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1.
华北地区上古生界二次生烃及成藏条件特征   总被引:1,自引:0,他引:1  
华北地区是我国东部的主要含油气区,其上古生界烃源岩主要以煤系和暗色泥岩为主。由于石炭—二叠系烃源岩埋藏深,热演化程度高,且古生代以来构造条件复杂,为上古生界烃源岩的二次生烃提供了条件。一次生烃多数发生在印支期,而二次生烃发生在燕山期和喜马拉雅期。烃源岩主要分布于本溪组、太原组和山西组中,且南北厚、中间薄,据参数分析属于中等—好烃源岩。其储层分布于下古生界的白云岩和上古生界的碎屑岩中,原生孔隙不发育,储集空间以次生孔隙为主。物性差,为低孔低渗储层。峰峰组碳酸盐岩、本溪组铝土岩及铝土质泥岩及上覆煤系地层、石千峰组及下三叠统紫红色泥岩及粉砂质泥岩是华北地区的有效盖层,与储集层匹配形成多套储盖组合。圈闭以断背斜、断鼻和断块为主,大部分圈闭形成于主要生烃期之前,是有效圈闭。通过成藏条件分析认为,华北地区的成藏主控因素是生排烃史和构造发育史的匹配以及成藏后的保存条件,因此将来应主要寻找那些二次生烃区的古构造或喜马拉雅期形成的新构造。   相似文献   

2.
鄂尔多斯盆地东北部上古生界发育多套含煤碎屑岩系,为上古生界气藏主要烃源岩。结合煤系气概念及其内涵,将上古生界天然气藏以下石盒子组区域分布的"桃花泥岩"为界划分为下部(C2b-P2x)煤系气藏以及上部(P2sh-P3q)非煤系气藏,并在沉降史模拟与构造热年代学分析的基础上,结合上古生界气藏压力分布特征,探讨了其成藏机制,认为上古生界天然气成藏可划分为4个阶段,其中煤系气成藏主要集中于145~115 Ma的加载增压原生成藏阶段以及115~65 Ma的压力调整再平衡成藏阶段;早白垩世末期以来南北生烃能力差异、煤系气横向运移的生气增压能量亏损、煤系气作为非煤系气源以及后期天然气逸散共同造成了煤系气藏纵向和横向上的压力分异;上古生界煤系气勘查应主要集中于研究区南部的米脂地区。  相似文献   

3.
鄂尔多斯盆地北部上古生界天然气的地球化学研究   总被引:17,自引:0,他引:17  
鄂尔多斯盆地北部上古生界天然气的地球化学参数显示出煤成气的特征为高-较高的甲烷化系数、低-较低的C2 组分含量、低凝析油含量、烃类组分均相对富同位素 13C、轻烃(C5~C7)中高环烷烃含量等,其源岩无疑是石炭-二叠系(C2b-P1s)海陆交互相腐殖型母质为主的煤系气源岩.天然气地球化学参数中的甲烷化系数在平面上和纵向上的变化趋势与气层组的热演化程度存在着良好的相关性,反映出上古生界低渗透储层天然气的"广覆式生(供)气、持续运聚成藏"特征,天然气的主要成藏时期与气源岩的大量生、排烃时期(J2-K1)相匹配.局部地区的石千峰组发育晚期(K1抬升后)形成的天然气藏.气源岩母质的非均质性、成熟度的差异、运移与成藏特征等多因素叠加作用是引起天然气地球化学参数的变化在总体上的规律性与局部的复杂性共存的主要原因.  相似文献   

4.
试论合肥盆地燕山运动古城幕及其石油地质意义   总被引:2,自引:0,他引:2  
合肥盆地是中国东部目前勘探面积最大、勘探程度最低的复合型残留盆地.本文简要地介绍了合肥盆地的构造演化历史,并利用野外露头资料、沉积学资料和地震资料进行综合研究,论证了晚白垩世内幕存在一次大规模的由南向北的挤压推覆运动,并建议将该期构造运动命名为燕山运动古城幕;通过对下侏罗统防虎山组和下白垩统朱巷组烃源岩主要生烃过程的分析,认为下侏罗统防虎山组烃源岩在晚侏罗-早白垩世时开始生烃,下白垩统朱巷组烃源岩主要在燕山运动古城幕之前开始生烃.燕山运动古城幕对下侏罗统防虎山组烃源岩形成的油气有利也有弊,有利的一面是利于所生成油气的排烃,不利的一面是早期聚集形成的油气藏可能遭到改造和破坏;对下白垩统朱巷组烃源岩形成的油气,主要排烃期与圈闭形成期相匹配,有利于油气的排烃和聚集成藏,据此指出了合肥盆地大桥向斜的勘探思路,即应以寻找古背斜及其上形成的披覆构造以及浅层的盖层条件较好的构造圈闭,这种类型的圈闭受构造运动改造较弱,保存条件较好,是寻找原生油气藏的主要勘探目标区.  相似文献   

5.
鄂尔多斯盆地北部上古生界天然气的地球化学参数显示出煤成气的特征为高一较高的甲烷化系数、低一较低的C2 组分含量、低凝析油含量、烃类组分均相对富同位素^13C、轻烃(C6~C7)中高环烷烃含量等,其源岩无疑是石炭-二叠系(C2b-P1s)海陆交互相腐殖型母质为主的煤系气源岩。天然气地球化学参数中的甲烷化系数在平面上和纵向上的变化趋势与气层组的热演化程度存在着良好的相关性,反映出上古生界低渗透储层天然气的“广覆式生(供)气、持续运聚成藏”特征,天然气的主要成藏时期与气源岩的大量生、排烃时期(J2-K1)相匹配。局部地区的石千峰组发育晚期(K1抬升后)形成的天然气藏。气源岩母质的非均质性、成熟度的差异、运移与成藏特征等多因素叠加作用是引起天然气地球化学参数的变化在总体上的规律性与局部的复杂性共存的主要原因。  相似文献   

6.
煤系烃源层的构造—热演化过程研究对揭示煤系气的生成机制具有重要意义.为揭示鄂尔多斯盆地东南缘黄陵矿区向斜核部中生代煤系烃源层的构造—热演化过程、生排烃阶段及煤系气成因类型,根据含煤地层岩性、剩余地层现今埋深、储层孔隙度、镜质组最大反射率、甲烷碳氢同位素组成和生物甲烷产率等数据,运用Petromod 1D模拟软件与回剥反演法及EASY%Ro法对研究区煤系烃源岩的受热和生烃演化过程进行重建.研究结果表明:黄陵矿区自晚三叠世以来,煤系主要经历了3~4次"沉降—抬升"过程,其生烃演化过程可分为原生生物成因气、热成因气和次生生物成因气3个阶段.晚三叠世末期至中侏罗世早期,煤系烃源岩镜质组最大反射率演化至0.3%,对应原生生物成因气生成阶段;中侏罗世早期至早白垩世末期,煤系埋深及受热温度逐渐升高至最大值,镜质组最大反射率演化至0.67%~0.74%,热解生烃作用停止,对应热成因气生成阶段;自始新世早期至今,煤系发生抬升且埋深浅于2077~2148 m,受热温度低于75℃,对应次生生物成因气生成阶段.侏罗系延安组3号和2号煤层中甲烷碳、氢同位素组成数据和微生物降解煤岩生成生物气实验(甲烷累计产率为10.5~16.1μmol/g)为该区存在次生生物成因气提供了直接证据.  相似文献   

7.
琼东南盆地中央峡谷天然气成藏特征及其主控因素   总被引:1,自引:0,他引:1  
基于地震、测井、岩芯、岩屑和天然气样品分析化验等资料,研究了中央峡谷天然气成藏特征,探讨了成藏主控因素与成藏模式。研究结果表明,晚中新世—早上新世沿琼东南盆地中央坳陷发育一条大型海底峡谷,称之为中央峡谷,峡谷内充填了多期相互叠置的浊积砂岩,平均孔隙度为15%~33%,渗透率为11×10-3~971.3×10-3μm2,为较好的储层;发育了岩性和构造-岩性复合两大类圈闭。峡谷的气源来自于崖城组的煤系地层,属于煤型气。烃源岩的有机质类型为Ⅱ2和Ⅲ型,以Ⅲ型为主;热演化程度处于成熟—高成熟阶段,晚中新世—上新世达到生烃高峰。琼东南盆地中央坳陷是一个高温高压的坳陷,实测地温梯度平均值高达4.2~4.6℃/100m,实测压力系数为1.20~2.15。在高温高压的环境下,盆地内孕育众多的底辟构造,而峡谷下伏的底辟构造与谷内相互叠置的复合砂体在空间上有效的配置构成了天然气垂向与侧向运移的输导体系,成为峡谷天然气成藏的关键因素。  相似文献   

8.
南海北部边缘盆地天然气成因类型及气源构成特点   总被引:12,自引:3,他引:9  
南海北部边缘盆地油气地质现象丰富多彩,天然气成因类型及分布规律复杂。根据该区天然气勘探及研究程度,迄今为止勘探所发现烃类天然气可划分为生物气及生物-低熟过渡带气(亚生物气)、成熟-高熟油型气及煤型气以及高熟-过熟天然气等3大成因类型;非烃天然气CO2可划分为壳源型(有机/无机)、壳幔混合型及幔源型等3型4类。生物气及亚生物气在莺—琼盆地及珠江口盆地浅层广泛分布,气源来自上新统及第四系海相沉积;成熟油型气主要分布于北部湾、琼东南东北部及珠江口盆地,气源来自始新统中深湖相偏腐泥型烃源岩;成熟-高熟煤型气及高熟-过熟天然气,则主要展布于莺—琼盆地及珠江口盆地部分地区,前者气源主要由渐新统煤系和中新统海相偏腐殖型烃源岩所供给,后者气源则来自不同类型高熟-过熟烃源岩。CO2则主要富集于莺歌海盆地泥底辟带浅层及琼东南盆地东部和珠江口盆地部分区域,气源分别来自受泥底辟热流体活动影响强烈的中新统海相含钙砂泥岩和深部地幔活动。  相似文献   

9.
鄂尔多斯盆地北部杭锦旗探区泊尔江海子—三眼井断裂带南北两侧石炭—二叠系的烃源岩、储集层、源储关系、气水分布、油气运移及产能等成藏条件与特征都具有明显的区别。通过分析断裂带南、北天然气甲烷含量和密度特征的差异,认为断裂带以北天然气部分来自于南部。划分了3种不整合面运移通道类型,并通过分析断层特征,明确了南部生成的天然气可以通过不整合面和断层运移至断裂带以北。结合生储盖组合、运移输导等特征,确定了断裂带以南的伊陕斜坡区煤系气源岩与河流相致密砂岩储层的成藏组合特点为源储紧邻、广覆式分布,断裂带以北的继承性隆起区,虽本地气源条件较差,但与断裂带以南的源岩区构成侧接式组合。探区位于鄂尔多斯盆地北部石炭—二叠系准连续—非连续成藏过渡带上,依此建立了“源储紧邻、物性控藏”和“双源供气、圈闭控藏”南北两种不同的天然气成藏模式。  相似文献   

10.
准噶尔盆地南缘天然气成藏及勘探方向   总被引:4,自引:0,他引:4  
准噶尔盆地南缘地区与塔里木库车坳陷有着相似的沉积地层和构造演化历史,但是天然气勘探始终未取得重大突破。本文在南缘地区天然气成因类型与气源判识的基础上,分析该地区天然气成藏条件,探讨有利勘探方向与目标层系。结果表明,南缘地区天然气存在煤型气、混合气与油型气三类,且以煤型气和混合气为主;侏罗纪煤系为该地区主要的天然气源岩,其大量生气期与背斜构造形成期相匹配,构成最佳源灶-圈闭成藏组合;二叠系湖相和上三叠统湖相-湖沼相烃源岩也是重要的天然气源岩,其主要生气期在中部地区早于绝大多数背斜构造形成期,而在西部地区与背斜构造形成期相匹配。南缘地区生烃物质基础好于库车坳陷,只是主要气源岩侏罗纪煤系的成熟度略低于库车坳陷,盖层封盖性和储层发育规模略逊于库车坳陷,但仍具备形成大规模油气田的成藏条件。深层二叠系-侏罗系-白垩系成藏组合是最为有利的天然气勘探目标层系,西部是寻找和发现侏罗纪煤系和二叠系湖相油气藏的有利目标区域,中部是寻找和发现侏罗纪煤系天然气藏的有利目标区域。中浅层白垩系-新近系成藏组合是次要的天然气勘探目标层系,具有寻找和发现一定规模天然气藏的潜力。高探1井获得重大突破充分表明制约南缘天然气勘探大发现的因素不是气源规模、运移通道、储层物性和盖层封闭性,而是有效圈闭的落实、钻井工程技术及勘探工作量的投入。  相似文献   

11.
The dissolution of H2O and CO2 in structurally dense, nominally anhydrous and non-carbonate oxide matrices such as MgO and CaO is reviewed. H2O and CO2 are treated as gaseous oxide components which enter into solid solution with the refractory oxide hosts. They form anion complexes associated with cation vacancy sites. Evidence is presented that OH? pairs which derive from the dissolution of H2O are subject to a charge transfer (CT) conversion into peroxy moieties and molecular hydrogen, O 2 2? ... H2. Because the O 2 2? moiety is small (O?-O? distance ≈ 1.5 Å) high pressure probably favors the CT conversion. Mass spectroscopic studies show that molecular H2 may be lost from the solid which retains excess oxygen in the form of O 2 2? , leading to the release of atomic O. The dissociation of O 2 2? moieties into a vacancy-bound O? state and an unbound O? state can be followed by measuring the internal redox reactions involving transition metal impurities, the transient paramagnetism of the O? and their effect on the d.c. conductivity. Evidence is presented that CO2 molecules dissolve dissociatively in the structurally dense oxide matrix, as if they were first to dissociate into CO+O and then to form separate solute moieties CO 2 2? and O 2 2? , both associated with cation vacancy sites. In the CO 2 2? moiety (C-O? distance 1.2–1.3 Å, OCO angle ≈ 130°) the C atom probably sits off center. The transition of the C atom into interstitial sites is accompanied by dissociation of the CO 2 2? moiety into CO? and O?. This transition can be followed by infrared spectroscopy, using OH? as local probes. Further support derives from magnetic susceptibility, thermal expansion, low frequency dielectric loss and low temperature deformation measurements. The recently observed emission of O and Mg atoms besides a variety of molecules such as CO, CO2, CH4, HCN and other hydrocarbons during impact fracture of MgO single crystals is presented and discussed in the light of the other experimental data.  相似文献   

12.
There are few inter-African country urban analyses because of the continent’s enormous size and socioeconomic diversity, language barriers, and wide variations in national and regional urban research capacity. Nevertheless, comparative urban studies are critical in understanding contemporary African urbanization. In this comparative spatial and temporal analysis of Ghana and Kenya’s urbanization, we find that both countries are urbanizing rapidly and are faced with many common urban problems. Moreover, Ghana is more urbanized than Kenya and has a larger indigenous urban imprint and a more widely dispersed urban pattern. Besides their physiographic and population conditions, we trace these countries’ convergent and divergent urban trends to their shared but unique experiences of colonialism, nationalism and globalization.  相似文献   

13.
煤中气孔和镶嵌结构及其在煤变质研究中的意义   总被引:1,自引:0,他引:1  
河南省禹县、新密和荥巩煤田山西组Ⅱ1煤的贫煤和无烟煤中,气孔发育。气孔形态有椭圆状(图版1)、圆状及不规则状(图版2),有的几个气孔连在一起呈大的朵状气孔(图版3)。此外,在荥巩煤田西部无烟煤中还发育有镀嵌结构(图版4)。   相似文献   

14.
利用GC-MS(气相色谱—质谱仪),对采自湖北清江流域和尚洞洞顶的土壤样品与洞内石笋样品进行分析,发现土壤中存在的七个系列单甲基支链烷烃在所有的石笋样品中均可以找到,呈现相似的分布模式,石笋中七个系列支链烷烃有可能来自洞穴滴水携带的土壤中的支链烷烃,但是也不能排除石笋原地生长的微生物的贡献。烷基环己烷的分布在土壤与石笋中呈现了相似的分布模式,但是主峰碳数有所变化,高碳数部分与低碳数部分的相对含量也发生了变化。主要原因可能是微生物选择性降解的结果,也有可能是土壤与石笋中微生物种类分布差异所造成的。本次研究初步显示了相对封闭稳定的洞穴沉积物与上覆土壤层中生物标志化合物的异同。   相似文献   

15.
At 31 sites in Finland the Zn content was determined of the epiphytic lichen Hypogymnia physodes (L.) Nyl. growing on pine and birch, the terricolous lichen Cladina spp. in pine bark, and the inner part of birch bark. The anomalous contents of Zn in H. physodes on pine and Cladina spp. in soil appeared to be strongly related to sulphide ore deposits. Anthropogenic Zn correlated closely with S and Fe in H. physodes on pine and with Fe in Cladina spp. The binding of geogenic Zn was related to iron hydroxides, and was attributed to the different uptake mechanism of S in these lichens. Elevated values of Zn in H. physodes on birch were due to both geogenic and anthropogenic sources. Zinc in pine bark increased with the Zn content in H. physodes and reached a limiting value.  相似文献   

16.
Using improved analytical techniques, which reduce the Re blanks by factors of 8 to 10, we report new Re-Os data on low Re and low PGE pallasites (PAL-anom) and IIIAB irons. The new pallasite samples nearly double the observed range in Re/Os for pallasites and allow the determination of an isochron of slope 0.0775 ± 0.0008 (T = 4.50 ± 0.04 Ga, using the adjusted λ187Re = 1.66 × 10−11 a−1) and initial (187Os/188Os)0 = 0.09599 ± 0.00046. If the data on different groups of pallasites (including the “anomalous” pallasites) are considered to define a whole-rock isochron, their formation would appear to be distinctly younger than for the iron meteorites by ∼60 Ma. Five IIIAB irons (Acuna, Bella Roca, Chupaderos, Grant, and Bear Creek), with Re contents ranging from 0.9 to 2.8 ppb, show limited Re/Os fractionation and plot within errors on the IIAB iron meteorite isochron of slope 0.07848 ± 0.00018 (T = 4.56 ± 0.01 Ga) and initial (187Os/188Os)0 = 0.09563 ± 0.00011. Many of the meteorites were analyzed also for Pd-Ag and show 107Ag enrichments correlated with Pd/Ag, requiring early formation and fractionation of the FeNi metal, in a narrow time interval, after injection of live 107Pd (t1/2 = 6.5 Ma) into the solar nebula. Based on Pd-Ag, the typical range in relative ages of these meteorites is ≤10 Ma. The Pd-Ag results suggest early formation and preservation of the 107Pd-107Ag systematics, both for IIIAB irons and for pallasites, while the younger Re-Os apparent age for pallasites suggests that the Re-Os system in pallasites was subject to re-equilibration. The low Re and low PGE pallasites show significant Re/Os fractionation (higher Re/Os) as the Re and PGE contents decrease. By contrast, the IIIAB irons show a restricted range in Re/Os, even for samples with extremely low Re and PGE contents. There is a good correlation of Re and Ir contents. The correlation of Re and Os contents for IIIAB irons shows a similar complex pattern as observed for IIAB irons (Morgan et al., 1995), and neither can be ascribed to a continuous fractional crystallization process with uniform solid-metal/liquid-metal distribution coefficients.  相似文献   

17.
The evolution of the border region of part or all of a craton, on the basis of geological data gathered from Mexico, may best be described in terms of geotectonic cycles. These consist, in chronological order, of (1) an orthogeosynclinal phase (eu- and miogeosynclines) with or without initial magmatic activity, (2) an anatexitic phase consisting of batholith emplacement with attendant regional metamorphism in the eugeosyncline and deposition of a clastic or flysch wedge over the miogeosyncline, (3) an orogenic phase consisting principally of the folding and thrusting of the sediments of the miogeosyncline together with the clastic or flysch wedge against the foreland, and (4) a taphrogenic or block-faulting phase accompanied by (a) accumulation of post-orogenic debris or molasse, (b) subsequent magmatic activity consisting largely of igneous extrusions with fewer intrusions, and (c) final magmatic activity consisting of igneous extrusions. A region that has gone through the above phases of a geotectonic cycle may be termed a structural belt. In the post-Precambrian geologic history of Mexico, three geotectonic cycles are recognized: one occurred along the Pacific border of Mexico between Cambrian and middle Jurassic (?) time (Jaliscoan geotectonic cycle), the second occurred along the present Gulf of Mexico border of the country at the same time (Huastecan geotectonic cycle), and the third occurred over the entire country from the United States border to the Guatemalan border between Late Jurassic and Pliocene time (Mexican geotectonic cycle). The early Mesozoic clastic rocks in northwestern Mexico may signify a fourth geotectonic cycle in that region. In the three recognized geotectonic cycles, however, the geologic record shows only two orogenic phases, one of which occurred in late Paleozoic time in an arcuate belt along the eastern side of Mexico (Coahuilan orogeny), and the other in early Tertiary time in a belt traversing central Mexico from the United States border to the Guatemalan border (Hidalgoan orogeny).  相似文献   

18.
Aqueous extraction contributes to the formation and weathering of planetary materials and renders electrolytes such as phosphate available for biology. In this context, the solubility of phosphate is measured in planetary materials, represented by the Mars meteorites Nakhla, Dar al Gani 476 (DaG 476), Elephant Morraine 79001 (EETA 79001), and terrestrial analogs, and in the Murchison CM2 and Allende CV3 carbonaceous chondrites. The Mars meteorites contain high levels of phosphate that is readily extracted by water, up to 15 mg kg−1 in Nakhla and DaG 476 and 38 mg kg−1 in EETA 79001, while the terrestrial analogs and the carbonaceous chondrites contain 0.5 to 6 mg kg−1. Correspondingly, high phosphate concentrations of 4 to >28 mg L−1 are obtained in extracts of the Mars meteorites at high solid/solution ratios, exceeding the concentrations of 0.4 to 2.0 mg L−1 in the extracts of the terrestrial analogs. A wide range of planetary conditions, including N2 and CO2 atmospheres, solid/solution ratios of 0.01 to 1.0 kg L−1, extraction times of 1 to 21 d, and temperatures of 20 to 121°C affect the amounts of extractable phosphate by factors of only 2 to 5 in most materials. Phosphate-fixing capacity and exchangeable phosphate are assessed by the isotopic exchange kinetics (IEK) method, which quantifies the amount of P isotopically exchangeable within 1 min (E1min) and between 1 min and 3 months (E1min-3m) and the amount of P that cannot be exchanged within 3 months (E>3m). The IEK results show that the DaG 476 Mars meteorite and terrestrial analogs have low P-fixing capacities, while the carbonaceous chondrites have high P-fixing capacities. Aqueous processing under early planetary CO2 atmospheres has large effects on the available phosphate. For example, the fraction of total P that is exchangeable in 3 months increases from 1.6 to 11%, 13 to 51.6%, and 43.9 to 90.4% in the DaG 476 Mars meteorite, Allende, and Murchison, respectively. The results show that solutions with high phosphate concentrations can form in the pores of planetary lava ash and basalts and in carbonaceous asteroids and meteorites. These solutions can help prebiotic synthesis and early microbial nutrition. The Martian and carbonaceous chondrite materials contain sufficient phosphate for space-based agriculture.  相似文献   

19.
Stabilities of amphibole and chlorite in mafic and ultramafic compositions have been considered in the model system CaO+MgO+Al2O3+SiO2+H2O. From topological arguments two petrogenetic grids have been constructed. Although available experimental data in CMASH are compatible with the grid in which amphibole reacts out before chlorite in model ultramafic compositions for the pressure range 6 to 15 kbar, naturally observed mineral assemblages and some experimental data in more complex systems favour the other grid in which chlorite reacts out before amphibole at all pressures. This discrepancy between natural and model systems is due to differential movement of the dehydration equilibria of the two hydrates reflecting the variation of activity of H2O or of components other than CMASH.  相似文献   

20.
银川平原地下水资源开发与植被变化   总被引:4,自引:0,他引:4  
植被状况的变化是反映区域性生态环境状况的重要指标。地下水是影响植被变化的主要因素。宁夏地处干旱半干旱地带,是全国生态系统最脆弱的省区之一。2000年后,随着宁夏黄河引水量的减小,水资源的不合理应用使银川平原的生态植被出现了退化的趋势。本文利用MODIS-NDVI遥感数据,对银川平原2000~2004年间的植被变化趋势进行了研究。在此基础上,对引用黄河水量及多年地下水位的变化对植被的影响进行了分析,并对适宜于植被发育的地下水位埋深进行了探讨。  相似文献   

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