钛合金表面激光熔覆Ni基梯度涂层的研究

为了改善Ti6Al4V钛合金表面耐磨性能和抗高温氧化性能,采用CO2激光在Ti6Al4V钛合金表面进行激光熔覆Ni基梯度涂层试验.利用扫描电镜和显微硬度计等手段分析了熔覆层组织,测试了基体和熔覆层的显微硬度.结果表明,采用适当的工艺参数,可以在钛合金表面获得连续、均匀、无裂纹和气孔的熔覆层.熔覆层组织由树枝晶和晶间共晶组织构成,并与基体形成牢固的冶金结合.由基体到表面,显微硬度过渡平稳,呈明显梯度渐变特征.     

基底材料对NiCrBSiC合金激光熔覆层组织和磨损性能的影响

采用横流CO2激光在45钢和TC4钛合金表面熔覆NiCrBSiC合金涂层,利用XRD,SEM和TEM分析了激光熔覆层的微观组织,测试了激光熔覆层的硬度和摩擦磨损性能.结果表明,NiCrBSiC合金激光熔覆层的组织和性能与基底材料的种类密切相关.45钢表面激光熔覆层由γ-Ni,Ni3B,Cr7C3和CrB相组成,硬度在HV800～900之间;TC4合金表面激光熔覆层由γ-Ni,Ni3B,TiC和TiB2相组成,硬度在HV900～1100之间.TC4合金表面NiCrBSiC激光熔覆层的摩擦系数和质量磨损率分别低于45钢表面NiCrBSiC激光熔覆层的摩擦系数和质量磨损率.     

钛合金表面激光熔覆技术的研究进展

金属表面激光熔覆技术是近年来发展起来的一种新型表面处理工艺.利用高能激光束对材料表面瞬间加热和熔池快速冷却的特性,在钛合金表面用激光熔覆一层陶瓷增强复合材料,能够显著提高钛合金的耐磨性能.简要阐述了金属表面激光熔覆工艺、钛合金表面激光熔覆技术及其在未来的发展方向.     

钛合金表面激光熔覆TiC/NiCrBSi涂层温度场有限元模拟

为在钛合金表面获得优质激光熔覆涂层,用有限元方法研究了激光熔覆工艺对熔池温度场分布和凝固后熔覆层组织的影响,考虑相变潜热、辐射对流散热以及温度对热物理性能的影响等因素,建立三维有限元模型模拟了Ti6Al4V合金表面激光熔覆TiC/NiCrBSi复合涂层过程中的温度场,并结合熔覆过程的温度场分布,对涂层的形貌、结合区、基...     

Ti6Al4V钛合金表面Ni60-10％hBN激光熔覆层的摩擦学性能

为了提高Ti6Al4V钛合金的摩擦学性能,以Ni60-hBN混合粉末为原料,对其表面进行激光熔覆,并与Ni60粉末激光熔覆层进行了对比,分析了2种熔覆层的物相组成、显微组织;在2,5,8N下测试了2种熔覆层的干滑动磨损性能.结果表明:在2～8N内,Ni60熔覆层和Ni60-10 ％hBN熔覆层的摩擦系数和磨损率均随载荷的增加先减小后升高,在5N时,Ni60-10％ hBN熔覆层具有优异的自润滑耐磨效果.     

铜和铜合金表面激光熔覆最新研究及进展

激光熔覆由于瞬间加热温度高,对工件热影响小而广泛应用于铜及其合金的表面改性。从熔覆材料体系、熔覆层质量与制备工艺、熔覆层组织与性能(主要包括耐磨性、耐电蚀性、耐腐蚀性和导电性)三方面综述了铜和铜合金表面激光熔覆的最新研究进展,指出了铜表面激光熔覆存在的主要问题是铜对激光的反射率,并对今后的研究方向进行了展望。     

面向轴件应用的激光熔覆修复强化试验研究

轴件是机械设备的关键基础构件之一,由于服役环境的影响,其表面磨损、划伤和腐蚀是常见的损伤形式.通过采用激光熔覆工艺,开展了轴件修复及强化的试验研究.为给后续激光熔覆修复工程化应用奠定工艺和理论基础,针对表面缺陷去除方式,研究了梯形和弧形挖槽对覆层与基体的结合特征的影响,分析了修复后覆层与基体界面处成分及硬度的梯度分布、熔覆层与基体复合体的拉伸性能、室温及高温下的磨损行为.结果表明:激光熔覆工艺是轴件修复强化的可行技术手段.     

2205钢表面激光熔覆Ni基+WC合金涂层的研究

采用激光熔覆技术在2205双相不锈钢表面制备Ni基与WC合金熔覆层,并对添加不同WC含量的合金粉末在相同激光熔覆工艺参数下的合金熔覆层进行成分和性能分析,探讨不同WC添加量对熔覆层微观组织、耐腐蚀性能及硬度的影响。研究结果表明:激光熔覆层与基体之间获得了良好的冶金结合,熔覆层与基体元素有较好的对流和扩散;熔覆层的耐腐蚀性能随WC添加量的增加呈负相关,在WC添加量为15%时,熔覆层的耐腐蚀性能最差;熔覆层的硬度值从熔覆层至基体呈梯度降低趋势,熔覆层硬度约为基体硬度的2~3倍,而单一熔覆Ni基WC合金层硬度值变化较大。     

激光熔覆技术研究进展

首先从激光熔覆用设备与材料、熔覆层的性能以及工业应用等方面,综述了国内外激光熔覆技术的研究动态与进展.其中,着重介绍了激光熔覆层的性能,如耐磨、耐蚀、耐高温等.随后指出了激光熔覆技术目前存在的一些技术难题,如熔覆层的开裂与剥落、工件的变形、不完整的熔覆层材料体系以及轻金属的熔覆质量等问题.最后展望了激光熔覆技术的发展前景,并针对目前该技术存在的问题指明了今后的发展方向.     

激光熔覆与等离子熔覆的镍基合金熔覆层组织和性能对比

在低碳钢等廉价金属表面熔覆一层高强高韧或高耐蚀性的熔覆层可极大提高材料的使用性能及利用率,但是不同熔覆方法对熔覆层组织和性能可能会造成不同影响。利用激光熔覆和等离子熔覆技术分别在Q345基材表面熔覆镍基合金粉末,获得具有一定厚度的熔覆层。通过对2种熔覆方法获得的熔覆层进行微观组织、冲击韧性以及耐磨损性能对比分析可知,激光熔覆镍基合金的熔覆层组织细密,冲击吸收功略低于等离子熔覆试样,但稳定性优于等离子熔覆层,耐磨损性能及表面硬度明显优于等离子熔覆层。     

Research status of laser cladding on titanium and its alloys: A review

Titanium and its alloys are restricted in the field of application. Laser cladding, as a kind of surface modification technique, is employed to fabricate coatings with improved wear resistance, high temperature oxidation resistance and good biocompatibility on titanium and its alloys. Apart from laser cladding process parameters, material selection is vital to obtain the improved properties mentioned above. In this paper, recent developments of different material system are summarized and the developments in laser cladding for functional coatings with high wear resistance, good corrosion and oxidation resistance, and better medical biocompatibility are reviewed. Besides, the existing problems and the corresponding solutions are discussed. Finally, the trend of development in the future is forecasted.     

钛合金激光表面熔覆的研究与进展

钛合金具有优异的高比强,良好的抗腐蚀、蠕变、疲劳和韧性,但其表面抗磨性能差,不能作为机械零件使用,大大限制了其性能潜力的发挥.为提高钛合金的表面性能,激光熔覆技术在钛合金表面上进行了相关的研究,获得了陶瓷相增强的高硬度金属基体复合涂层,为钛合金在机械零件上的应用提供了理论基础.本文综述了近几年来钛合金激光熔覆技术的状况,存在的问题,提出进一步研究的方向.     

粉末钛合金的表面强化技术

低硬度和低耐磨性限制了钛合金尤其是粉末钛合金的实际应用.表面强化技术是提高粉末铁合金表面性能的有效手段之一.综述了近年来为提高钛合金表面硬度和耐磨性而采用的典型的表面强化技术,如激光表面改性、激光熔覆涂层、微孤氧化、离子注入、双层辉光离子渗和高频感应处理等.讨论了每种工艺方法的特点及其所获得表面强化层的结构和性能.最近,乌克兰国家科学院提出氮环境下钛合全的淬水技术,为钛合金表面强化提出了一个新的发展方向.     

钛合金干滑动摩擦行为与磨损机理研究进展

钛合金因具有高的比强度、比刚度,良好的耐蚀性和耐热性等优点,在航空航天、化工、能源等领域广泛应用,但钛合金存在表面硬度低、抗塑性剪切能力较差、不易加工硬化以及表面氧化物保护作用较差等缺陷,使其耐磨性较差,阻碍了其在耐磨损领域的发展。为了提高钛合金自身的耐磨性潜力和扩大其应用领域,本文主要概述了近年来国内外有关钛合金干滑动摩擦磨损领域的研究现状,讨论了影响钛合金摩擦磨损性能的主要因素以及在不同条件下的磨损机理,并对钛合金干滑动摩擦磨损行为的研究进行了展望。     

Lasergaslegieren – ein Verfahren zur Erzeugung verschleißfester Randschichten auf Titanwerkstoffen

Laser gas alloying – manufactoring process for wear resistant layers on titanium alloys Titanium alloys combine very high specific strength with biocompatibility and corrosion resistance. Because of these excellent properties they were frequently used in space travel, aeronautics, chemical industry, medicine and, increasingly, automotive industry. A handicap of titanium alloys is their low wear resistance against abrasive and sliding wear. Additional applications for titanium alloys can be established by increasing their wear resistance High loadable and wear resistant layers on titanium alloys are generated by the new method for laser gas alloying, developed at the Fraunhofer IWS Dresden. The new method overcomes drawbacks of conventional methodes and is a reliable process for industrial application. By a hard amorphous carbon layer (DLC), deposited by Laser-Arc, an additional increase of sliding wear resistance is possible. First we briefly present the methode itself. The enormous increase of wear resistance is proven with the help of diverse wear tests.     

生物医用超弹性β型钛合金研究现状

新型β钛合金具有良好的耐磨性和力学性能、高抗腐蚀性以及优良的生物相容性,因而在生物医学领域得到了越来越广泛的应用.综述了钛合金的发展阶段及新型超弹性β钛合金的研究发展状况和最新进展,探讨了几种热处理工艺对钛合金超弹性的影响,介绍了几种钛合金表面改性方法,结合我国研究现状提出了新型超弹性β钛合金存在的问题,展望了其研究发展方向.     

Cr3C2 incorporation into an Inconel 625 laser cladded coating: Effects on matrix microstructure,mechanical properties and local scratch resistance

There is an increasing industrial demand for metal alloys with high wear resistance under severe operating conditions. Ni-based alloys, such as Inconel superalloys, are an excellent option for these applications; however, their use is limited by their high cost. Ni-based coatings deposited onto carbon steel substrates are being developed to achieve desired surface properties with reduced cost. Laser cladding deposition has emerged as an excellent method for processing Ni based coatings. In this work, microstructure, mechanical properties and local wear behaviour have been investigated in response to the addition of Cr₃C₂ ceramic particles into an Inconel 625 alloy deposited onto a ferritic steel substrate by laser cladding. Using this deposition technique, a homogeneous distribution of Cr₃C₂ particles was observed in the coating microstructure. The addition of ceramic particles to the starting powder resulted in the formation of hard precipitates in the coating microstructure. The partial dissolution of Cr₃C₂ particles during the laser cladding process increased the hardness of the Inconel 625 matrix. Depth sensing indentation and scratch tests were performed to study the local wear behaviour and scratch resistance of the cermet matrix compared with the conventional Inconel 625 alloy. Finally, the effect of Cr₃C₂ on mechanical properties was correlated with the observed microstructure modifications.     

铁碳合金表面激光熔覆的研究进展

激光熔覆技术具有加热速度快、熔覆过程中产生的热影响区小、基体表面温度低等优点,因此能够较好地保证零部件的尺寸精度,近年来发展成广泛应用的表面改性技术。激光熔覆技术对涂层粉末以及基材选择要求不高,因此广泛应用于不同种类基体材料的再制造修复。从铁碳合金材料出发,分别对激光熔覆技术在改善铸铁、碳钢及合金钢材料的力学性能、耐磨性、耐蚀性、抗热疲劳性等方面的应用进展和存在的问题及对策进行了分析,阐明了工艺参数、材料成分以及工件的预热或后处理对制备高质量大熔覆层组织和性能的影响规律,最后指出了激光熔覆技术在目前研究中存在的问题并对其未来发展方向进行了展望。     

Verschleißschutz für Titanbauteile

Wear Protection for Titanium Components The use of titanium and its alloys in the last decades keeps on increasing due to its material‐specific characteristics like high firmness, good corrosion characteristics and very high thermal maximum stress. However nowadays, the use of titanium components in systems where wear resistance is important is limited by titanium’s relatively low wear resistance. Surface wear is in principle a characteristic, conditioned by chemical and physical effects of the elements involved as well as collective stress. The necessity for new systems where good wear resistance and excellent mechanical properties are combined keeps on showing up. Due to titanium’s tendency to react with surrounding media, titanium alloys are difficult to be welded. Embrittlement by admission of hydrogen and oxygen can occur at high temperature processes or even changes on titanium’s microstructure may appear. Brazing techniques, which are actually applied to steel, have been modified and adapted for using them to titanium materials. Here, commercially available braze pastes and hard materials where combined and applied on titanium.