共查询到19条相似文献,搜索用时 140 毫秒
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TEOS溶胶-凝胶法制备SiO_2-有机杂化材料研究进展 总被引:2,自引:0,他引:2
无机-有机杂化材料是指将无机和有机材料以一定的方法键合在一起而得到的一种新型复合材料。随着溶胶-凝胶法的发展,Si O2及其Si O2-有机杂化材料的合成过程越来越多样化,产物形态更为复杂,产物结构表现出一定的可控性。本文分别对溶胶-凝胶法制备Si O2-有机杂化材料诸方面最新研究进展进行总结与评述。 相似文献
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《高分子材料科学与工程》2012,(1):4-4
本发明提供了一种聚酰亚胺/无机纳米杂化材料制备方法,首先合成适用于聚酰亚胺的无机纳米粒子改性剂——亚胺环基硅烷;采用溶胶-凝胶法制备无机氧化物纳米粒子,在溶胶一凝胶反应过程中加入改性剂亚胺环基硅烷,得到有机-无机复合体纳米颗粒;将有机-无机复合体纳米颗粒均匀分散于聚酰胺酸溶液中,经过加热处理得到聚酰亚胺/无机纳米杂化材料。本发明的聚酰亚胺/无机纳米杂化材料制备方法解决了纳米粒子分散的难题,在聚酰亚胺/无机纳米杂化材料中纳米粒子分布均匀,不团聚,有利于其各项性能的充分发挥。 相似文献
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聚合物/无机纳米复合材料研究进展 总被引:28,自引:1,他引:27
本文对无机纳米材料的结构特征及预处理技术 ,对用于制备聚合物 /无机纳米复合材料的直接分散法、插层复合法、溶胶 -凝胶 (sol-gel)法等 3种方法及聚合物 /无机纳米复合材料的性能进行了综述。并对本领域今后的发展趋势提出了一些看法。 相似文献
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溶胶-凝胶法制备的有机/无机纳米杂化涂料具有许多优点。介绍了溶胶-凝胶法制备有机/无机纳米杂化涂料的研究现状,并对此作出了展望。 相似文献
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有机-无机纳米复合材料的制备、性能及应用 总被引:2,自引:0,他引:2
综述了有机-无机纳米复合材料的最新发展,包括该类材料的制备方法、性能研究和应用前景.纳米复合技术主要有3种:溶胶-凝胶法、嵌入法和纳米微粒填充法.纳米复合材料的光学和磁学等性能可用Maxwell形态理论、层状结构理论和分形结构理论等来研究.这类材料已在力学、热学、电学、磁学、光学、宇航和生物仿生等领域表现出广阔的应用前景. 相似文献
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以空心球表面负载的叔丁基过氧化氢为引发剂,通过反向原子转移自由基聚合制备了空心球-聚甲基丙烯酸甲酯杂化材料,以此为引发剂,以含有甲基丙烯酸甲酯的铽配合物为第二单体,通过原子转移自由基聚合制备了空心球-g-PMMA-b-Tb杂化材料,并用FT-IR、GPC、TG和荧光光谱等对产物进行了测试与分析。结果表明,PMMA在空心球表面的接枝率约为8%;溶液中形成的PMMA的-Mw为28800,分子量分布指数(PDI)为1.2;杂化材料在489 nm,545 nm,583 nm,621 nm左右出现了四组发射峰,分属于Tb3+的5D4→7F6、5D4→7F5、5D4→7F4和5D4→7F3跃迁;铽配合物已接枝到空心球表面,生成了具有发光性能的杂化材料。 相似文献
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作为一种新兴的可控/活性聚合方法,原子转移自由基聚合(ATRP)兼具了自由基聚合与可控/活性聚合的优点。水作为一种环境友好性的溶剂,使其作为ATRP的反应介质有着强烈的吸引力。文中从均相水溶液体系以及悬浮、乳液、微乳液等非均相水溶液体系,分别介绍了近年来水介质中ATRP的研究进展,并对其发展方向进行了展望。 相似文献
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Leonie Barner 《Advanced materials (Deerfield Beach, Fla.)》2009,21(24):2547-2553
Functional polymeric microspheres are of great interest as they have high potential as functional scaffolds in material science applications. Highly cross‐linked poly(divinyl benzene) (pDVB) microspheres can be synthesized via the precipitation polymerization technique. Recently, various methods of controlled polymerization techniques (e.g., atom transfer radical polymerization (ATRP), reversible addition fragmentation chain transfer (RAFT), and anionic ring‐opening polymerization (AROP)) and highly orthogonal conjugation methods (e.g., copper‐catalyzed Huisgen 1,3‐dipolar cycloaddition of azides and terminal alkynes (CuAAc), thiol‐ene addition and RAFT hetero Diels–Alder cycloaddition (RAFT‐HDA)) have been applied to functionalize microspheres via the “grafting from” and “grafting to” approaches. The synthesis of pDVB microspheres, their subsequent modification via grafting of polymer strands to the surface, and the characterization of the obtained functional particles are reviewed. 相似文献
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电子转移生成催化剂原子转移自由聚合(AGET ATRP)和电子转移再生催化剂原子转移自由基聚合(ARGET ATRP)是两种新型的原子转移自由基聚合体系,它们不仅克服了传统原子转移自由基聚合体系(NormalATRP)中低价态过渡金属催化剂容易氧化、用量大、后处理困难等问题,而且在制备嵌段共聚物的过程中不会生成均聚物,可以进行本体、溶液、细乳液聚合,尤其是使电子转移再生催化剂原子转移自由基聚合体系中催化剂浓度降到10×10-6,对原子转移自由基聚合的工业化应用产生了深远影响。综述了这两种原子转移自由基聚合的最新研究进展,包括目前适用于该引发体系的单体、引发剂、过渡金属络合物、配体和还原剂,展望了原子转移自由基聚合的发展。 相似文献
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含有糖单元的聚合物因其在药学和生物技术等领域的潜在应用价值吸引了科研工作者的广泛关注.文中介绍了原子转移自由基聚合(ATRP),氮氧稳定自由基聚合(NMP),可逆加成断裂链转移聚合(RAFT)等"活性"/可控自由基聚合在制备含糖聚合物中的应用进展,重点介绍了上述三种聚合方法对含糖聚合物分子量和结构的控制. 相似文献
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Gold and Au@SiO2 nanoparticles were synthesized and surface-functionalized by initiators for atom transfer radical polymerization (ATRP), either using a thiol or a trialkoxysilane anchor group for the immobilization of the initiating functionality. The thus obtained initiator-capped gold systems were applied in polymerizations of various monomers, such as styrene, methacrylic acid trimethyloxysilyl propylester and isoprene and copolymers thereof. The final inorganic-organic core-shell nanoparticles were characterized applying different techniques such as electron microscopy and light scattering. Kinetic studies of the polymerizations revealed that they were highly controlled and therefore the thickness of the polymer shell could be easily adjusted. The obtained nanoparticles formed stable suspensions in various organic solvents and can therefore be used as building blocks for polymer nanocomposites. 相似文献
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One effective strategy in the field of biomaterials is to develop biomimetic interfaces to modulate the cell behavior and promote tissue regeneration and surface modification is the best way to obtain biomaterial surfaces with the desired biological functions and properties. Surface radical polymerization offers many advantages compared to other methods, for instance, low cost and simplicity, ability to control the surface chemistry without changing the properties of the bulk materials by introducing high-density graft chains and precisely controlling the location of the chains grafted to the surface, as well as long-term chemical stability of the chains introduced by this method due to the covalent bonding. Because of the precise control of the macromolecules and easy preparation, controlled/living radical polymerization has been widely used to modify biomaterials. There are three main techniques: atom transfer radical polymerization (ATRP), nitroxide-mediated polymerization (NMP), and reversible radical addition-fragmentation chain transfer (RAFT) polymerization. Some other grafting methods such as plasma-induced polymerization, irradiation-induced polymerization, and photo-induced polymerization also have great potential pertaining to functionalization of biomaterials and tailoring of surface chemistry. This paper summarizes recent advances in the various grafting polymerization methods to enhance the surface properties and biological functions of biomaterials. 相似文献
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Fundamentals of controlled/“living” radical polymerization are given together with a discussion of selected initiating/catalytic systems which provide structural, compositional, and functionality control during radical polymerization. Four systems which enable the synthesis of polymers with low polydispersities (Mw/Mn< 1.2), relatively high molecular weights (Mn>10 000), and high degrees of functionality are: nitroxide-mediated polymerization of styrene and styrene copolymers; organometallic compounds used for polymerization of acrylates; atom transfer radical polymerization of various monomers; and the degenerative transfer process. Also important in this field are new structural features and potential applications of controlled radical polymerization. 相似文献