Anthropogenic CO2 distribution in the North Pacific Ocean

The depth of penetration of anthropogenic CO₂ in the North Pacific Ocean based on carbonate data in the literature is discussed. The results indicate that the deepest penetration (over 2000 m) is found in the northwest North Pacific. The shallowest penetration (to less than 400 m) is found in the eastern equatorial Pacific. Depth of penetration of anthropogenic CO₂ appears to have been controlled by such factors as deep water formation in the Northwest Pacific; upwelling in the equatorial Pacific and; vertical mixing in the western boundary areas. These results compare well with results implied from tritium, C-14, and freons distributions. The total inventory of excess carbon in the North Pacific was 14.7±4×10¹⁵ g around 1980.     

Temporal variations of surface oceanic and atmospheric CO2 fugacity and total dissolved inorganic carbon in the northwestern North Pacific

In order to examine temporal variations of the surface oceanic and atmospheric fCO₂ and the DIC concentration, we analyzed air and seawater samples collected during the period May 1992–June 1996 in the northwestern North Pacific, about 30 km off the coast of the main island of Japan. The atmospheric CO₂ concentration has increased secularly at a rate of 1.9 ppmv yr⁻¹, and it showed a clear seasonal cycle with a maximum in spring and a minimum late in summer, produced mainly by seasonally-dependent terrestrial biospheric activities. DIC also showed a prominent seasonal cycle in the surface ocean; the minimum and maximum values of the cycle appeared in early fall and in early spring, respectively, due primarily to the seasonally-dependent activities of marine biota and partly to the vertical mixing of seawater and the coastal upwelling. The oceanic fCO₂ values were almost always lower than those of the atmospheric fCO₂, suggesting that this area of the ocean acts as a sink for atmospheric CO₂. Values varied seasonally, mainly reflecting seasonal changes of SST and DIC, with a secular increase at a rate of 3.7 μatm yr⁻¹. The average values of the annual net CO₂ flux between the ocean and the atmosphere calculated by using the different bulk equations ranged between −0.8 and −1.7 mol m⁻²yr⁻¹, and its magnitude was enhanced and reduced late in spring and mid-summer, respectively, due mainly to the seasonally varying oceanic fCO₂.     

Temporal Evolution of the North Pacific CO2 Uptake Rate

The recent changes in the North Pacific uptake rate of carbon have been estimated using a number of different techniques over the past decade. Recently, there has been a marked increase in the number of estimates being submitted for publication. Most of these estimates can be grouped into one of five basic techniques: carbon time-series, non-carbon tracers, carbon tracers, empirical relationships, and inverse calculations. Examples of each of these techniques as they have been applied in the North Pacific are given and the estimates summarized. The results are divided into three categories: integrated water column uptake rate estimates, mixed layer increases, and surface pCO₂ increases. Most of the published values fall under the water column integrated uptake rate category. All of the estimates varied by region and depth range of integration, but generally showed consistent patterns of increased uptake from the tropics to the subtropics. The most disagreement between the methods was in the sub-arctic Pacific. Column integrated uptake rates ranged from 0.25 to 1.3 mol m⁻²yr⁻¹. The mixed layer uptake estimates were much more consistent, with values of 1.0–1.3 μmol kg⁻¹yr⁻¹ based on direct observations and multiple linear regression approaches. Surface pCO₂ changes showed the most obvious regional variability (0.5–2.5 μatm yr⁻¹) reflecting the sensitivity of these measurements to differences in the physical and biological forcing. The different techniques used to evaluate the changes in North Pacific carbon distributions do not completely agree on the exact magnitude or spatial and temporal patterns of carbon uptake rate. Additional research is necessary to resolve these issues and better constrain the role of the North Pacific in the global carbon cycle. This revised version was published online in July 2006 with corrections to the Cover Date.     

Interdecadal modulation of interannual atmospheric and oceanic variability over the North Pacific

The interdecadal modulation of interannual variability of the atmosphere and ocean is examined over the North Pacific by using Wavelet Transform combined with Empirical Orthogonal Function (EOF) or Singular Value Decomposition (SVD) analysis. For the period of record 1899–1997, the interannual variability of the wintertime Aleutian Low, identified by either the North Pacific Index or the leading eigenvector (EOF-1) of North Pacific sea level pressure (SLP), exhibits an interdecadal modulation. Interannual variance in the strength of the Aleutian Low was relatively large from the mid-1920s to mid-1940s and in the mid-1980s, but relatively small in the periods from 1899 to the mid-1920s and from the mid-1940s to the mid-1970s. The periods of high (low) interannual variability roughly coincide with pentadecadal regimes having a time averaged relatively intense (weak) Aleutian Low. Consistent with this SLP variability the interannual variance in the zonal wind stress is strengthened in the central North Pacific after the 1970s. The SLP EOF-2, which is related to the North Pacific Oscillation, exhibited a strengthening trend from the beginning of this century to the mid-1960s. After the 1970s, the interannual variance of SLP EOF-2 is generally smaller than that in the period from 1930 to 1970. Similar interdecadal changes in interannual variance are found in expansion coefficients for the first two EOFs of the Pacific sector 500 hPa height field for the period 1946–1993. EOF-1 of Pacific sector 500 hPa corresponds to the Pacific/North American (PNA) teleconnection pattern, while EOF-2 is related to the Western Pacific (WP) pattern. The relative influence of the atmospheric PNA and WP interannual variability on North Pacific SSTs appears to have varied at pentadecadal time scales. Results from an SVD analysis of winter season (December–February) 500 hPa and North Pacific spring season (March–May) SST fields demonstrate that the PNA-related SST anomaly exhibited larger interannual variance after the 1970s, whereas the interannual variance of the WP related SST anomaly is larger before the 1970s. Correlations between the coastal North Pacific SST records and gridded atmospheric field data also change on interdecadal time scales. Our results suggest that the SST records from both the northwest and northeast Pacific coasts were more closely coupled with the PNA teleconnection pattern during the periods of 1925–1947 and 1977–1997 than in the regime from 1948 to 1976. Teleconnections between ENSO and preferred patterns of atmospheric variability over the North Pacific also appear to vary on interdecadal time scales. However, these variations do not reflect a unique regime-dependent influence. Our results indicate that ENSO is primarily related to the PNA (WP) pattern in the first (last) half of the present century. Correlation coefficients between indices for ENSO and PNA-like atmospheric variability are remarkably weak in the period from 1948 to 1976.     

Lethality of increasing CO2 levels on deep-sea copepods in the western North Pacific

The first CO₂ exposure experiments on several species of pelagic copepods inhabiting surface and deep layers in the western North Pacific were conducted. Living organisms were collected from two layers between the surface and 1,500 m between latitudes of 11 and 44°N, and they were exposed aboard ship to various pCO₂ up to about 98,000 μatm. Mortality of copepods from both shallow and deep layers in subarctic to subtropical regions increased with increasing pCO₂ and exposure time. Deep-living copepods showed higher tolerance to pCO₂ than shallow-living copepods. Furthermore, deep-living copepods from subarctic and transitional regions had higher tolerances than the subtropical copepods. The higher tolerances of the deep-living copepods from subarctic and transitional regions may be due to the adaptation to the natural pCO₂ conditions in the subarctic ocean.     

Seasonal variation of atmospheric coupling with oceanic mesoscale eddies in the North Pacific Subtropical Countercurrent

This study investigated the seasonal variation in the atmospheric response to oceanic mesoscale eddies in the North Pacific Subtropical Countercurrent (STCC) and its mechanism, based on satellite altimetric and reanalysis datasets. Although mesoscale eddy in the study area is more active in summer, the sea surface temperature (SST) anomaly associated with mesoscale eddies is more intense and dipolar in winter, which is largely due to the larger background SST gradient. Similarly, the impact of the oceanic eddy on sea surface wind speed and heat flux is strongest in winter, whereas its effect on precipitation rate is more significant in summer. The study revealed that the SST gradient in STCC could impact the atmosphere layer by up to 800 hPa (900 hPa) in boreal winter (summer) through the dominant vertical mixing mechanism. Moreover, the intensity of the SST gradient causes such seasonal variation in mesoscale air-sea coupling in the study region. In brief, a stronger (weaker) background SST gradient field in wintertime (summertime) leads to a larger (smaller) eddy-induced SST anomaly, thus differently impacting atmosphere instability and transitional kinetic energy flux over oceanic eddies, leading to seasonal variation in mesoscale air-sea coupling intensity.     

Concentration and toxic potential of polychlorinated biphenyl congeners in migratory oceanic birds from the North Pacific and the Southern Ocean

Concentrations of PCBs and their toxic potential were examined in subcutaneous fat of eight albatross and one petrel species collected from the North Pacific and the Southern Oceans. Among all the species analyzed, high PCB levels were found in adult male blackfooted albatross from the North Pacific with the mean value of 92 microg/g wet weight. No significant gender difference in PCB accumulation was observed (P>0.1). The mean PCB levels in Southern Oceanic birds were 1 or 2 orders of magnitude lower than those from the North Pacific albatrosses. A regional-specific accumulation of non-ortho coplanar congeners were observed, most birds from the Southern Ocean had higher IUPAC 169 levels while IUPAC 126 concentrations were higher in those from the North Pacific. The estimated toxic equivalents for black-footed and Laysan albatrosses from the North Pacific were in the same range of some fish-eating birds, which were highly contaminated by PCBs. The correlation between ratio of IUPAC 169/126 concentration and total PCBs concentration indicated the possibility of induction in cytochrome P450 activities in North Pacific albatrosses (P<0.01). The calculated hazard indices indicated that black-footed and Laysan albatrosses inhabiting in the North Pacific had similar threshold levels which were known to cause toxic effects in some populations of fish-eating birds.     

A study of the subarctic boundary region in the Western North Pacific

During autumn 1968 an oceanographic investigation was conducted in the region of the Subarctic boundary between 155°E and 180°. The geostrophic flow of the upper 500 m was remarkably similar in direction; hence the salinity-minimum, Intermediate water must have the same path of flow as water at the surface. A water mass analysis revealed a decrease in the percentage of Subarctic water to the south and east, plus an increase in the homogeneity of water to the east, which supports Reid's conclusions that the salinity minimum results mainly from lateral mixing in the pycnocline in this region. Salinity at the minimum increases toward the south and east, and the density at this level also increases slightly from the western to the central Pacific, perhaps as a result of unequal vertical mixing above and below the minimum.     

热带外太平洋通过海洋过程对热带太平洋的影响

利用MOM2海洋环流模式分别研究了年际和年代际尺度上热带外太平洋通过海洋过程对热带太平洋的影响.利用1945~1993年COADS资料的表面通量强迫海洋模式,积分46 a作为模式控制试验.取热带外太平洋海表面强迫为气候值做敏感性试验.将控制试验结果减去敏感性结果就可以得到热带外太平洋通过海洋过程对热带太平洋的影响.结果表明,年际尺度上,主要是海洋波动过程起作用,但总的海洋过程的影响较小.年代际尺度上,主要是副热带环流输送起作用,其中包括平均环流输送的温度异常以及异常环流输送的平均温度,并且后者贡献相对较大.年际和年代际尺度上,热带太平洋的温度异常主要发生在密度跃层附近.研究发现热带外南太平洋对热带和热带外太平洋之间的水量交换有影响,而热带外北太平洋的影响较弱.     

Uncoupled transport of chlorofluorocarbons and anthropogenic carbon in the subpolar North Atlantic

Chlorofluorocarbon (CFC) 11 and 12 transports across the transoceanic World Ocean Circulation Experiment (WOCE) A25 section in the subpolar North Atlantic are derived from an inverse model using hydrographic and ADCP data (Lherminier et al., 2007). CFC and anthropogenic carbon (C_ANT) advective transports contrary to expected are uncoupled: C_ANT is transported northeastwards (82±39 kmol s^?1) mainly within the overturning circulation, while CFC-11 and CFC-12 are transported southwestwards (?24±4 and ?11±2 mol s^?1, respectively) as part of the large-scale horizontal circulation. The main reason for this uncoupled behaviour is the complex CFC vs. C_ANT relation in the ocean, which stems from the contrasting temperature relation for both tracers: more C_ANT dissolves in warmer waters with a low Revelle factor, while CFC’s solubility is higher in cold waters. These results point to C_ANT and CFC having different routes of uptake, accumulation and transport within the ocean, and hence: C_ANT transport would be more sensitive to changes in the overturning circulation strength, while CFC to changes in the East Greenland Current and Labrador Sea Water formation in the Irminger Sea. Additionally, C_ANT and CFCs would have different sensitivities to circulation and climate changes derived from global warming as the slowdown of the overturning circulation, increase stratification due to warming and changes in wind stress.     

Thickening of the oceanic layer in the Pacific Ocean

A statistical analysis of published seismic refraction results in the Pacific Ocean confirms the existence of a progressive thickening of the oceanic layer with age, following an inverse exponential law. There is no strong indication in the Pacific data of an increase in the thickness of layer 2 with decreasing spreading rate.Contribution No. 93 of the Département Scientifique of the Centre Océanologique de Bretagne, B.P. 337, 29200, Brest, France.     

Decadal-to-interdecadal response and adjustment of the North Pacific to prescribed surface forcing in an oceanic general circulation model

1IntroductionAvariety of observational evidences have shownthe existence of decadal-to-interdecadal variabilitiesin the Pacific Ocean.The phase transition for thosevariabilities could be gradual or abrupt.A strikingexample for abrupt change is the so-call…     

Cadmium and zinc concentrations in zooplankton in the subarctic region of the North Pacific

Cadmium and zinc concentrations were determined in 10 species of pelagic zooplankton collected in the northern North Pacific, the Bering Sea, the Okhotsk Sea and off Hokkaid?, during the summers of 1974–1976. The mean cadmium contents in euphausiids, copepods, and amphipods were 1.16μg/g dry wt (range: 0.36–2.17μg/g), 6.63μg/g (1.66–14.55μg/g), and 8.28μg/g (2.83–14.50μg/g), respectively. Cadmium in euphausiids was significantly lower in concentration than in the other two crustacean groups. The difference in cadmium levels among the crustacean groups is discussed on the basis of feeding habits and physiological characteristics of the zooplankton. Zinc levels in the crustaceans were similar, with values around 100μg/g (range: 59–195μg/g). Both cadmium and zinc concentrations in euphausiids taken from coastal waters off Hokkaid? were significantly higher than those from the Bering Sea and the northern North Pacific. This trend may reflect coastal pollution rather than characteristics of the species. Contribution No. 117 from the Research Institute of North Pacific Fisheries, Faculty of Fisheries, Hokkaido University     

Geotechnical characteristics of deep-sea sediments from the North Atlantic and North Pacific oceans

Geotechnical properties from a series of deep-sea sites in the North Atlantic and North Pacific oceans are examined to evaluate overall trends and to compare with similar fine-grained soils found on land. The study areas encompass a range of sedimentary environments dominated by combinations of turbidite and pelagic deposits. Carbonate content in excess of 20% is seen to result in a decrease in liquid limit and compressibility. Vertical profiles of geotechnical properties in the North Pacific show broader changes in down-core geotechnical properties compared to the North Atlantic and reflect the effects of long-term climatic changes and seafloor spreading. Sediments in the North Atlantic indicate significant differences depending on location, which is attributed to variability in turbidite deposition, water depth, distance from sediment sources, and the effects of bottom currents. Compared to equivalent fine-grained soils on land, deep-sea sediments are generally softer, more compressible and have higher friction angles at comparable Atterberg limits. Deeper and older sediments in the North Pacific are characterized by unusually large plastic limits, which are attributed to the presence of volcanic fractions. Empirical relationships for compression index and friction angle are discussed for sediments from both oceans.     

Variability and propagation of Labrador Sea Water in the southern subpolar North Atlantic

The variability of two modes of Labrador Sea Water (LSW) (upper and deep Labrador Sea Water) and their respective spreading in the interior North Atlantic Ocean are investigated by means of repeated ship surveys carried out along the zonal WOCE line A2/AR19 located at 43–48°N (1993–2007) and along the GOOS line at about 48–51°N (1997–2002). Hydrographic section data are complemented by temperature, salinity, and velocity time series recorded by two moorings. They have been deployed at the western flank of the Mid-Atlantic Ridge (MAR) in the Newfoundland Basin during 1996–2004. The analysis of hydrographic anomalies at various longitudes points to a gradual eastward propagation of LSW-related signals, which happens on time scales of 3–6 years from the formation region towards the MAR. Interactions of the North Atlantic Current (NAC) with the Deep Western Boundary Current (DWBC) close to Flemish Cap point to the NAC being the main distributor of the different types of LSW into the interior of the Newfoundland Basin. Comparisons between the ship data and the mooring records revealed that the mooring sites are located in a region affected by highly variable flow. The mooring time series demonstrate an elevated level of variability with eddy activity and variability associated with the NAC considerably influencing the LSW signals in this region. Hydrographic data taken from Argo profiles from the vicinity of the mooring sites turned out to mimic quite well the temporal evolution captured by the moorings. There is some indication of occasional southward flow in the LSW layer near the MAR. If this can be considered as a hint to an interior LSW-route, it is at least of minor importance in comparison to the DWBC. It acts as an important supplier for the interior North Atlantic, distributing older and recently formed LSW modes southward along the MAR.     

Long-term trend of oceanic surface carbon in the Northwest Pacific from 1958 to 2017

Contrasting decrease and increase trends of sea surface temperature（SST） have been documented in the western Subarctic（WSA） and the rest of the Northwest Pacific（NWP） from 1958 to 2017, respectively. Consequently, more（less） total carbon dioxide（TCO₂） due to ocean cooling（warming） is transported to the surface, which leads to increase（decrease） of oceanic surface partial pressure of carbon dioxide（pCO₂）. With the combined influence of the rising atmospheric carbon dioxide（C...     

Amino acids in suspended particulate matter from oceanic and coastal waters of the Pacific

The concentration of 15 amino acids in hydrolyzed particulate matter from different regions and depths of the Pacific Ocean has been measured by gas—liquid chromatography. The relative composition was similar for all samples in the euphotic zone, where the particulate amino acid (PAA) concentration ranged from 370 to 2260 nmoles/1 in coastal waters and from 90 to 260 nmoles/1 in the open ocean. Total PAA concentration dropped rapidly with depth, levelling off at 10–40 nmoles/1 below 200 m. Glycine, serine, glutamic acid and aspartic acid were the most abundant PAA in deep equatorial water and in deep off-shore California water. The nitrogen content of PAA could often account for 100% of the total particulate organic nitrogen present, while PAA carbon contributed up to 50% of the total particulate organic carbon in euphotic waters and down to 20% in deep waters. The protein equivalent to the total PAA content of particulate matter in near-surface waters amounted to 11–32 μg/1 at oceanic stations and up to 270 μg/1 at coastal stations.     

Clay minerals in the deep-sea cores from the North Pacific

Clay minerals in the <2 fraction of the four deep-sea cores collected from the northeast and central North Pacific are studied. In the surface layers of the cores, illite is more dominant in the pelagic samples than in the near-shore ones, and montmorillonite is vice versa. Chlorite in the near-shore sample is relatively abundant in the areas of higher latitude than in those of lower latitude. Kaolinite content is less than 10 percent in all samples. The presence of particles of amphibole in the clay-size was confirmed by X-ray analysis in the whole of the core-st. 18 taken from the northeastern portion of the area. This fact suggests that, for a long time probably since the Tertiary age, particles of amphibole have been supplied from source areas. In the three cores except the core-st. 18 it is shown that montmorillonite clearly increases downward. It is suggested that montmorillonite has been derived from volcanic glassy material by a diagenetic change. Montmorillonite in the bottom layer (400–405 cm) of the core-st. 9 is particularly rich in iron.     

Assessment of the influence of air invasions from the upper troposphere on the CO total column amount in the St. Petersburg region

The influence of air invasions from the upper troposphere on the CO total column amount is studied on the basis of spectroscopic measurements of the CO total column amount, backward trajectories of air-mass motions (the HYSPLIT model), and meteorological data. It is shown that the observed invasions of substratospheric and upper-troposphere air masses determine the minimum CO total column amount in late January-late March. The invasion of air masses from the upper troposphere can result in a decrease in the CO total column amount to 30% (of its mean values). Using January 31, 2000, as an example, we show the influence of the invasion of Arctic air masses from the upper troposphere on the CO total column amount in the St. Petersburg region: the results of measurements of the CO total column amount in the St. Petersburg region and at the Kiruna polar station (NDACC) are in agreement to within 1% if the vertical transport of air masses is taken into account. Thus, for a correct combined analysis of measurement data on the CO total column amount for different observation stations, it is necessary to use data on air-mass trajectories.     

Deep-water circulation in the North Pacific deduced from Si-O diagrams

A simple dissolved silica (Si) and dissolved oxygen (O) diagram method was applied to study the deep-water circulation in the North Pacific and the following results and conclusion have been obtained. In the abyssal water flowing northward in the western Pacific Si increases with a constant ratio of Si to decreasing O(Si/O=–0.30). The water is designated as the main sequence. In the eastern Pacific the Si-O diagram is characteristic of the location and reflects the degrees of mixing with older waters and of alteration due to decomposition of biogenic material. The Bay of Alaska is found to be a great source of silica in the North Pacific and its bottom water spreads out to the central North Pacific north of 40°N, called here the abyssal front. The younger abyssal water in the Aleutian Trench flowing to the eastern North Pacific north of 40°N comes through the north end of the Kuril-Kamchatka Trench instead of the gap in the Emperor Seamounts at about 46°N. The deep water is almost completely homogenized by active isopycnal mixing and advection when the deep water reaches its upper boundary by upwelling in the western North Pacific including the Bering Sea. Thus the high productivity in the Bering Sea is principally caused neither by the direct supply of abyssal water rich in nutrients nor by the extremely active vertical mixing reaching depths greater than 500 m, but it may be caused simply by the shallower upper boundary of the deep water mass in the Bering Sea, from which nutrients are easily transported to the surface.