加热温度对管线钢奥氏体晶粒尺寸和铌固溶的影响

 研究了X70管线钢的原始奥氏体晶粒尺寸随加热温度的变化。通过测试淬火后回火硬度的方法分析了加热过程中铌的固溶。结果表明,随加热温度升高,原始奥氏体晶粒尺寸逐渐增大,并在1 200 ℃附近出现粗大晶粒,而钢中铌在1 150 ℃左右已基本固溶,由此对X70管线钢在控轧控冷工艺中加热温度的选择进行了探讨。     

加热温度对管线钢第二相粒子固溶及晶粒长的影响

高韧性管线钢主要用于制造石油和天然气输送管，这类钢采用控轧控冷工艺生产，具有良好的综合性能，文中对X60管线钢中第二相粒子随加热温度升高在钢中的固溶情况进行了定量分析，测试了奥氏体晶粒粗化 温度并对控轧控冷工艺中加强温度的选择进行了探讨。     

加热温度对钛微合金化钢奥氏体晶粒长大的影响

通过将钛微合金化钢在箱式电炉中加热至850~1 250℃保温30 min,观察其奥氏体晶粒组织及Ti的析出粒子分布情况,研究钛微合金化钢奥氏体晶粒长大行为及Ti的固溶规律。结果表明:随着加热温度的升高,试验钢存在两个奥氏体晶粒粗化温度,分别为1 050℃和1 250℃,与Ti两种析出粒子的固溶温度相对应,但数值比固溶温度低。分析奥氏体晶粒两个阶段的长大过程发现,随着TiC析出粒子的溶解,晶粒长大激活能从265.6 k J/mol降低至239.8 k J/mol。     

加热温度对管线钢第二相粒子固溶及晶粒长大的影响

高韧性管线钢主要用于制造石油和天然气输送管 ,这类钢采用控轧控冷工艺生产 ,具有良好的综合性能。文中对X6 0管线钢中第二相粒子随加热温度升高在钢中的固溶情况进行了定量分析 ,测试了奥氏体晶粒粗化温度并对控轧控冷工艺中加热温度的选择进行了探讨     

加热过程中X80管线钢奥氏体晶粒长大行为

通过改变均热温度和均热时间,来研究X80管线钢在不同热条件下的奥氏体晶粒的长大行为。分别得出均热温度和均热时问与奥氏体晶粒尺寸的关系。结果表明：随着均热温度和时间的升高与延长,先形成奥氏体晶粒开始长大。当均热温度低于1180℃时,奥氏体晶粒尺寸和长大速率较小,当温度高于1200℃时,奥氏体晶粒快速长大并出现晶粒反常长大。均热温度在1180℃时,奥氏体晶粒长大速率刚开始最大,然当均热温度超过1h后晶粒长大速率开始降低。     

再加热温度对含Nb，Ti钢第二相粒子固溶及晶粒长大的影响

 通过热力学计算和萃取复型分析技术,对高Ti含Nb钢中第二相粒子在不同加热温度下的固溶情况和奥氏体晶粒的长大规律进行了研究。结果表明：再加热温度低于1 180 ℃时,钢中Nb、Ti含量随温度升高显著增加。Nb、Ti固溶量分别在1 210 ℃和1 180 ℃以上趋于稳定;再加热温度在800~1 100 ℃时,以尺寸小于30 nm、分布较均匀的小粒子为主,呈球形,奥氏体晶粒尺寸在30 μm以下。再加热温度在1 180~1 210 ℃时,第二相粒子数量减少,尺寸多在100~200 nm之间,形态多为立方形和球形,奥氏体晶粒尺寸略微增加。随着再加热温度的进一步升高,析出粒子数量迅速下降,尺寸多为大于200 nm的方形粒子,此时奥氏体晶粒迅速长大至100 μm以上;析出粒子组成均为Nb、Ti复合的碳氮化物,其Nb/Ti原子比随温度升高而降低;试验钢的晶粒粗化温度为1 210 ℃,确定实际加热温度为1 180~1 210 ℃。     

加热温度对X80钢级弯管用管线钢板冲击韧性的影响

根据X80钢级管线钢原始奥氏体晶粒尺寸随加热温度的变化规律,通过工业性试验研究了不同加热温度对冲击韧性的影响。结果表明:因加热温度过高获得的粗大原始奥氏体晶粒在变形后依然粗大,相变后获得的组织相对粗大,不同原始奥氏体晶粒间获得组织具有明显的取向差,同时可以清晰看到原始奥氏体晶界,冲击断口为解理断口,严重影响X80钢级管线钢的冲击韧性。而加热温度较低时,原始奥氏体晶粒细小,断口为韧窝状,具有良好的冲击韧性。     

34CrMoV钢热变形对奥氏体晶粒尺寸的影响

通过Gleeble-1500热模拟实验机的物理模拟实验,研究了34CrMoV钢发生加工硬化、动态回复或动态再结晶时,奥氏体晶粒尺寸的变化规律,及变形量和高温停留时间对其奥氏体晶粒尺寸的影响．     

晶粒尺寸对高锰奥氏体TWIP钢氢脆行为的影响

主要研究了晶粒尺寸对Fe- 17Mn- 1Al- 0.6C TWIP钢的氢脆行为的影响。原始材料经过不同的热处理制度,得到晶粒尺寸为17和45μm的材料。通过慢拉伸试验研究氢质量分数在0～0.001%材料的氢脆敏感性。试验结果表明,充氢后的试验材料比未充氢试验材料易发生氢脆,充氢后的试验材料断裂强度和断裂应变均降低。随着晶粒尺寸的增大,试验材料的氢脆敏感性增强。在氢质量分数为0.001%,晶粒尺寸增加到45μm时,应变损失率为17%,随着晶粒尺寸的增大,氢脆敏感性增加的原因是晶粒尺寸较大的材料孪晶较早出现,孪晶密度较大,同时单位晶界氢质量分数增加。     

预备热处理对508-3钢奥氏体晶粒尺寸的影响

试验用钢508-3(/%:0.19C、0.26Si、1.48Mn、0.009F、0.007S、0.78Ni、0.50Mo、0.003Al)由真空感应炉冶炼,50kg铸锭,经1150℃锻成Φ16 mm棒材,终锻≥900℃。研究了正火温度(900～1 200℃)和多次正火工艺(900～1 200℃1 h-900℃1 h-890℃1 h)对508-3钢奥氏体晶粒尺寸的影响。结果表明,在900～1 200℃正火时,随着正火温度升高,奥氏体晶粒尺寸出现明显粗化,奥氏体晶粒度级别由6.5级粗化到3级。随后经过900℃二次正火,钢中原粗大的奥氏体晶粒可以细化到6级,再进行890℃三次正火后,奥氏体晶粒细化不明显。多次阶梯正火处理可以细化508-3钢粗大的奥氏体晶粒,但在同一温度重复正火时,钢中晶粒细化效果不明显。     

Controlling Properties of HSLA Line Pipe Steels for Oil and Gas Applications

DANIELI has recently implemented its Coil Quality Estimator (DANIELI-CQETM) system to the Hot Strip Mill of United Metallurgical Company (OMK) at Vyksa,Russia.This system is developed for the purpose of real time assessment and control of mechanical properties for hot rolled coils.Mechanical properties such as strength,toughness,ductility and hardness are predicted over the entire length of a strip while it is processed.The property estimation is based on the final microstructure as predicted from a group of interconnected physically based metallurgical models,supplemented by Artificial Neural Network.The CQE system is used for prediction and control of properties of HSLA line pipe grades steel and other grades.The system performance,is judged by accuracy and reliability of prediction,has been compared with the physical material testing data from the plant.The results are found to be excellent.CQE is found useful for generation of test certificate of coil,quality assurance,process control,product development,and customer claim assessment.It is used for resource optimization for production,and other operational improvements such as reduction of downgrades.The present paper shares the results of CQE performance for prediction of HSLA line pipe grade steels.     

可控硅中频感应加热在无缝钢管厂AG机组生产线上的应用

鞍钢无缝钢管厂采用新的工艺，在定径机前设中频感应加热炉，对钢管进行在线加热，在国内钢管厂属首例。此设计属环保型设计，占地面积小，节省燃料。具有稳定可靠、控制精确、保护功能齐全等特点，可对被加热的钢管进行精确的温度控制，确保加热后的钢管温度。     

Microstructure and Deformation Mechanics of X100 Line Pipe Steel

In present paper,microstructure is observed by means of OM,SEM,EBSD and TEM analysis on material obtained from X100 linepipe with wall thickness as 20.6mm and outside diameter as 1016mm diameter Grade 690.To study the deformation mechanics,microstructure transformation is also investigated on deformed specimens with different strain level as 0%,5% and 8%.Results show that X100 line pipe material consists mainly of acicular ferrite whose ratio in material reaches 64%,obvious cellular structures formed by tangled dislocation and M/A island distributed in acicular plates indicate abundant dislocation and substructure existed in material.It is measured that line pipe steel has a much finer effective grain size as 2.07μm,which can results in a higher strength and toughness for line pipe steel.Contrast analysis for Kikuchi Pattern reveals that the ratio of large-angle boundary is comparatively higher as 55%,implying that line pipe steel has a good toughness.It is observed that the proportion of small-angle grain boundary increases greatly after material deformed,which consequently results in the increment of dislocation and sub-structure.     

Investigation on Recrystallization Behavior of Cold-Rolled Silicon Steel in Continuous Heating with Three-Point Bending Testing

Understanding the recrystallization behavior of cold-rolled silicon steel during continuous heating is essential for optimizing continuous annealing parameters and accurately controlling material performance. To address the limitations of isothermal annealing studies in interpreting actual continuous annealing processes, this study investigates the recrystallization kinetics of Fe–2.3 wt%Si steel using a continuous heating three-point bending method. The method effectively determines the characteristic recrystallization temperatures. Interestingly, these recrystallization characteristic temperatures remain unaffected by the initial load but shift toward higher temperatures with increasing heating rates in the range of 5–15 °C min⁻¹. The average activation energy of recrystallization is estimated to be 144.5 kJ mol⁻¹, comparable to the value of 147.0 kJ mol⁻¹ obtained from the isothermal process through microhardness measurement. The recrystallization kinetics, described by an extended version of the Ozawa–Flynn–Wall model, exhibits excellent agreement with experimental evaluations. By combining the present processing technologies with continuous heating recrystallization kinetics, different recrystallization temperatures and times can be determined, offering valuable insights for optimizing annealing processes.     

X60钢级海底无缝管线管的研发

总结了X60钢级海底无缝管线管的研发工作,阐述了微合金化钢种的设计方法。归纳了生产控制过程中的难点,介绍了生产工艺流程和热处理工艺的制定,提出了进一步改进的观点。     

Analysis of Microstructure and Orientation in X80 Line Pipe Steels

Microstructures in X80 line pipe were classified by SEM analysis.The experimental results showed that the microstructures in X 80 line pipe steels were complicated consisting of polygonal ferrite,bainite and acicular ferrite.Orientation relation within acicular ferrite was investigated systematically by means of EBSD-OIM.The sub-structures were observed maximum in acicular ferrite which gives high strength and high toughness to line pipe steels.The K-S orientation relation was generally observed between acicular ferrite and austenite during phase transformation.The low energy CSL boundary characterized by Σ3 orientation relation according to Brandon criterion appeared with higher probability,which was benefit to improve the mechanical properties of line pipe steels.The orientations or texture of initial austenite grains could be deduced based on the Σ3 orientation relationship of acicular ferrite variants.     

X70管线钢的成分设计及其轧制工艺的控制

根据低碳-锰(Mn)-铌(Nb)合金系针状铁素体钢进行成分设计,并从加热温度、变形量、终轧温度、冷却速度和卷取温度等参数对轧制工艺加以控制,在本钢2300热连轧机组生产线一次试轧X70管线钢获得成功。检验结果表明,所生产的X70管线钢是以针状铁素体组织为主,并具有良好的机械性能。     

Mathematical Modelling on the Microstructure Evolution of X60 Line Pipe Steel during CSP Hot Rolling

 An integrated process modelling system for simulating the microstructure evolution of Nb-microalloyed HSLA steel produced in CSP hot rolling process has been developed on the basis of the microstructure simulation and mechanical properties prediction technology. Thermo-mechanical coupled finite element models for simulating hot strip rolling have been developed and the distribution of equivalent plastic strain through the thickness direction in the rolled material of CSP rolling was carried out. Thus the distribution of temperature, strain and strain rate through the thickness of the steel stocks, as well as the microstructure evolution during hot rolling of X60 line pipe steel strip have been investigated by using the developed integrated process modelling system. In addition the determination and optimization of controllable process parameters during CSP hot strip rolling for the Nb-microalloyed X60 line pipe steel have been implemented, and control strategies such as adopting larger pass reduction in the first stand, and arranging appropriate pass interval times and proper rolling speed, to reduce or eliminate mixed-grains microstructure of Nb microalloyed strip in CSP processing have been proposed.