Co SiO2颗粒膜的巨磁电阻效应

测量了Ｃｕ Ａｌ混合粉末经过不同时间球磨后的２７Ａｌ核磁共振（ＮＭＲ）谱,分析了２７ＡｌＮＭＲ谱的特征参量随球磨时间的变化．根据２７ＡｌＮＭＲ谱所提供的信息,研究了Ｃｕ Ａｌ混合粉末机械合金化反应的微观过程．Ｃｕ Ａｌ混合粉末的２７ＡｌＫｎｉｇｈｔ位移随球磨时间的增加而减小．对于Ｃｕ Ａｌ混合粉末,球磨不仅改变了２７Ａｌ附近的化学短程序,而且也直接地影响了２７Ａｌ的外层电子态,后者使传导电子的ｓ态成分减小．实验结果表明,Ｃｕ Ａｌ混合粉末在球磨过程中发生了真正的合金化反应;经过９０ｈ球磨完成了合金化反应; 关键词：     

Co SiO2颗粒膜的巨磁电阻效应

采用离子束溅射方法在玻璃基片上制备了一系列的Co－SiO\-2颗 粒膜样品,并对样品的巨磁电阻效应进行了研究.在Co35(SiO\-2)65(体积 百分比)颗粒膜样品中,观测到室温下近4%的巨磁电阻效应.研究了不同基片温度对巨磁电 阻效应的影响并发现,随着基片温度的升高样品的巨磁电阻效应下降.根据样品的电阻率温度关系曲线分析,在铁磁金属- 非磁绝缘介质颗粒膜中,除了电子自旋相关隧穿效应外, 可能还存在其他的导电机制. 关键词：     

Fe-Al2O3颗粒膜的隧道巨磁电阻效应

对射频共溅射法制备的ＦｅＡｌ２Ｏ３颗粒膜的隧道巨磁电阻效应进行了研究．当Ｆｅ体积百分比为４５％时,样品的室温磁电阻的变化率（ＭＲ）在１Ｔ的平行膜面的磁场下可达４４％．磁测量表明在室温时样品呈超顺磁态．另外,从ＭＲ随温度的变化关系曲线可以看出,当温度低于５０Ｋ时,ＭＲ随着温度的下降而显著增加,ＭＲ在２０Ｋ时达到１４９％,４２Ｋ时可达２６％,大大超过理论的预期值,这可能与低温下由库仑抑制效应引起的自旋相关隧穿的高阶效应有关．     

Co-SiO2颗粒膜的巨磁电阻效应

采用离子束溅射方法在玻璃基片上制备了一系列的Co-SiO2颗粒膜样品,并对样品的巨磁电阻效应进行了研究.在Co35(SiO2)65(体积百分比)颗粒膜样品中,观测到室温下近4%的巨磁电阻效应.研究了不同基片温度对巨磁电阻效应的影响并发现,随着基片温度的升高样品的巨磁电阻效应下降.根据样品的电阻率-温度关系曲线分析,在铁磁金属-非磁绝缘介质颗粒膜中,除了电子自旋相关隧穿效应外,可能还存在其他的导电机制.     

纳米结构ZnxFe3-xO4-α-Fe2O3多晶材料中的巨隧道磁电阻效应

在具有纳米绝缘层的多晶锌铁氧体体系中,当晶界为α-Fe₂O₃纳米量级(6—7nm)的绝缘层时,则构成(Zn_xFe_3-xO₄)-α-Fe₂O₃非均匀体,高分辨电子显微镜已证实了这种微结构,该体系在0.5T磁场、4.2K温度下,磁电阻效应可达1280%,300℃下为158%. 关键词： 隧道磁电阻效应 锌铁氧体 纳米结构     

退火对Co35(SiO2)65颗粒膜巨磁电阻效应的影响

采用多靶离子束溅射镀膜机制备了一系列不同退火温度的Co₃₅(SiO₂)₆₅（体积百分数）颗粒膜样品,发现样品的巨磁电阻效应随着退火温度T_a的升高而单调下降.应用磁力显微镜对样品的磁结构进行了观测,发现随着退火温度的升高,近邻的Co颗粒的磁矩倾向于平行排列,形成磁畴结构,从而导致Co₃₅(SiO₂)₆₅颗粒膜巨磁电阻效应单调下降. 关键词：     

La1-xCaxMnO3的巨磁电阻效应

通过测量La_2/3Ca_1/3MnO₃，La_0.6Ca_0.4MnO₃单相多晶样品的磁电阻、电阻与温度的依赖关系，发现在La_1-xCa_xMnO₃体系中随x的变化，其磁电阻峰和电阻峰都发生了位移．作者认为体系中Mn⁴⁺含量是受Ca含量调制的，正是Mn⁴⁺含量的变化，导致磁性 关键词：     

Fe-Ag金属颗粒膜的巨磁电阻

采用量子唯象模型研究金属颗粒膜巨磁电阻的特性．在计算散射截面时，考虑了颗粒内各杂质原子之间的相位相干性．依据实验报告提供的颗粒尺寸分布的数据，推导了巨磁电阻依赖于颗粒尺寸及其分布和外磁场的函数表示式．对样品Fe-Ag的计算结果表明，其磁电阻随外磁场的变化和颗粒尺寸的分布有关；在某个颗粒尺寸标度D₀，磁电阻出现极大值，尺寸标度D₀的大小与外加磁场、样品材料和制备条件有关 关键词：     

巨磁电阻效应实验仪

自制了巨磁电阻效应实验仪,测量了不同外磁场和工作电压下巨磁阻传感器输出电压的变化.研究了巨磁阻传感器敏感轴与外磁场间夹角与传感器输出电压间关系,传感器输出电压的与偏离角度成余弦关系.     

金属颗粒薄膜巨磁电阻效应的影响因素

研究金属颗粒薄膜的颗粒尺寸、磁性组分等对巨磁电阻效应的影响.在自由电子模型和自旋相关散射理论的基础上，计算了金属颗粒膜体系的电子平均散射势.在计算过程中将自旋相关项与宏观量相联系，得到了巨磁电阻效应与磁性成分比例、颗粒尺寸的关系.磁电阻效应的模拟曲线表明，增加磁性成分比例和减小磁性颗粒尺寸可增强颗粒膜的巨磁电阻效应. 关键词：     

Surface composition of Fe-Al2O3 granular thin films by X-ray photoemission spectroscopy

X-ray photoemission Spectroscopy (XPS) results are presented which have given a direct insight into the surface composition of Fe-Al₂ O₃ “granular” thin films consisting of fine iron particles (φ ~ 40–150 Å) dispersed in an insulating alumina matrix. The data are mainly discussed in relation to: (i) the bulk iron content in the sample, (ii) the sample preparation procedure (e.g., by rotation of the sample target) and (iii) the mean iron particle size.At the surface, the iron is in a fully oxidized 3⁺ state within an alumina-rich partly hydrated region. Depth analysis, achieved by an Ar⁺ etching procedure, provides evidence of metallic iron and iron aluminate forms. In general, the metallic iron percentage increases with depth and with increasing iron bulk content.Good agreement is found between X-ray photoemission spectroscopy and Mössbauer Spectroscopy data. Fe²⁺ aluminate forms, which indicate an interaction between the metal particle and the alumina matrix, show increasing percentages with decreasing mean particle sizes.Particular attention is paid to evaluating the accuracy of XPS quantitative results, obtained by use of a first-principles model, and to assessing the importance of the artefacts associated with the Ar⁺ etching procedure.     

Atmospheric reactive plasma sprayed Fe-Al2O3-FeAl2O4 composite coating and its property evaluation

In the present study, Fe-Al₂O₃-FeAl₂O₄ composite coatings were successfully deposited by reactive plasma sprayed Al/Fe₂O₃ agglomerated powder. Phase composition and microstructure of the coatings were determined by XRD and SEM. The results indicated that the composite coatings were principally composed of three different phases, i.e. FeAl₂O₄ phase as main framework, dispersed ball-like Fe-rich phase, and small splats of Al₂O₃ phase, and it was thought that the in situ synthesized metal phase was helpful to toughen the coating matrix. According to the results of the indentation and frictional wear tests, the composite coating exhibited excellent toughness and anti-friction properties in comparison with conventional Al₂O₃ monophase coating, though its microhardness value was a little lower than that of Al₂O₃ coating. The formation mechanism and the toughening mechanism of the composite coating were clarified in detail.     

典型颗粒超导体YBa2Cu3O7/V2O5中临界电流随温度变化的特性

通过制备（ＹＢａ₂Ｃｕ₃Ｏ₇）_1-x（Ｖ₂Ｏ₅）_x（０≤ｘ≤０．１５）复合材料，获得了一系列典型的弱连接的颗粒超导体，其中以ｄＲ／ｄＴ－Ｔ关系中呈现出双峰转变为主要特征。第一峰代表晶粒的超导转变，第二峰代表颗粒系统超导长程序的形成。对于具有双峰转变的样品，其临界电流密度一致地符合ｉ_c～（１－ｔ）^ｎ，ｎ＝１．６．这一行为与三维Ｊｏｓｅｐｈｓｏｎ结网络系统的渗流行为相一致；对于不具有双峰转变的系统，临界电流密度随温度的变化尽管也可以用ｊ_c～（１－ｔ）^ｎ描述，但是幂指数ｎ明显地大于１．６，且随样品的不同而离散地分布。本文还对产生这种离散的原因进行探索和分析。 关键词：     

In替代(La2/3Ca1/3)(Mn(3-2x)/3In2x/3)O3体系巨磁电阻效应的研究

采用固态反应法制备了In替代的(La_2/3Ca_1/3)(Mn_(3-2x)/3In_2x/3)O₃(x=0.00，0.10，0.15)体系.通过测量其零场和1.6T磁场下样品的电阻-温度关系以及一定温度下磁电阻率与磁场的关系.发现随In³⁺替代量的增加其磁电阻峰和电阻峰均向低温方向移动，同时巨磁电阻效应减弱，磁电阻峰也展宽.这是由于In³⁺替代量的变化，引起 关键词：     

DETERMINATION OF THE OXYGEN CONTENT IN YBa2Cu3O7-y FILMS

A method for determination of the oxygen content (y) in YBa₂Cu₃O_7-y films has been established, in which the lattice conetant difference (b-a) of the films was measured and used to fit the function of (b-a) vs y for the experimental data of bulk YBaaCuaO?-y given in the literature. It is suggested that the function of (b-a) vs y can indeed be used in the case of film. In this process the twin structure of the YBa₂Cu₃O_7-y films was used.