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ADP晶体{100}面族二维成核生长微观形貌的AFM研究 总被引:1,自引:0,他引:1
ADP晶体{100}面族微观形貌的非实时AFM(atomic force microscopy,AFM)成像表明,过饱和度σ=0.053时,晶面上出现二维成核生长;随σ增加至0.11,二维岛数量急剧增加,尺寸减小,分布渐趋均匀,二维成核生长逐渐增强,界面呈现出由光滑向粗糙转变的特征;各二维岛形状趋近于长条形,表现出各向异性,长轴平行于[001]晶向;二维岛上有单分子高度的台阶和台阶聚并后高度为2~3nm的大台阶;二维岛间融合时取向相同;σ=0.053时,融合后所形成的较大二维岛的生长呈现出周边快中心慢的情况,将可能导致产生晶体缺陷. 相似文献
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pH值对水热合成HA晶须形貌的影响 总被引:2,自引:0,他引:2
研究了不同pH值条件下水热法制备羟基磷灰石晶须的形貌特征。采用X射线衍射仪(XRD),场发射扫描电子显微镜(FESEM)等分析了pH值对HA晶须组成、形貌和结构的影响。结果表明,在水热条件下,可以成功地合成结晶度高、组成均一的羟基磷灰石晶须。随着pH值的提高,a轴方向尺寸上升,c轴方向基本不变,长径比减小。在微观形貌上羟基磷灰石逐渐由针状向球状形态转变。在pH值=7~8之间,合成的羟基磷灰石晶粒尺寸变化不大,稳定性较高,适合工业化生产。还初步讨论了HA的生长机制。 相似文献
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pH值对氢氧化镁晶体生长的影响 总被引:5,自引:0,他引:5
以氯化镁(分析纯)为原料,反向滴加到氨水中制备普通氢氧化镁,然后在200℃反应釜中对普通氢氧化镁进行水热改性.通过扫描电镜(SEM),X射线多晶衍射仪(XRD),全自动氮物理吸附仪(BET)和激光粒度仪等对样品进行表征分析,得到不同pH条件下晶体生长情况和产品收率.结果表明,常温沉淀过程中pH值为10.0时,产品收率高,粒径分布均匀,分散性好.并且分析了pH值对氢氧化镁晶体生长作用机理. 相似文献
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pH值对镀铁层性能及结构的影响 总被引:2,自引:0,他引:2
研究了在不同PH值条件下所获得的无刻蚀镀铁层的硬度,金相组织及耐蚀性,结果表明,在PH值为0.7时,镀铁层致密,结合割固,具有最佳的结构及性能,镀铁层的织构最强,且随pH值的升高而增强。 相似文献
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亚硫酸铵镀金具有镀层密实、分散能力和深镀能力好、沉积逯度快和外观悦目等优点,所以已成为工业镀金中一种较重要的工艺方法。但pH值较难控制和调整,槽液稳定性差及污染环境等问题至今尚未引起人们的重视。 相似文献
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硫酸羟胺和pH值对低温磷化过程的影响 总被引:2,自引:0,他引:2
利用多种方法研究了硫酸羟胺(HAS)和pH值对低温锌系磷化过程的影响,结果表明,HAS是一种非常好的低温磷化促进剂,可以使钢铁材料在低温下生成黑灰色均匀的磷化膜.但是其含量并不是越多越好,而是存在一个峰值.pH值的大小是成膜的一个重要因素,过大或过小均不能成膜;另外pH值对HAS的用量也有影响,pH值大时需要的HAS量多,小时所需量少. 相似文献
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Jianxu Ding Shenglai Wang Xinguang Xu Qingtian Gu Xun Sun Yiping Li Bo Wang Guangxia Liu Wenjie Liu Yun Sun 《Journal of Materials Science》2012,47(13):5232-5240
Potassium dihydrogen phosphate (KDP) single crystals doped with molybdate (MoO4
2−) were grown via the conventional temperature cooling and rapid growth methods, respectively. MoO4
2− made KDP crystals tapering for conventional temperature cooling method. When KDP crystals were grown by rapid growth method,
MoO4
2− could induce liquid inclusions and simultaneous crystals. The measurement on growth rates indicated that MoO4
2− broadened the dead zone and decreased the growth rate of (100) face of KDP crystals. The growth kinetic analysis in terms
of two-dimensional nucleus and screw dislocation models implied that the energetic parameter γ/kT decreased with an increase of MoO4
2− concentration. The influence of MoO4
2− growth steps on (100) face of KDP crystal was observed through ex situ AFM technique. It gave evidence that MoO4
2− could postpone the step bunching and make the step edge curving and knaggy to reduce the edge free energy, which was in agreement
with the growth kinetics calculations. Additionally, the poisoned mechanism of MoO4
2− and Fe3+ on step morphologies was detailed contrasted. The interaction process was discussed according to electro negativity analysis,
which indicated MoO4
2− (actually were HMoO4
− and H2MoO4) could be absorbed onto (100) face through charge-assisted hydrogen bonds and caused more Mo element distributed in prismatic
sector. 相似文献
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STM, LEED, AES, TDS and Δ? measurements were performed to investigate the adsorption of Ni on the molybdenum (111) surface. The adsorption energy of Ni atoms on the Mo(111) surface was determined. At 300 K the layer-by-layer growth mechanism was observed. No faceting of the Mo(111) surface was observed after the annealing. Annealing leads to the adsorbate agglomeration and formation of Ni islands in the shape of pyramids. 相似文献
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Andrew J. Francis 《Thin solid films》2006,496(2):317-325
Pulsed laser deposition has been used to grow epitaxially oriented thin films of Cu and Pt on (100)-oriented SrTiO3 and LaAlO3 substrates. X-ray diffraction results illustrated that purely epitaxial Cu(100) films could be obtained at temperatures as low as 100 °C on SrTiO3 and 300 °C on LaAlO3. In contrast, epitaxial (100)-oriented Pt films were attained on LaAlO3(100) only when deposited at 600 °C. Atomic force microscopy images showed that films deposited at higher temperatures consisted of 3D islands and that flat, layered films were obtained at the lowest deposition temperatures. Importantly, Cu films deposited at 100 °C on SrTiO3(100) were both purely (100)-oriented and morphologically flat. Pt and Cu films displaying both epitaxial growth and smooth surfaces could be obtained on LaAlO3(100) only by using a three-step deposition process. High-resolution transmission electron microscopy demonstrated an atomically sharp Cu/SrTiO3 interface. The crystalline and morphological features of Cu and Pt films are interpreted in terms of the thermodynamic and kinetic properties of these metals. 相似文献
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《Materials Letters》1988,7(4):127-130
The growth of PbTe films on GaAs by molecular beam epitaxy was studied by reflection high energy diffraction. The strains in the films were investigated by X-ray diffraction. Despite a lattice mismatch of 14.2%, oriented films can be grown up to a thickness of 4000 Å. For thicker films the thermal strain causes cracks if the samples are cooled from growth to liquid-nitrogen temperature. 相似文献
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Noriaki Murakami Koji Arafune Tadanobu Koyama Yoshimi Momose Tetsuo Ozawa Yasunori Okano Sadik Dost Le. H. Dao Masashi Kumagawa Yasuhiro Hayakawa 《Microgravity science and technology》2005,16(1-4):79-83
The effect of gravity on dissolution of GaSb in InSb melt and growth of InGaSb was experimentally investigated. Experiments were carried out in a GaSb(seed)/InSb/GaSb(feed) sandwich system under an imposed temperature gradient. In the experiments, the GaSb feed crystal dissolved into the InSb melt to supply the required GaSb component for the growth of In0.1Ga0.9Sb crystal. Two parameters were considered: (1) the inclination angle (θ) of the sample for gravity as 0° and 53°, and (2) the sample diameter (D) as 9 mm and 5mm. When θ was 0°, the interface was almost flat, indicating that convection was axisymmetric and stable. Whereas the interface was distorted towards gravitational direction when θ was 53°, indicating that solutal convection was dominant. The decrease of growth temperature and sample diameter reduced the distortion of interface and the dissolution amount of GaSb feed. The homogeneous crystals were grown at the initial growth stage by supplying the GaSb component during growth. 相似文献
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Arrays of (Ga,Mn)As crystal nanowires on a GaAs (100) substrate were first obtained using molecular-beam epitaxy at 485°C. From the diffraction patterns of the reflected fast electrons, it was found that crystal nanowires are formed in this system in a cubic crystallographic phase. 相似文献
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The oxidation of a CoGa(100) surface at high temperatures has been studied by scanning tunnelling microscopy (STM) and auger electron spectroscopy (AES). When CoGa(100) is oxidised at a sufficiently high temperature (>600 K), an ordered Ga2O3 film is formed. The stability of the film depends on the sample temperature and partial oxygen pressure of the ambient gas. At negligible oxygen pressure (<10−11 mbar) the oxide is stable up to 850 K. At an oxygen pressure of 10−6 mbar the oxide is stable up to 930 K and some of the oxide remains present up to 970 K. The oxide film is found to be very uniform. The thickness of the film is constant and independent of the oxidation temperature (600 K<T<930 K), oxygen pressure (<10−6 mbar), and exposure (10−4–10−2 mbar.s≈102–104 L). We find a clear improvement of the order of the oxide film surface with increasing oxidation temperature. In STM images, a domain structure of the oxide film is observed. The size of the domains increases by a factor of 5–10 when the oxidation temperature is increased from 700 to 900 K. 相似文献