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当x<0.5时,Nd2(Fe1-xMnx)14B可形成四方晶体结构,空间群为P42/mnm。在低温下,该赝三元化合物的大块铸态样品具有高矫顽力。此矫顽力不依赖于热处理等工艺过程,因此具有内禀性质。内禀矫顽力 iHc与样品的成分有关。Nd2(Fe1-xMnx)14B的起始磁化曲线具有传播场Hp,并且Hp的数值与 iHc接近。这表明内禀矫顽力是由畴壁钉扎造成的。研究了 iHc与温度的变化关系,并估算了钉扎位垒的强度。测量了Nd2(Fe1-xMnx)14B的居里温度和饱和磁化强度。在此赝三元化合物中,交换作用随Mn对Fe的替换而急剧降低。这使得畴壁厚度变窄。Nd2(Fe1-xMnx)14B的磁化和反磁化行为可用窄畴壁的特征来解释。
关键词: 相似文献
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在0.0001-2.4GPa流体静压力范围详细研究了非晶(Fe1-xCox)77.5Nd4B18.5(0≤x≤1.0)合金的电阻率与压力的关系,得到该非晶合金电阻率的压力系数随组分x变化的规律。结果表明:用少量的钴(x=0.2)替代铁,不会影响其硬磁性和热稳定性,同时却可减小电阻率的压力系数,从而增强电磁性能在压力下的稳定性。此外还观测到在0.51GPa保压3-24h的结构弛豫,进一步求出该非晶台金电阻率的压力弛豫时间对组分x的依赖关系。
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MAGNETIC PROPERTIES AND CRYSTALLIZATION OF THE RAPIDLY QUENCHED (Fe1-xNdx) 81.5B18.5 ALLOYS 下载免费PDF全文
Magnetic properties and crystallization behaviors of amorphous (Fe1-xNdx) 81.5B18.5 alloys were studied. The crystallization temperature is found to rise at first and then drop monotonically with x, having a maximum value of 976K at x=0.11 (9at% Nd). The (Fe1-xNdx) 81.5B18.5 alloys prepared at a quenching rate of vs = 6.6m /s are amorphous, and exhibit good glass formability. Both the coercive field Hc and energy product (BH)max depend strongly on Nd concentration. Amorphous (Fe1-xNdx) 81.5B18.5 alloys with higher Nd concentration have a high coercive field at low temperature, due to the large random uniaxial anisotropy of Nd. The room-temperature Hc and (BH)max obtained on optimal annealing con-ditions show two maxima as a function of Nd concentration x. The highest room-temperature coercive field Hc =22 kOe within the Nd concentrations around x=0.368 and the maximum energy product(RH)max= 13.3 MG·Oe at x =0.055 are observed. The hard magnetic properties of these crystallized samples are related to the presence of the bard magnetic Nd2Fe14B phase. 相似文献
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研究了(Fe1-xWx)84.5B15.5(x=0—0.1)非晶态合金的电阻率ρ与温度T(4.2—300K)的关系。实验结果表明,在所研究浓度区域内均出现电阻率与温度关系的极小值,电阻率极小值的温度Tmin在x=0.06时出现峰值。用x=0.02—0.1浓度区域内,当Tmin时,又出现了电阻率与温度关系的极大值,电阻率极大值的温度Tmax在26—35K之间。低温电阻率反常现象与类Kondo效应及局域磁矩之间RKKY相互作用有关。
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用单辊急冷法制备了非晶态(Fe1-xVx)84B16(x=0,0.02,0.04,0.06,0.10)合金的薄带,分别用磁天平和四端引线法测量了饱和磁化强度和高温电阻率的温度关系。得到平均每个磁性原子的磁矩随V含量的增加近似线性下降,计算出每个Fe原子和每个V原子的平均磁矩分别为2.08μB和-5.08μB。居里温度Tc从x=0时的622K下降到x=0.10时的478K。利用自旋波激发公式:σ(T)=σ(0)(1-BT*
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The magnetic properties of (Cox Fe1-x)A (Zn1-x Fe1+x)B O4 are studied using mean-field theory and the probability distribution law to obtain the saturation magnetization, the coercive field, the critical temperature, and the exchange interactions with different values of D (nm) and x. High-temperature series expansions (HTSEs) combined with the Pade approximant are used to calculate the critical temperature of (CoxFe1-x)A(Znl-xFe1+x)BO4, and the critical exponent associated with magnetic susceptibility is obtained. 相似文献
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The magnetic properties of Nd4.5Fe77−xMnxB18.5 (x=0, 1 and 2) nanocomposites prepared by the crystallization of amorphous precursors were investigated. Addition of Mn is found to decrease the crystallization temperature of the amorphous ribbons. The intrinsic coercivity iHc and maximum energy product (BH)max increase from 2.6 kOe and 9.1 MGOe for x=0 to 3.1 kOe and 10.3 MGOe for x=1, respectively, and the remanence ratio Mr/Ms increases from 0.70 to 0.72. The effect of Mn on Curie temperature TC and the thermal stability of Mr and iHc were also studied. 57Fe Mössbauer spectra have been recorded for x=0, 1 and 2 ribbons at room temperature and site preference of the Mn atoms in Fe3B and Nd2Fe14B phases is discussed using the Mössbauer spectroscopy. 相似文献
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The crystal structure and the superconductivity for samples Mg(B1-xCx)2 (0〈 x 〈0.09) prepared by a hybrid microwave synthesis have been investigated. The starting material B10C is also obtained by using the microwave method. The carbon can distribute uniformly in the Mg(B1-xCx)2 samples because boron and carbon are mixed on an atomic scale in the staring material B10C. The dependences of both lattice parameters and superconducting transition temperature Tc on carbon content accord with those reported in the literature. The upper critical field He2 at 20 K can be enhanced from about 4.3 T for x = 0 to 10 T for x = 0.05. The critical current density Jc of Mg(B0.95 C0.05)2 is 1.05×10^4 A/cm^2 at 20 K and 1 T. 相似文献
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采用熔体快淬的方法制备Pr2Fe14B/α-Fe纳米晶复合永磁材料.使用振动样品磁强计(VSM)测量样品的室温磁性能.实验合金成分为(PrxFe94.3-xB5.7)0.99Zr1(其中x=8.2,8.6,9.0,9.4,9.8,10.2,10.6,11.0,11.4(原子分数,%)).系统地研究了辊速及合金成分对快淬带磁性能的影响,当Pr原子分数由8.
关键词:
纳米复合永磁材料
熔体快淬
2Fe14B/α-Fe')" href="#">Pr2Fe14B/α-Fe
磁性 相似文献
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INTER-GRAIN EXCHANGE INTERACTION FOR SINGLE-PHASE NANOCRYSTALLINE Nd-Fe-B MAGNETS 总被引:1,自引:0,他引:1 下载免费PDF全文
The demagnetization curve as a function of intensity of the inter-grain exchange interaction was calculated for single-phase nanocrystalline Nd-Fe-B magnets by use of the finite-element technique of micromagnetics. Also, the strength of the exchange interaction was estimated as a function of the Nd content x for the nanocrystalline NdxFe94-xB6 magnets by comparing the above result with the experimental relation between iHc and x for the magnets. We found that the inter-grain exchange interaction decreases with the increase of x, are ≈70% and ≈60% of the inter-grain exchange interaction for x=15.5(μ0iHc≈2.0T) and x=19(μ0iHc≈2.3T), respectively. 相似文献
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X.K. Lv W. LiuW.J. Ren B. LiX.G. Zhao D. LiZ.D. Zhang 《Journal of magnetism and magnetic materials》2008
The C15 Laves phases with composition Nd1−xPrx(Fe0.35Co0.55B0.1)2 (0?x?1) have been synthesized by arc melting and subsequent annealing. The Curie temperature Tc and the saturation magnetizations Ms at 5 and 295 K decrease with increasing Pr content. The linear anisotropic magnetostriction λa=λ∥−λ⊥ at room temperature for Nd1−xPrx(Fe0.35Co0.55B0.1)2 alloys with 0?x?0.4 initially reaches a negative minimum, then increases and changes its sign with increasing magnetic field H, and the λa for the alloys with x?0.6 is positive and increases as magnetic field H increases. 相似文献
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Amorphous NdxFe81B19-x (0≤x≤19) alloys have been studied by57Fe Mössbauer spectroscopy. It is found that the average and peak hyperfine fields and the isomer shift decrease with increasing Nd content x. The magnetization for the samples containing Nd shows a strong tendency to lie in the direction perpendicular to the ribbon plane and its direction varies with Nd content. 相似文献
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通过X射线衍射和磁性测量等手段研究了(Nd1-xGdx)3Fe27.31Ti1.69(0≤x≤0.6)化合物的结构和磁性.X射线衍射测量结果表明Gd替代后并未改变Nd3(Fe,Ti)29化合物的晶体结构,但引起了晶胞体积收缩.随着Gd含量的增加,化合物的居里温度TC和室温磁晶各向异性场Ba单调增加,而自旋重取向
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1-xGdx)3Fe27.31Ti1.69化合物')" href="#">(Nd1-xGdx)3Fe27.31Ti1.69化合物
磁晶各向异性
自旋重取向
磁相图 相似文献
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Magnetic properties and magnetostriction of PrxNd1-xFe1.9 (0≤x≤1.0) alloys at low temperature 下载免费PDF全文
The crystal structure, magnetic and magnetostrictive properties of high-pressure synthesized PrxNd1-xFe1.9 (0≤x≤1.0) alloys were studied. The alloys exhibit single cubic Laves phase with MgCu2-type structure. The initial magnetization curve reveals that Pr0.2Nd0.8Fe1.9 has a minimum magnetocrystalline anisotropy at 5 K. The magnetostriction curve at 5 K shows that Pr0.2Nd0.8Fe1.9 has a very good low-field magnetostrictive property, and the magnetostriction of the PrxNd1-xFe1.9 alloy in high magnetic field is attributable mainly to Pr. The temperature dependence of the magnetostriction (λ||) at the field of 5 kOe shows that the substitution of Nd reduces the K1 remarkably, and the values of λ|| of Pr0.2Nd0.8Fe1.9 and Pr0.8Nd0.2Fe1.9 alloys are nearly five times larger than that of PrFe1.9 alloy below 50 K; the λ|| of Pr0.8Nd0.2Fe1.9 reaches up to 1082 ppm at 100 K, which makes it a potential candidate for application in this temperature range. 相似文献