共查询到20条相似文献,搜索用时 435 毫秒
1.
噻唑类杀虫剂的研究进展 总被引:2,自引:0,他引:2
目前杂环化合物的发展呈现出多元化的趋势,其中噻唑类化合物是近年来发展的一个新亮点。尤其噻唑基团引入到各种不同的化合物结构中,通过结构修饰能产生一系列具有广谱生物活性化合物,使得它在新型超高效农药创制中发挥出越来越重要的作用。本文从杀虫方面对噻唑化合物的生物活性研究进行了综述,重点介绍了该类化合物的一些生物活性研究方面的工作,简述了不同取代基团对噻唑类衍生物生物活性的影响,并对它的发展趋势和应用前景作了展望。 相似文献
2.
3.
笔者等对含硫杂环化合物的合成及其生物活性进行了研究。其间,亦对由有机硫化合物(例如二硫化碳和异硫氰酸酯)衍生的中间体的反应性进行了广泛的研究。为了创制新的生物活性化合物,其有效的方法之一,是对已知生物活性化合物进行化学结构的改进。防治水稻稻瘟病的内吸杀菌剂富士一号(2)对某些植物和害虫都呈现生长调节活性。鉴于富士一号化学结构的新颖性和生物活性的多样性,引起了笔者等人的注意,以它作为新的农药化学结构的先导化合物。 相似文献
4.
5.
6.
7.
8.
酰基硫脲类化合物的生物活性研究进展 总被引:3,自引:1,他引:2
酰基硫脲类化合物具有广泛的生物活性,可作为除草剂、杀菌剂及植物生长调节剂等。本文简要综述了近年来该类化合物生物活性的研究近况。 相似文献
9.
10.
香豆素是一类重要杂环化合物,具多种生物活性,在医药、食品等领域有重要用途。本文综述了近年来香豆素生物活性研究进展,并简单介绍了含有苯并吡喃酮化合物的合成方法,为香豆素类化合物生物活性的深入研究提供依据。 相似文献
11.
采用DUO-ICP-AES同时测定精对苯二甲酸中钴、铬、铁、锰、钼、镍、钛,并对仪器的分析线选择、背景校正、入射功率、雾化器压力、辅助气流量、冷却气流量、蠕动泵转速的影响及共存元素的干扰、硝酸铯灰化助剂等因素进行了详细的研究。方法的检测限:钴0.0097 mg/L;铬0.0021 mg/L;铁0.0078 mg/L;锰0.0012 mg/L;钼0.0027 mg/L;镍0.016 mg/L;钛0.0027 mg/L,回收率和精密度分别为93.0%~99.5%和0.37%~3.2%。该方法快速简便,具有良好的精密度和准确度,适用于进出口精对苯二甲酸的日常检验。 相似文献
12.
The development of new methods for preparing polyfunctional organometallics has made a broad range of such reagents available for various transition metal-catalyzed cross-couplings. An overview of the most general preparation methods will be presented. Applications to practical cross-coupling procedures will be covered, emphasizing the functional group compatibility and the reaction scope. 相似文献
13.
Mailadil T. Sebastian Sam Solomon Ravindran Ratheesh Jacob George Pezholil Mohanan 《Journal of the American Ceramic Society》2001,84(7):1487-1489
Microwave ceramic dielectric resonators (DRs) based on RETiNbO6 (RE = Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Y, and Yb) have been prepared using the conventional solid-state ceramic route. The DR samples are characterized using XRD and SEM methods. The microwave dielectric properties are measured using resonant methods and a net work analyzer. The ceramics based on Ce, Pr, Nd, and Sm have dielectric constants in the range 32–54 and positive coefficient of thermal variation of resonant frequency (τf ). The ceramics based on Gd, Tb, Dy, Y, and Yb have dielectric constants in the range 19–22 and negative τf . 相似文献
14.
Clive A. Randall Zhongming Fan Ian Reaney Long-Qing Chen Susan Trolier-McKinstry 《Journal of the American Ceramic Society》2021,104(8):3775-3810
Antiferroelectric (AFE) materials are of great interest owing to their scientific richness and their utility in high-energy density capacitors. Here, the history of AFEs is reviewed, and the characteristics of antiferroelectricity and the phase transition of an AFE material are described. AFEs are energetically close to ferroelectric (FE) phases, and thus both the electric field strength and applied stress (pressure) influence the nature of the transition. With the comparable energetics between the AFE and FE phases, there can be a competition and frustration of these phases, and either incommensurate and/or a glassy (relaxor) structures may be observed. The phase transition in AFEs can also be influenced by the crystal/grain size, particularly at nanometric dimensions, and may be tuned through the formation of solid solutions. There have been extensive studies on the perovskite family of AFE materials, but many other crystal structures host AFE behavior, such as CuBiP2Se6. AFE applications include DC-link capacitors for power electronics, defibrillator capacitors, pulse power devices, and electromechanical actuators. The paper concludes with a perspective on the future needs and opportunities with respect to discovery, science, and applications of AFE. 相似文献
15.
16.
《国际聚合物材料杂志》2012,61(6):497-509
Glass fiber reinforced composites based on thermosets are the traditional materials used for many applications due to their good mechanical properties. The non-recyclability of these materials has led to the necessity to develop thermoplastic composites and industrial processes for their manufacture [1]. The present paper deals with the preparation of thermoplastic pre-pregs unidirectionally reinforced with Twarn® and their mechanical characterization. 相似文献
17.
Pravin Kumar Sahu Suryakant Chakradhari Elise Sipeniece Inga Miina Ying Qian Ania Grygier Magdalena Rudziska Khageshwar Singh Patel Pawe Grna 《European Journal of Lipid Science and Technology》2020,122(7)
The oil yield and composition of fatty acids, tocopherols, tocotrienols, sterols, carotenoids, and squalene in the seeds of three species—Hyptis suaveolens, Leonotis nepetifolia, Ocimum sanctum—belonging to the Lamiaceae family, are studied. The oil yields are 12.1%, 16.1%, and 29.0% in O. sanctum, H. suaveolens, and L. nepetifolia, respectively. The unsaturated fatty acids are a predominant group (86.8–92.1%) in all three investigated plants; however, the profile for each species is unique. The main fatty acid differs as follows: H. suaveolens—linoleic acid (85.8%), L. nepetifolia—oleic acid (58.3%), and O. sanctum—α‐linolenic (48.6%). γ‐Tocopherol accounts for over 97%, 90%, and 93% of the total tocochromanol content (sum of tocopherols and tocotrienols) in H. suaveolens, L. nepetifolia, and O. sanctum, respectively. Two tocotrienol homologues, α and γ, are detected only in L. nepetifolia. β‐Sitosterol is the main detected sterol (38–59%) in all three species. High levels of campesterol (18–20%), Δ5‐stigmasterol (9–21%), and Δ5‐avenasterol (7–12%) are also detected. Squalene is detected only in O. sanctum (45.8 mg/100 g oil). The content of sterols, tocochromanols, and carotenoids in the investigated Lamiaceae plant seed oils ranges between 279.5–576.3, 54.5–66.7, and 0.3–3.1 mg/100 g oil, respectively. Practical Applications: Lamiaceae plants are of medicinal interest due to the presence of a broad spectrum of bioactive molecules. The present study demonstrates that seeds of the species H. suaveolens, L. nepetifolia, and O. sanctum are rich sources of bioactive compounds of lipophilic nature. There is limited knowledge associated with the composition of tocopherols, tocotrienols, sterols, carotenoids, and squalene. The results of the studied medicinal plants may enhance future targeted applications in various sectors. 相似文献
18.
Yasuto Fujimaki Minoru Takekawa Shoji Fujisawa Shigeru Ohshima Yohko Sakamoto 《Polycyclic Aromatic Compounds》2013,33(2):107-122
Hexabenzo[a,cd,f,j,lm,o]perylene (HBP), an undecacyclic condensed polycyclic aromatic hydrocarbon with two severely crowded fjord regions, was synthesized by Clar's method; the starting material 8H-benzo[fg]-naphthacene-8-one was newly prepared by the glycerol condensation of 5,12-dihydro-naphthacene-5,12-dione. 1H and 13C NMR spectra of HBP were measured and the chemical shifts were completely assigned. Absorption and fluorescence spectra of HBP were also measured and the effects of nonplanarity on its spectroscopic properties was discussed. 相似文献
19.
ICP-OES测定大量元素水溶肥料中锌、镁、铜、铁、锰、钼、硼含量 总被引:1,自引:0,他引:1
采用ICP-OES对大量元素水溶肥料中微量元素锌、镁、铜、铁、锰、钼、硼进行分析,研究确定了最佳分析条件。加标回收率为96.94%~106.2%,RSD为0.50%~1.40%,检出限为0.001 8~0.218 0 mg/L,方法简便、快速、准确。 相似文献
20.
R. W. Riemenschneider T. Zell W. E. Scott 《Journal of the American Oil Chemists' Society》1966,43(5):325-326
A series of esters of 12,13-epoxyoleic acid were prepared by means of alcoholysis of triepoxyolein (trivernolin). The procedure
for the alcoholysis, and isolation and purification of the esters are described. Analytical characteristics of the esters
are reported.
E. Util. Res. Devel. Div., ARS, USDA. 相似文献