共查询到17条相似文献,搜索用时 343 毫秒
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为了获得高质量AlN晶体,通过物理气相传输(PVT)法,采用AlN籽晶进行AlN晶体生长,并通过双温区加热装置对衬底与原料之间的温差进行调节。研究结果表明,籽晶形核阶段,随着AlN籽晶与原料顶温差的减小,AlN的形核机制呈现三种模式,分别为岛生长模式、畴生长模式和螺旋位错生长模式;晶体生长阶段,通过增加AlN籽晶与原料顶温差来提高晶体生长速率,采用10℃/h的变温速率将温差从10℃增加为30℃时,AlN晶体生长模式不变,仍然保持螺旋位错生长模式,该生长模式下获得的AlN晶体结晶质量最高,(0002)面摇摆曲线半峰宽(FWHM)约为55 arcsec。 相似文献
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根据物理气相传输法(PVT) AlN晶体生长特点及工艺要求,自主设计了AlN晶体生长炉及其配套热场.FEMAG软件热场模拟结果表明,自主设计的晶体生长炉及其配套热场可以达到AlN晶体生长所需坩埚内部温度梯度要求.基于设计的PVT生长炉,开展了在2 250℃生长温度、40 h长晶时间条件下的自发形核生长实验.实验研究结果表明,在该工艺条件下,通过自发形核可生长得到典型长度为3~Smm、直径为2 mm的高质量AlN单晶;AlN晶体的c-plane(0001)生长速率最快,易形成尖锥形晶体结构,不利于晶体的扩径;Raman表征图谱中AlN晶体的E2 (high)半峰宽仅为5.65 cm-1,表明AlN晶体质量非常高;SEM、EDS分析得出晶体内部质量较为均匀,c-plane和m-plane腐蚀形貌特征明显. 相似文献
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AlN晶体中的氧杂质会严重影响晶体性能.因此,氧含量的控制一直是AlN晶体生长工艺中的热点和难点.为了减少AlN晶体中的氧杂质含量,通常在长晶之前使用粉料高温烧结工艺去除大部分的氧杂质.使用XRD及EGA等检测方法,对不同烧结工艺下AlN烧结过程中坩埚盖处的氧杂质沉积行为及其规律进行了对比研究.研究发现,使用低温(900~1 100℃)真空保温与1 500℃的氮气保护下保温相结合的方法可以极大促进氧杂质在坩埚盖处的前期沉积.在氮气保护环境下进一步提升烧结温度至2 000~2 100℃并经过一段时间的保温后,坩埚盖沉积物表面会出现黄褐色AlN结晶层,相应的检测结果表明此阶段坩埚盖处的氧杂质大量挥发,沉积过程已经基本结束. 相似文献
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借助多物理场耦合软件模拟了物理气相传输法AlN单晶生长系统中的热场分布.探讨了生长不同厚度晶体的系统内部热场分布,并与实际生长不同厚度晶体的表面形貌进行比对.模拟结果表明,随着晶体厚度的增大,生长系统内部的轴向温度梯度出现不同程度的降低.晶体表面的径向温度曲线逐渐变为微凸界面,这与实际单晶厚度增大时表面形貌的变化趋势基本一致.另外模拟了多晶AlN源的升华收缩对热场分布稳定性的影响.结果表明,多晶AlN源收缩导致系统稳定性下降.通过分析不同电流下的热场分布结果,提出改善系统稳定性的措施. 相似文献
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采用有限元分析法系统地研究了大尺寸6H-SiC晶体PVT法生长装置中感应加热线圈的不同高度和匝间距对生长腔、粉源以及生长晶体温度场的影响;分析比较了线圈取不同匝间距时晶体生长面径向温度梯度的变化.结果表明,在中频电源的输出功率和频率固定,盲孔内径不变的情况下,通过适当调整线圈匝间距和高度可以减小晶体生长面径向温度梯度,提高晶体的质量,同时又有比较高的生长率. 相似文献
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采用有限元分析法系统地研究了大尺寸6H-SiC晶体PVT法生长装置中感应加热线圈的不同高度和匝间距对生长腔、粉源以及生长晶体温度场的影响;分析比较了线圈取不同匝间距时晶体生长面径向温度梯度的变化.结果表明,在中频电源的输出功率和频率固定,盲孔内径不变的情况下,通过适当调整线圈匝间距和高度可以减小晶体生长面径向温度梯度,提高晶体的质量,同时又有比较高的生长率. 相似文献
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D. Zhuang Z. G. Herro R. Schlesser B. Raghothamachar M. Dudley Z. Sitar 《Journal of Electronic Materials》2006,35(7):1513-1517
Seeded growth of AlN single crystals was demonstrated in an induction-heated, high-temperature reactor via a physical vapor
transport (PVT) process. AlN seeds were prepared from a self-seeded boule containing large single-crystalline grains. Seeded
growth was interrupted several times in order to refill the AlN powder source, and a dedicated process scheme was used to
ensure epitaxial growth on the seed surface, after prior exposure to air. The growth temperatures were in the range of 2200–2300°C,
and the reactor pressure was in the range of 500–900 torr of UHP-grade nitrogen during each growth run. Under these growth
conditions, a seed (10 mm diameter) expanded at an angle of 45°, and a larger single crystal up to 18 mm in diameter was obtained.
The as-grown surface had three facets, of which facet (1120) was smooth and featureless while the other two, (4150) and (2570),
showed serrated morphologies. The double-crystal x-ray rocking curve and glow discharge mass spectroscopy analysis confirmed
that the grown crystal was of high crystalline quality with low impurity incorporation. 相似文献
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M. Bo
kowski M. Wrblewski B.
ucznik I. Grzegory 《Materials Science in Semiconductor Processing》2001,4(6)
We report on the results of AlN crystal growth at high nitrogen pressure of the order of 1 GPa and temperatures up to 2000 K. Both, needle-like and bulk form of AlN single crystals up to 1 cm and 1 mm, respectively, have been obtained. We discuss the influence of temperature and supersaturation on the habit and morphology of AlN crystals. The crystals were characterized by X-ray diffraction method, scanning electron microscopy (SEM) and energy dispersive X-ray analyser attached to SEM. 相似文献
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MINJia-hua SANGWen-bing LIWan-wan LIUHong-tao YUFang WANGKun-shu CAOZe-chun 《半导体光子学与技术》2005,11(1):20-27
During the crystal grown by VBM, the solid/liquid interface configurations greatly influence the quality of as-grown crystals. In this paper, finite element method (FEM) was used to simulate the growth process of CdZnTe crystal. The effects of different crucible moving rates and temperature gradient of adiabatic zone on crystal growth rate and solid-liquid interface configuration were studied as well. Simulation results show that when crucible moves at the rate of about 1 mm/h, which is nearly equal to crystal growth rate, nearly flat solid/liquid interface and little variation of axial temperature gradient near it can be attained, which are well consistent with the results of experiments. CdZnTe crystal with low dislocation density can be obtained by employing appropriate crucible moving rate during the crystal growth process. 相似文献