Thermal analysis of solar thermal energy storage in a molten-salt thermocline

A comprehensive, two-temperature model is developed to investigate energy storage in a molten-salt thermocline. The commercially available molten salt HITEC is considered for illustration with quartzite rocks as the filler. Heat transfer between the molten salt and quartzite rock is represented by an interstitial heat transfer coefficient. Volume-averaged mass and momentum equations are employed, with the Brinkman-Forchheimer extension to the Darcy law used to model the porous-medium resistance. The governing equations are solved using a finite-volume approach. The model is first validated against experiments from the literature and then used to systematically study the discharge behavior of thermocline thermal storage system. Thermal characteristics including temperature profiles and discharge efficiency are explored. Guidelines are developed for designing solar thermocline systems. The discharge efficiency is found to be improved at small Reynolds numbers and larger tank heights. The filler particle size strongly influences the interstitial heat transfer rate, and thus the discharge efficiency.     

A method to determine stratification efficiency of thermal energy storage processes independently from storage heat losses

A new method for the calculation of a stratification efficiency of thermal energy storages based on the second law of thermodynamics is presented. The biasing influence of heat losses is studied theoretically and experimentally. Theoretically, it does not make a difference if the stratification efficiency is calculated based on entropy balances or based on exergy balances. In practice, however, exergy balances are less affected by measurement uncertainties, whereas entropy balances can not be recommended if measurement uncertainties are not corrected in a way that the energy balance of the storage process is in agreement with the first law of thermodynamics. A comparison of the stratification efficiencies obtained from experimental results of charging, standby, and discharging processes gives meaningful insights into the different mixing behaviors of a storage tank that is charged and discharged directly, and a tank-in-tank system whose outer tank is charged and the inner tank is discharged thereafter. The new method has a great potential for the comparison of the stratification efficiencies of thermal energy storages and storage components such as stratifying devices.     

Experimental research on thermal characteristics of a hybrid thermocline heat storage system

Considering the high-temperature thermal utilization of solar energy as the research background in this paper and focussing on the heat storage process, a kind of hybrid thermocline heat storage method in multi-scale structure and relevant experimental systems are designed by using the mixed molten nitrate salt as the heat storage medium and two representative porous materials, i.e. zirconium ball and silicon carbide (SiC) foam, as the heat storage fillers. The fluid flow and heat storage performance of molten salt in multi-scale structure are experimentally investigated. The results show that the theoretical heat storage efficiencies amongst the three experimental heat storage manners are less than 80% because of the existence of thermocline layers. Comparing to the single-phase molten salt heat storage, the two hybrid thermocline heat storage manners with porous fillers lead to a certain decrease in the effective heat storage capacity. The presence of porous fillers can also help to maintain the molten salt fluid as ideal gravity flow or piston flow and partially replace expensive molten salt. Therefore, it requires a combination of heat storage capacity and economical consideration for optimization design when similar spherical particles or foam ceramics are employed as the porous fillers.     

Thermal property characterization of a low melting-temperature ternary nitrate salt mixture for thermal energy storage systems

Molten salts have better thermal properties than synthetic mineral oil, and hence they can be directly used as heat transfer fluids in solar power plants, but in practice their direct applications as heat transfer fluids are constrained due to their high freezing temperature points. In this paper, a class of ternary nitrate salt mixtures consisting of 50-80 wt% KNO₃, 0-25 wt% LiNO₃ and 10-45 wt% Ca(NO₃)₂ were processed and tested. Experimental results indicated that some mixtures within this range exhibited excellent thermal properties, such as a low melting point (<100 °C), robust reliability, high-temperature stability (upto 500 °C) and a low viscosity (e.g.,<5 cP at 190 °C). Apart from these desirable thermo-physical properties, the manufacturing cost of these novel inorganic salts HTFs (Heat Transfer Fluids) is considerably lower than those of the existing commercial heat transfer fluids (HTFs).     

Methods to determine stratification efficiency of thermal energy storage processes - Review and theoretical comparison

This paper reviews different methods that have been proposed to characterize thermal stratification in energy storages from a theoretical point of view. Specifically, this paper focuses on the methods that can be used to determine the ability of a storage to promote and maintain stratification during charging, storing and discharging, and represent this ability with a single numerical value in terms of a stratification efficiency for a given experiment or under given boundary conditions. Existing methods for calculating stratification efficiencies have been applied to hypothetical storage processes of charging, discharging and storing, and compared with the rate of entropy production caused by mixing calculated for the same experiments. The results depict that only one of the applied methods is in qualitative agreement with the rate of entropy production, however, none of the applied methods is in agreement with the rate of entropy production and also able to distinguish between the entropy production caused by mixing and the entropy changes due to heat losses.     

Recent progress in thermal energy storage materials

本文结合储热材料的分类、特点、应用及存在的问题对储热材料的最新研究进展进行了综述,主要包括有机相变储热材料、熔融盐类相变储热材料、合金相变储热材料及复合类储热材料。探讨了储热材料成分组成、制备工艺及性能特点,进一步介绍了其最新研究进展,并对储热材料的下一步研究进行了展望,提出开发高性能纳微复合结构储热材料是未来研究的重点。     

Concentrating solar thermal power as a viable alternative in China's electricity supply

Study of low-carbon and pollution renewable alternatives for China revealed that concentrating solar thermal (CST) electric power generation was underemphasized in China's renewable energy plan. The analysis shows the competitive viability of CST: (1) China has the key prerequisites to make CST power generation economical including high-quality insolation and appropriate land, (2) CST's proven history, scale, and dispatchability makes it a good utility-scale power option, especially in the economically underdeveloped Western regions, (3) while CST power is currently more expensive than coal-fired electricity on a nominal basis, when costs of externalities are accounted for, CST, at 11.4 US cents/kWh, can become 57% cheaper than scrubbed coal and 29% cheaper than nuclear power, (4) CST power continues dropping in cost due to economies of scale and technological improvements and can potentially realize a levelized electricity cost of around 4 cents/kWh within ten years, (5) it would significantly rise in competitiveness if and when China completes the extensive smart grid for connecting its solar-abundant western regions with the high-demand eastern regions, (6) CST has the potential to positively impact Western China's economy, but proper policy and deal structure must be in place to ensure that the local community shares the benefit.     

The potential of metal hydrides paired with compressed hydrogen as thermal energy storage for concentrating solar power plants

Concentrating solar power (CSP) plants require thermal energy storage (TES) systems to produce electricity during the night and periods of cloud cover. The high energy density of high-temperature metal hydrides (HTMHs) compared to state-of-the-art two-tank molten salt systems has recently promoted their investigation as TES systems. A common challenge associated with high-temperature metal hydride thermal energy storage systems (HTMH TES systems) is storing the hydrogen gas until it is required by the HTMH to generate heat. Low-temperature metal hydrides can be used to store the hydrogen but can comprise a significant proportion of the overall system cost and they also require thermal management, which increases the engineering complexity. In this work, the potential of using a hydrogen compressor and large-scale underground hydrogen gas storage using either salt caverns or lined rock caverns has been assessed for a number of magnesium- and sodium-based hydrides: MgH₂, Mg₂FeH₆, NaMgH₃, NaMgH₂F and NaH. Previous work has assumed that the sensible heat of the hydrogen released from the HTMH would be stored in a small, inexpensive regenerative material system. However, we show that storing the sensible heat of the hydrogen released would add between US$3.6 and US$7.5/kWh_th to the total system cost for HTMHs operating at 565 °C. If the sensible heat of released hydrogen is instead exploited to perform work then there is a flow-on cost reduction for each component of the system. The HTMHs combined with underground hydrogen storage all have specific installed costs that range between US$13.7 and US$26.7/kWh_th which is less than that for current state-of-the-art molten salt heat storage. Systems based on the HTMHs Mg₂FeH₆ or NaH have the most near term and long term potential to meet SunShot cost targets for CSP thermal energy storage. Increasing the operating temperature and hydrogen equilibrium pressure of the HTMH is the most effective means to reduce costs further.     

Large-scale hydrogen energy storage in salt caverns

Large-scale energy storage methods can be used to meet energy demand fluctuations and to integrate electricity generation from intermittent renewable wind and solar energy farms into power grids. Pumped hydropower energy storage method is significantly used for grid electricity storage requirements. Alternatives are underground storage of compressed air and hydrogen gas in suitable geological formations. Underground storage of natural gas is widely used to meet both base and peak load demands of gas grids. Salt caverns for natural gas storage can also be suitable for underground compressed hydrogen gas energy storage. In this paper, large quantities underground gas storage methods and design aspects of salt caverns are investigated. A pre-evaluation is made for a salt cavern gas storage field in Turkey. It is concluded that a system of solar-hydrogen and natural gas can be utilised to meet future large-scale energy storage requirements.     

Heating and cooling of a hospital using solar energy coupled with seasonal thermal energy storage in an aquifer

A system is being designed, using solar energy in combination with Aquifer Thermal Energy Storage (ATES), that will conserve a major part of the oil and electricity used for heating or cooling the Cukurova University, Balcali Hospital in Adana, Turkey. The general objective of the system is to provide heating and cooling to the hospital by storing solar heat underground in summer and cold in winter. As the main source of cold energy, ventilation air at the hospital and surface water from the nearby Seyhan Lake will be used.     

Thermal energy storage technologies and systems for concentrating solar power plants

This paper presents a review of thermal energy storage system design methodologies and the factors to be considered at different hierarchical levels for concentrating solar power (CSP) plants. Thermal energy storage forms a key component of a power plant for improvement of its dispatchability. Though there have been many reviews of storage media, there are not many that focus on storage system design along with its integration into the power plant. This paper discusses the thermal energy storage system designs presented in the literature along with thermal and exergy efficiency analyses of various thermal energy storage systems integrated into the power plant. Economic aspects of these systems and the relevant publications in literature are also summarized in this effort.     

Lessons learnt during the design,construction and start-up phase of a molten salt testing facility

In 2010, CIEMAT (Centro de investigaciones energéticas medioambientales y tecnológicas) signed a turn-key contract to have an experimental plant for thermal storage using molten salts at its PSA (Plataforma Solar de Almeria) facilities. This plant was designed to evaluate components, instrumentation and operation strategies and to give support to the industry in the qualification and evaluation of components.During the design, construction and start-up phases of this plant, many different aspects regarding design, construction and commissioning have been learnt and these will contribute to the improvement of other plants.Among other tips explained in the paper, we recommend the use of venting valves to eliminate the water present in the system after the pressure test or released by the salts during the first melting. The selection of instrumentation with no electronic components near a heat source, thus preventing them from overheating, is also advisable. The heat exchanger design and dimensioning should take into account not only the thermal losses to the atmosphere and through pipes and supports, but any possible reduction in the heat exchange surface that could have detrimental consequences in the thermal performance.Special attention must be paid when dimensioning and installing the EHT and insulation because both components are decisive in the avoidance of plug formation. Its correct installation in valves and supports and the proper positioning of the temperature control sensors, i.e. where no other heat source can distort the readings, are crucial.Recommendations and strategies for the operation and shutdown of this experimental plant are being gathered for a future paper.     

Analysis of CSP plants for the definition of energy policies: The influence on electricity cost of solar multiples,capacity factors and energy storage

The effect on the cost of electricity from concentrating solar power (CSP) plants of the solar multiple, the capacity factor and the storage capacity is studied. The interplay among these factors can be used to search for a minimal-cost objective that can serve as a technical criterion to guide in the design of economic incentives for CSP plants. The probability-density function of irradiation is used in conjunction with screening models to evaluate the performance characteristics and costs of concentrating solar power plants. Two technologies have been analyzed in this study: parabolic-trough and tower plants. The results provide information to define the optimal operational range as a function of the desired objective. Thus, it is possible to derive a technical criterion for the design of CSP plants which optimizes the solar electricity produced and its generation cost. The methodology is applied to Spain, and the analysis of the results shows that a solar energy production of 37 kWh/m²/year for tower plants and 66 kWh/m²/year for parabolic-trough ones define the approximate optimal working conditions for the mean DNI in Spain.     

Generalized charts of energy storage effectiveness for thermocline heat storage tank design and calibration

Solar thermal energy storage is important to the daily extended operation and cost reduction of a concentrated solar thermal power plant. To provide industrial engineers with an effective tool for sizing a thermocline heat storage tank, this paper used dimensionless heat transfer governing equations for fluid and solid filler material and studied all scenarios of energy charge and discharge processes. It has been found that what can be provided through the analysis is a series of well-configured general charts bearing curves of energy storage effectiveness against four dimensionless parameters grouped up from the storage tank dimensions, properties of the fluid and filler material, and operational conditions (such as mass flow rate of fluid and energy charge and discharge periods). As the curves in the charts are generalized, they are applicable to general thermocline heat storage systems. Engineers can conveniently look up the charts to design and calibrate the dimensions of thermocline solar thermal storage tanks and operational conditions, without doing complicated modeling and computations. It is of great significance that the generalized charts will serve as tools for thermal energy storage system design and calibration in energy industry.     

Solar thermal storage systems using phase change materials

Using Fourier series expansion of the involving temperatures and the forcing parameters i.e. the solar radiation and the ambient temperature, an iterative procedure has been developed to solve the heat transfer problem with moving boundaries. Calculations specific to a typical summer and winter day in Delhi have been presented for a numerical appreciation of the developed analysis. Experiments have been performed to validate the developed theoretical analysis. A good agreement is seen between theoretical and experimental results with in the domain of the applicability of theory.     

Latent heat storage for solar energy systems: Transient simulation of refrigerant storage

This paper presents a brief review of the available latent heat storage systems for solar energy utilization. A new concept of latent heat storage of solar energy via the refrigerant-absorbent mass storage in absorption cycle heat pump systems used for solar space heating/cooling has been proposed and assessed thermodynamically. A computer modelling and numerical simulation study shows that the concept of refrigerant storage is fundamentally sound, technically feasible and yields the following advantages over other storage methods: (i) the storage capacity per unit volume is high as the latent heat of vaporization of the refrigerant is high; (ii) the heat loss from the storage to the surroundings is minimum as the storage temperature is near the ambient; (iii) prolonged energy storage is possible with no degradation in system performance and hence suitable for combined solar heating and airconditioning. The effects of operating parameters on the energy storage concentration and storage efficiency have been studied in detail.     

Numerical study on thermal energy storage performance of phase change material under non-steady-state inlet boundary

Due to the solar radiation intensity variation over time, the outlet temperature or mass flow rate of heat transfer fluid (HTF) presents non-steady-state characteristics for solar collector. So, in the phase change thermal energy storage (PCTES) unit which is connected to solar collector, the phase change process occurs under the non-steady-state inlet boundary condition. In present paper, regarding the non-steady-state boundary, based on enthalpy method, a two dimensional physical and mathematical model for a shell-and-tube PCTES unit was established and the simulation code was self-developed. The effects of the non-steady-state inlet condition of HTF on the thermal performance of the PCTES unit were numerically analyzed. The results show that when the average HTF inlet temperature in an hour is fixed at a constant value, the melting time (time required for PCM completely melting) decreases with the increase of initial inlet temperature. When the initial inlet temperature increases from 30 °C to 90 °C, the melting time will decrease from 42.75 min to 20.58 min. However, the total TES capacity in an hour reduces from 338.9 kJ/kg to 211.5 kJ/kg. When the average inlet mass flow rate in an hour is fixed at a constant value, with the initial HTF inlet mass flow rate increasing, the melting time of PCM decreases. The initial inlet mass flow rate increasing from 2.0 × 10⁻⁴ kg/s to 8.0 × 10⁻⁴ kg/s will lead to the melting time decreasing from 37.42 min to 23.75 min and the TES capacity of PCM increasing from 265.8 kJ/kg to 273.8 kJ/kg. Under all the studied cases, the heat flux on the tube surface increases at first, until it reaches a maximum then it decreases over time. And the larger the initial inlet temperature or mass flow rate, the earlier the maximum value appearance and the larger the maximum value.     

Short communication simple transient thermal model for solar colector/storage water heaters

This note presents a simple transient model for predicting the thermal performance of some novel solar water heaters which combine both collection and storage of solar energy. These heaters consist of either (i) an insulated rectangular tank whose top surface is blackened and suitably glazed, or (ii) an insulated open shallow tank with black bottom/inner sides and a top glass cover (shallow solar pond). the heaters are adequately covered with an insulation during the night to reduce the heat losses. the proposed model is based on different characteristic equations during sunshine and off-sunshine hours. It is seen that the model predicts the water temperature in close agreement with the experimental observations and earlier theoretical investigations.     

An integrated thermal and mechanical investigation of molten-salt thermocline energy storage

Thermal ratcheting is a critical phenomenon associated with the cyclic operation of dual-medium thermocline tanks in solar energy applications. Although thermal ratcheting poses a serious impediment to thermocline operation, this failure mode in dual-medium thermocline tanks is not yet well understood. To study the potential for the occurrence of ratcheting, a comprehensive model of a thermocline tank that includes both the heterogeneous filler region as well as the composite tank wall is formulated. The filler region consists of a rock bed with interstitial molten salt, while the tank wall is composed of a steel shell with two layers of insulation (firebrick and ceramic). The model accounts separately for the rock and molten-salt regions in view of their different thermal properties. Various heat loss conditions are applied at the external tank surface to evaluate the effect of energy losses to the surroundings. Hoop stresses, which are governed by the magnitude of temperature fluctuations, are determined through both a detailed finite-element analysis and simple strain relations. The two methods are found to yield almost identical results. Temperature fluctuations are damped by heat losses to the surroundings, leading to a reduction in hoop stresses with increased heat losses. Failure is prevented when the peak hoop stress is less than the material yield strength of the steel shell. To avoid ratcheting without incurring excessive energy loss, insulation between the steel shell and the filler region should be maximized.