Evolution of groundwater salinity in the unconfined aquifer of Bou-Areg, Northeastern Mediterranean coast, Morocco

The Bou-Areg plain in the Mediterranean coast at the North-eastern of Morocco is characterized by a semi-arid climate. The aquifer consists of two sedimentary formations of Plio-quaternary age: the upper formation of fine silts and the lower one of coarse silts with sand and gravels. The aquifer is underlain by marly bedrock of Miocene age that dips toward the coastal lagoon of Bou-Areg. The hydrodynamic characteristics vary between 10⁻⁴ and 10⁻³ m/s; and transmissivities range between 10⁻⁴ and 10⁻¹ m²/s. The general direction of flow is SW to NE, toward the lagoon. The aquifer is crossed by the river Selouane, which also ends in the lagoon. The groundwater is characterized by a high salinity that can reach 7.5 g/l. The highest values are observed in the upstream and in the downstream sectors of the aquifer. The temporal evolution of the physico-chemical parameters depends on the climatic conditions and piezometric variations. The analysis of the spatio-temporal distribution of the physico-chemical parameters suggests different sources of groundwater salinization: the seawater intrusion, the influence of marly gypsum-bearing terrains, and the influence of anthropogenic products as the agricultural fertilizers, which cause great nitrate concentrations that vary between 80 and 140 mg/l.     

An extension to the DRASTIC model to assess groundwater vulnerability to pollution: application to the Haouz aquifer of Marrakech (Morocco)

An extension to the DRASTIC model is proposed in order to assess aquifer vulnerability to pollution. In contrast to the DRASTIC model, which considers the unsaturated and saturated zones together and computes a global intrinsic vulnerability index, the suggested approach discriminates between the aquifer vertical vulnerability (a concept related to the pollutant percolation) and the groundwater susceptibility (a concept that depends on the behaviour and uses of the groundwater). This approach is applied to the Haouz aquifer (Morocco) that supplies water to the Marrakech area. This aquifer is widely overexploited and there is evidence that the groundwater quality is threatened by various sources of pollution. Evaluation of the vertical vulnerability indicates that the aquifer mainly presents a moderate-to-weak vertical vulnerability. The zones potentially most favourable to pollutant percolation are mainly located in Central Haouz, along or near the surface wadis. The aquifer susceptibility is high in places located near the N’Fis, Baaja and Issil wadis. Everywhere else, low-to-moderate susceptibility is observed. This new approach therefore enables areas of vertical vulnerability and areas of susceptibility to be delineated separately. As a result, it constitutes a valuable decision-making tool for optimising the management of aquifer water resources and land-use planning.     

Hydrochemical and isotopic characteristics of groundwater in the Souss Upstream Basin, southwestern Morocco

Heterogeneous shallow Plio-Quaternary formations of the Souss Plain represent the most important aquifer in southern High Atlas Mountains in Morocco. The present work was conducted in the Souss Upstream Basin to identify the chemical characteristics and the origin of groundwater in an aquifer under semi-arid climate. Isotopic and hydrochemical compositions combined with geological and hydrogeological data were used for this purpose. The total dissolved solids vary from 239 to 997 mg l⁻¹, and the following groundwater types are recognized: Ca²⁺–Mg²⁺–HCO₃⁻, Ca²⁺–Mg²⁺–SO₄²⁻ and Ca²⁺–Mg²⁺–Cl⁻. The groundwater is saturated and slightly supersaturated with respect to carbonate minerals and undersaturated with respect to evaporite minerals, which means that the groundwater composition is largely controlled by the dissolution of carbonate rocks known in the basin. The isotopic contents of groundwaters ranged from −8‰ to −5.2‰ for δ¹⁸O, from −52‰ to −34‰ for δD, and from 0 to 5.5 TU for tritium. The hydrogen (δD) and oxygen (δ¹⁸O) isotope signatures reveal a significant infiltration before evaporation takes place, indicating a major recharge directly from fractures in the crystalline and limestone formations of Atlas Mountains (above 800 m a.s.l.) and infiltration of surface water in the alluvial cones at the border of the Atlas basins. The very low tritium values suggest that the groundwater recharge follows a long flow path and a mixing between old and modern water is shown. However, a slight evaporation effect is noted in the southern part of the basin close to the Anti-Atlas Mountains.     

Vulnerability mapping of the Turonian limestone aquifer in the Phosphates Plateau (Morocco)

Turonian limestones are an important source of water indispensable for industrial, urban and agricultural development in the Phosphates Plateau. This is an elaboration of a vulnerability map of the aquifer, based on a multicriterion approach according to the DRASTIC charter that serves as a tool for assessment, management and protection of the groundwater quality.     

A thirty-year artificial recharge experiment in a coastal aquifer in an arid zone: The Teboulba aquifer system (Tunisian Sahel)

With the increased demand for groundwater resulting from fast demographic growth, accelerated urbanization, economic and agricultural activity diversification, and the increase of per capita consumption, ground water resources, in particular in coastal regions, remain relatively low, compared to demand. The groundwater quality and piezometric variations result mainly from intensive exploitation, agricultural activities and the intrusion of seawater. This phenomenon is observed mostly in semi-arid areas, such as the oriental Sahel of Tunisia, where an apparent reduction in rainfall in recent years can be seen. Groundwater becomes overexploited especially as its natural recharge by rainwater does not succeed in maintaining the hydrologic balance. The imbalance between water demand and resources induces the degradation of the water quality. In such a case, the artificial recharge of water-table aquifers by water from dams is a credible alternative to improve the hydrodynamic and physicochemical conditions of the groundwater. Like most coastal aquifers, the Teboulba water-table aquifer is threatened by overexploitation for at least three decades. This threat appears by a considerable piezometric level drop and by water salinisation, due to seawater intrusion. Given this alarming situation, since 1971, artificial recharge through wells with surface water from a dam was tested in order to restore the water levels and to improve water quality. The piezometric and chemical surveys of the Teboulba aquifer permitted one to describe the temporal and spatial piezometric and geochemical conditions of the aquifer and to show the effect of the artificial recharge. Indeed, the artificial recharge undertaken since 1971 made the geochemical and piezometric conditions of the Teboulba aquifer improve. This example is a rare, well-documented case-study of the benefits of artificial recharge in a coastal aquifer, over the long term.     

Geochemical evolution of groundwater in the Maneadero coastal aquifer during a dry year in Baja California, Mexico

Water pumped from 25 shallow wells (<31 m) in the Maneadero unconfined coastal aquifer was studied geochemically in order to determine the short-term compositional variability of the aquifer due to seawater intrusion during a drier than normal year (Fall 2001 to Fall 2002). The groundwater was commonly found to be mixed with seawater, with TDS concentrations in November 2002 ranging from 0.99 to 9.46 g l^–1, having an intermediate Na⁺Cl^– to Ca²⁺Cl^– water-type. Rapid recharge events of short duration, after low and short rainfall events during the study period, are suggested from short-term fluctuations in water quality. Seawater intrusion is progressing faster in the central and southern coastal sections of the aquifer and has recently affected the quality of the sites pumping water to the nearby city of Ensenada. Only one of the wells used for the Ensenada water supply had a TDS concentration lower than the 1.0 g l^–1 official limit. Low flow rates and high residence times of water are inferred to be the cause for high alkalinity in the east-central section of the aquifer. High NO₃ in the east-central aquifer indicates that any NO₃ infiltration due to fertilizer use was only slightly dispersed. After a short rainfall season during winter 2001, a significant decrease was seen for the previously most enriched site. However, concentrations above the 10 mg l^–1 official limit persisted in 2002, affecting one well for urban supply (15.9 mg l^–1). The water from this well is nevertheless mixed with better-quality water from other wells before being distributed through the citys piping system.

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Resumen Se estudió la geoquímica de aguas bombeadas por medio de 25 pozos no muy profundos (<31 m) en el acuifero costero no confinado de Maneadero con el objetivo de determinar la variación de la composición en el corto plazo en el acuifero por la intrusión de agua de mar durante un año más seco de lo normal (otoño 2001 a otoño 2002). Se observó que comúnmente las aguas subterráneas estaban mezcladas con agua de mar, con concentraciones de sólidos totales disveltos (STD) de entre 0.99--9.46 g l^–1 y un tipo de agua intermedia Na⁺Cl^– to Ca²⁺Cl^–. A partir de las fluctuaciones en la calidad del agua en el corto plazo se puede inferir que se dan eventos de recarga rápida de poca duración después de eventos de poca lluvia de poca duración y poco volumen durante el periodo de estudio. La intrusión de agua de mar está progresando más rápido en el centro y sur del acuifero costero y ha afectado recientemente la calidad de los sitios de bombeo de agua para la ciudad de Ensenada. Solamente uno de los pozos usados para el abastamiento de Ensenada tiene un STD por debajo del límite oficial de 1.0 g l^–1. Se presume que las razones lentas de flujo y los tiempos de residencia largos del agua son la causa de la alta alcalinidad en el centro-este del acuifero. Una concentración alta de NO₃ en el este-centro del acuifero indica que cualquier infiltración de NO₃ por aplicación de fertilizantes ha sido poco dispersad. Después de poca lluvia en el invierno de 2001, se observó una disminución importante en la zona previamente más enriquecida. Sin embargo, concentraciones sobre el límite oficial de 10 mg l^–1 continuaron en 2002, afectando a un pozo para suministro de agua urbana (15.9 mg l^–1). El agua extraída de este pozo es mezclada con agua de mejor calidad y se distribuye por el sistema urbano de suministro de agua.

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Résumé Leau de pompage de 25 puits peu profonds (<31 m) situés dans laquifère côtier non-confiné de Maneadero a été étudiée dans le but de déterminer la variation géochimique à court terme qui résulte de lintrusion deau de mer lors dune année plus sèche quà lhabitude (automne 2001 à automne 2002). Leau souterraine est souvent retrouvée mélangée avec de leau de mer, avec des concentrations en résidus solides dissous (RSD) qui sétalent entre 0.99 et 9.46 g l^–1 pour novembre 2002, avec un type intermédiaire en Na⁺Cl^– jusquà Ca²⁺Cl^–. Les processus suggérés pour les fluctuations rapides de la qualité de leau sont des événements de recharge de courte duré suite à de faibles et brèves périodes de précipitations. Lintrusion deau de mer progresse plus rapidement dans les parties centrales et sud de laquifère côtier où la qualité de leau pompée vers la ville de Ensenada a récemment été affectée. Un seul des puits utilisés par la ville de Ensenada pour lapprovisionnement en eau potable a une concentration en RSD sous la limite officielle permise de 1.0 g l^–1. Le temps de résidence élevé et le faible taux découlement de leau souterraine sont présumés être la cause de lalcalinité élevée dans la partie centrale-est de laquifère. La concentration élevée en NO₃ dans cette partie de laquifère indique que la totalité de linfiltration de NO₃ dû à lutilisation de fertilisants ne sest que très peu dispersée. Suite à une courte saison des pluies à lhiver 2001, une diminution substantielle a été notée au site qui était le plus enrichi avant la saison des pluies. Malgré tout, des concentrations dépassant la limite officielle permise de 10 mg l^–1 ont persisté, affectant un puits utilisé pour lapprovisionnement urbain (15.9 mg l^–1). Leau provenant de ce puits est toutefois mélangée avec de leau de meilleure qualité provenant dautres puits avant dêtre distribuée par laqueduc municipal.

     

Using DC resistivity method to characterize the geometry and the salinity of the Plioquaternary consolidated coastal aquifer of the Mamora plain,Morocco

The Direct Current resistivity method was applied to the consolidated coastal Plioquaternary aquifer of Mamora plain, located on the Atlantic coast of Morocco. The aim is to determine the depth of the base of the saturated zone in the aquifer and to help in imaging lateral and vertical distribution of groundwater salinity. The geoelectric survey showed four geoelectric formations with the following electrical resistivities from top to bottom: 20–80, 200–2000, 200–300 and 5–70 Ohm m. The latter designates the basement of the aquifer constituted of marls and sandy marls. The mean resistivity of 250 Ohm m designates the aquifer formation. It decreases to less than 25% of its initial values for the soundings near the shore, reflecting the oceanic impact on the aquifer formation resistivity. The contour map shows that the basement of the saturated zone in the aquifer is deeper in the Northwest near the Sebou River estuary with values up to 70 m below sea level. This results in a larger thickness of the saturated zone of the aquifer leading to a consequent hydraulic potential. On the other hand, it has been deduced that the extent of marine intrusion inside the continent can be governed by human activities, natural properties and substratum geometry of the aquifer as well as by ecological factors. An optimal network of electrical soundings has been proposed for the monitoring of saltwater intrusion.     

Evaluation and numerical modeling of seawater intrusion in the Gaza aquifer (Palestine)

A numerical assessment of seawater intrusion in Gaza, Palestine, has been achieved applying a 3-D variable density groundwater flow model. A two-stage finite difference simulation algorithm was used in steady state and transient models. SEAWAT computer code was used for simulating the spatial and temporal evolution of hydraulic heads and solute concentrations of groundwater. A regular finite difference grid with a 400 m² cell in the horizontal plane, in addition to a 12-layer model were chosen. The model has been calibrated under steady state and transient conditions. Simulation results indicate that the proposed schemes successfully simulate the intrusion mechanism. Two pumpage schemes were designed to use the calibrated model for prediction of future changes in water levels and solute concentrations in the groundwater for a planning period of 17 years. The results show that seawater intrusion would worsen in the aquifer if the current rates of groundwater pumpage continue. The alternative, to eliminate pumpage in the intruded area, to moderate pumpage rates from water supply wells far from the seashore and to increase the aquifer replenishment by encouraging the implementation of suitable solutions like artificial recharge, may limit significantly seawater intrusion and reduce the current rate of decline of the water levels.     

Hydrogeochemical evolution of groundwater in a Mediterranean coastal aquifer, Mersin-Erdemli basin (Turkey)

In this study, hydrogeologic and hydrochemical information from the Mersin-Erdemli groundwater system were integrated and used to determine the main factors and mechanisms controlling the chemistry of groundwaters in the area and anthropogenic factors presently affecting them. The PHREEQC geochemical modeling demonstrated that relatively few phases are required to derive water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area fall into four categories: (1) silicate weathering reactions; (2) dissolution of salts; (3) precipitation of calcite, amorphous silica and kaolinite; (4) ion exchange. As determined by multivariate statistical analysis, anthropogenic factors show seasonality in the area where most contaminated waters related to fertilizer and fungicide applications that occur during early summer season.     

Mapping of groundwater quality in the Turonian aquifer of Oum Er-Rabia Basin, Morocco: a case study

This study takes the groundwater of the Moroccan limestone aquifer of Oum Er-Rabia as an example of statistical and cartographical approaches in water resources management. Statistical analyses based on frequency distribution and PCA methods revealed the homogeneity of waters with the existence of abnormal points and have helped to assess correlations between the studied variables. The mapping approach illustrated that waters are influenced by the lithology of the surrounding rocks and are of Ca–Mg–HCO₃, Ca–Mg–Cl–SO₄, and mixed types according to the Piper classification. The quality of water is of high to medium, north of the basin, but it is of medium to bad, NE and south, due to excessive contents of chloride, sulfate and nitrate. According to the US Salinity Laboratory classification, water used for irrigation in the eastern and the southern parts of the basin should take into consideration the drainage conditions, the nature of plants and the addition of gypsum doses.

Incidences of water-rock interaction on natural resources characters,Oum Er-Rabia Basin (Morocco)

The Oum Er-Rabia Basin provides important water resources from a multi-layer aquifer system of which the Turonian limestone aquifer constitutes the main potential resource. The same basin is also known by its wealth in phosphates and comprises the Ouled Abdoun Series, the largest Moroccan phosphate occurrence. The present work attempts to characterize the interaction of natural resources with their impacts on water and phosphates quality. Hydrogeochemical data on waters of the Turonian and the Eocene aquifers, as well as their petrographical analyses, by optical and electronic microscopes and by the X-ray diffraction method on weathered and non-weathered rocks of relative aquifers, have shown that water-rock interaction has a large influence on the quality of water and phosphate resources in the Oum Er-Rabia Basin.     

Environmental impact assessment using rapid impact assessment matrix (RIAM) for Russeifa landfill, Jordan

An environmental impact assessment (EIA) study for the solid waste landfill was prepared for the Russeifa area, northeast Jordan. As landfill was not subjected to sophisticated EIA, serious environmental problems are still occurring, such as groundwater contamination and air pollution. Three alternatives were proposed to rehabilitate the landfill: upgrading the existing landfill, construction of a biogas plant and its relocation. The EIA for the three options was carried out using the rapid impact assessment matrix (RIAM), it applies a consistent and recordable assessment of the importance of the different components. The scoping components included in the RIAM were: physical/chemical, biological/ecological, social/cultural and economic/operational components. The RIAM analysis showed that the least negative impacts would be to relocate to a better-managed sanitary landfill. The most serious negative impacts were the contamination of groundwater, air pollution and public health. These impacts can be mitigated through a comprehensive environmental management plan for the Russeifa landfill to address the deterioration of environmental components in the vicinity of landfill.     

Identification of hydrogeochemical zones in postglacial buried valley aquifer (Wielkopolska Buried Valley aquifer,Poland)

This article presents the difficulty in identifying the hydrochemical zoning of a semi-confined aquifer, characterised by a relative small spatial differentiation of groundwater chemistry. It is shown that multivariate statistical methods can be used for the recognition and interpretation of the groundwater chemistry distribution in an aquifer. The hydrochemical zonation caused by both natural and anthropogenic processes was identified using factor analyses in combination with a classical interpretation of the hydrogeological material. The interpretation of the groundwater chemistry allows both identification of the aquifer recharge mechanism and verification of the groundwater-flow system.     

Chemical composition of landfill leachate in a karst area with a Mediterranean climate (Marbella, southern Spain)

 Between March 1994 and April 1997, the physical and chemical parameters and chemical composition of the urban solid waste leachate of the Marbella landfill (southern Spain) were determined. The data obtained show an ammonium and sodium chloride and bicarbonate type, a pH>7 and high mineralization, effectively described by the following parameters: Na⁺, K⁺, NH₄ ⁺, Cl^– and alkalinity. The chemical composition depends on the rainfall: in dry years, the mineralization and component concentrations have values as much as double those found in normal rainfall years. After storm events, a major and rapid dilution (within several hours) is seen in the leachate. Received: 28 January 1998 · Accepted: 2 June 1998     

Numerical modelling of surfacewater/groundwater flows for freshwater/saltwater hydrology: the case of the alluvial coastal aquifer of the Low Guadalhorce River, Malaga, Spain

This applied research deals with the numerical modelling and transient simulation of the joint surfacewater/groundwater flows that characterize the freshwater/saltwater hydrology of the coastal alluvial valley of the Low Guadalhorce River, Malaga, Spain. The MELEF model used was mainly adapted and calibrated for a simulation period of two hydrological years 1989/1990–1990/1991, before the current channelling of the river, where floods and low precipitations have been recorded. The model calibration process was performed with the aid of phreatic levels measured in numerous wells and piezometers, as well as recharges from precipitation and irrigation on the alluvial surface, which was also assessed by the hydrologic model SSMA-2. The present numerical approach can predict the forthcoming hydrology of the coastal alluvial of the Guadalhorce River after its final channelling.     

Evolution of the groundwater environment under a long-term exploitation in the coastal area near Zhanjiang, China

Aquifers consisting of unconsolidated sediments in the coastal area near Zhanjiang in southern China are grouped into the shallow, middle-deep and deep aquifer systems. Groundwater exploitation began in the 1950s in this district and has increased from year to year since 1980. Measurements of groundwater levels and monitoring data of groundwater chemistry at some 60 wells since 1981 are examined to analyze the evolution of hydrodynamics and hydrochemistry in the coastal aquifers. The results indicate that groundwater levels in the middle-deep and deep aquifer systems have fallen continuously and the extents of the depression cones in water levels have increased in the past two decades, even though the water levels recovered to some degree during the period of 1997–2001. In 2004, the lowest water levels in the middle-deep and deep aquifer systems were 23.58 and 21.84 m below sea level, respectively. The groundwater has TDS ranging from 40 to 550 mg/L, and is of low pH, commonly varies between 4 and 7. Concentrations of total iron and manganese exceed the concentration limits of the drinking water standards. The hardness is in the range of 10–250 mg/L. Chloride contents of the groundwater range from 10 to 60 mg/L. The chloride and TDS do not show systematically increasing trends. Although the water levels in the exploitation center near the coast are significantly lower than the sea level and the depression cones of water levels in the middle-deep and deep aquifer systems have expanded to the sea, sea water intrusion has not been observed until recently. This phenomenon is quite unique in the coastal area near Zhanjiang.     

The influence of a heavily polluted urban river on the adjacent aquifer systems

 Ankara Creek is often subjected to overflowing of sewage caused by rainfall or direct discharge of raw sewage. Alluvial aquifers adjacent to Ankara Creek and its tributaries have considerable groundwater potential. The present status of groundwater quality is far from drinking water standards. Groundwater contamination in Ankara is suspected to be caused by Ankara Creek which is heavily polluted by raw sewage discharge, surface runoff and other common sources. In order to investigate the influence of heavily polluted Ankara Creek on the groundwater contamination in the adjacent alluvial aquifers, five sampling stations on Ankara Creek and 25 water wells were monitored during 1996. At five different sampling periods, water samples were collected from both surface water and groundwater. Chemical analyses of basic ions, pollution parameters and heavy metals in natural waters were carried out. The organic pollution prevails in Ankara Creek whereas total dissolved solids (TDS) and heavy metal concentrations are considerably low. Starting from the idea that Ankara Creek somewhat influences the groundwater quality and the contaminants in groundwater should attenuate with respect to distance, a series of water wells in a certain area, each having different distance from the creek, were examined using four pollution parameters. It is concluded that Ankara Creek barely influences the aquifer systems in connection. This is attributed to two reasons: rapid attenuation of contaminants due to dilution in groundwater and a blanket of very fine sized materials covering the bottom of Ankara Creek. Received: 28. April 1997 · Accepted: 23. February 1998     

The impact of human activities in the Malia coastal area (Crete) on groundwater quality

The evaluation of the long-term effects of seawater intrusion into the aquifers due to negative water balance and nitrate pollution of drinking-water quality due to human activities requires detailed knowledge of both the transport of the chemical constituents and the geochemical processes within aquifers. Hydrogeological and hydrochemical studies in the unconfined aquifer of Malia have provided the necessary data to define the areas at increased risk from these phenomena. The solution of the second Fick's low under given boundary conditions gave an estimate of the propagation of groundwater pollution by NO₃ ^–. Additionally, in order to simulate the ion concentration changes during a period, for example a period of positive water balance or refreshening, groundwater transport and cation exchange reactions were modelled using the code PHREEQM. Received: 25 July 1997 · Accepted: 4 November 1997     

Groundwater pollution in Quaternary aquifer of Vitoria – Gasteiz (Basque Country, Spain)

 As a result of diverse changes in land use and in water-resource management in the high basin of the Zadorra River (Basque Country), an important loss of water resources and an intense contamination by nitrogen compounds has taken place. The purpose of this paper is to detail the land transformations that have taken place on the aquifer since the 1950s: increase of drainage network, change from dry to irrigated farming, and diversion of rivers at the aquifer unit inlet. Furthermore, we analyze the impact of these transformations on the hydrodynamics and water quality of this aquifer system. Received: 12 January 1996 · Accepted: 10 March 1996     

垃圾渗滤液污染场地NO_3~-、PO_4~(3-)和SO_4~(2-)对微生物活性的影响

通过实验研究垃圾渗滤液污染场地N、S、P和湿度等因素对微生物活性的影响.结果表明：同时添加N和P后,土壤和细砂中微生物活性分别在第7 天和第14 天达到最大值0.685和0.588,有机质质量分数分别降低了10.97%和22.1%,平均降解速率分别为0.405和0.190 mg/(kg·d);添加NO_3~-后,土壤和细砂中有机质质量分数分别减少了10.3%和28.9%;添加SO_4~(2-)后,土壤和细砂中有机质质量分数分别减少了8.87%和28.4%;另外,湿度为50%和60%时,土壤中微生物活性的最大值分别为0.259和0.266,有机质平均分解速率分别为0.195和0.305 mg/(kg·d).因此,N、S、P和湿度对地下环境中微生物的活性有重要影响.