共查询到20条相似文献,搜索用时 0 毫秒
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首先以不同比例的铬绿和氧化铝粉电熔制得Cr2O3质量分数分别为15%、40%、50%、60%、85%、99%的6种Cr2O3-Al2O3电熔颗粒料(其编号依次为CR15、CR40、CR50、CR60、CR85和CR99),然后采用回转渣蚀法研究了此电熔颗粒料(4~1 mm)的抗侵蚀性。结果显示:电熔颗粒料的抗侵蚀性随Cr2O3含量的增加及颗粒尺寸的增大而增强;高Cr2O3含量的CR99、CR85颗粒料在渣面层被侵蚀,主要是渣中的FeO和Al2O3对颗粒料的侵蚀,FeO与骨料中的Cr2O3反应,首先形成(Fe,Cr)3O4尖晶石,再与其他物相反应形成了复合尖晶石,当FeO耗尽后,渗入到颗粒内的Al2O3开始和Cr2O3反应,在颗粒表面形成铝铬固溶体;CR60颗粒料在渣面层和渗透层都存在侵蚀,渗透层的侵蚀主要是CaO、SiO2对颗粒料中铝铬固溶体中Al2O3的熔蚀,形成钙长石、钙黄长石以及玻璃相;Cr2O3含量较低的CR50、CR40、CR15颗粒料在渗透层内的侵蚀机制和CR60颗粒料的相同。 相似文献
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The ionic conduction in sintered Bi2O2-Y2O3 was investigated by measuring the conductivity and the emf of an oxygen concentration cell using the specimen tablet as electrolyte. The face centred cubic phase in this system was found to show high oxide ion conduction accompanied by a little electronic conduction when exposed to air. This phase was stable with a composition of 25 ~ 43 mol % Y2O3 over a wide range of temperatures, and the oxide ion conductivity increased with decrease in Y2O3. The conductivities of (Bi2O3)0.75 (Y2O3)0.25 were 1.6×10?1 Ω?1 cm?1 at 700°C and 1.2×10?2 Ω?1 cm?1 at 500°C values which are many times higher than those of stabilized zirconia (ZrO2)0.90(Y2O3)0.10 at corresponding temperatures. Specimens containing less than 25 mol % Y2O3 showed a phase transition at 700 ~ 580°C and the conductivities decreased remarkably below these temperatures. High oxide ion conduction in the fcc phase is attributed to the migration of oxide ion vacancies which were present in an appreciable amount. 相似文献
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E. S. Lukin A. S. Vlasov N. M. Astakhova E. V. Bykova 《Refractories and Industrial Ceramics》1987,28(1-2):63-65
Conclusions A highly dense ceramic based on the eutectic composition of the Al2O3-ZrO2 system was obtained using 3 mole % Y2O3 addition. The ceramic has a fine-grained structure and high hardness and strength.Translated from Ogneupory, No. 2, pp. 8–10, February, 1987. 相似文献
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《Ceramics International》2019,45(12):14505-14509
Combustion synthesis of SiC-MoSi2-Al2O3 composites by using highly exothermic reactive system of MoO3-Al-Si-SiO2 was investigated. It has been shown that, by using the combustion synthesis method, it is feasible to prepare, at 1500 °C, an electrical heating element with room temperature resistivity and element watt loading of 12 Ω cm and 20 W/cm2 respectively. The colloid containing nano-sized material 30 wt% SiO2, was used as the plasticizer medium as well as combustion source. The β-SiC functioned as a filler material to control the combustion reaction and also constituted part of the final product. The amount of SiC additive varied in the range from 45% to 65% wt. and was optimized with respect to porosity level, reaction conversion and net-shape quality of the heating elements. The element containing about 60% wt. SiC reveals low porosity level, with full conversion for the reaction and superior net-shape quality. However, despite the relatively high level of porosity present in the final synthesized product, it can be used as an electrical heating element in accordance with the investigation at the element temperatures up to 1500 °C. 相似文献
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P. Yadav A. A. Muley C. P. Joshi S. V. Moharil P. L. Muthal S. M. Dhopte 《International Journal of Self-Propagating High-Temperature Synthesis》2012,21(2):124-133
In the Y2O3-Al2O3 system, compounds Y3Al5O12 (yttrium aluminum garnet, YAG), YAlO3 (yttrium aluminum perovskite, YAP), and Y4Al2O9 (yttrium aluminate monoclinic, YAM) are well known. YAG and YAP are of considerable technological importance. Conventional solid-state reaction techniques require high sintering temperatures (above 1800°C) to prepare phase-pure compounds. Though several soft chemical routes have been explored for synthesis of YAG, YAP and YAM, most of these methods are complex. Moreover, phase-pure materials are not obtained in one step and prolonged annealing at temperatures around 1000°C is necessary. In this paper, one-step combustion synthesis of these compounds is reported using a modified procedure and employing mixed (glycine + urea) fuel. Phosphors based on Ce3+ activation were also prepared and exhibited characteristic photoluminescence. 相似文献
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V. A. Rakhmanov 《Glass and Ceramics》1991,48(11):522-523
Translated from Steklo i Keramika, No. 11, pp. 22–23, November, 1991. 相似文献
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N.A. Wójcik N.S. Tagiara S. Ali K. Górnicka H. Segawa T. Klimczuk B. Jonson D. Möncke E.I. Kamitsos 《Journal of the European Ceramic Society》2021,41(10):5214-5222
In this work, glass-ceramics in the xBeO–20Fe2O3–(80-x)TeO2 system with x = 0–25 mol% were synthesized by the traditional melt quenching route and studied by inductively coupled plasma optical emission spectroscopy, X-ray diffraction, confocal microscopy, infrared and Raman spectroscopy. BeO addition was found to support the crystallization process of Fe2O3 during melting, and an increased BeO content was associated with an increased fraction of the crystalline Fe2O3 phase and an increased size of these crystallites. Furthermore, samples doped with BeO exhibit an increasing polymerization of the residual tellurite glass network compared to the undoped sample. The magnetic properties and specific heat of all synthesized materials were measured, and the results show that all studied samples behave as spin-glasses. Also, the Morin transition of hematite was observed at 260 K with intensity depending on the material content in Fe2O3 crystalline phase, the formation of which correlates with the amount of added BeO. 相似文献
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H.C. Yao 《Journal of Catalysis》1981,70(2):440-444