3英寸CdTe/Si复合衬底外延技术研究

报道了采用分子束外延法,在3 in硅衬底上通过As钝化、ZnTe缓冲层生长、CdTe生长、周期性退火等工艺进行CdTe/Si复合衬底制备技术研究情况,采用光学显微镜、X射线高分辨衍射仪、原子力显微镜、红外傅里叶光谱仪和湿化学腐蚀等手段对碲化镉薄膜进行了表征,测试分析结果表明碲化镉薄膜的晶向得到了较好的控制,孪晶得到了抑制,且具有较好晶体结构质量和均匀性。     

3英寸CdTe/Si复合衬底外延技术研究

报道了采用分子束外延法,在3 in硅衬底上通过As钝化、ZnTe缓冲层生长、CdTe生长、周期性退火等工艺进行CdTe/Si复合衬底制备技术研究情况,采用光学显微镜、X射线高分辨衍射仪、原子力显微镜、红外傅里叶光谱仪和湿化学腐蚀等手段对碲化镉薄膜进行了表征,测试分析结果表明碲化镉薄膜的晶向得到了较好的控制,孪晶得到了抑...     

Si基CdTe复合衬底分子束外延研究

文章引入晶格过渡的Si/ZnTe /CdTe作为复合外延基底材料,以阻挡Si/HgCdTe之间大晶格失配产生的高密度位错。通过对低温表面清洁化、面极性控制和孪晶抑制等的研究,解决了Si基CdTe分子束外延生长中诸多的技术难题。在国内首次采用分子束外延(MBE)的方法获得了大面积的Si基CdTe复合衬底材料,对应厚度为4～4. 4μm Si/CdTe (211)样品双晶半峰宽的统计平均结果为83弧秒,与相同厚度的GaAs/CdTe (211)双晶平均水平相当。     

偏转角(211)Si基CdTe复合衬底研究

晶面偏角是提高(211) Si基CdTe复合衬底质量的方法之一。通过对偏转角Si基CdTe复合衬底分子束外延工艺的研究,发现2°和3°偏转角(211)Si基CdTe复合衬底在晶体质量方面优于标准(211)Si基CdTe复合衬底,是未来提高Si基CdTe复合衬底质量的新方向。     

Si(100)和Si(111)衬底上的同质分子束外延

用超高真空电子束蒸发系统进行了硅的同质分子束外延.发现采用适当的表面化学处理方法,然后在超高真空中加热,可以在较低温度下(800—814℃)获得清洁和平整的有序表面.Si(100)和Si(111)的外延分别在520℃和714℃进行,外延膜的结构和电学特性良好.     

分子束外延CdTe（211）B／GaAs（211）B的特性研究

ＣｄＴｅ／ＧａＡｓ是ＨｇＣｄＴｅ分子束外延的重要替代衬底材料。用Ｘ双晶衍射和光致发光测试研究了分子束外延生长的ＣｄＴｅ（２１１）Ｂ／ｇＡｓ（２１１）Ｂ的晶体结构质量，表明外延膜昌体结构完整，具有很高的质量。用高分辨率的透射电镜研究其界面特性，观察到ＣｄＴｅ（２１１）Ｂ相对于ＧａＡｓ（２１１）Ｂ向着（１１１）方向倾斜一个小角度，界面的四面体键网发生扭曲，由于晶格失配，在界面存在很高的失配位错密度。     

在Si(211)衬底上分子束外延CdTe的晶格应变

文章利用高分辨率X射线衍射技术对分子束外延CdTe（211）B/Si（211）材料的CdTe外延薄膜进行了倒易点二维扫描,并通过获得的对称衍射面和非对称衍射面的倒易空间图,对CdTe外延层的剪切应变和正应变状况进行了分析.研究发现,对于CdTe/Si结构,随着CdTe厚度的增加,[1-1-1]、[01-1]两个方向的剪切角γ[1-1-1]和λ[01-1]都有变小的趋势,且γ[1-1-1]的大小约为γ[01-1]的两倍;对于CdTe/ZnTe/Si,ZnTe缓冲层的引入可以有效地降低CdTe层的剪切应变.CdTe层的正应变表现为张应变,主要来源于CdTe和Si的热膨胀系数存在差异,而在从生长温度280℃降至室温20℃的过程产生的热应变.     

在Si(211)衬底上分子束外延CdTe的剪切应变

利用高分辨率X射线衍射技术对分子束外延CdTe（211）B/Si（211）材料的CdTe外延薄膜进行了倒易点二维扫描,并通过获得的对称衍射面和非对称衍射面的倒易空间图,对CdTe缓冲层的剪切应变状况进行了分析.研究发现,对于CdTe/Si结构,随着CdTe厚度的增加,[1-1-1]、[01-1]两个方向的剪切角γ[1-1-1]和γ[01-1]都有变小的趋势,且γ[1-1-1]的大小约为γ[01-1]的两倍;对于CdTe/ZnTe/Si结构,ZnTe缓冲层的引入可以有效地降低CdTe层的剪切应变.     

在Si和Ge衬底上用分子束外延生长HgCdTe

在当前大规模红外焦平面器件的研制中,高性能器件的制备需要高质量、大面积、组分均匀的碲镉汞材料。衬底和外延材料的晶格失配导致了大量的位错增殖,严重影响红外焦平面器件的工作性能。本文对各种衬底进行了比较,并对Si基和Ge基上的外延碲镉汞材料的生长工艺及性能进行了调研和评价。     

Ge(211)衬底上分子束外延CdTe薄膜

采用分子束外延在3英寸Ge(211)衬底上生长了10 μm厚的CdTe(211)B薄膜.CdTe表面镜面光亮,3英寸范围厚度平均值9.72 μm,偏差0.3 μm;薄膜晶体质量通过X射线双晶迴摆曲线进行评价,FWHM平均值80.23 arcsec,偏差3.03 arcsec; EPD平均值为4.5×106cm-2.通过研究CdTe薄膜厚度与FWHM和EPD的关系,得到CdTe的理想厚度为8～9 μm.     

分子束外延生长3英寸HgCdTe晶片

报道了用分子束外延的方法制备 3英寸HgCdTe薄膜的研究结果 ,获得的HgCdTe外延材料均匀性良好 ,在直径 70mm圆内 ,组份标准偏差率为 1.2 % ,对应 80K截止波长偏差仅为 0 .1μm .经过生长条件的改进 ,表面形貌获得了大幅度改善 ,缺陷密度小于 30 0cm-2 ,缺陷尺寸小于 10 μm ,可以满足大规模HgCdTe焦平面列阵的应用需求     

Microstructural and optical characterization of CdTe(211)B/ZnTe/Si(211) grown by molecular beam epitaxy

CdTe layers have been grown by molecular beam epitaxy on 3 inch nominal Si(211) under various conditions to study the effect of growth parameters on the structural quality. The microstructure of several samples was investigated by high resolution transmission electron microscopy (HRTEM). The orientation of the CdTe layers was affected strongly by the ZnTe buffer deposition temperature. Both single domain CdTe(133)B and CdTe(211)B were obtained by selective growth of ZnTe buffer layers at different temperatures. We demonstrated that thin ZnTe buffer layers (<2 nm) are sufficient to maintain the (211) orientation. CdTe deposited at ∼300°C grows with its normal lattice parameter from the onset of growth, demonstrating the effective strain accommodation of the buffer layer. The low tilt angle (<1°) between CdTe[211] and Si[211] indicates that high miscut Si(211) substrates are unnecessary. From low temperature photoluminescence, it is shown that Cd-substituted Li is the main residual impurity in the CdTe layer. In addition, deep emission bands are attributed to the presence of As_Te and Ag_Cd acceptors. There is no evidence that copper plays a role in the impurity contamination of the samples.     

MBE CdTe／GaAs光致发光研究

在１０Ｋ低温下对分子束外延（ＭＢＥ）生长的ＣｄＴｅ（１１１）Ｂ／ＧａＡｓ（１００）／ＣｄＴｅ（２１１）Ｂ／ＧａＡｓ（２１１）Ｂ外延膜进行了光致发光（ＰＬ）测量，得到了ＰＬ谱和带边激子辐射的精细结构．计算得到束缚激子的半峰宽（ＦＷＨＭ）分别为０．２～０．ｓｍｅＶ和１～２ｍｅＶ．实验结果表明外廷膜的质量和生长工艺均良好．     

Structure of CdTe(111)B grown by MBE on misoriented Si(001)

Single domain CdTe(111)B has been grown on Si(001) substrates tilted 1^o 2^o, and 4^o toward [110]. All the layers started with a double-domain structure, then a transition from a double- to a single-domain was observed by reflection high energy electron diffraction. A microscopic picture of this transition is presented. We also measured the tilt between CdTe(111)B and Si(001). The result does not follow the tilt predicted by the currently existing model. A new model of the microscopic mechanism of CdTe(111)B growth is presented. New evidence indicates that optimizing the tilt of the substrate surface is very crucial in improving the CdTe(111)B crystal quality.     

In-situ ellipsometry studies of adsorption of Hg on CdTe(211)B/Si(211) and molecular beam epitaxy growth of HgCdTe(211)B

We study the adsorption of Hg on CdTe(211)B using an 88-wavelength spectroscopic ellipsometer mounted on a commercial, molecular beam epitaxy (MBE) chamber. A detailed analysis of the pseudo-dielectric function shows that Hg is present at the surface both in chemisorbed and physisorbed form. Effective medium models for a mixture of chemisorbed and physisorbed Hg on the microscopically rough CdTe surface could not fit our data. However, a proposed model in which a partial layer of physisorbed Hg sits on top of a partial layer of chemisorbed Hg fits the measured pseudo-dielectric function well and yields precise values for the thicknesses of the chemisorbed and the physisorbed Hg layers. These values change in the expected manner as a function of Hg flux, temperature, and Te coverage. An analysis of the uncertainty in the measured thicknesses is carried out in detail, and a study of the limitations of the ellipsometer used for this study is presented. The effects of these limitations on the precision and accuracy of in-situ data are enumerated.     

化学束—气源外延生长HgCdTe

评论了Ⅱ-Ⅵ族半导体HgCdTe的化学束-气源外延生长系统的设计和研制,介绍了生长HgCdTe外延层和气体源掺碘CdTe外延层的最新结果,这些结果表明了用这种技术生长用于制备先进红外探测器的优质材料的可能性.