河南汝阳东沟超大型钼矿床地质特征及找矿标志

东沟钼矿属斑岩型钼矿床,矿床(体)赋存于下铺花岗斑岩体内外接触带中,沿岩体呈似层状(帽状)分布,钼矿化与岩石中裂隙发育程度关系密切,矿厚一般130～170 m,最大259.62m.主要矿石类型有安山岩型、英安岩型、闪长细晶岩型和花岗斑岩型辉钼矿矿石,矿化蚀变具典型斑岩型矿床的特征,地球化学异常和花岗斑岩体是主要找矿标志.     

豫西栾川鱼库锌多金属矿床地质及S、Pb同位素地球化学特征

鱼库锌多金属矿床位于豫西栾川钼钨铅锌银矿集区内的鱼库—赤土店铅锌矿带的北西端。矿床赋存于新元古界栾川群三川组碳酸盐岩夹碎屑岩地层中,矿体呈似层状、透镜状产于透辉石-石榴石矽卡岩中,受矽卡岩带控制。硫化物的硫同位素组成比较稳定,δ~(34)S变化范围为2.3‰~3.9‰,平均3.2‰。硫同位素组成与区域内斑岩-矽卡岩型矿床的硫同位素组成一致,反映硫的主要来源为深部岩浆;金属硫化物样品的~(206)Pb/~(204)Pb变化范围为17.781~18.455,平均值18.043;~(207)Pb/~(204)Pb变化范围为15.502~15.590,平均值15.545;~(208)Pb/~(204)Pb变化范围为38.232~38.624,平均值38.438,矿石铅同位素组成稳定,矿石铅主要来源于地幔,成矿作用与构造岩浆作用相关的热液过程关系密切。综合分析认为矿床成因应属于岩浆热液接触交代矽卡岩型矿床。     

东秦岭大别山段斑岩型钼(钨、铜)矿床地质特征

东秦岭大别山段矿化中酸性小岩体集中分布在东秦岭钼(钨、铜)矿带东段,呈带状沿深大断裂两侧分布,受构造控制明显.已发现主要钼矿床属斑岩型,成因多与中生代中酸性花岗质斑岩有关.根据斑岩型钼(钨、铜)矿床地质特征,通过控岩控矿构造、围岩蚀变、矿体特征、矿石物质组份及其成矿机制等方面的研究,把东秦岭大别山段斑岩钼(鸽、铜)矿划分为浅成-超浅成斑岩钼(铜)矿床,中-深成斑岩-夕卡岩钼(钨、铜)矿床两种类型.     

中国主要斑岩钨矿床特征

根据我国主要斑岩型钨矿床地质地球化学资料,斑岩钨矿床产布在特定板块构造位置,受中生代区域深(大)断裂的控制,其成矿与燕山中晚期花岗闪长斑岩、花岗斑岩、石英斑岩和二长花岗斑岩体有关,总结综合了我国斑岩钨矿床成矿特征和成矿模式。 斑岩钨矿床常与斑岩型和其他型钼、铜、锡矿床产于同一成矿区带;成矿具有深源岩浆热液成矿和深源岩浆热液一表生改造成矿系列;斑岩钨矿床成矿于斑岩体内外接触带,而以内带为主;矿体形态有板状、脉状、似层状和岩钟状,矿化类型常见为钨型和钨钼型,矿物简单;矿化-蚀变具有分带特征。     

栾川西鱼库隐伏斑岩型Mo-W矿床地球化学及其意义

西鱼库大型隐伏斑岩钼-钨矿床是近年来在栾川地区开展深部找矿勘查过程中的新发现。该矿床与南泥湖、上房沟钼矿不同,其矿体主要赋存于斑岩体内部而非岩体外接触带的矽卡岩或角岩中。与南泥湖和上房岩体相比,西鱼库隐伏斑岩体的Si O2、K2O含量略低,具有正Eu异常,表明西鱼库隐伏斑岩体比南泥湖和上房岩体分异程度略低,更接近成矿岩浆中心位置。     

东秦岭钼铅锌银多金属矿集区地球物理场特征及综合信息找矿模型

东秦岭地区是我国重要的钼矿资源产地,已查明大型、超大型斑岩型钼(钨)矿床十多处;在这些钼(钨)矿床外围,近年又找到了许多达中大型规模的脉型铅锌银(金)矿床,形成钼(钨)铅锌银(金)多金属矿集区。区内众多的矿集区均分布于重磁推断的隐伏岩体(基)区及其边部附近,矿床的形成严格受隐伏岩体的侵入形态、顶面深度和所处构造的控制,二者具有非常明显的时空关系。研究矿集区地球物理场特征,推定隐伏岩体和断裂构造的分布,是深部找矿工作的有效途径。通过研究矿集区和典型矿床的地质特征和重、磁、电异常特征,建立了矿田和矿床的地质成矿模型和综合信息找矿模型。地质成矿模型描述了隐伏岩体、小花岗斑岩体和钼(钨)铅锌银(金)矿床的顺序约束,即隐伏岩体控制小花岗斑岩体的形成,小花岗斑岩体控制钼(钨)铅锌银(金)矿床的形成;综合信息找矿模型包括隐伏岩体、小花岗斑岩体和矿体(矿化体)的重、磁、电异常标志。根据找矿模型进行了深部找矿预测。研究成果对在东秦岭地区进行深部找矿工作具有重要意义。     

柿竹园超大型钨-锡-钼-铋-铍矿床形成的条件

柿竹园已探明的钨、锡、钼、铋金属储量已超过百万吨,是罕见的超大型矿床。 1.矿床地质概况矿床产于燕山早期壳源重熔型花岗岩株与中晚泥盆世碳酸盐地层的接触带上。自花岗岩体向外,可分为5个矿石带:内接触带面型云英岩钨锡钼铋矿石带,网脉状云英岩—矽卡岩复合型钨锡钼铋矿石带,矽卡岩钨铋矿石带,大理岩网脉状锡铍矿石带,     

内蒙古自治区阿巴嘎旗必鲁甘干铜钼矿地质特征及成因探讨

必鲁甘干矿区位于天山—阴山内蒙地槽华力西晚期褶皱带阿巴嘎旗复向斜中段,查干敖包(必鲁甘干)倒转背斜核部。区内NE向断裂构造控制了印支期花岗斑岩体及特大型斑岩型铜钼矿床的分布。通过勘探查明主矿体延长2 300m,延深1 850m,平均厚度46.24m。铜钼矿赋存于花岗斑岩与硅质角岩内外接触带,赋矿岩石主要为花岗斑岩和硅质角岩。矿体形态以透镜状—似层状为主,属斑岩型铜钼矿。     

新疆东天山小白石头钨(钼)矿辉钼矿Re-Os同位素年龄及成矿时代

小白石头钨(钼)矿床位于新疆东天山造山带中的中天山地块南缘,该矿床是一个由黑云母花岗岩和花岗闪长岩侵入中元古界卡瓦布拉格群形成的矽卡岩型钨(钼)矿床。辉钼矿作为其主要的矿石矿物之一,呈不同产出状态分布于花岗闪长岩、黑云母花岗岩、矽卡岩和石英脉中。目前,对于小白石头钨(钼)矿成矿时代尚有争议,特别是与花岗闪长岩有关的辉钼矿化形成时代缺乏精确的限定。本文选取与花岗闪长岩有关的不同产状辉钼矿进行Re-Os同位素定年,获得Re-Os加权平均模式年龄为245. 0±1. 7Ma,Re-Os等时线年龄为245. 5±4. 3Ma。准确的Re-Os同位素定年限定小白石头钨(钼)矿床的成矿年龄和花岗闪长岩的侵位年龄为245Ma左右,为矿床模型建立和找矿方向确定提供了关键依据,同时也为东天山区域成矿规律总结提供了重要的年代学证据,并指出新疆东天山—甘肃北山地区存在一条找矿潜力巨大的三叠纪钨钼成矿带。     

竹园沟钨钼矿床地质特征及找矿远景分析

竹园沟钨钼矿是近年来在东秦岭地区发现的又一大型钨钼矿.在讨论成矿地质背景基础上,对矿床地质特征进行了研究.矿体的空间分布与矿区内褶皱、断裂、岩性、围岩热液蚀变强度有关,矿体受黄背岭背斜及石宝沟斑状二长花岗岩侵入体向北西侧伏的内外接触带控制.矿床成因为斑岩-矽卡岩型钼矿床.同时指出了找矿标志.分析了找矿远景,对以后的找矿工作有一定的指导意义.     

Geochronology and Ore‐Forming Fluids of the Baizhangyan W–Mo Deposit in the Chizhou Area,Middle‐Lower Yangtze Valley,SE‐China

The Baizhangyan skarn‐porphyry type W–Mo deposit is located in a newly defined Mo–W–Pb–Zn metallogenic belt, which is in the south of Middle‐Lower Yangtze Valley Cu–Fe–Au polymetallic metallogenic belt in SE China. The W–Mo orebodies occur mainly within the contact zone between fine‐grained granite and Sinian limestone strata. There are two types of W–Mo mineralization: major skarn W–Mo mineralization and minor granite‐hosted disseminated Mo mineralization which was traced by drilling at depth. Eight molybdenite samples from Mo‐bearing ores yield Re–Os dates that overlap within analytical error, with a weighted average age of 134.1 ± 2.2 Ma. These dates are in close agreement with SIMS U–Pb concordant zircon age for fine‐grained granite at 133.3 ± 1.3 Ma, indicating that crystallization of the granite and hydrothermal molybdenite formation were coeval and likely cogenetic. The Baizhangyan W–Mo deposit formed in the Early Cretaceous extensional tectonic setting at the Middle‐Lower Yangtze Valley metallogenic belt and the Jaingnan Ancient Continent. Based on mineral compositions and crosscutting relationships of veinlets, hydrothermal alteration and mineralization, the ore mineral paragenesis of the Baizhangyan deposit is divided into four stages: skarn stage (I), oxide stage (II), sulfide stage (III), and carbonate stage (IV). Fluid inclusions in garnet, scheelite, quartz and calcite from W–Mo ores are mainly aqueous‐rich (L + V) type inclusions. Following garnet deposition at stage I, the high‐temperature fluids gave way to progressively cooler, more dilute fluids associated with tungsten–molybdenite–base metal sulfide deposition (stage II and stage III) (162–360°C, 2.7–13.2 wt % NaCl equivalent) and carbonate deposition (stage IV) (137–190°C, 0.9–5 wt % NaCl equiv.). Hydrogen‐oxygen isotope data from minerals of different stages suggest that the ore‐forming fluids consisted of magmatic water, mixed in various proportions with meteoric water. From stage I to stage IV, there is a systematic decrease in the homogenization temperature of the fluid‐inclusion fluids and calculated δ¹⁸O values of the fluids. These suggest that increasing involvement of formation water or meteoric water during the fluid ascent resulted in successive deposition of scheelite and molybdenite at Baizhangyan.     

湖北大冶铜山口铜(钼)矿床中钨矿化特征及其地质意义

为了查明鄂东矿集区内铜山口矽卡岩-斑岩型铜(钼)矿床中钨矿化作用的地质特征.对该矿床中的钨矿(化)体开展了系统的矿床地质特征、岩石学和矿物学研究,并探讨基底对区内钨矿在空间上分布的影响.钨矿体主要产出于花岗闪长斑岩与碳酸盐岩地层的接触部位及其附近,其产状受接触面形态的控制;钨既可形成独立的钨矿体,也可作为铜和钼矿体的伴生组分;钨矿物主要为含Mo的白钨矿.铜山口矿床中的钨矿化与矽卡岩化有着密切的时间、空间和成因联系,具有典型的氧化性矽卡岩型钨矿特征,钨和铜矿化是同一岩浆-热液事件不同阶段的产物,但钨矿体的产出位置比铜矿化相对更深;鄂东矿集区南部的钨矿化岩体具有很多相似性,他们很可能在一定程度上受富含铜和钨的江南式基底控制,江南式和董岭式基底在鄂东矿集区的结合部位可能位于阳新岩体附近.     

Geology and mineralization of the supergiant Shimensi granitic-type W-Cu-Mo deposit (1.168 Mt) in northern Jiangxi,South China: A Review

The Shimensi deposit is a recently discovered W-Cu-Mo polymetallic deposit located in the Jiangnan porphyry-skarn W belt in South China. The deposit has a resource of 0.74×10⁶ t of WO₃ accompanied by 0.4×10⁶ t Cu and 28000 t Mo and other useful components like Ga, making it one of the largest W deposits in the world. This paper is aimed to reveal the ore-controlling mechanisms of the Shimensi deposit, involving the role of the ore-related granites, the tectonic background for its formation, and the metallogenesis model. The systematic geological survey suggests multi-types of alteration are developed in the deposit, mainly including greisenization, potassic-alteration, sericitization, chloritization, and silicification. Drilling engineering data and mining works indicate that the Shimensi deposit consists of two main orebodies of I and II. Therein, the W resource has reached a supergiant scale, and the accompanied Cu, Mo, Au, Bi, Ga, and some other useful components are also of economic significance. The main ore-minerals consist of scheelite, wolframite and chalcopyrite. Disseminated mineralization is the dominant type of the W-Cu-Mo polymetallic orebodies, and mainly distributes in the inner and external contact zone that between the Neoproterozoic biotite granodiorite and the Yanshanian granites. The main orebody occurs at the external contact zone, and the pegmatoid crust near the inner contact zone is an important prospecting marker of the W mineralization. Of them, the disseminated W ores within the wall rock of the Neoproterozoic biotite granodiorite is a new mineralization type identified in this paper. Combining previous geochronological and isotopic data, we propose that the mineralization of the Shimensi deposit is closely related to the intruding of the Yanshanian porphyritic biotite granite and granite porphyry. Geochemical data suggest that the biotite granodiorite is rich in Ca and had provided a large amount of Ca for the precipitation of scheelite in this area. Thus, it is a favorable wall rock type for W mineralization. The Shimensi deposit belongs to granitic-type W polymetallic deposit related to post-magmatic hydrothermal, and the ore-forming fluid was initially derived from the Yanshanian magmas.©2022 China Geology Editorial Office.     

内蒙古阿巴嘎旗比鲁甘干斑岩型钼矿床辉钼矿Re-Os同位素年龄及其地质意义

采用辉钼矿Re-Os同位素定年,获得的内蒙古阿巴嘎旗比鲁甘干钼矿的辉钼矿Re-Os同位素模式年龄变化范围为236.9±3.7~238.7±2.4Ma,年龄加权平均值为237.9±1.7Ma,表明该矿床形成时代应为印支期。辉钼矿的Re含量平均值为74.065×10~(-6),表明其主要为幔壳混合来源特征。该矿床位于贺根山断裂带以南的兴蒙造山系索伦山-霍林郭勒弧盆系内,为斑岩型钼矿床。钼矿体主要赋存在黑云母花岗斑岩和角岩内,受内外接触带控制。接触带控矿容矿断裂主要有北西向、北东向及近东西向,其内多充填有石英脉。细脉状、网脉状石英脉越发育,钼矿化越强。区域研究表明,印支期是兴蒙造山带及其邻区钼(钨)成矿的重要成矿期之一,但在本区尚属首次发现,为开展索伦山-霍林郭勒成矿带区域成矿规律研究提供了重要参考。     

Geochronologic and isotope geochemical constraints on magmatism and associated W–Mo mineralization of the Jitoushan W–Mo deposit,middle–lower Yangtze Valley

The Jitoushan W–Mo ore body is a typical skarn-type deposit with the potential for porphyry Mo mineralization at depth. As it is newly discovered, only a few studies have been conducted on the geochronology and ore genesis of this deposit. The ore district consists of Cambrian to Silurian sedimentary and low-grade metasedimentary strata, intruded by granodiorite, diorite porphyry, granite porphyry, and quartz porphyry. Skarn W–Mo ore bodies are hosted in the contact zone between the granodiorite and Cambrian limestone strata. Within the granodiorite near the contact zone, quartz vein type and disseminated sulphide mineralization are well developed. The Mo-bearing granite porphyry has been traced at depth by drilling. Our results reveal two discrete magmatic events at ca. 138 and ca. 127 Ma in the study area. The molybdenite Re–Os isochronal age of 136.6 ± 1.5 million years is consistent with the first magmatic event. The zircon Hf isotope (?_Hf(t) =??12.55?3.91), sulphide isotopes (δ³⁴S = 3.32–5.59‰), and Re content of molybdenite (Re_content = 6.424–19.07 μg) indicate that the ore-forming materials were mainly derived from the deep crust. The regional tectonic system switched from a Late Jurassic transpressive regime to an earliest Cretaceous extensional regime at ca. 145 Ma, and at ca. 138 Ma, the Jitoushan W–Mo deposit formed in an extensional setting.     

黑龙江省某地区钼、铅锌多金属矿(化)点地质特征及找矿标志

研究区位于小兴安岭—张广才岭多金属成矿带之翠宏山—二股铁、有色金属成矿亚带(也称铁力—玉泉有色金属、贵金属成矿带)的中南段,呈南北向带状展布。成矿带中区域上发育三期成矿作用,加里东中期成矿作用、印支晚期成矿作用和燕山期成矿作用,是黑龙江省重要的铅、锌、银、铁、钨、钼等多金属成矿带。测区先后发现了前进东山铅锌矿点、前进先锋沟铁矿化点、牛奶沟钼矿点、九小工队钼矿化点。本文以牛奶沟钼矿点、九小工队钼矿化点为例总结了五三零和寒月林场地区钼、铅锌多金属矿化点的地质特征并确定了其成矿规律与找矿标志。     

内蒙古中西部钼多金属矿床地质特征及其动力学背景

本文首次对内蒙古中西部白乃庙铜-钼-金矿床、大苏计钼矿床、西沙德盖钼矿床、柳坝沟金-钼矿床、哈达门沟金-钼矿床、查干花钼-钨矿床和流沙山钼-金矿床的产出环境、地质特征、成因类型和时空分布特点进行了简要总结,对成矿作用与构造-岩浆活动的关系进行了概略性论述。柳坝沟、哈达门沟和白乃庙矿床均在前寒武纪变质岩地层中产出,大苏计、查干花、西沙德盖和流沙山矿床直接产于海西-印支期中酸性侵入岩中,尽管上述矿床在产出环境和地理位置上存在有一定差别,但是它们均与花岗岩类侵入岩体(或岩脉)具有密切的空间分布关系,属与中酸性侵入岩有关的钼多金属矿床。另外,根据矿床(点)的空间分布特点,可划分出5个钼多金属矿化集中区:即大苏计-明星沟钼矿化集中区、白乃庙-谷那乌苏铜-钼-金矿化集中区、哈达门沟-沙德盖金-钼矿化集中区、马尼图-查干花钼-铋-钨矿化集中区和流沙山-黑鹰山钼-金-铁矿化集中区。研究结果表明,成矿作用与板块消减、碰撞和缝合过程中所诱发的构造-岩浆事件密切相关,是地壳特定演化阶段构造-岩浆活动的产物。     

河南省桐柏县银洞坡金矿床(西段) 地球化学找矿标志及预测评价

通过对河南银洞坡金矿床地球化学特征的研究, 建立了地球化学找矿标志。元素组合复杂, 由Au、Ag、Pb、Zn、As、Cd形成了强异常;主要异常元素浓集中心明显, 分带清晰;w(As)/w(Mo)≥4;w(As)+w(Cd)+w(Au)/w(Ni)+w(Co)+w(Mo)≥10;浓集克拉克值≥0.5, 变异系数≥1;异常呈条带状有规律分布并受含矿层及构造控制。根据这些标志, 在银洞坡矿区外围W4～W24线等地进行了成矿预测, 预测结果新增加金金属量11.945 t。     

福建南靖南坑钼多金属矿异常特征及找矿远景分析

南靖南坑土壤地球化学圈出5个Mo多金属综合异常,异常呈北东向分布在燕山早期中酸性侵入岩与文宾山组碎屑岩接触带及断裂带附近,异常元素组合以Cu、Mo为主,伴有Pb、Zn、W等,浓集中心明显,局部证实为矿致异常,其中甲3-1异常经详查,Mo多金属矿达中型规模,综合分析该区成矿地质背景、地球化学特征和已发现矿(化)点,认为南坑一带具有良好的钼矿找矿远景。     

福建省上杭县罗卜岭斑岩铜钼矿床构造控矿规律研究

罗卜岭铜(钼)矿区位于紫金山矿田的东北部,是与晚中生代花岗闪长斑岩体有关的隐伏斑岩型铜钼矿床;主要斑岩矿体产于绿泥石化-绢英岩化和(弱)钾化-绢英岩化带中,矿石矿物组合为黄铜矿+辉钼矿;少量过渡类型矿体产于高级泥化带中,矿石矿物组合为蓝辉铜矿+铜蓝+辉钼矿。罗卜岭矿区地表露头含矿裂隙的统计结果显示,罗卜岭成矿晚期的含矿裂隙具有明显的方向性。远离斑岩体的含矿裂隙与其附近的区域构造方位或侵入体走向相近,表明受到北东向区域构造活动控制;而斑岩体西侧露头附近的含矿裂隙呈放射状,主要受到斑岩体侵入作用的影响。深部隐伏矿体则受到区域断裂和花岗闪长(斑)岩侵入体的共同控制,具体表现为:垂向上,以隐伏似斑状花岗闪长岩为中心,由深至浅,矿体铜钼品位比值依次变大,显示了Mo\Cu-Mo\Cu(Mo)的元素垂向分带;平面上,铜、钼元素沿着北东向、北西向断裂和岩体接触带附近有明显富集;斑岩型铜钼矿体主要产于似斑状花岗闪长岩外接触带的花岗闪长斑岩中,形态和产状受到区域北东向断裂或岩体接触带构造影响;蓝辉铜矿体主要产于罗卜岭花岗闪长斑岩外接触带的花岗闪长岩体内,形态和产状受接触带控制。区域构造和斑岩侵入体对斑岩型铜钼矿化有不同的影响,浅部铜、钼矿化受区域断裂构造控制作用明显,而深部矿体主要受花岗闪长(斑)岩体和断裂构造共同控制。区域上北东向背斜构造和北东、北西向断裂构造控制了花岗闪长质侵入岩体的侵位,矿区尺度的断裂构造对斑岩体的就位和成矿作用有一定的影响,罗卜岭花岗闪长斑岩体及其接触带则直接控制了斑岩型矿体的产出,这一规律对紫金山矿田深部和外围隐伏斑岩型矿体的勘查工作具有重要的参考意义。