放电等离子合成Ti3AlC2/TiB2复合材料的研究

采用放电等离子烧结工艺成功地制备了Ti3AlC2/TiB2复合材料.研究表明:在1 250 ℃,30 MPa压力和保温8 min下烧结,可以得到相对密度达98%以上的致密Ti3AlC2/TiB2块体材料;在Ti3AlC2中添加TiB2能大幅度提高材料性能,Ti3AlC2/TiB2复合材料Vickers硬度随TiB2掺量的增加而增大,最大可达到10.4 GPa;当TiB2体积含量为10%时,复合材料的最大的抗弯强度为696 MPa,断裂韧性为6.6 MPa·m1/2.     

TiB_2/SiC陶瓷复合材料制备工艺的研究

以TiO2、B4C和C为原料,基于原位合成法在SiC基体中生成TiB2颗粒,并采用无压烧结法制备出TiB2/SiC复合陶瓷.通过对复合材料制备工艺的研究,发现：高于1 300℃的预烧结能形成TiB2/SiC复合陶瓷坯体.C含量、烧结温度和保温时间对复合材料的相对密度均有影响.当C含量（质量分数）为4%时、在1 400℃×60 min＋2000℃×30 min的烧结工艺下能够制备出致密的TiB2/SiC陶瓷复合材料.微米级TiO2粉比纳米级TiO2粉更有利于形成较致密的烧结复合材料.随着生成TiB2体积分数的增加（5%～20%）,复合材料中TiB2颗粒逐渐粗化,间距逐渐变小.对复合材料的烧结机理还进行了分析.     

TiB2-BN复相陶瓷的制备工艺及性能研究

采用等离子放电热压烧结方法研究了TiB2-BN复合材料的制备条件和烧结工艺，获得了综合性能良好的TiB2-BN复合材料。研究表明，混料方式的选择对最终获得性能良好的TiB2-BN复合材料有很大影响，且TiB2含量(体积分数)为50％左右时可获得较好的材料性能。在烧结过程中，随着保温时间的延长，TiB2-BN复合材料的相对密度有较大提高，电阻率和抗弯强度则出现极值。     

Ti3SiC2/TiB2复合材料的制备及其组织和力学性能

以2TiC／Ti／Si／0．2Al／TiB2粉为原料，采用热压烧结工艺成功制备了Ti3SiC2／TiB2复合材料。结果表明：不同TiB2含量的试样中主晶相为Ti3siC2与TiB2两相，没有发现其它杂质相；当复合材料中TiB2的体积分数为10％时，其硬度、抗压强度、弯曲强度、断裂韧性都有显著的提高。经热处理后，Ti3SiC2／10％TiB2复合材料的弯曲强度由367．5MPa     

Cu-Ti3SiC2复合材料真空热压法制备及性能研究

Ti3SiC2是一种具有MAX层状结构的先进材料,兼具金属与陶瓷的双重性能。将Ti3SiC2作为弥散强化相与Cu复合制备金属基复合材料,综合力学性能较好,有望在电接触材料中有较好的应用前景。采用热压烧结法制备Cu-Ti3SiC2复合材料,试验证明Cu-Ti3SiC2复合材料的最佳烧结工艺为:烧结温度750℃,压力30 MPa,保温30min,制得复合材料的组织均匀,团聚较少。其次研究了Ti3SiC2含量对复合材料硬度、电阻率等性能的影响,随着Ti3SiC2的体积分数的增加,硬度先增加后降低,相对密度和抗弯强度呈减小趋势,电阻率增加;通过微观显微分析,Cu-Ti3SiC2致密度随Ti3SiC2含量增加而下降。     

TiO2原位反应合成MgO-TiC颗粒增强的铜基复合材料

利用TiO₂镁热碳热原位还原技术制备MgO-TiC增强的铜基复合材料,通过XRD、SEM和力学性能检测方法研究TiO₂原位合成对MgO-TiC增强铜基复合材料的相、组织和力学性能的影响。结果显示:在烧结过程中TiO₂、Mg和C粉发生了原位合成反应,生成了MgO和TiC相,并产生了少量的MgTiO₃;材料的组织与增强相含量有着密切的关系,当增强相含量较小时,MgO-TiC颗粒弥散分布在铜基体上,随着增强相含量的增加,材料的组织中出现了MgO-TiC颗粒聚集分布的组织;材料的尺寸变化在烧结过程中主要以收缩为主,随着保温时间的延长或温度的升高,增强相含量为5%的材料的相对密度和硬度逐渐增大,增强相含量为10%的材料的相对密度和硬度逐渐降低。     

Mo/SiO2复合材料的制备及其导电性能

采用放电等离子烧结(SPS)技术,对具有不同组成含量的Mo/SiO2复合材料的烧结行为和烧结致密化机理进行研究,并着重探讨了复合材料中Mo含量、分布状态对导电性能的影响。结果表明,Mo/SiO2复合材料中Mo与SiO2以机械混合的形式存在,SiO2的部分软化、Mo颗粒填充空隙促进了复合材料的致密化。当Mo的质量含量小于35%,Mo弥散分布在SiO2中,复合材料为绝缘体;当Mo的质量含量超过40%时,Mo的渗流导通使复合材料成为导体。     

微波烧结金刚石-WC硬质合金复合材料研究

采用微波烧结工艺制备金刚石-WC硬质合金复合材料,并和常规烧结工艺进行对比.分别对烧结样品进行了硬度、致密度等性能测试,采用扫描电镜(SEM)观察样品微观形貌,并采用能谱仪(EDX)对样品进行元素分析.结果表明,微波烧结升温速度快,周期短;在烧结温度为1 000℃,保温时间为1 h条件下,微波烧结样品的硬度HRA为75.33,相对密度为95.85%,较常规烧结样品的硬度69.58和相对密度87.28%要高;此外,相比于常规烧结,微波烧结样品烧结较为充分,金刚石受烧损情况较轻,且与基体结合较好,微波烧结工艺在制备金刚石-WC硬质合金复合材料过程中优势较为明显.     

(TiB_2+SiC_p)/ZL101复合材料组份优化及其力学性能

为了确定(TiB2+SiCp)/ZL101复合材料的最佳成分,通过采用正交实验分析方法,研究复合材料的制备工艺,测试了复合材料的力学性能,并对该材料进行了显微金相分析和透射电子显微分析.结果表明,复合材料经过热处理后,抗拉强度、布氏硬度分别较基体合金ZL101提高了21.4%、49.3%;热膨胀系数较基体合金降低了14.1%;热处理后,复合材料中的共晶硅以粒状形态均匀分布于基体中;复合材料中增强相TiB2为粒状,SiC粒子为多边形尖角块状,两相较均匀分布于基体晶粒内部,且与-αAl的界面结合良好.     

一种原位TiB_2颗粒增强铝基复合材料的制备及特性

以Al-6Cu-0.2Mg-1Mn合金为基体,采用混合盐原位反应法制备不同TiB2颗粒含量（质量分数分别为1%、3%、5%）的颗粒增强铝基复合材料,对不同处理状态的TiB2颗粒增强复合材料及Al-6Cu-0.2Mg-1Mn合金的相结构与显微组织进行分析,并测试其维氏硬度。结果表明,原位反应生成的TiB2颗粒能改善基体组织,阻止基体晶粒生长的方向性,得到等轴晶;随着增强相TiB2颗粒含量的增加,基体组织得到明显细化;不同处理状态3%及5%含量TiB2颗粒增强复合材料的维氏硬度均显著高于相应Al-6Cu-0.2Mg-1Mn合金的维氏硬度。     

Combustion Synthesis and Densification of NiAl/TiB_2 Composites

A suitable combustion synthesis and densification process was designed to fabricate dense NiAl/ TiB2 composites from Ni-Al- Ti-B system. Combustion synthesis processing and microstructure characteristics of products were studied in detail. The results show that the amount of TiB2 ceramics has a great influence on the combustion synthesis processing and microstructure; with the increase of the amount of TiB2 ceramics, the combustion temperature and combustion velocity increase rapidly. The volume of synthesized products and the grain size of ceramics particle size are also affected by the amount of TiB2 ceramics. TiB2 ceramics fiber can be produced in this synthesis system. The dense NiAl/ TiB2 composites with residual porosity of no more than 1% are fabricated by the combustion synthesis and hot pressing, the mechanical properties of the dense NiAl/ TiB2 composites increase with increase of the amount of TiB2 ceramics.     

Effect of TiB_2 content on resistance to sodium penetration of TiB_2/C cathode composites for aluminium electrolysis

1　INTRODUCTIONInrecent years ,therehavebeenincreasingeffortstoimprovetheHall Heroult processintheprimaryaluminiumindustry[1 ] .InordertoovercometheshortagesofHall Heroultprocess ,suchashighconsumptionofelectricalpower ,highconsumptionofcarbonanodeandserious pollutionduetocarbonanodemanufactureandconsumptionetc ,anoveltypeofaluminareducedcellsbasedoninertanodeandwettablecathodesystemwasdevelopedtoreplaceconventionalHall Heroultprocess[2 ,3 ] .Titaniumdiboride(TiB2 )appearstobethebestca…     

Processing technique and sliding friction and wear behavior of TiB2／ZA27 composite

In-situ TiB2 particles reinforced ZA27 composite was prepared by the stir-casting technique and a twostep method. TiB2/Al composite was produced by incorporating K2 TiF6, KBF4 salts and other agents into Al melt. As a master alloy, TiB2/Al composite was used to manufacture TiB2/ZA27 composite, which results in the generation of well-distributed reinforcing TiB2 phase. The hardness, friction and wear behavior of TiB2/ZA27 composite were investigated. The results show that the hardness of the composite is enhanced with increasing the content of TiB2 particles, the incorporation of TiB2 reduces the wear rate of TiB2/ZA27 composite and improves the friction property under lubricated and dry sliding friction conditions. The worn track width of ZA27 alloy is 1.6 and 2.5 times as long as that of 2.1%TiB2/ZA27 composite at 150 N and 700 N load under lubricated conditions, which indicates that TiB2/ZA27 composite possesses higher bearing ability.     

Structure and Properties of TiB2 Thin Films Deposited at Low Temperatures Using RF Magnetron Sputtering

The TiB2 thin films were deposited on steel substrates using RF magnetron sputtering technique with the low normalized substrate temperature (0.1相似文献   

Synthesis of Ti3SiC2/TiB2 Composite by In-situ Hot Pressing (HP) Method

Ti3SiC2/TiB2 composite was successfully obtained by hot pressing Ti/TiC/Si/B4C power mixtures.Volume fraction of TiB2 in Ti3SiC2/TiB2 composite can not exceed 10%.Incorporation of excessive TiB2 will affect the reactions process.TiC and Ti5Si3 were two important intermediate phases during the whole reactions.The microstructure characteristics of the Ti3SiC2/TiB2 composites were analyzed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM).The experimental results show that the grains of Ti3SiC2/TiB2 composite are structured in a layered form,and the formation of TiB2 particles as reinforcements with elongated or equiaxed shape distributes in Ti3SiC2 matrix.     

TiB_2-xFe体系SHS合成的热力学计算与实验

对ＳＨＳ法制备ＴｉＢ２－ｘＦｅ系统复合材料进行了热力学计算，得到了绝热燃烧温度同金属稀释剂含量、绝热燃烧温度同反应预热温度等关系。依据热力学计算的结果对ＳＨＳ合成ＴｉＢ２－ｘＦｅ系统的过程机理进行了预测，并运用实验结果加以验证。     

Self-Propagating High-Temperature Reductive Synthesis of TiB_2-Al_2O_3 Composite Powders

TiB2-Al2O3 composite powders were produced by self-propagating high-temperature synthesis(SHS) method with reductive process from B2O3-TiO2-Al system. X-ray diffraction(XRD) and scanning electron microscopy(SEM) analyses show the presence of TiB2 and Al2O3 only in the composite powders produced by SHS. The powders are uniform and free-agglomerate. Transmission electron microscopy (TEM) and high resolution electron microscopy (HREM) observation of microstructure of the composite powders indicate that the interfaces of the TiB2-Al2O3 bond well, without any interfacial reaction products. It is proposed that the good interfacial bonding of the composite powders can be resulted from the TiB2 particles crystallizing and growing on the Al2O3 particles surface with surface defects acting as nucleation centers.