青海省扎日根结扎群火山岩形成时代及构造背景分析

青海扎日根结扎群火山岩中基性岩以贫硅、钾,高钛、钙,中性岩类以低硅、中钾、钛、钙,酸性岩类以高硅、钾,中钛,低钙为特征。根据Fe＊/MgO-TiO2图解上显示出本区火山岩绝大多数火山岩落在岛弧区。微量元素中Th/Nb=0.9〉0.11,Nb/Zr〉0.04显示出其构造背景为陆-陆碰撞形成的岛弧区。扎日根结扎群火山岩时代Rb-Sr同位素等时线给出的年龄为231±28Ma和225±8 Ma,属晚三叠世。另外Sr同位素的初始比值ISr=0.70522±0.00023,小于0.719,表明岩浆（原始）来源于上地幔,并且在上升的过程中受到地壳的混染。     

Evolution of an englacial volcanic ridge: Pillow Ridge tindar, Mount Edziza volcanic complex, NCVP, British Columbia, Canada

Glaciovolcanic deposits are critical for documenting the presence and thickness of terrestrial ice-sheets, and for testing hypotheses about inferred terrestrial ice volumes based on the marine record. Deposits formed by the coincidence of volcanism and ice at the Mount Edziza volcanic complex (MEVC) in northern British Columbia, Canada, preserve an important record for documenting local and possibly regional ice dynamics. Pillow Ridge, located at the northwestern end of the MEVC, formed by ice-confined, fissure-fed eruptions. It comprises predominantly pillow lavas and volcanic breccias of alkaline basalt composition, with subordinate finer-grained volcaniclastic deposits and dykes. The ridge is presently  4 km long,  1000 m in maximum width, and  600 m high. Fifteen syn- and post-eruptive lithofacies are recognized in excellent exposures along the glacially dissected western side of the ridge. We recognize five lithofacies associations: (1) poorly sorted tuff breccia and dykes, (2) proximal pillow lava, dykes and tuff breccia, (3) distal pillow lava, poorly sorted conglomerate and well-sorted volcanic sandstone, (4) interbedded tuff, lapilli tuff, and tuff breccia units, and (5) heterolithic volcanogenic conglomerate and sandstone. Given the abundance of pillow lavas and the lack of surrounding topographic barriers capable of impounding water, we agree with Souther [Souther, J.G., 1992. The late Cenozoic Mount Edziza volcanic complex. Geol. Soc. Can. Mem., vol. 420. 320 pp] that the bulk of the edifice formed while confined by ice, but have found evidence for a more complex and variable eruption history than that which he proposed. Preliminary estimates of water-ice depths derived from FTIR analyses of H₂O give ranges of 300 to 680 m assuming 0 ppm CO₂, and 857 to 1297 m assuming 25 ppm CO₂. Variations in depth estimates among samples may indicate that water/ice depths changed during the evolution of the ridge, which is consistent with our interpretations for the origins of different lithofacies associations. Given that the age of the units are likely to be ca. 0.9 Ma [Souther, J.G., 1992. The late Cenozoic Mount Edziza volcanic complex. Geol. Soc. Can. Mem., vol. 420. 320 pp], Pillow Ridge may be the best documentation of a regional high stand of the Cordilleran Ice Sheet (CIS) in the middle Pleistocene, and an excellent example of the lithofacies and stratigraphic complexities produced by variations in water levels during a prolonged glaciovolcanic eruption.     

Platinum-group element geochemistry of mafic rocks from the Dongchuan area,southwestern China

Mafic intrusions and dykes are well preserved in the Yinmin and Lanniping districts,located within the western margin of the Yangtze Block,SW China.Although these mafic rocks from the two areas formed during different periods,they share similar ranges of PGE concentration.Most of the Yinmin gabbroic dykes contain relatively high PGE concentrations(PGEs = 13.9-87.0 ppb) and low S contents(0.003%-0.020%),higher than the maximum PGE concentrations of mafic magmas melting from the mantle.Two exceptional Yinmin samples are characterized by relatively low PGE(PGEs = 0.31-0.37 ppb) and high S(0.114%-0.257%) contents.In contrast,most samples from the Lanniping gabbroic intrusion have low PGE concentrations(PGEs — 0.12-1.02 ppb) and high S contents(0.130%-0.360%),except that the three samples exhibit relatively high PGE(PGEs = 16.3-34.8 ppb) and low S concentrations(0.014%-0.070%).All the Yinmin and Lanniping samples are characterized by the enrichment of PPGE relative to IPGE in the primitive-mantle normalized diagrams,and the high-PGE samples exhibit obvious Ru anomalies.This study suggests that during the ascent of the parental magma,removal of Os-Ir-Ru alloys and/or chromite/spinel leads to high Pd/Ir ratios and Ru anomalies for the Yinmin high-PGE samples and relatively lower Pd/Ir ratios and Ru anomalies for the Lanniping low-PGE samples.We propose that the magmas parental to the Yinmin gabbroic dykes are initially S-unsaturated,and subsequently,minor evolved magma reached sulfur saturation and led to sulfide segregation.Although the Lanniping parental magmas are originally not saturated in S,the high Cu/Pd ratios(3.8 × 10~4 to 3.2 ×10~6) for most of the Lanniping samples indicate the S-saturated state and sulfide segregation.A calculation shows that the PGE-poor magmas might have experienced 0.01%-0.1% sulfide segregation in the magma chamber.Therefore,our study provides a possible opportunity to discover PGE-enriched sulfide mineralization somewhere near or within the Lanniping mafic intrusion.     

The eruptive history of the Mascota volcanic field,western Mexico: Age and volume constraints on the origin of andesite among a diverse suite of lamprophyric and calc-alkaline lavas

The Mascota volcanic field is located in the Jalisco Block of western Mexico, where the Rivera Plate subducts beneath the North American Plate. It spans an area of ∼ 2000 km² and contains ∼ 87 small cones and lava flows of minette, absarokite, basic hornblende lamprophyre, basaltic andesite, and andesite. There are no contemporary dacite or rhyolite lavas. New ⁴⁰Ar/³⁹Ar ages are presented for 35 samples, which are combined with nine dates from the literature to document the eruptive history of this volcanic field. The oldest lavas (2.4 to 0.5 Ma) are found in the southern part of the field area, whereas the youngest lavas (predominantly < 0.5 Ma) are found in the northern portion. On the basis of these ages, field mapping, and the use of ortho aerial photographs and digital elevation models, it is estimated that a combined volume of 6.8 ± 3.1 km³ erupted in the last 2.4 Myr, which leads to an average eruption rate of ∼ 0.003 km³/kyr, and an average volume per eruptive unit of < 0.1 km³. The dominant lava type is andesite (2.1 ± 0.9 km³), followed by absarokite (1.6 ± 0.8 km³), basaltic andesite (1.2 ± 0.5 km³), basic hornblende lamprophyre (1.0 ± 0.4 km³), and minette (0.9 ± 0.5 km³). Thus, the medium-K andesite and basaltic andesite comprise approximately half (49%) of the erupted magma, with twice as much andesite as basaltic andesite, and they occur in close spatial and temporal association with the highly potassic, lamprophyric lavas. There is no time progression to the type of magma erupted. A wide variety of evidence indicate that the high-MgO (8–9 wt.% ) basaltic andesites (52–53% wt.% SiO₂) were formed by H₂O flux melting of the asthenopheric arc mantle wedge, whereas the mafic minettes and absarokites were formed by partial melting (induced by thermal erosion) of depleted lithospheric mantle containing phlogopite-bearing veins. There is only limited differentiation of the potassic magmas, with none more evolved than 55.4 wt.% SiO₂ and 4.4 wt.% MgO. This may be attributable to rapid crystallization of the mantle-derived melts in the deep crust, owing to their low volumes. Thus, the andesites (58–63 wt.% SiO₂) are notable for being both the most voluminous and the most evolved of all lava types in the Mascota volcanic field, which is not consistent with their extraction from extensively crystallized (60–70%), low-volume intrusions. Instead, the evidence supports the origin of the andesites by partial melting of amphibolitized, mafic lower crust, driven by the emplacement of the minettes, absarokites, and the high-Mg basaltic andesites.     

Kos Plateau Tuff (KPT) on Kalymnos island, Aegean volcanic arc: A geochemical approach

Thirteen pumice samples from the D and E ignimbrite units of Kalymnos Tuff have been analyzed for their biotite and feldspar phenocryst mineral chemistry and for bulk major and 20 trace, including 14 Rare Earth elements, to define and compare their petrochemistry with the Kos Plateau Tuff (KPT). For the same purpose major element analyses were obtained from Kalymnos Tuff and KPT glasses. Both KPT and Kalymnos pumice lapilli are rhyolites characterized by a well-developed ‘silky’ texture and roundish quartz. Phenocrysts of biotite and feldspars (sanidine, oligoclase) from both tuffs display compositional overlap. Crystals are charac-terized by undulatory extinction (quartz), fractures (sanidine, oligoclase) and bent cleavages (biotite) due to the explosive origin of their host. Both tuffs show well-defined petrogenetic trends and extensive compositional overlaps on major and trace element variation diagrams suggesting that they are consanguineous. However, D ignimbrite samples are more evolved than those obtained from E ignimbrite as indicated from major elements, alkali earths (Ba, Rb, Sr), immobile (Zr, Y), compatible (V) and hygromagmatophile trace element (Th) distributions. This evidence indicates a stratified magma chamber under a ～16 Km caldera superstructure which is mostly submarine.     

Methana,the westernmost active volcanic system of the south Aegean arc (Greece): Insight from fluids geochemistry

An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers.     

Miocene and pliocene volcanic rocks of the addis ababa-debra berhan area (ethiopia). Geo-petrographic and radiometric study

North and south of the long basaltic range running from Addis Ababa to Debra Berhan (Ethiopia) there are large ignimbritic plateaux which are very similar both morphologically and lithologically, and which are considered to be stratigraphically equivalent by previous researchers. Accurate geological reconstructions and many radiometric age determinations have allowed these plateaux to be distinguished into two distinct ignimbritic formations. The first corresponds to the most recent rocks (Miocene) of the « Alaji Series », and the second to the Pliocene « Balchi Series ». The two formations are separated from one another by basalts attributable to the « Termaber » central-type volcanism taking place in the Addis Ababa-Debra Berhan area more recently than in other parts of the Ethiopian plateau.     

Transition from mildly-tholeiitic to calc-alkaline suite: the case of Chichontepec volcanic centre, El Salvador, Central America

The Chichontepec volcano is a Plio-Pleistocene composite volcano that erupted lavas ranging from high-alumina basalts to dacites. It experienced a caldera-forming paroxysmal eruption during the early Pleistocene. Pre-caldera lavas are mildly tholeiitic and they evolved mainly by low pressure crystal fractionation, notwithstanding the fact that most mafic lavas (low-MgO high-alumina basalts) retain traces of polybaric evolution. Conversely, post-caldera lavas, which are mainly pyroxene andesites, are clearly calc-alkaline, having evolved by open-system crystal fractionation. Sr–Nd isotopic data and trace elements characteristics indicate that the same mantle source was involved in the petrogenesis of these series. Modelling the AFC process showed that it did not play any role in the petrogenesis of these rocks; a crystal fractionation model is considered to be more relevant. A slight variation in the fractionating assemblage could have caused the transition from an early mildly tholeiitic trend to a late calc-alkaline one. Mineralogical evidence, mass-balance calculations and elemental chemistry support this hypothesis, assuming that the greater amount of pyroxene on the liquidus is at the expense of plagioclase; this would have prevented the trend in iron enrichment.     

Petrology of tholeiitic lavas from Tanna Island (New Hebrides): Importance of cumulative processes in Island arc magmatism

Tanna, one of the southernmost islands of the New Hebrides volcanic arc, is made of Late Pliocene to Recent island arc tholeiitic basalts and andesites, with SiO₂ contents ranging from 45 to 57%. These lavas are highly porphyritic (30–50% in volume): phenocrysts of plagioclase are the most abundant, together with olivine and clinopyroxene. The groundmass contain plagioclase, augite, olivine, magnetite and glass; pigeonite, tridymite, sanidine and, rarely, biotite may also occur. The olivines and clinopyroxenes show an iron enrichment from the cores of phenocrysts to their rims and the groundmass crystals, but their compositional variations are not correlated with the Mg/Fe ratio of bulk host rocks, the most Fe-rich compositions being found in Mg-rich lavas. Plagioclase compositions range from An₉₅ to An₆₀ in the basalts and An₆₀ to An₅₀ in the andesites, but, within each group, they are not correlated with SiO₂ or Na₂O contents of host lavas. Consequently, the bulk major element compositions of Tanna volcanic rocks cannot be considered as primarily controlled by crystal separation from successive liquids. The oxyde-SiO₂ variations diagrams, and the modal compositions and mineral chemistry show that crystal accumulation is the predominant mechanism accounting for bulk rock compositions. However, this does not exclude fractional crystallization: the variation of the calculated groundmass mineralogy strongly suggest the occurrence of crystal removal mainly clinopyroxene and magnetite.     

Carboniferous tectono-magmatic evolution of the northern Luliang arc: evidence from geochemistry and petrography of Carboniferous volcanic rocks in the northern Luliang Uplift,NW China

The Northern Junggar Basin experienced extensive subduction and a complex tectono-magmatic evolution during the Late Paleozoic,resulting in a heterogeneous distribution of volcanic rocks in the Junggar Basin.In this study,the Carboniferous tectono-magmatic evolution of the northern Luliang arc was described by exploring the petrography and geochemistry of Carboniferous volcanic rocks collected from well Y-2 and outcrop WW' in the northern Luliang Uplift.The distribution,types,and formation ages of these volcanic rocks were characterized and the volcanic sequence in well Y-1 was divided into upper and lower parts according to vertical variations in selected geochemical data.Then the petrogenesis and tectonic settings of different volcanic rocks were evaluated and this was used to infer the tectonomagmatic evolution of the northern Luliang arc during the Carboniferous.The results indicate that:(1) Carboniferous high-K calc-alkali andesite-dacite associations are distributed in the west of the northern Luliang Uplift,and Lower Carboniferous calc-alkali basalt-dacite-rhyolite assemblages are preserved in its east.(2) The intermediateacid volcanic rocks in wells Y-1 and Y-2 were derived from calc-alkali basaltic magma through melting of the juvenile lower crust,and geochemical variations indicate increasing addition of slab melting in a subduction-related arc environment.The bimodal volcanic rocks from outcrop WW' were derived from lithospheric underplating of basaltic magma in an intra-arc extensional setting.(3) The closure of the eastern Keramaili Oceanic basin occurred before the Early Carboniferous,and the tectono-magmatic difference between the east and the west of the northern Luliang Uplift appeared before the Carboniferous period.     

Alkaline igneous rocks,a potential source of rare metals and radioactive minerals:Case study at Amreit area,south Eastern Desert,EgyptOA

Alkaline igneous rocks represent one of the most economically important resources of radioactive minerals and rare metals.New field observations and petrographic studies are integrated with whole-rock geochemical analyses and Gamma ray spectroscopy data of alkaline rocks associated with the Amreit complex.The fieldwork was achieved by the collection of more than forty samples from alkaline granites and alkaline syenites.The youngest rocks cropping out in the study area are the cogenetic alkaline rocks,ranging from alkaline granite to alkaline syenite.These alkaline rocks are composed essentially of K-feldspar,alkali amphiboles （arfvedsonite）,and sodic pyroxene,with accessories such as zircon,apatite,and ilmenite.Mineral characterization of the highly radioactive zones in both alkaline granite and alkaline syenite displays enrichment in monazite,thorite,zircon,ferro-columbite,xenotime,and allanite minerals.Geochemical analyses indicate that the Amreit rocks are alkaline with peralkaline affinity and have high concentrations of total alkalis （K₂O+Na₂O）,large ion lithophile elements （LILEs;Ba and Rb）,high field strength elements（HFSEs;Y,Zr and Nb）,rare earth elements （REEs） and significantly depleted in K,Sr,P,Ti,and Eu,typically of post-collision A-type granites.Typically,the Amreit alkaline igneous rocks are classified as within plate granites and display A2 subtype characteristics.The fractionation of K-feldspars played a distinctive role during the magmatic evolution of these alkaline rocks.The geochemical characteristics indicate that the studied alkaline igneous rocks which were originated by fractional crystallization of alkaline magmas were responsible for the enrichment of the REE and rare metals in the residual melt.The high radioactivity is essentially related to accessory minerals,such as zircon,allanite,and monazite.The alkaline granite is the most U-and Thrich rock,where radioactivity level reaches up to 14.7 ppm（181.55 Bq/kg） e U,40.6 ppm （164.84 Bq/kg） e Th,whereas in alkaline syenite radioactivity level is 8.5 ppm （104.96 Bq/kg） e U,30.2 ppm （122.61 Bq/kg） e Th.These observations suppose that these alkaline rocks may be important targets for REEs and radioactive mineral exploration.     

Lead isotopic study of the Xigaze ophiolite (Tibet): the problem of the relationship between magmatites (gabbros,dolerites, lavas) and tectonites (harzburgites)

The Pb isotopic study of the Xigaze ophiolite (Tibet) shows that the tectonic (harzburgites) and magmatic (gabbros, dolerites, lavas) units bear different isotopic signatures, the harzburgitic rocks show much higher²⁰⁷Pb/²⁰⁴Pb values than the samples from the magmatic unit. Analyses of primary magmatic clinopyroxenes separated from the harzburgites confirmed that this difference is real and not due to secondary alteration processes. UPb analysis allowed determination of the crystallization age of the magmatites at 120 ± 10 m.y. This age is compatible with paleontological age determinations and thus demonstrates that UPb behaved more or less as a closed system since formation of the ophiolite. If an exchange with seawater has occurred, it must necessarily have happened shortly after crystallization of the Xigaze oceanic crust. Dolerite dykes crossing the harzburgites show similar Pb isotopic composition as the magmatites, indicating that they were emplaced when the ultramafic rocks were already brittle; however, the time difference of the emplacement was probably not larger than 280 m.y. This makes it evident that two sources with different isotopic signatures, one similar to normal MORB, the other with much higher²⁰⁷Pb/²⁰⁴Pb ratios, were active in the immediate neighborhood. One possible environment which can account for this association is a propagating ridge.     

Caldera-scale inflation of the Lazufre volcanic area, South America: Evidence from InSAR

Collapsed calderas are the structural surface expression of the largest volcanic eruptions on Earth and may reach diameters of tens of kilometres while erupting volumes larger than 1000 km³. Remnants of collapse calderas can be found along the South American volcanic arc and are thought to be inactive. However, this study shows that systems of such dimension may become active in a relatively short period of time without attracting much attention. Using satellite-based InSAR data, a 45 km wide elongated area of ground deformation was observed in the Lazufre volcanic region (Chile), where no deformation was detected 10 years ago. The deformation signal shows an uplift of up to ~ 3 cm yr^− 1 during 2003–2006, affecting an area of about 1100 km², comparable in size to super-volcanoes such as Yellowstone or Long Valley. This deformation signal can be explained by an inflating magma body at about 10 km depth, expanding and propagating laterally at a velocity of up to 4 km per year. Although it is not clear whether this intrusion will lead to an eruption, its dimensions and the rapid deformation rate insinuate that a potentially large volcanic system is forming.     

Nd-Sr systematics of the Setouchi volcanic rocks,southwest Japan: a clue to the origin of orogenic andesite

Twenty-three volcanic rocks from the Setouchi volcanic belt, southwest Japan, were analyzed for Nd and Sr isotopic compositions for the purpose of examining the genetic relationships among the basalt, high-magnesium andesite (HMA) and evolved porphyritic andesite. The andesites have higher⁸⁷Sr/⁸⁶Sr (0.70487–0.70537) and lower¹⁴³Nd/¹⁴⁴Nd (0.512509–0.512731) than the basalts, i.e., 0.70408–0.70468 and 0.512691–0.512830, respectively. This result confirms earlier conclusions obtained from petrologic study that the andesites cannot be fractionation products of basaltic magma but that the andesitic and basaltic magmas were generated independently. On the basis of melting experiments for HMA and basalt, it is inferred that there is an isotopically stratified mantle beneath southwest Japan. Evolved porphyritic andesites have essentially identical Sr and Nd isotopic ratios to HMA and can be derived by fractionation of primary andesitic magma. A model to produce orogenic andesite is proposed on petrologic, experimental and isotopic bases.     

Zircon U-Pb SHRIMP ages of the Taiping (calc-alkaline)-Huangshan (alkaline) composite intrusion: Constraints on Mesozoic lithospheric thinning of the southeastern Yangtze Craton,China

The Taiping-Huangshan composite intrusion is a unique complex with characteristics changing from calc-alkaline (Taiping intrusion) to alkaline (Huangshan intrusion). Huangshan intrusion samples show a spectacular tetrad effect in their REE distribution patterns as well as non-CHARAC (charge-and-radius-controlled) trace element behavior, indicating a highly evolved late-stage magma component. This composite intrusion provides a rare opportunity to investigate the variance of tectonic setting and lithospheric thinning of the southeastern Yangtze Craton in late Mesozoic era. Zircon SHRIMP U-Pb analyses yield an emplacement age of 140.6±1.2 Ma for the Taiping intrusion, and ages of 127.7±1.3, 125.7±1.4, 125.1±1.5, and 125.2±5.5 Ma for four samples from the Huangshan intrusion respectively. The ages for four different phases of the Huangshan intrusion agree within their small analytical errors, indicating that the emplacement was in a short time. The Taiping and Huangshan intrusions are intimately associated, but there is about 15 Ma interval between their intrusion, and the magma characters change from calc-alkaline to alkaline without transition. This probably corresponds to lithospheric thinning of the southeastern Yangtze Craton. This event possibly happened from about 141 Ma (the emplacement age of the Taiping intrusion), to 128 Ma (start of emplacement of the Huangshan intrusion). The thinning mechanism is dominantly delamination.     

Cretaceous volcanic rocks of the South Tethyan suture zone, Pakistan: implications for the Réunion hotspot and Deccan Traps

The location, ages, and geochemical characteristics of marine volcanic rocks preserved in the South Tethyan suture zone of Pakistan suggest that the Réunion hotspot was active off northwestern Greater India well before the emplacement, far to the south, of the Deccan flood basalts, the great bulk of which were erupted at 65-66 Ma and are widely believed to be associated with the hotspot’s plume-head phase. Most of the suture zone samples have Nd-Pb-Sr isotopic ratios (e.g. age-corrected ?_Nd(t)=+3.0 to +4.6) close to those expected for modern-type Réunion source mantle in the Late Cretaceous, and their incompatible element patterns resemble those of recent Réunion shield lavas. ⁴⁰Ar-³⁹Ar incremental heating yields ages of 73.4-72.0 Ma. Nevertheless, unless even older ages are discovered among the suture zone rocks, a pre-Deccan marine phase of Réunion hotspot activity on the Tethyan side of Greater India can be accommodated within the framework of the plume-head model.     

Long-term observation of volcanic tremor on Stromboli volcano (Italy): A synopsis

The features of seismic activity on Stromboli are discussed and compared in terms of their relationship with the main changes of volcanic activity from 1990 to 1993.We considered a statistical approach for our data analysis. Cluster analysis was used to seek out classes of spectra which might characterize the condition of the volcanic system. The classes we have found provide insights into a scenario which evolves through different phases of volcanic activity, from paroxysms to low activity. We show that episodes of lava effusion and lava fountaining are heralded by variations in the spectral features of tremor after a preparation time. This result highlights the importance of tremor, and reveals that long-term observations are key to examine slow modifications in a volcanic system such as Stromboli, characterized by open conduits, and persistent explosive activity.