Role of bedrock groundwater in the rainfall–runoff process in a small headwater catchment underlain by volcanic rock

The role of bedrock groundwater in rainfall–runoff processes is poorly understood. Hydrometric, tracer and subsurface water potential observations were conducted to study the role of bedrock groundwater and subsurface flow in the rainfall–runoff process in a small headwater catchment in Shiranui, Kumamoto prefecture, south‐west Japan. The catchment bedrock consists of a strongly weathered, fractured andesite layer and a relatively fresh continuous layer. Major chemical constituents and stable isotopic ratios of δ¹⁸O and δD were analysed for spring water, rainwater, soil water and bedrock groundwater. Temporal and spatial variation in SiO₂ showed that stream flow under the base flow condition was maintained by bedrock groundwater. Time series of three components of the rainstorm hydrograph (rainwater, soil water and bedrock groundwater) separated by end member mixing analysis showed that each component fluctuated during rainstorm, and their patterns and magnitudes differed between events. During a typical mid‐magnitude storm event, a delayed secondary runoff peak with 1·0 l s⁻¹ was caused by increase in the bedrock groundwater component, whereas during a large rainstorm event the bedrock groundwater component increased to ≈ 2·5 l s⁻¹. This research shows that the contribution of bedrock groundwater and soil water depends strongly on the location of the groundwater table, i.e. whether or not it rises above the soil–bedrock interface. Copyright © 2010 John Wiley & Sons, Ltd.     

The application of electrical conductivity as a tracer for hydrograph separation in urban catchments

Two‐component hydrograph separation was performed on 19 low‐to‐moderate intensity rainfall events in a 4·1‐km² urban watershed to infer the relative and absolute contribution of surface runoff (e.g. new water) to stormflow generation between 2001 and 2003. The electrical conductivity (EC) of water was used as a continuous and inexpensive tracer, with order of magnitude differences in precipitation (12–46 µS/cm) and pre‐event streamwater EC values (520–1297 µS/cm). While new water accounted for most of the increased discharge during storms (61–117%), the contribution of new water to total discharge during events was typically lower (18–78%) and negatively correlated with antecedent stream discharge (r² = 0·55, p < 0·01). The amount of new water was positively correlated with total rainfall (r² = 0·77), but hydrograph separation results suggest that less than half (9–46%) of the total rainfall on impervious surfaces is rapidly routed to the stream channel as new water. Comparison of hydrograph separation results using non‐conservative tracers (EC and Si) and a conservative isotopic tracer (δD) for two events showed similar results and highlighted the potential application of EC as an inexpensive, high frequency tracer for hydrograph separation studies in urban catchments. The use of a simple tracer‐based approach may help hydrologists and watershed managers to better understand impervious surface runoff, stormflow generation and non‐point‐source pollutant loading to urban streams. Copyright © 2007 John Wiley & Sons, Ltd.     

Determination of runoff components using path analysis and isotopic measurements in a glacier‐covered alpine catchment (upper Hailuogou Valley) in southwest China

Monitoring of stable water isotopes (δ¹⁸O and δ²H) at the watershed scales can improve our understanding of complex hydrology and hydroclimatology of the watershed, especially in remote regions. Previous studies that used tracers for hydrograph separation are largely based on end‐member mixing approach (EMMA), but one drawback of this approach is that at least two independent tracers are required for multi‐component separation. Here we introduce a new approach—path analysis, in combination with isotopic measurements to investigate the runoff generation in a glacier‐covered alpine catchment (upper Hailuogou Valley) in southwest China. This newly developed method can not only provide a multi‐component hydrograph separation with the aid of only one tracer but also determine the direct and indirect influence of sources on streamflow. Path analysis show that the majority of streamflow is dominated by ice/snow meltwater that represents about 63–78% of the total discharge, whereas precipitation and groundwater contribute approximately 19–39% and 2–4% of the streamflow discharge, respectively. These results are in good agreement with those derived from EMMA (using ¹⁸O and Cl^? as tracers), corroborating that our proposed approach is successful in hydrograph separation of the catchment. This approach may provide new opportunities for the hydrograph separation of catchment with sparse data and be of interest to catchment hydrologists who seek to understand the behaviour of hydrologic systems. Copyright © 2015 John Wiley & Sons, Ltd.     

Spatially distributed tracer‐aided modelling to explore water and isotope transport,storage and mixing in a pristine,humid tropical catchment

Rapidly transforming headwater catchments in the humid tropics provide important resources for drinking water, irrigation, hydropower, and ecosystem connectivity. However, such resources for downstream use remain unstudied. To improve understanding of the behaviour and influence of pristine rainforests on water and tracer fluxes, we adapted the relatively parsimonious, spatially distributed tracer‐aided rainfall–runoff (STARR) model using event‐based stable isotope data for the 3.2‐km² San Lorencito catchment in Costa Rica. STARR was used to simulate rainforest interception of water and stable isotopes, which showed a significant isotopic enrichment in throughfall compared with gross rainfall. Acceptable concurrent simulations of discharge (Kling–Gupta efficiency [KGE] ~0.8) and stable isotopes in stream water (KGE ~0.6) at high spatial (10 m) and temporal (hourly) resolution indicated a rapidly responding system. Around 90% of average annual streamflow (2,099 mm) was composed of quick, near‐surface runoff components, whereas only ~10% originated from groundwater in deeper layers. Simulated actual evapotranspiration (ET) from interception and soil storage were low (~420 mm/year) due to high relative humidity (average 96%) and cloud cover limiting radiation inputs. Modelling suggested a highly variable groundwater storage (~10 to 500 mm) in this steep, fractured volcanic catchment that sustains dry season baseflows. This groundwater is concentrated in riparian areas as an alluvial–colluvial aquifer connected to the stream. This was supported by rainfall–runoff isotope simulations, showing a “flashy” stream response to rainfall with only a moderate damping effect and a constant isotope signature from deeper groundwater (~400‐mm additional mixing volume) during baseflow. The work serves as a first attempt to apply a spatially distributed tracer‐aided model to a tropical rainforest environment exploring the hydrological functioning of a steep, fractured‐volcanic catchment. We also highlight limitations and propose a roadmap for future data collection and spatially distributed tracer‐aided model development in tropical headwater catchments.     

Effect of bedrock flow on catchment rainfall‐runoff characteristics and the water balance in forested catchments in Tanzawa Mountains,Japan

In this paper, we examined the role of bedrock groundwater discharge and recharge on the water balance and runoff characteristics in forested headwater catchments. Using rigorous observations of catchment precipitation, discharge and streamwater chemistry, we quantified net bedrock flow rates and contributions to streamwater runoff and the water balance in three forested catchments (second‐order to third‐order catchments) underlain by uniform bedrock in Japan. We found that annual rainfall in 2010 was 3130 mm. In the same period, annual discharge in the three catchments varied from 1800 to 3900 mm/year. Annual net bedrock flow rates estimated by the chloride mass balance method at each catchment ranged from ?1600 to 700 mm/year. The net bedrock flow rates were substantially different in the second‐order and third‐order catchments. During baseflow, discharge from the three catchments was significantly different; conversely, peak flows during large storm events and direct runoff ratios were not significantly different. These results suggest that differences in baseflow discharge rates, which are affected by bedrock flow and intercatchment groundwater transfer, result in the differences in water balance among the catchments. This study also suggests that in these second‐order to third‐order catchments, the drainage area during baseflow varies because of differences between the bedrock drainage area and surface drainage area, but that the effective drainage area during storm flow approaches the surface drainage area. Copyright © 2012 John Wiley & Sons, Ltd.     

Response time and water origin in a steep nested catchment in the Italian Dolomites

In this study, we investigate the surface flow time of rise in response to rainfall and snowmelt events at different spatial scales and the main sources originating channel runoff and spring water in a steep nested headwater catchment (Rio Vauz, Italian Dolomites), characterized by a marked elevation gradient. We monitored precipitation at different elevations and measured water stage/streamflow at the outlet of two rocky subcatchments of the same size, representative of the upper part of the catchment dominated by outcropping bedrock, at the outlet of a soil‐mantled and vegetated subcatchment of similar size but different morphology, and at the outlet of the main catchment. Hydrometric data are coupled with stable isotopes and electrical conductivity sampled from different water sources during five years, and used as tracers in end‐member mixing analysis, application of two component mixing models and analysis of the slope of the dual‐isotope regression line. Results reveal that times of rise are slightly shorter for the two rocky subcatchments, particularly for snowmelt and mixed rainfall/snowmelt events, compared to the soil‐mantled catchment and the entire Rio Vauz Catchment. The highly‐variable tracer signature of the different water sources reflects the geomorphological and geological complexity of the study area. The principal end‐members for channel runoff and spring water are identified in rainfall and snowmelt, which are the dominant water sources in the rocky upper part of the study catchment, and soil water and shallow groundwater, which play a relevant role in originating baseflow and spring water in the soil‐mantled and vegetated lower part of the catchment. Particularly, snowmelt contributes up to 64 ± 8% to spring water in the concave upper parts of the catchment and up to 62 ± 11% to channel runoff in the lower part of the catchment. These results offer new experimental evidences on how Dolomitic catchments capture and store rain water and meltwater, releasing it through a complex network of surface and subsurface flow pathways, and allow for the construction of a preliminary conceptual model on water transmission in snowmelt‐dominated catchments featuring marked elevation gradients.     

Hydrological processes in the different landscape zones of alpine cold regions in the wet season,combining isotopic and hydrochemical tracers

Studies on hydrological processes are often emphasized in resource and environmental studies. This paper identifies the hydrological processes in different landscape zones during the wet season based on the isotopic and hydrochemical analysis of glacier, snow, frozen soil, groundwater and other water sources in the headwater catchment of alpine cold regions. Hydrochemical tracers indicated that the chemical compositions of the water are typically characterized by: (1) Ca? HCO₃ type in glacier snow zone, (2) Mg? Ca? SO₄ type for surface runoff and Ca? Mg? HCO₃ type for groundwater in alpine desert zone, (3) Ca? Mg? SO₄ type for surface water and Ca? Mg? HCO₃ type for groundwater in alpine shrub zone, and (4) Ca? Na? SO₄ type in surface runoff in the alpine grassland zone. The End‐Members Mixing Analysis (EMMA) was employed for hydrograph separation. The results showed that the Mafengou River in the wet season was mainly recharged by groundwater in alpine cold desert zones and shrub zones (52%), which came from the infiltration and transformation of precipitation, thawed frozen soil water and glacier‐snow meltwater. Surface runoff in the glacier‐snow zone accounted for 11%, surface runoff in alpine cold desert zones and alpine shrub meadow zones accounted for 20%, thawed frozen soil water in alpine grassland zones accounted for 9% of recharge and precipitation directly into the river channel (8%). This study suggested that the whole catchment precipitation did not produce significant surface runoff directly, but mostly transformed into groundwater or interflow, and finally arrived in the river channel. Copyright © 2011 John Wiley & Sons, Ltd.     

Investigating mechanisms of stormflow generation by natural tracers and hydrometric data: a small catchment study in the Black Forest,Germany

The importance and interaction of various hydrological pathways and identification of runoff source areas involved in solute transport are still under considerable debate in catchment hydrology. To reveal stormflow generating areas and flow paths, hydrometric behaviour of throughfall, soil water from various depths, runoff, and respective concentrations of the environmental tracers ¹⁸O, Si, K, SO₄ and dissolved organic carbon were monitored for a 14‐week period in a steep headwater catchment in the Black Forest Mountains, Germany. Two stormflow hydrographs were selected and, based on ¹⁸O and Si, chemically separated into three flow components. Their sources were defined using mixing diagrams. Additional information about stormflow generating mechanisms was derived from recession analyses of the basin's complete 5‐year hydrograph record. By providing insight into storage properties and residence times of outflowing reservoirs of the basin, recession analysis proved to be a valuable tool in runoff model conceptualization. Its results agreed well with hydrometric and hydrochemical data. Supported by evaluation of 30 hillslope soil profiles a coherent concept of stormflow generation could be derived: whereas in many steeply sloped basins in the temperate region soil water from hillslopes appears to have an immediate effect on the shape of the stormflow hydrograph, its role at this basin is basically restricted to the recharge of the groundwater reservoir in the near‐channel area. Storm hydrograph peaks appear to be derived from a small direct runoff component supplemented by a fast delivery of baseflow from the groundwater reservoir in the valley bottom. Copyright © 2001 John Wiley & Sons, Ltd.     

Contributions of bedrock groundwater to the upscaling of storm‐runoff generation processes in weathered granitic headwater catchments

We examined the contributions of bedrock groundwater to the upscaling of storm‐runoff generation processes in weathered granitic headwater catchments by conducting detailed hydrochemical observations in five catchments that ranged from zero to second order. End‐member mixing analysis (EMMA) was performed to identify the geographical sources of stream water. Throughfall, hillslope groundwater, shallow bedrock groundwater, and deep bedrock groundwater were identified as end members. The contribution of each end member to storm runoff differed among the catchments because of the differing quantities of riparian groundwater, which was recharged by the bedrock groundwater prior to rainfall events. Among the five catchments, the contribution of throughfall was highest during both baseflow and storm flow in a zero‐order catchment with little contribution from the bedrock groundwater to the riparian reservoir. In zero‐order catchments with some contribution from bedrock groundwater, stream water was dominated by shallow bedrock groundwater during baseflow, but it was significantly influenced by hillslope groundwater during storms. In the first‐order catchment, stream water was dominated by shallow bedrock groundwater during storms as well as baseflow periods. In the second‐order catchment, deeper bedrock groundwater than that found in the zero‐order and first‐order catchments contributed to stream water in all periods, except during large storm events. These results suggest that bedrock groundwater influences the upscaling of storm‐runoff generation processes by affecting the linkages of geomorphic units such as hillslopes, riparian zones, and stream channels. Our results highlight the need for a three‐dimensional approach that considers bedrock groundwater flow when studying the upscaling of storm‐runoff generation processes. Copyright © 2014 John Wiley & Sons, Ltd.     

Quantifying aggregation and change in runoff source in accordance with catchment area increase in a forested headwater catchment

There has been a great deal of research interest regarding changes in flow path/runoff source with increases in catchment area. However, there have been very few quantitative studies taking subscale variability and convergence of flow path/runoff source into account, especially in relation to headwater catchments. This study was performed to elucidate how the contributions and discharge rates of subsurface water (water in the soil layer) and groundwater (water in fractured bedrock) aggregate and change with catchment area increase, and to elucidate whether the spatial variability of the discharge rate of groundwater determines the spatial variability of stream discharge or groundwater contribution. The study area was a 5‐km² forested headwater catchment in Japan. We measured stream discharge at 113 points and water chemistry at 159 points under base flow conditions. End‐member mixing analysis was used to separate stream water into subsurface water and groundwater. The contributions of both subsurface water and groundwater had large variability below 1 km². The contribution of subsurface water decreased markedly, while that of groundwater increased markedly, with increases in catchment area. The specific discharge of subsurface water showed a large degree of variability and decreased with catchment area below 0.1 km², becoming almost constant above 0.1 km². The specific discharge of groundwater showed large variability below 1 km² and increased with catchment area. These results indicated that the variabilities of stream discharge and groundwater contribution corresponded well with the variability of the discharge rate of groundwater. However, below 0.1 km², it was necessary to consider variations in the discharge rates of both subsurface water and groundwater. Copyright © 2016 John Wiley & Sons, Ltd.     

Controls of streamflow generation in small catchments across the snow–rain transition in the Southern Sierra Nevada,California

Processes controlling streamflow generation were determined using geochemical tracers for water years 2004–2007 at eight headwater catchments at the Kings River Experimental Watersheds in southern Sierra Nevada. Four catchments are snow‐dominated, and four receive a mix of rain and snow. Results of diagnostic tools of mixing models indicate that Ca²⁺, Mg²⁺, K⁺ and Cl^? behaved conservatively in the streamflow at all catchments, reflecting mixing of three endmembers. Using endmember mixing analysis, the endmembers were determined to be snowmelt runoff (including rain on snow), subsurface flow and fall storm runoff. In seven of the eight catchments, streamflow was dominated by subsurface flow, with an average relative contribution (% of streamflow discharge) greater than 60%. Snowmelt runoff contributed less than 40%, and fall storm runoff less than 7% on average. Streamflow peaked 2–4 weeks earlier at mixed rain–snow than snow‐dominated catchments, but relative endmember contributions were not significantly different between the two groups of catchments. Both soil water in the unsaturated zone and regional groundwater were not significant contributors to streamflow. The contributions of snowmelt runoff and subsurface flow, when expressed as discharge, were linearly correlated with streamflow discharge (R² of 0.85–0.99). These results suggest that subsurface flow is generated from the soil–bedrock interface through preferential pathways and is not very sensitive to snow–rain proportions. Thus, a declining of the snow–rain ratio under a warming climate should not systematically affect the processes controlling the streamflow generation at these catchments. Copyright © 2012 John Wiley & Sons, Ltd.     

Groundwater–surface water connectivity in a chain-of-ponds semiarid river

Semiarid rivers are often characterized by chains of small pools connected by riffles and wet meadows. The pools can be maintained by wet season surface runoff, groundwater discharge, or some combination thereof. Using synoptic surveys for several environmental tracers (δD and δ¹⁸O of H₂O, specific electrical conductance at 25°C [EC], chloride and ²²²Rn), we evaluated the groundwater—surface water connectivity of the Light River (South Australia) along an 8 km section in the vicinity of a proposed mining development. In all three surveys (representing spring, summer and winter conditions), the pools were maintained by regional groundwater discharge based on an elevated surface water EC (9–12 dS m⁻¹) similar to regional groundwater, elevated radon-222 activities (0.09–3.0 Bq L⁻¹) and low rainfall. Most pools were perennial, either because they directly received groundwater discharge or, indirectly, had an inflow originating from upstream groundwater-fed pools. The elevated salinity of regional groundwater is a key factor for the maintenance of perennial pools in the Light River because the potential for baseflow depletion by groundwater pumping is more limited.     

Groundwater–surface‐water interactions in a braided river: a tracer‐based assessment

Natural tracers (alkalinity and silica) were used to infer groundwater–surface‐water exchanges in the main braided reach of the River Feshie, Cairngorms, Scotland. Stream‐water samples were collected upstream and downstream of the braided section at fortnightly intervals throughout the 2001–2002 hydrological year and subsequently at finer resolution over two rainfall events. The braided reach was found to exert a significant downstream buffering effect on the alkalinity of these waters, particularly at moderate flows (4–8 m³ s^?1/?Q_30–70). Extensive hydrochemical surveys were undertaken to characterize the different source waters feeding the braids. Shallow groundwater flow systems at the edge of the braided floodplain, recharged by effluent streams and hillslope drainage, appeared to be of particular significance. Deeper groundwater was identified closer to the main channel, upwelling through the hyporheic zone. Both sources contributed to the significant groundwater–surface‐water interactions that promote the buffering effect observed through the braided reach. Their impact was less significant at higher flows (>15 m³ s^?1/>Q₁₀) when acidic storm runoff from the peat‐covered catchment headwaters dominated, as well as under baseflow conditions (<4 m³ s^?1/<Q₇₀), when upstream alkalinity was already buffered owing to headwater groundwater sources assuming dominance. The significant temporally and spatially dynamic influence of these groundwater–surface‐water interactions was therefore seen to have important implications for both catchment functioning and instream ecology. Copyright © 2004 John Wiley & Sons, Ltd.     

Testing a spatially distributed tracer‐aided runoff model in a snow‐influenced catchment: Effects of multicriteria calibration on streamwater ages

Integrating stable isotope tracers into rainfall‐runoff models allows investigation of water partitioning and direct estimation of travel times and water ages. Tracer data have valuable information content that can be used to constrain models and, in integration with hydrometric observations, test the conceptualization of catchment processes in model structure and parameterization. There is great potential in using tracer‐aided modelling in snow‐influenced catchments to improve understanding of these catchments' dynamics and sensitivity to environmental change. We used the spatially distributed tracer‐aided rainfall‐runoff (STARR) model to simulate the interactions between water storage, flux, and isotope dynamics in a snow‐influenced, long‐term monitored catchment in Ontario, Canada. Multiple realizations of the model were achieved using a combination of single and multiple objectives as calibration targets. Although good simulations of hydrometric targets such as discharge and snow water equivalent could be achieved by local calibration alone, adequate capture of the stream isotope dynamics was predicated on the inclusion of isotope data in the calibration. Parameter sensitivity was highest, and most local, for single calibration targets. With multiple calibration targets, key sensitive parameters were still identifiable in snow and runoff generation routines. Water ages derived from flux tracking subroutines in the model indicated a catchment where runoff is dominated by younger waters, particularly during spring snowmelt. However, resulting water ages were most sensitive to the partitioning of runoff sources from soil and groundwater sources, which was most realistically achieved when isotopes were included in the calibration. Given the paucity of studies where hydrological models explicitly incorporate tracers in snow‐influenced regions, this study using STARR is an important contribution to satisfactorily simulating snowpack dynamics and runoff generation processes, while simultaneously capturing stable isotope variability in snow‐influenced catchments.     

Sulfur Hexafluoride and Potassium Bromide as Groundwater Tracers for Managed Aquifer Recharge

Sulfur hexafluoride (SF₆) is an established tracer for use in managed aquifer recharge projects. SF₆ exsolves from groundwater when it encounters trapped air according to Henry's law. This results in its retardation relative to groundwater flow, which can help determine porous media saturation and flow dynamics. SF₆ and the conservative, nonpartitioning tracer, bromide (Br⁻ added as KBr), were introduced to recharge water infiltrated into stacked glacial aquifers in Thurston County, Washington, providing the opportunity to observe SF₆ partitioning. Br⁻, which is assumed to travel at the same velocity as the groundwater, precedes SF₆ at most monitoring wells (MWs). Average groundwater velocity in the unconfined aquifer in the study area ranges from 3.9 to 40 m/d, except in the southwestern corner where it is slower. SF₆ in the shallow aquifer exhibits an average retardation factor of 2.5 ± 3.8, suggesting an air-to-water ratio on the order of 10⁻³ to 10⁻² in the pore space. Notable differences in tracer arrival times at adjacent wells indicate very heterogeneous conductivity. One MW exhibits double peaks in concentrations of both tracers with different degrees of retardation for the first and second peaks. This suggests multiple flowpaths to the well with variable saturation. The confining layer between the upper two aquifers appears to allow intermittent connection between aquifers but serves as an aquitard in most areas. This study demonstrates the utility of SF₆ partitioning for evaluating hydrologic conditions at prospective recharge sites.     

Spatial delineation of groundwater–surface water interactions through intensive in‐stream profiling

The dominance of ‘old’ pre‐event water in headwater storm runoff has been recorded in numerous upland catchment studies; however, the mechanisms by which this pre‐event water enters the stream channel are poorly understood. Understanding these processes is fundamental to determining the controls on surface water quality and associated impacts on stream ecology. Previous studies in the upland forested catchment of the Afon Hafren (River Severn) at Plynlimon, mid‐Wales, identified an active bedrock groundwater system that was discharging into the stream channel during storm response. Detailed analysis showed that these discharges were small and could not account for the majority of pre‐event storm water response identified at this site; pre‐event storm runoff had to be sourced predominantly from further upstream. An intensive stream survey was used to determine the spatial nature of groundwater–surface water (GW–SW) interactions in the Hafren Catchment. Detailed physico‐chemical in‐stream profiling identified a marked change in water quality indicating a significant discrete point of bedrock groundwater discharge upstream of the Hafren Transect study site. The in‐stream profiling showed the importance of high spatial resolution sampling as a key to understanding processes of GW–SW interaction and how quick and cost‐effective measurements of specific electrical conductance of stream waters could be used to highlight in‐stream heterogeneity. This approach is recommended for use in headwater catchments for initial characterisation of the stream channel in order to better locate instrumentation and to determine more effective targeted sampling protocols in upland catchment research. Copyright © 2012 John Wiley & Sons, Ltd.     

Characterizing the climatic water balance dynamics and different runoff components in a poorly gauged tropical forested catchment,Nicaragua

ABSTRACT

The water balance dynamics and runoff components of a tropical forested catchment (46?km²) on the southwestern Pacific coast of Nicaragua were studied combining hydrometry, geological characterization and hydrochemical and isotopic tracers (three-component hydrograph separation). The climatic water balance was estimated for 2010/11, 2011/12 and 2012/13 with net values of 811?mm year^-1, 782?mm year^-1 and –447?mm year^-1, respectively. Runoff components were studied at different spatial and temporal scales, demonstrating that different sources and temporal contributions are controlled by dominant landscape elements and antecedent rainfall. In forested sub-catchments, permeable soils, stratigraphy and steep slopes favour subsurface stormflow generation contributing 50% and 53% to total discharge. At catchment scale, landscape elements such as smooth slopes, wide valleys, deeper soils and water table allow groundwater recharge during rainfall events. Groundwater dominates the hydrograph (50% of total discharge) under dry prior conditions. However, low soil infiltration capacity generates a larger surface runoff component (42%) under wet prior conditions which dominates total discharge. Our results show that forested areas are important to reduce surface runoff and thus soil degradation, which is relevant for the design of water management plans.

Editor D. Koutsoyiannis Associate editor D. Gerten     

APPLICATION OF UNIT HYDROGRAPH TECHNIQUES TO SOLUTE TRANSPORT IN CATCHMENTS

Current models of solute movement in catchments are based on rainfall–runoff models and are consequently biased towards processes which determine the magnitude and timing of water flux. It is shown here that the instantaneous unit hydrograph (IUH), or runoff response function, obtained from a hydrograph is fundamentally different from the residence time distribution which governs the response to solutes/tracers. Using hydrometric and tracer data obtained from a small (25 ha) catchment in the humid tropics a modification of the IUH technique is demonstrated which also allows approximate modelling of the tracer data. New features of the modified conceptual model are identified with known hillslope processes.     

Spatio‐temporal tracer variability in the glacier melt end‐member — How does it affect hydrograph separation results?

Geochemical and isotopic tracers were often used in mixing models to estimate glacier melt contributions to streamflow, whereas the spatio‐temporal variability in the glacier melt tracer signature and its influence on tracer‐based hydrograph separation results received less attention. We present novel tracer data from a high‐elevation catchment (17 km², glacierized area: 34%) in the Oetztal Alps (Austria) and investigated the spatial, as well as the subdaily to monthly tracer variability of supraglacial meltwater and the temporal tracer variability of winter baseflow to infer groundwater dynamics. The streamflow tracer variability during winter baseflow conditions was small, and the glacier melt tracer variation was higher, especially at the end of the ablation period. We applied a three‐component mixing model with electrical conductivity and oxygen‐18. Hydrograph separation (groundwater, glacier melt, and rain) was performed for 6 single glacier melt‐induced days (i.e., 6 events) during the ablation period 2016 (July to September). Median fractions (±uncertainty) of groundwater, glacier melt, and rain for the events were estimated at 49±2%, 35±11%, and 16±11%, respectively. Minimum and maximum glacier melt fractions at the subdaily scale ranged between 2±5% and 76±11%, respectively. A sensitivity analysis showed that the intraseasonal glacier melt tracer variability had a marked effect on the estimated glacier melt contribution during events with large glacier melt fractions of streamflow. Intra‐daily and spatial variation of the glacier melt tracer signature played a negligible role in applying the mixing model. The results of this study (a) show the necessity to apply a multiple sampling approach in order to characterize the glacier melt end‐member and (b) reveal the importance of groundwater and rainfall–runoff dynamics in catchments with a glacial flow regime.