Phase relations in the CaMgSi<Subscript>2</Subscript>O<Subscript>6</Subscript>–KAlSi<Subscript>3</Subscript>O<Subscript>8</Subscript> join at 6 and 3.5 GPa as a model for formation of some potassium-bearing deep-seated mineral assemblages

The join CaMgSi₂O₆–KAlSi₃O₈ has been studied at 6 GPa (890–1,500°C) and 3.5 GPa (1,000–1,100°C). K-rich melts in the join produce assemblages Cpx + Grt, Cpx + Opx, Cpx + San, and Cpx + Grt + San at 1,100–1,300°C. At N_San^system<~70 mol%, sanidine is unstable on the solidus and appears at the liquidus, if N_San^system>90 mol%. This explains a scarcity of San in mantle Cpx-rich assemblages and its association with high-K aluminosilicate melt inclusions in diamonds. In absence of San, KCpx is the only host for potassium. The K-jadeite content in KCpx systematically increases with decreasing temperature and reaches 10–12 mol% near the solidus. However, KCpx coexists with San at N_San^system>70 mol% and <1,300°C, being formed via reaction San + L=KCpx. The KJd content in KCpx is controlled by the equilibrium San=KJd + SiO₂^L that displaces to the right with increasing pressure and decreasing both the temperature and This equilibrium is considered to be responsible for the formation of San lamellae in natural UHP Cpx. In our experiments at 3.5 GPa, garnet is absent whereas the KJd and Ca-Eskola contents in Cpx are low, and the join CaMgSi₂O₆–KAlSi₃O₈ is close to binary (with the eutectic Cpx + San + L). Different topologies of the join at 6 and 3.5 GPa define a sequence of mineral crystallization from K-rich aluminosilicate melts during cooling and decompression: from KCpx + Grt without San at P>4 GPa to Cpx + San at P<4 GPa. Similar sequence of assemblages is observed in some eclogitic xenoliths from kimberlites and Grt–Cpx rocks of the Kokchetav Complex (Northern Kazakhstan).     

Study on the CO<Subscript>2</Subscript> emissions embodied in the trade of China’s steel industry: based on the input–output model

The impact of trade on the environment and the climate has become a focus of attention. Tending to develop industries with higher added values, developed countries rely on importing high energy consumption goods from developing countries, and however, some CO₂ emissions are embodied in the process of import. Currently, the accounting method of the territorial responsibility used to get the international data of greenhouse gas inventories ignores the difference between domestic consumption and export demands. Thus, developing countries bear the responsibility of pollution emissions from the export. The steel industry is an important basic industry of China’s national economy as well as a vital part in the industrial system. With the expansion of trade scale, the impact of the export and import of China’s steel on CO₂ emissions is growing. This paper studied the embodied CO₂ emissions in the trade of China’s steel from 2005 to 2014, using the input–output model and the trade data of the China’s steel imports and exports. The results indicate that (1) the complete CO₂ emissions of China’s steel industry are high. (2) The increase in the export scale makes the embodied CO₂ emissions in the trade of China’s steel export increase, and (3) China is a net exporter of CO₂ emissions in the steel trade. Especially after 2007, the value of China’s steel exports has been larger than that of China’s steel imports, so China had borne much CO₂ emissions responsibility in the trade of China’s steel. Therefore, this paper puts forward that, in the future, the export structure of goods should be optimized into the high-tech products with the high added value, low energy consumption and low carbon emissions, and meanwhile, service industry is promoted to improve technical support to reduce CO₂ emissions in the steel industry.     

CO<Subscript>2</Subscript> Air–Sea Exchange due to Calcium Carbonate and Organic Matter Storage,and its Implications for the Global Carbon Cycle

Release of CO₂ from surface ocean water owing to precipitation of CaCO₃ and the imbalance between biological production of organic matter and its respiration, and their net removal from surface water to sedimentary storage was studied by means of a quotient θ = (CO₂ flux to the atmosphere)/(CaCO₃ precipitated). θ depends not only on water temperature and atmospheric CO₂ concentration but also on the CaCO₃ and organic carbon masses formed. In CO₂ generation by CaCO₃ precipitation, θ varies from a fraction of 0.44 to 0.79, increasing with decreasing temperature (25 to 5°C), increasing atmospheric CO₂ concentration (195–375 ppmv), and increasing CaCO₃ precipitated mass (up to 45% of the initial DIC concentration in surface water). Primary production and net storage of organic carbon counteracts the CO₂ production by carbonate precipitation and it results in lower CO₂ emissions from the surface layer. When atmospheric CO₂ increases due to the ocean-to-atmosphere flux rather than remaining constant, the amount of CO₂ transferred is a non-linear function of the surface layer thickness because of the back-pressure of the rising atmospheric CO₂. For a surface ocean layer approximated by a 50-m-thick euphotic zone that receives input of inorganic and organic carbon from land, the calculated CO₂ flux to the atmosphere is a function of the CaCO₃ and C_org net storage rates. In general, the carbonate storage rate has been greater than that of organic carbon. The CO₂ flux near the Last Glacial Maximum is 17 to 7×10¹² mol/yr (0.2–0.08 Gt C/yr), reflecting the range of organic carbon storage rates in sediments, and for pre-industrial time it is 38–42×10¹² mol/yr (0.46–0.50 Gt C/yr). Within the imbalanced global carbon cycle, our estimates indicate that prior to anthropogenic emissions of CO₂ to the atmosphere the land organic reservoir was gaining carbon and the surface ocean was losing carbon, calcium, and total alkalinity owing to the CaCO₃ storage and consequent emission of CO₂. These results are in agreement with the conclusions of a number of other investigators. As the CO₂ uptake in mineral weathering is a major flux in the global carbon cycle, the CO₂ weathering pathway that originates in the CO₂ produced by remineralization of soil humus rather than by direct uptake from the atmosphere may reduce the relatively large imbalances of the atmosphere and land organic reservoir at 10²–10⁴-year time scales.     

Air–water CO<Subscript>2</Subscript> flux in an algae bloom year for Lake Hongfeng,Southwest China: implications for the carbon cycle of global inland waters

The carbon cycle of global inland waters is quantitatively comparable to other components in the global carbon budget. Among inland waters, a significant part is man-made lakes formed by damming rivers. Man-made lakes are undergoing a rapid increase in number and size. Human impacts and frequent algae blooms lead to it necessary to make a better constraint on their carbon cycles. Here, we make a primary estimation on the air–water CO₂ transfer flux through an algae bloom year for a subtropical man-made lake—Hongfeng Lake, Southwest China. To do this a new type of glass bottles was designed for content and isotopic analysis of DIC and other environmental parameters. At the early stage of algae bloom, CO₂ was transferred from the atmosphere to the lake with a net flux of 1.770 g·C·m^?2. Later, the partial pressure (pCO₂) of the aqueous CO₂ increased rapidly and the lake outgassed to the atmosphere with a net flux of 95.727 g·C·m^?2. In the remaining days, the lake again took up CO₂ from the atmosphere with a net flux of 14.804 g·C·m^?2. As a whole, Lake Hongfeng released 4527 t C to the atmosphere, accounting for one-third of the atmosphere/soil CO₂ sequestered by chemical weathering in the whole drainage. With an empirical mode decomposition method, we found air temperature plays a major role in controlling water temperature, aqueous pCO₂ and hence CO₂ flux. This work indicates a necessity to make detailed and comprehensive carbon budgets in man-made lakes.