贵州晴隆锑矿古油藏沥青稀土元素地球化学特征及意义

晴隆锑矿沙子岭火山岩型古油藏的发现,对晴隆锑矿床的成因研究乃至于金属矿和油气勘探均具有重要意义。本文分析了晴隆锑矿古油藏沥青的稀土元素地球化学特征,并将沥青与锑矿及围岩、区域烃源岩的稀土元素作对比分析,探讨古油藏与锑矿成矿关系。结果表明:古油藏中沥青稀土元素ΣREE低,轻重稀土分馏明显,Eu和Ce整体无明显异常,稀土配分属轻稀土富集右倾模式;沥青与锑矿及围岩稀土元素地球化学特征差异较大,二者在稀土质量分数、Ce异常以及配分模式均有明显差异,判定古油藏与锑矿成矿物质和成矿流体来源不同。结合流体包裹体和同位素测试等资料,通过对比沥青与区域烃源岩稀土元素特征,我们认为晴隆锑矿古油藏沥青与泥盆系泥质烃源岩有成因关系;古油藏在演化过程中提供了烃类气体(CH_4),使SO_4~(2-)还原出S~(2-)而参与成矿作用,形成辉锑矿。     

南盘江盆地中北部三叠纪深水盆地古水流方向研究

南盘江盆地位于中国广西、贵州、云南三省毗邻地区,为晚二叠世-三叠纪期间演化的海相沉积盆地,建立在晚二叠世开始的裂谷系统基础之上,进入三叠纪中期,盆地范围进一步扩展、海水深度进一步加深,盆地内部主要沉积了一套深水复理石,晚三叠世沉积环境为前陆盆地,在盆地北部沉积有碎屑岩和碳酸盐岩建造。针对南盘江盆地中北部深水复理石沉积,测量了鲍马序列C段中的小型斜层理、爬升层理、包卷层理轴面倒向、槽模等反映古水流方向的沉积构造的产状,通过野外和室内复平面校正、古流向玫瑰花图的绘制,对研究区三叠纪古流向进行了系统研究,共获得49组古流向测量数据,通过古流向分析并结合沉积环境演化特征,对南盘江盆地物源区进行了讨论。研究结果认为中三叠世期间盆地南部广南、底圩、八达、富宁一线物源区来自南部的越北古陆;盆地东部的巴马、龙川、望谟一线物源区来自于东部及北东的江南古陆;盆地北部物源区位于盆地西北部和北部的扬子台地内部;盆地的沉积中心位于册亨以南、潞城以北地区;隆林县城和西林县城之间、阳圩和剥隘之间存在古隆起。晚三叠世期间盆地北部古流向发生明显变化,应与构造体制的变化密切相关。     

吐鲁番盆地原油成因及地球化学特征

本文重点研究了我国西部吐鲁番盆地原油的有机地球化学特征,探讨了各类原油的形成环境及油源关系,并着重研究了煤成油及其判识特征。     

羌塘盆地毕洛错地区古油藏地球化学特征与油源对比

羌塘盆地是一个大型中生代海相沉积盆地,盆地内发育多套烃源岩,并发现多处古油藏和油气显示,确定古油藏油源对油气勘探至关重要.为明确古油藏油源,对古油藏和烃源岩样品进行地球化学分析.研究表明古油藏可分为2类:Ⅰ类古油藏整体处于成熟-高成熟阶段,C₂₄四环萜烷丰度较高,三环萜烷丰度低,C₂₉规则甾烷占有一定优势,C₂₉藿烷含量较高,体现出以陆源有机质贡献为主的特征.Ⅱ类古油藏整体处于低成熟-成熟阶段,以C₂₃三环萜烷为主峰,低丰度C₂₄四环萜烷,C₂₇规则甾烷占优势,表明母质来源以低等水生生物为主.油源对比表明,两类古油藏来源于不同的烃源岩,Ⅰ类油藏来自于上三叠统扎那组烃源岩,Ⅱ类油藏主要为下侏罗统曲色组烃源岩的贡献.      

金沙岩孔灯影组古油藏沥青有机地球化学特征及油源分析

为详细研究华南海相震旦系古油藏沥青来源,对金沙岩孔灯影组古油藏进行了系统解剖.古油藏沥青主要富集于灯影组上部砂屑白云岩、鲕粒白云岩及藻白云岩中,野外采集固体沥青呈块状富集,质地坚硬,有污手性,沥青主要赋存在白云岩晶间孔、铸模孔以及溶洞内,呈黑色固态物质产出,镜下观察沥青具镶嵌状结构特征.含沥青白云岩有机碳含量0.52%~1.89%,表明其较高的有机质含量.沥青受高温裂解及地表水淋滤氧化作用,氯仿沥青“A”及热解潜量较低,沥青有机碳同位素值为–33.22‰~–32.06‰, V/(V+Ni)比值较高为0.75~0.94,沥青反射率2.95%~3.86%,双反射明显,热演化程度高,大部分样品 H/C 比值小于0.5.综合研究表明,沥青在地质历史中曾经受了高温热演化作用,为原油高温裂解焦沥青.通过生物标志物、有机碳同位素、单体烃同位素及 V/(V+Ni)比值对比分析认为沥青来源于下寒武统牛蹄塘组黑色岩系.     

川西坳陷中段上三叠统须家河组储层沥青地球化学特征及成因研究

川西坳陷上三叠统须二、须四段致密砂岩的溶蚀孔洞、裂缝及砂岩层理界面上分布大量的沥青,沥青的热演化程度极高,须二段达到干气阶段,须四段达到湿气一干气早期阶段;经过针对砂岩中层理界面及裂缝、溶孔洞中充填的沥青及泥岩层裂缝中充填沥青取样的有机地球化学指标分析后显示:沥青具有较低的H/C、O/C比,须二段沥青残余生烃能力极小,须四段沥青还具有较大的残余生烃潜力;须家河组须二、须四段沥青为马鞍塘-小塘子组与须二段海湾相油型烃源岩在生油窗期成的古油藏,在后来的高温条件下裂解成天然气后残留物;须二,须四的古油藏构成了川西坳陷上三叠统须家河组天然气重要的气源.     

北部湾盆地流二段油页岩地球化学特征及成因

北部湾盆地涠西南凹陷和乌石凹陷流二段普遍发育油页岩。有机地球化学分析表明,北部湾盆地流二段油页岩具有高的有机质丰度,油页岩的有机碳含量下限为3%,含油率介于3.5%~10%,达到中等和优质油页岩矿品级,同时属于优质烃源岩。全岩有机显微组分、干酪根镜检和热解等分析表明,北部湾盆地流二段油页岩藻类含量丰富,藻类是有机质的主要来源,有机质类型主要为腐殖—腐泥型,部分为腐泥型,以湖相腐殖—腐泥型油页岩为主,部分为湖相腐泥型油页岩。流二段油页岩中镍和钼等微量元素含量普遍较高,镍和钼的含量与有机碳含量之间存在很好的正相关关系,说明流二段油页岩形成时期北部湾盆地具有富营养湖泊特征。北部湾盆地流二段油页岩中还原硫含量高,普遍大于1%,流二段油页岩形成于还原的沉积环境,具有很好的有机质保存条件。高有机质生产力及湖侵体系域顶部和高位体系域底部的中深湖还原环境共同控制了北部湾盆地流二段油页岩的发育。     

非洲乍得盆地火山岩地球化学特征及成因

钻井揭示了乍得盆地中新生代有大量玄武岩喷发,主要为橄榄拉斑玄武岩,少数为石英拉斑玄武岩和碱性橄榄玄武岩。主量、微量元素及Sr-Nd-Pb同位素地球化学研究表明,乍得盆地玄武岩岩浆在上升过程中经历了橄榄石、单斜辉石的分离结晶作用,且未受到陆壳物质的混染;岩石明显富集轻稀土元素、大离子亲石元素和高场强元素,Nb、Ta、Zr、Hf具正异常。晚白垩世玄武岩(⁸⁷Sr/⁸⁶Sr) _i比值（0.704167~0.706564）高于古近纪玄武岩（0.703545~0.705380）,(¹⁴³Nd/¹⁴⁴Nd)_i比值（0.512451~0.512703）低于古近纪玄武岩（0.512690~0.512847）;晚白垩世玄武岩ε_Nd(t)u值变化范围较大（-1.4~3.5）,且明显低于古近纪玄武岩（2.6~5.6）。两者具有相似的Pb同位素比值,²⁰⁶Pb/²⁰⁴Pb=18.14~18.96,²⁰⁷Pb/²⁰⁴Pb=15.56~15.62,²⁰⁸Pb/²⁰⁴Pb=38.33~38.88。乍得盆地玄武岩主要来自于亏损地幔DM和富集地幔EMⅡ两种端元组分混合产生的,石榴石橄榄岩的母熔体可能是本区玄武岩产生的源区,是地幔高度部分熔融的结果（15%左右）。乍得盆地玄武岩的地幔组份随时间的演化可能与中生代以来中、西非地区软流圈上涌、岩石圈减薄作用密切相关。     

羌塘盆地昂达尔错白云岩古油藏地质特征及成藏条件

昂达尔错白云岩古油藏位于羌塘盆地南羌塘坳陷,是羌塘盆地规模最大的古油藏带,对该区油气勘探具有重要意义。依据铸体薄片、储层物性、沥青族组分分析,剖析了白云岩古油藏地质特征。分析结果表明,昂达尔错古油藏的储集体可归类为低孔—低渗型到中孔—中渗型储层,为较好储层类型;其石油族组分呈现饱和烃含量低、非烃+沥青质含量高的特征,为芳香沥青型、芳香环烷型石油。划分出两套生储盖组合,其中的下侏罗统曲色组—中侏罗统布曲组组合为较好的生储盖组合类型,具有较好的勘探远景。认为古油藏在晚侏罗世成藏,在喜马拉雅期遭受逆冲破坏。     

川东北地区普光2井飞仙关组储层沥青地球化学特征及成因分析

根据储层中沥青的产状及类型、族组成、饱和烃色谱、生物标志化合物以及储层沥青反射率等,对普光2井飞仙关组储层固体沥青的地球化学特征及成因进行了详尽的剖析。研究结果表明,普光2井飞仙关组储层沥青为古油藏原油经裂解成气之后的残留物,属热演化的焦沥青。储层沥青的正构烷烃分布较为完整,碳数在C14~C30范围,没有受到明显的生物降解作用。Pr/Ph、Pr/nC17和Ph/nC18比值都小于1.0;OEP值1.25～1.43,CPI值0.98～1.19,无奇偶优势或偶奇优势;规则甾烷系列中C27化合物含量占优势,C27-C29规则甾烷呈不对称的“V”字型分布,甾烷异构化程度较低,明显低于异构化平衡值,认为是由于高、过成熟阶段S构型比R构型裂解速率更快的结果。飞一段、飞二段孕甾烷、升孕甾烷含量明显较飞三段高,可能是有机质生源或沉积环境性质上的不同所致。萜类化合物以五环萜烷为主,三环萜烷较为发育,其以C23三环萜烷为基峰,伽马蜡烷的含量较高。这些特征表明普光2井储层沥青主要来源于低等水生生物,有机质的热演化程度较高,主要处于高-过成熟阶段,有机母质形成于沉积水体咸度较高的海相沉积环境中。储层沥青中高含量25 降藿烷并非生物降解作用所致,而主要与源岩的热演化程度较高有关。     

南盘江盆地油气成藏过程及天然气勘探前景分析

本文采用多种研究手段探讨了南盘江盆地的多期成藏、破坏过程。根据有机质成油、成气和油成气的化学动力学模型,计算了南盘江盆地主要烃源岩的油气演化过程;并通过对沥青充填期次、包裹体研究和胶结物期次与沥青的关系,研究了古油藏经历的多期次充注、破坏过程,据此初步建立了南盘江盆地古油藏演化模式。从南盘江盆地古油藏演化过程来看,南盘江盆地油气勘探应以原油裂解的天然气为主,但是由于该地区具有聚气早、破坏时间长的特征,尤其是三叠系沉积之后的巨厚剥蚀使原油裂解气保存的可能性变小,因此在该地区形成大中型天然气藏的难度很大,天然气勘探前景需要进一步研究。     

Reserve and Pressure Change of Paleo-oil Reservoir in Puguang Area,Sichuan Basin

The Puguang (普光) gas field is the largest gas field found in marine carbonates in China.The Feixiangnan (飞仙关) and Changxing (长兴) reservoirs are two such reservoirs that had been buried to a depth of about 7 000 m and experienced maximum temperature of up to 220 ℃ before uplift to the present-day depth of 5 000-5 500 m,with present-day thermal maturity between 2.0% and 3.0% equivalent vitrinite reflectance (Ro).Bitumen staining is ubiquitous throughout the Feixianguan and Changxing formations,with the greatest concentrations in zones with the highest porosity and permeability,suggesting that the solid bitumen is the result of in-situ cracking of oil.According to the distribution of bitumen in the core,the paleo-oil boundary can be approximately determined.The paleo-oil resource is calculated to be about (0.61-0.92)×109 t (average 0.76×109 t),and the cracked gas volume is about (380.80-595.80)×109 m3 (average 488.30×109 m3); at least 58.74% of cracked gas is preserved in Puguang gas field.The study area experienced not only the cracking of oil but also thermochemical sulfate reduction,resulting in large quantities of nonhydrocarbon gas,with about 15.2% H2S and 8.3% CO2,together with the structural reconfiguration.During the whole process,the great change of volume and pressure compels the PVTsim modeling software to simulate various factors,such as the cracking of oil,the thermochemical sulfate reduction (TSR) and the tectonic uplift in both isolated and open geological conditions,respectively.The results show that although any one of these factors may induce greater pressure changes in an isolated system than in a closed system,the oil cracking and C3+involving TSR lead to overpressure during the early stage of gas reservoir.Therefore,the tectonic uplift and the methane-dominated TSR,as well as the semi-open system contribute to the reducing pressure resulting in the current normal formation pressure.     

四川盆地磨溪地区龙王庙组储层沥青的地球化学特征及其意义

根据储层中沥青的产状、元素组成、固体碳同位素、饱和烃色谱、生物标志化合物以及芳烃色谱-质谱等,对磨溪地区龙王庙组储层固体沥青的地球化学特征、成因及来源进行了剖析。研究结果表明,其总体上具有低H/C原子比值、高反射率的特征,是古油藏原油经裂解形成的残留物。储层沥青的正构烷烃分布较为完整,碳数在C₁₆-C₃₁范围,没有受到明显的生物降解作用。其可能的烃源岩发育于还原环境,有机质来源于低等水生生物,为海相泥页岩。固体沥青碳同位素值介于-33.1‰~-35.4‰之间,与下寒武统烃源岩干酪根碳同位素具有很好的可比性,同时,其生物标志化合物组成也与下寒武统烃源岩相似,表明其烃源来自于下寒武统筇竹寺组。     

Discovery and Analysis of Shale Gas in a Carboniferous Reservoir and its Enrichment Characteristics in the Northern Nanpanjiang Depression,Guizhou Province,China

Shale gas resources are considered to be extremely abundant in southern China, which has dedicated considerable attention to shale gas exploration in recent years. Exploration of shale gas has considerably progressed and several breakthroughs have been made in China. However, shale gas explorations are still scarce. Summary and detailed analysis studies on black shale reservoirs are still to be performed for many areas. This lack of information slows the progress of shale gas explorations and results in low quantities of stored black shale. The Carboniferous Dawuba Formation, which is widely distributed and considerably thick, is one of the black shale formations targeted for shale gas exploration in southern China in the recent years. The acquisition and analysis of total organic carbon, vitrinite reflectance,types of organic matter, mineral composition, porosity, and permeability are basic but important processes. In addition, we analyzed the microscopic pores present in the shale. This study also showesd the good gas content of the Dawuba Formation, as well as the geological factors affecting its gas content and other characteristics. To understand the prospect of exploration, we compared this with other shale reservoirs which have been already successfully explored for gas. Our comparison showesd that those shale reservoirs have similar but not identical geological characteristics.     

塔里木盆地寒武系白云岩的主要成因类型及其储层评价

塔里木盆地寒武系发育规模巨大的白云岩地层。对覆盖区钻孔岩心的岩石学分析表明,塔里木盆地寒武系白云岩成因主要有六种:潮坪相沉积成因、潟湖相沉积成因、渗透回流交代成因、压实排挤流交代成因、岩溶低温结晶成因和岩溶高温结晶成因。岩心物性分析与铸体薄片分析结果表明,岩溶低温结晶成因白云岩本质上可成为最优质的白云岩储层,储层特征为高孔高渗;潮坪沉积成因与岩溶高温结晶成因白云岩可形成高孔低渗的白云岩储层;潟湖相沉积成因白云岩、渗透回流交代成因白云岩与压实排挤流交代白云岩一般不作为优质的白云岩储层。     

南盘江盆地中三叠统复理石中的同沉积挤压构造——一类新的沉积构造的归类、命名和构造意义探讨

南盘江盆地在中三叠世时接受了厚达5000m的复理石沉积，而该复理石中保存有丰富的原生沉积构造。笔者等在这些沉积构造中识别并命名了一类新的构造——同沉积挤压构造，并用简单的实验定性地模拟了该类构造的形成机理。这些同沉积挤压构造包括：挤压皱纹、挤压岩枕、挤压裂隙和挤压皱脊，发育于复理石砂岩层的底面或泥岩层的顶面，是相关砂层或泥层沉积后到成岩前复理石盆地遭受挤压收缩的动态记录。根据这些同沉积挤压构造的方向初步判断，南盘江盆地在中三叠世接受复理石沉积的同时受到了SSW—NNE方向的挤压作用，盆地处于挤压收缩阶段。这些构造为复理石盆地的动态演化研究提供了新的证据。     

Geochemistry and genesis of heavy oil in the Erlian Basin

1Introduction StudyonheavyoilintheErlianBasin,NorthChi na,hasbeenreportedbysomescholars(DouLironget al.,1995;TangJietingetal.,1992),butthegene sisandformingmechanismofheavyoilneedtobefur therstudied.Thepapersyntheticallydiscussedthege ochemistry,genesisandinspissationseriesofheavyoil intheErlianBasinbaseduponalargenumberofsta tisticsdataonthephysicalpropertiesofdifferenttypes ofheavyoil,theGCanalysesofsaturatedandaromatic hydrocarbons,andtheGC MSanalysesofsteranesand terpanes. T…     

Geochemistry and Genesis of the Sodium-Charnockitic Gneisses, Eastern Hebei Province, China

High in sodium and low in potassium (Na_2O/ K_2O>1), the charnockitic gneiss series in theSantunying- Taipingzhai area, eastern Hebei province, consists of hypersthene- quartz- diorite,hypersthene-granodiorite and hypersthene-plagioclase-granite. Geological, petrological and large ion lithophileelement(LILE), high field strength element (HFSE) and REE geochemical studies suggest that themedium-coarse-grained hypersthene-granodiorite is the product of crystallization of anatectic magmas of thesame composition. Under granulite facies conditions, the equilibrium crystallization differentiation of themagmas yielded the early crystallization phase-high-SiO_2, LILE-depleted, low-∑REE, positive Eu anomalyand REE- saturated hypersthene- plagioclase- granite. The residual phase, coarse- grained to pegmatitichypersthene- granodiorite, is marked by low SiO_2, LILE-enrichment, high ∑REE and REE-undersaturation.These rocks and hypersthene-quartz-diorite enclaves constitute the sodium-charnockitic gneiss series in easternHebei province. Model calculation for trace elements in the granitoids was applied. On the basis of a systematicgeological study, the equation for calculation was chosen, the source magma was determined and the partitioncoefficients were obtained. The resulting curves are entirely consistent with those observed in the patterns of ac-tual rocks. The study indicates that whole-rock REE patterns can not be used directly in the comparison of thesources and genesis of granitoids.     

塔里木盆地英买力-哈拉哈塘地区奥陶系碳酸盐岩岩溶型储层特征及成因

塔里木盆地近期获得重大突破的英买力-哈拉哈塘地区奥陶系碳酸盐岩油气藏在很大程度上受岩溶型储层发育的控制,深入总结其储层特征及成因机制对油气勘探开发具有重要意义.通过大量的岩芯、薄片、阴极发光、常规测井、成像测井及测试分析等资料进行综合研究,认为该区储层的基质孔渗极差,难以形成有利的储集空间,而次生孔隙(溶蚀孔洞、洞穴、...