得到Er3+质量分数为0.5%以及Yb3+质量分数为2.5%时上转换发光强度最大。研究结果表明,在970nm泵浦激发下,Er3+/Yb3+共掺杂B45G45P10玻璃在532,545,673nm处产生较强的上转换绿光和红光,是一种较为理想的上转换发光基质材料。 相似文献
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在玻璃基片表面制作了Coumarin 500、Coumarin 540和Rhodamine 6G 3种染料掺杂的聚合物薄膜,并以市售LED灯和氙灯为光源,实验研究了单一染料掺杂和混合染料掺杂的聚合物薄膜的吸收光谱、荧光光谱及其光谱下转换的特征。研究结果表明:这种多染料掺杂的聚合物薄膜能够吸收350~550 nm波长范围内的光子并将其转换至波长为580 nm左右的光子。在一定的浓度范围内,较高的染料浓度能够获得较高的下转换光子输出。由于Nd3+/Yb3+共掺玻璃中Nd3+离子在 580 nm 附近有一个较强的吸收峰,这种染料掺杂聚合物薄膜的光谱下转换有助于提高Nd3+/Yb3+共掺玻璃对太阳光中蓝绿光的吸收并通过共振能量转移激发Yb3+离子的近红外发光,对提高单晶硅太阳能电池的综合光伏转换效率有潜在的应用价值。 相似文献
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Up-conversion photoluminescence characteristics of Yb3+:Er3+:Tm3+ co-doped borosilicate glasses 下载免费PDF全文
Yb3+:Er3+:Tm3+ co-doped borosilicate glasses are prepared.Their strong up-conversion photoluminescence spectra in a range from ultra-violet to near-infrared,which are excited by a 978-nm laser diode,are measured,and the mechanisms of energy transfer among Yb3+,Er3+ and Tm3+ ions are discussed.The results show that there is an unexpected wavelength at 900-nm emission from Yb3+ Stark splitting levels to pump Tm3+ ions and there exists an optimum pump power.The concentration of the Tm3+ dopant gives rise to a prominent effect on the intensity of visible and near-infrared emissions for the Yb3+:Er3+:Tm3+ co-doped borosilicate glasses. 相似文献
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Q.Y. Zhang Z.M. Feng Z.H. Jiang 《Journal of Quantitative Spectroscopy & Radiative Transfer》2006,98(2):167-179
We report on the energy transfer and frequency upconversion spectroscopic properties of Er3+-doped and Er3+/Yb3+-codoped TeO2-ZnO-Na2O-PbCl2 halide modified tellurite glasses upon excitation with 808 and 978 nm laser diode. Three intense emissions centered at around 529, 546 and 657 nm, alongwith a very weak blue emission at 410 nm have clearly been observed for the Er3+/Yb3+-codoped halide modified tellurite glasses upon excitation at 978 nm and the involved mechanisms are explained. The quadratic dependence of fluorescence on excitation laser power confirms the fact that the two-photon contribute to the infrared to green-red upconversion emissions. And the blue upconversion at 410 nm involved a sequential three-photon absorption process. 相似文献
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The up-conversion emission properties of Yb3+-Ho3+ co-doped germanium-borate glasses have been investigated with 980 nm excitation. The violet, blue, green and red emission bands at about 350, 485, 544 and 653 nm can be identified, respectively. Experimental results indicated that the relative intensity ratios of the peaks IRed/IGreen increased with increasing B2O3 concentration, which led to changing color of up-conversion emission from green at x=0 to yellow at x=40, to red at x=60. The violet emission at 350 nm was first reported in germanium-borate glass host and up-conversion mechanisms of the emissions were discussed. The Yb3+-Ho3+ co-doped germanium-borate glasses could be an alternative for the generation of violet and primary colors for application in solid-state displays. 相似文献
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L. J. Borrero-González I. A. A. Terra L. A. O. Nunes A. M. Farias M. J. Barboza J. H. Rohling A. N. Medina M. L. Baesso 《Applied physics. B, Lasers and optics》2012,107(2):415-420
We have studied the influence of SiO2 content on the spectroscopic properties and laser emission efficiency of Yb3+-Er3+ co-doped calcium aluminosilicate glasses. An increase in SiO2 content resulted in higher phonon energy, which reduced the up-conversion emission, enhanced the energy transfer efficiency up to 70 % from Yb3+ to Er3+, and enhanced the optical quality. All these results led to an increase from 20 to 30 % in the laser emission efficiency. 相似文献
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制备了不同Tm3+离子浓度的PbO-Bi2O3-Ga2O3-GeO2重金属氧化物玻璃,根据吸收光谱计算了JO强度参量以及Tm3+离子在玻璃中的自发辐射概率、荧光分支比及荧光辐射寿命等光谱参数.通过测量1470nm波段发射光谱,计算表明该玻璃系统在S波段有较宽的荧光半高宽和较大的峰值受激发射截面,但玻璃中荧光寿命随稀土离子浓度增加呈线性下降,而交叉弛豫速率随浓度的平方迅速增加.研究结果仍可表明掺铥重金属氧化物玻璃是一种理想的S波段宽带光纤放大器用基质材料.
关键词:
重金属氧化物玻璃
3+离子')" href="#">Tm3+离子
S波段光纤放大器
光谱性质 相似文献