Elevated temperature short crack fatigue behaviour in near eutectic Al–Si alloys

This paper considers two candidate automotive piston alloys and highlights the influence of microstructural features on fatigue behaviour. Fatigue initiation and subsequent short crack growth was assessed at 20, 200 and 350 °C. It is shown that both temperature and test frequency have a strong influence on the fatigue performance of the materials tested. The microstructure was quantitatively characterised in terms of the primary Si distribution. Together with post failure analysis, this allowed identification of critical microstructural features affecting both fatigue crack initiation and early growth. Large primary Si particles were found to act as preferential initiation sites by cracking or decohesion (dependent on test temperature) and are also sought out preferentially during short crack growth.     

Effect of rolling speed on microstructure and age-hardening behaviour of Al–Mg–Si alloy produced by twin roll casting process

In the present investigation the microstructure and age-hardening behaviour of Al–Mg–Si alloy prepared by twin roll casting (TRC), varying rolling speed (i.e., 3, 4, and 5 rpm), were studied. The as-cast samples were subjected to optical microscopy (OM) to understand the effect of rolling speed on the alloy microstructure. Significant difference in grain size and shape was observed for all the alloys in as-cast condition. The as-cast samples were solutionized at 540 °C for 2 h followed by isothermal heating at 180 °C for different time intervals. Thereafter, the as-cast and solutionized samples were subjected to scanning electron microscopy (SEM) equipped with energy dispersive spectroscopy (EDS). Segregation of solute atoms at grain boundaries were observed for both as-cast as well as solutionized samples. Age-hardening results show that time to attain peak hardness decreases for the alloy produced by higher rolling speed.     

Dry sliding wear behaviour of hypereutectic Al–Si piston alloys containing iron-rich intermetallics

The effect of iron-rich intermetallics on the wear behaviour of Al–Si hypereutectic alloys has been studied. Dry sliding wear tests have been conducted using a pin-on-disk machine under different normal loads of 18, 51, 74 and 100 N and at a constant sliding speed of 0.3 m/s. The addition of 1.2 wt.% Fe to the LM28 alloy increased the wear rate due to the formation of needle beta intermetallics. Introducing 0.6 wt.% Mn to the iron-rich alloy changed the beta intermetallics into the modified alpha phases, and therefore reduced the detrimental effect of iron. TIG welding method as a surface melting process was applied on the iron and manganese containing alloy and led to a fine microstructure and increased the wear resistance.     

Characteristics of α-dendritic and eutectic structures in Sr-treated Al—Si casting alloys

The present study was carried out to determine the effect of alloy composition and solidification conditions on changes in the dendritic and eutectic structures in Al—Si alloys containing strontium. A series of experimental and industrial alloys viz., Al-7% Si, Al-12% Si, 319 and 356 were selected, to cover a variety of alloy freezing ranges. The techniques of thermal analysis, optical microscopy, and SEM/EDX and EPMA analyses were employed to obtain the results presented here. Depression in the eutectic Si temperature in Al-7% Si alloys occurs on addition of alloying elements such as Mg and Cu. Introduction of Sr to these alloys further depresses the eutectic temperature, with a corresponding increase in the volume fraction of the -Al phase. The primary dendrite solidification pattern changes from parallel rows to a branched form, producing an equiaxed type of structure and hence shorter primary dendrite lengths. This is expected to enhance the interdendritic feedability. The lengths of the secondary dendrite arms are controlled by the rejection of solute atoms in front of the growing dendrites during solidification. The higher the alloying content in the alloy (i.e., 319), the smaller the dendrite cell size. The longer solidification time in the 319 alloy also appears to have a considerable influence on the amount of porosity formed in the alloy, in addition to that of Sr.     

Modification of eutectic silicon in Al–Si alloys

The mechanical properties of Al–Si alloys are strongly related to the size, shape and distribution of eutectic silicon present in the microstructure In order to improve mechanical properties, these alloys are generally subjected to modification melt treatment, which transforms the acicular silicon morphology to fibrous one resulting in a noticeable improvement in elongation and strength. Improper melt treatment procedures, fading and poisoning of modifiers often result in the structure which is far from the desired one. Hence it is essential to assess the effectiveness of melt treatment before pouring. A much investigated reliable thermal analysis technique is generally used for this purpose. The deviation from the standard curve in thermal analysis helps in assessing the level of refinement of the Si structure. In the present review an attempt is made to discuss various aspects of modification, including mechanism, interaction of defects and non-destructive assessment by thermal analysis.     

Effect of microstructure on fatigue behaviour of cast Al–7Si–Mg alloy

Abstract

The fatigue behaviour of a cast Al–7Si–Mg alloy, conforming to A356, has been studied. Specimens of this material were tested in both the as cast condition and a solution treated and aged condition. It was observed that the size, number, and position of casting defects influenced the fatigue life very strongly. This marked effect nearly hides that of the heat treatment. Nevertheless, if the analysis is carried out considering only results obtained from sound specimens it is revealed that the heat treatment causes an improvement in the fatigue resistance of the alloy.     

Experimental investigations on energy absorption capacity of selected Al–Si–Mg casting alloys

Three hypoeutectic Fe containing Al–Si–Mg alloys for casting crash relevant automotive components are experimentally investigated. The comparatively short heat treatments include solutionising at 540°C for 5 min or at 465°C for 60 min respectively, compressed air quenching and artificial aging at 223°C for 120 min. Characteristic mechanical parameters are determined by tensile, plate bending and Charpy pendulum impact tests. Intermetallic phases are identified by scanning electron and by light microscopy. The results show that increasing the Mg content promotes the precipitation of Mg₂Si particles, which enhance the strength. Increasing the Fe content promotes the formation of intermetallic Fe bearing particles which reduce the energy absorption capacity and the ductility. Increasing the Si content has the similar effect, since the volume fraction of the eutectic phase and the size of the intermetallic particles increase.     

Morphologies of Si phase and La-rich phase in as-cast hypereutectic Al–Si–xLa alloys

In the present study, the diversified morphologies of Si phase and La-rich phase in as-casted hypereutectic Al–Si–xLa alloys are presented and investigated. The morphological features were examined using conventional optical microscopy and SEM for observations conducted on the optical samples and deep-etched samples, respectively. The results show that primary Si crystals show several morphologies, such as feathery, star-shaped, faceted polygonal, platelet and so on. There are three types of fivefolded Si crystals existing in the present study, fivefold symmetry as radial growth alone: thin-branched, coarse-branched and well-defined star-shaped growing from the preferred growth from the tips of branches. The eutectic Si in unmodified Al–Si alloys appears only in fibrous morphology, while discrete and interconnected coral and rodlike eutectic Si particles were observed in alloys with the addition of La. The La-rich phase also grows into a variety of morphologies, such as needlelike, broken rodlike in pores, spherical, and flat platelet. In optical microscopy, La-rich phase is observed to envelope some small polygonal Si crystals.     

Effects of Si and Cu contents on grain size of Al–Si–Cu alloys

The influence of the silicon and copper contents on the grain size of high-purity Al–Si, Al–Cu, and Al–Si–Cu alloys was investigated. In the Al–Si alloys, a poisoning effect was observed and a poor correlation between the grain size and growth restriction factor was obtained. A possible cause of the poisoning effect in these alloys is the formation of a TiSi₂ monolayer on the particles acting as nucleation sites or another poisoning mechanism not associated with TiSi₂ phase formation. In the Al–Cu alloys, a good correlation between the grain size and growth restriction factor was found, whereas in the Al–Si–Cu alloys, the correlation between these two parameters was inferior.     

Effect of low voltage pulsed magnetic field on microstructure and wear behaviour of eutectic Al–Si alloys

Abstract

Effect of discharging frequency of low voltage pulsed magnetic field (LVPMF) on the morphology and size of eutectic Si in eutectic Al–Si (Al–12Si) alloys has been investigated, and some characteristic parameters the characterised the microstructure of the eutectic Si phase were obtained. Dry sliding wear behaviour of eutectic Al–Si alloys without and with LVPMF treatment were also tested using a pin-on-disc wear testing machine, and scanning electron microscopy and energy dispersive spectroscopy X-ray of worn surfaces were carried out to determine the governing mechanisms in the eutectic Al–Si alloys without and with LVPMF treatment. The results show that the eutectic Si became smaller with the increase in discharging frequency. Fine short rod-like or rounded particle-like eutectic silicon with 2·3 μm in length, 0·6 μm in the width, and 3·8 in aspect ratio was formed in eutectic Al–Si alloy treated by 6 Hz LVPMF. The wear resistance of eutectic Al–Si alloys increased with the increase in discharging frequency. The adhesive wear was observed in eutectic Al–Si alloy without LVPMF treatment under normal load of 80 N. However, mainly abrasive was observed in eutectic Al–Si alloy with 6 Hz LVPMF treatment.     

Decomposition of supersaturated solid solutions in Al–Cu–Mg–Si alloys

The Al–Cu–Mg–Si alloying system is a base for a diverse group of commercial alloys which acquire their properties after quenching and aging. Therefore, the knowledge of the phase composition of hardening precipitates and the conditions under which they are formed is very important. ast reference data were analyzed along with experimental results and calculations of phase equilibria. Different alloys were compared based on the composition of the supersaturated solid solution. It is shown that the phase composition of aging products in alloys with Mg : Si > 1 agrees well with the equilibrium phase composition at a temperature of annealing. However, the sequence of precipitation in the alloys with Mg : Si < 1 is more complicated. The hardening in these alloys occurs with precipitation of the and phases and their precursors. The former phase may contain copper and later transforms either to and (Mg₂Si) or to Q phase depending on the amount of copper and annealing temperature.     

Effect of casting and homogenizing treatment conditions on the formation of Al–Fe–Si intermetallic compounds in 6063 Al–Mg–Si alloys

The effect of casting and homogenizing treatment conditions on the formation of several Al–Fe–Si intermetallic compounds in 6063 aluminum alloy was investigated using X-ray diffraction and transmission electron microscopy (TEM). The four kinds of alloys containing 0.1 to 0.5 mass% Fe were melted and then cooled at three different cooling rates ranging from 0.06 to 50 K/s, following the homogenization at 858 K for 54 ks and 2400 ks. The Al–Fe–Si compound particles were extracted from the alloy ingots using the thermal phenol method. The as-cast 0.1 mass% Fe ingot obtained at the casting cooling rate of 0.06 K/s had a largest amount of the phase among the ingots investigated. When this ingot was homogenized at 858 K for 54 ks and 2400 ks, the amount of the phase decreased, while that of the phase increased. On the other hand, the as-cast 0.5 mass% Fe ingot obtained at the casting cooling rate of 50 K/s had the largest amount of the phase among the ingots investigated. When this ingot was homogenized at 858 K for 54 ks, a large amount of the phase remained. However, the homogenization at 858 K for 2400 ks resulted in the transformation of the phase to the phase. The main phase in the as-cast 0.2 mass% Fe ingot obtained at the casting cooling rate of 5 K/s, close to the industrial cooling rates, was the phase. The phase gradually decreased, and the relative amounts of the and phases increased during homogenization at 858 K for 54 ks. Furthermore, almost all of the Al–Fe–Si intermetallic compounds were transformed into the phase in the ingots homogenized at 858 K for 2400 ks.     

Tensile and fatigue behaviour of Ni–Ni3Si eutectic in situ composites

A Ni–Ni₃Si composite was fabricated via a eutectic reaction (Ni–Ni₃Si) using a rapidly cooled directional solidification technique at a solidification rate of 40?μm?s^?1. The composite consisted of approximately 62.2% Ni–Si solid solution and 37.8% Ni–Ni₃Si eutectic phase in volume. Four-point bend fatigue tests were carried out on the composite. The fatigue strength of the alloy was measured to be 520?MPa (maximum cyclic stress). It was found that the fatigue cracks were preferably initiated in the Ni–Ni₃Si eutectic phase, and that the Ni matrix was fractured in a cleavage fashion. It was probably attributed to the high level of supersaturated Si in the Ni matrix, which led to inducing the embrittlement of the Ni matrix.     

Effect of copper addition and heat treatment on segregation behaviour of Al–7Mg–Cu alloys

Abstract

Electron probe microanalysis showed that Al–7Mg–Cu alloys possess serious segregation tendencies. The addition of copper promoted the segregation of magnesium and led to the formation of non-equilibrium eutectic. With an increase in the copper content of the alloys, the severity of the solute segregation increased. Homogenisation reduced the solute segregation significantly. During homogenisation, the non-equilibrium eutectic compound Al_xCu_yMg_z gradually dissolved. Its dissolution behaviour depended on its copper content. Precipitates of Al_xCu_yMg_z with a comparatively low level of copper dissolved, while those with a high level of copper were less soluble and became divided into small blocks. The higher the copper content of the alloys, the larger and the greater in number the remaining Al_xCu_yMg_z particles. In the undissolved Al_xCu_yMg_z, the concentration of copper increased and that of magnesium decreased. Two step homogenisation reduced the solute segregation and dissolved the non-equilibrium eutectic further.

MST/3194     

Metallurgical parameters controlling the microstructure and hardness of Al–Si–Cu–Mg base alloys

Castings were prepared from both experimental and industrial 319 alloy melts containing 0–0.6 wt% Mg. Test bars were cast in two different cooling rate molds, a star-like permanent mold and an L-shaped permanent mold, with DASs of 24 μm and 50 μm, respectively. The bars were tempered at 180 °C (T6 treatment) and 220 °C (T7 treatment) for 2–48 h. The results showed that Mg content, aging conditions, and cooling rate have a significant effect on the microstructure of both experimental and industrial alloys and, consequently, on the hardness. The addition of Mg resulted in the precipitation of the β-Mg₂Si, Q-Al₅Mg₈Cu₂Si₆, π-Al₈Mg₃FeSi₆ and of the block-like θ-Al₂Cu phases. The Mg and Cu, as well as the higher cooling rates improved the hardness values, especially in the T6 heat-treated condition, whereas the addition of Sr decreased these values.     

Microstructure and tensile properties of squeeze cast Al–Zn–Mg–Cu alloy

Abstract

It is well known that wrought aluminium alloys have tensile properties superior to those of the cast products. Wrought grade alloys cannot usually be produced by conventional casting processes to attain the same level of tensile properties. However, progress in casting methods in recent years has made it possible to produce wrought alloys by means of squeeze casting techniques. In the present study an Al–Zn–Mg–Cu alloy has been produced by squeeze casting. Tensile properties close to those of wrought products have been achieved by controlling the microstructure, pressure, and other processing parameters.     

Effects of solidification structure on fatigue crack growth in rheocast and thixocast Al–Si–Mg alloys

Fatigue crack growth test was performed for rheocast and thixocast Al–Si–Mg aluminum alloys. At small stress intensity factor range (ΔK), fatigue crack growth (FCG) rate of sample with coarse acicular Si particles decreased slightly compared with specimen with small acicular Si particles. However, at large ΔK, fatigue crack growth rate of specimen with coarse acicular Si particles drastically increased. This is because large acicular Si particles induce high strain hardening at small ΔK, but such particles are easily cracked with the increase in ΔK. Morphology of the Si particles strongly affects striation formation.     

High- and low-cycle fatigue influence of silicon,copper, strontium and iron on hypo-eutectic Al–Si–Cu and Al–Si–Mg cast alloys used in cylinder heads

In this publication, ambient condition fatigue investigations with different types of Al–Si–Cu and Al–Si–Mg cast alloys in rotating-bending high-cycle fatigue (HCF) and push–pull low-cycle fatigue (LCF) regimes have been performed with varying Si, Cu, Fe and Sr contents. The cast alloys investigated here are common used in cylinder heads for automotive application. Because the cylinder head is one of the most fatigued parts in combustion chamber engines, the microstructural knowledge of the damage process provides a tool of construction and its material selection. The investigations were also supported with an in-situ microstructural crack observation in high plasticity rotating-bending regimes. The specimens were directly processed out of serial produced T79 heat-treated cylinder heads to provide the equal microstructure for testing as under operational conditions.The observations clearly identified the effects of the individual alloying elements both under low- and high-cycle fatigue. The crack propagation speed and the crack paths were majorly influenced by the eutectic silicon. Additional, the precipitation hardening due to copper affected significantly the fatigue endurance, too. In high plasticities the silicon’s influence got almost lost and only the matrix strength was crucial. Thus, increased fatigue strength in high loaded LCF regimes was observed for alloys with less copper content, thus higher ductility. By contrast, improved HCF and low loaded LCF endurance was only achieved when the matrix strength was increased by copper’s precipitation hardening. Crack branching and deflections strongly influenced the microstructural damage of the ductile AlSi7Mg(Sr) and hence, gained its fatigue strength. Iron phases could not identified as harmful inclusions, since the phases were similar in size of other hard phase elements like the other primary intermetallic phases like ${\text{Al}}_2\text{Cu}$ and β-$\text{Si}$ phases under notch stress aspects, by the well defined solidification process in the test section. Because the crack nucleation mainly occurred on Si particles, strontium as a refinement agent influenced the early crack onset and accordingly the fatigue in total. Thus, the AlSi6Cu4(Sr) had increased lifetimes compared to AlSi6Cu4 both in HCF and LCF. Further, the presented results provide a modification of the Manson–Coffin approach to describe the relationship between plastic strain and lifetime, valid for all proposed alloys with only one set of parameters. Thus, it was possible to perform the fatigue calculation with a reduced range of scatter.     

Effect of silver addition on formation of secondary phases in squeeze cast Al–Cu–Mg alloys

Abstract

The effect of silver addition on the formation of secondary phases in squeeze cast Al–4.0Cu–1.5Mg and Al–4.0Cu–1.5Mg–0.7Ag (all wt-%) alloys has been investigated using optical microscopy, scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffractometry, and transmission electron microscopy. The as cast microstructure of both alloys consists of primary dendritic α-Al and various types of secondary solidification phase, e.g. Al₂Cu, Al₂CuMg, Al(Cu,Ag)Mg, and icosahedral (I) and decagonal (D) quasicrystalline phases. However, the solidification path in the interdendritic region during squeeze casting is different for each alloy, i.e. L→ternary α-Al–Al₂Cu–Al₂CuMg eutectic in Al–4.0Cu–1.5Mg and L→L′+Al₂Cu→α-Al–Al₂Cu–Al(Cu_0.75Ag_0.25)Mg eutectic in Al–4.0Cu–1.5Mg–0.7Ag. This indicates that silver acts as an alloying element stabilising the formation of Al(Cu,Ag)Mg Laves phase. The remaining copper and iron rich liquid in the interdendritic region at the final stage of solidification solidifies into a mixed structure of α-Al, Al₂Cu, and AlCuFe I (or D) phases. The composition of the I and D phases, measured by energy dispersive X-ray spectroscopy, is in the range Al–(27～28)Cu–(9～10)Fe and Al–(26～27)Cu–(7～9)Fe (all at.-%) respectively.     

Relationships between microstructure and fatigue crack propagation paths in Al–Si–Mg cast alloys

Fatigue crack propagation of long and small cracks was investigated for hypoeutectic and eutectic Al–Si–Mg cast alloys. Crack propagation behavior in the near-threshold regime and Regions II and III was related to microstructural constituents namely primary α-Al dendrites and volume fraction and morphology of eutectic Si. Long crack thresholds reflect combined closure effects of global residual stress and microstructure/roughness. The small crack threshold behavior is explained through closure independent mechanisms, specifically through the barrier effects of characteristic microstructural features specific to each alloy. In Regions II and III changes in fracture surface roughness are associated with different crack propagation mechanisms at the microstructure scale. The extent of the plastic zone ahead of the crack tip was successfully used to explain the observed changes in crack propagation mechanisms.